共查询到20条相似文献,搜索用时 31 毫秒
1.
Edmund Elce Allan S. Hay 《Journal of polymer science. Part A, Polymer chemistry》1996,34(10):1897-1905
Two series of novel amorphous poly(aryl ether phthalazine)s have been prepared via an intramolecular ring closure reaction of poly(aryl ether ketone)s (PAEKs) with hydrazine monohydrate. Fluorinated PAEKs, which display solubility in solvents incorporating a ketone functionality such as acetone or ethyl acetate, were converted to poly(aryl ether phthalazine)s to observe if these polymers would display similar solubility characteristics. The poly(aryl ether phthalazine)s have glass transition temperatures in the range of 278–320°C and show 5% weight loss points greater than 500°C in air and nitrogen atmospheres. The fluorinated poly(aryl ether phthalazine)s were not soluble in ketonic solvents. A series of poly(aryl ether phthalazine)s incorporating pendant 2-naphthalenyl moieties has been prepared in an attempt to produce amorphous, thermally stable polymers with high glass transition temperatures. The polymers have glass transition temperatures in the range of 287–334°C and show 5% weight loss points greater than 500°C in air and nitrogen atmospheres. Poly(aryl ether phthalazine)s undergo an exothermic reaction above the glass transition temperature. The major product of this reaction is a rearrangement of the phthalazine moieties to quiazoline moieties, however some crosslinking of the polymers occurs. Cured samples of the poly(aryl ether phthalazine)s show a small increase in the polymer Tg and are insoluble in all solvents tested. © 1996 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 34:1897–1905, 1996 相似文献
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James V. Crivello Shengqian Kong 《Journal of polymer science. Part A, Polymer chemistry》1999,37(15):3017-3025
A series of aryl 1-propenyl ethers (ArPE) were prepared by the isomerization of the corresponding allyl aryl ethers (AArE) and used for photoinduced cationic polymerization studies. Attempted polymerization reactions using diaryliodonium salts as photoinitiators generally resulted in low yields of oligomers. Further studies revealed that these compounds have much lower reactivity in cationic vinyl polymerization as compared to their alkyl analogues. Moreover, side reactions resulting from chain transfer due to Friedel–Crafts alkylations take place and compete with vinyl polymerization. These side reactions are responsible for the low molecular weights observed in the cationic photopolymerization of aryl 1-propenyl ether monomers. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 3017–3025, 1999 相似文献
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Catalytic user-friendly approach to the syntheses of various functionalized aromatic phosphines from their corresponding substituted aryl triflates and triarylphosphines was accomplished. This method is carried out in neutral media and compatible with many functional groups including aldehyde, keto, ester, nitrile, ether and pyridyl groups. 相似文献
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Fernández-Rodríguez MA Shen Q Hartwig JF 《Chemistry (Weinheim an der Bergstrasse, Germany)》2006,12(30):7782-7796
The cross-coupling reaction of aryl chlorides with aliphatic and aromatic thiols catalyzed by palladium complexes of the strongly binding bisphosphine CyPF-tBu ligand (1) is reported. Most of the reactions catalyzed by complexes of ligand 1 occur with turnover numbers that exceed those of previous catalysts by two orders of magnitude. The reactions occur with excellent yields, broad scope and high tolerance of functional groups. Coupling of aryl halides with thiols in the presence of low loadings of catalysts derived from other Josiphos type ligands, as well as ligands of other structural types, are also described. 相似文献
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Sundermeier M Zapf A Mutyala S Baumann W Sans J Weiss S Beller M 《Chemistry (Weinheim an der Bergstrasse, Germany)》2003,9(8):1828-1836
The development of new palladium catalysts for the cyanation of various aryl and heteroaryl chlorides is described. The combination of amine co-catalysts with chelating phosphine ligands, for example, 1,4-bis(diphenylphosphino)butane (dppb) or 1,5-bis(diphenylphosphino)pentane (dpppe), allows an efficient cyanation of chloroarenes with simple potassium cyanide. General palladium-catalyzed cyanation of nonactivated and deactivated chloroarenes is possible for the first time. Studies of the oxidative addition of aryl halides to palladium triphenylphosphine complexes in the presence and absence of amines suggest that the co-catalyst is capable of preventing catalyst deactivation caused by the presence of excess cyanide ions in solution. 相似文献
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L. Roopesh Kumar Vishwanatha Thimmalapura Veladi Panduranga Mandipogula Mahesh P. Venkata Ramana 《合成通讯》2020,50(4):506-515
AbstractA simple and efficient method for the synthesis of aryl amides via oxidative copper-catalyzed coupling of commercially available aryl boronic acids and bench stable Nα-protected amino-acid azides is reported. The potential utility of this protocol is demonstrated through a survey of diversely substituted aryl boronic acids and several side-chain functionalized amino-acid azides, leading to the preparation of the desired amidated products in good to excellent yields. This amide synthesis is suitable for the preparation of amides (such as peptide aryl amides and sterically hindered amino acids) that are not or hardly accessible via classical approaches. 相似文献
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M. Lucas P. Brock J. L. Hedrick 《Journal of polymer science. Part A, Polymer chemistry》1993,31(9):2179-2185
A general method for the preparation of poly(aryl ether amide)s has been developed where the generation of an aryl ether linkage is the polymer-forming reaction. The amide linkage was found to be sufficiently electron-withdrawing to activate halo-substituents towards nucleophilic aromatic substitution analogous to conventional activating groups (i.e., sulfone, ketone, etc.). Model reactions demonstrated that the amide-activated displacement occurred with high selectivity in near quantitative yield and was judged suitable as a polymer-forming reaction. Appropriately fluoro-substituted amides were prepared and subjected to displacement polymerization with bisphenoxides in a N-methyl-2-pyrrolidone (NMP)/N-cyclohexyl-2-pyrrolidone (CHP) solvent mixture. High molecular weight polymers with glass transition temperatures in the 200–225°C range were obtained. © 1993 John Wiley & Sons, Inc. 相似文献
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《应用有机金属化学》2017,31(7)
This work describes a mild and efficient approach for the synthesis of aryl amides via catalytic aminocarbonylation of aryl halides with alicyclic amines using a Pd(Pt Bu3)2/NH4Cl catalyst system. Under mild reaction temperature of 60°C and balloon pressure of CO, 5 mol% Pd(Pt Bu3)2 with a cheap NH4Cl promoter is sufficient for high yields of aryl amides. The influence of reaction parameters such as reaction temperature, ligand type and promoter on catalytic activity was investigated. This work also discusses the catalytic intermediates in detail, and provides a plausible mechanism based on an acid chloride intermediate. 相似文献
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Kaizheng Zhu Scott T. Iacono Stephen M. Budy Jianyong Jin Dennis W. Smith Jr. 《Journal of polymer science. Part A, Polymer chemistry》2010,48(9):1887-1893
A diverse pool of aryl bistrifluorovinyl ether (BTFVE) compounds with reactive pendant groups were prepared in a facile, high yielding three step “one‐pot” synthesis from commercial 4‐bromo(trifluorovinyloxy)benzene. Monomers were confirmed from ATR–FTIR, 1H, 13C, and 19F NMR, and HRMS analysis. Aryl BTFVE compounds were thermally polymerized to afford perfluorocyclobutyl (PFCB) aryl ether polymers with high number–average molecular weight (Mn) for homopolymers (17,050–27,090) and copolymers with 4,4′‐bis(trifluorovinyloxy)biphenyl monomers (27,860–56,500). The PFCB aryl ether homo‐ and copolymers collectively possess high thermal stability (>299 °C in N2) and are readily solution processable producing optically transparent films. The thermal polymerization was achieved and reactive moieties remained intact, aside from those functionalized with acrylates. In the case with acrylate functionalized polymers, orthogonal polymerization was achieved by first photopolymerizing the acrylates followed by thermal curing of the aryl trifluorovinyl ether endgroups. Preliminary results in this study produced the successful preparation of photodefinable PFCB aryl ether material. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 1887–1893, 2010 相似文献
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《中国化学》2017,35(11):1661-1664
((2S ,4R )‐4‐Hydroxy‐N ‐(2‐methylnaphthalen‐1‐yl)pyrrolidine‐2‐carboxamide (HMNPC), an amide derived from 4‐hydroxy‐L ‐proline and 2‐methyl naphthalen‐1‐amine, is a powerful ligand for Cu‐catalyzed coupling of (hetero)aryl halides with sulfinic acid salts, allowing for first time the metal‐catalyzed coupling of (hetero)aryl chlorides and NaSO2Me. A considerable number of (hetero)aryl chlorides worked well, providing the pharmaceutically important (hetero)aryl methylsulfones in good to excellent yields. 相似文献
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Irina P Beletskaya Alexander S SigeevAlexander S Peregudov Pavel V Petrovskii 《Tetrahedron letters》2003,44(37):7039-7041
A new protocol to prepare unsymmetrical diarylselenides using the reaction of aryl bromides and iodides with easily available Bu3SnSeAr catalyzed by Cu(I) complexes under rather mild conditions and with a very high yield is described. 相似文献
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Yoshiaki Nakao 《Journal of organometallic chemistry》2003,687(2):570-573
Triallyl(aryl)silanes, stable and easily accessible arylsilanes, were found to react with aryl bromides in the presence of a palladium catalyst (PdCl2-PCy3) and tetrabutylammonium fluoride (TBAF) in good yields. The scope of the reaction is broad, and a wide variety of functional groups are tolerant. Allyl groups on Si are readily cleaved upon treatment with TBAF to form fluorosilanes, silanepolyols, siloxanes and/or their mixed forms, which might be responsible for high efficiency of the reaction. 相似文献
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Three families of ligands were prepared for use in Pd-catalyzed aryl aminations and possibly other Pd-catalyzed reactions. The first series is derived from diarylsulfones, the second from trityl imidazole, and the third from 2-bromobenzophenone. While these ligands were not very general in terms of substrate scope, they do work fairly well under certain specific conditions. Additionally, the preparation of these ligands is amenable to bulk synthesis. 相似文献
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The electroreduction of aryl halides (bromides or chlorides) allows the coupling reaction with vinylic acetates, in the presence of 2,2-bipyridine and catalytic amounts of cobalt bromide, leading to styrene derivatives in good yields. 相似文献
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Hong-Tao Zhang Li-Jun Gu Xiang-Zhong Huang Rui Wang Cheng Jin Gan-Peng Li 《中国化学快报》2016,27(2):256-260
A visible-light-catalyzed synthesis of indol-3-yl aryl ketones from aryldiazonium salts, CO and indoles at room temperature was developed. This process provides a useful method for the preparation of diverse indol-3-yl aryl ketones from readily accessible reactants under base-free, acid-free and transition-metalfree conditions. 相似文献
18.
含酚酞结构的聚芳醚酮环状齐聚物的激光质谱表征 总被引:6,自引:0,他引:6
在“拟高稀”条件下,以酚酞与甲基酚酞为双羟基型单体,与活性双氟基芳香化合物合成了聚芳醚酮环状齐聚物。通过基质辅助激光解吸电离飞行时间质谱对其环状结构进行了表征。 相似文献
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4-Chloro-2,5-bis(4-fluorophenyl)oxazole monomer has successfully been synthesized using cyclization reaction of 4-fluorobenzoyl cyanide with 4-fluorobenzaldehyde. This monomer was converted to poly(aryl ether)s by nucleophilic substitution of the fluorine atoms on the benzene rings of oxazole monomer with bisphenol A. The influence of the reaction time on the molecular weight had been investigated. The polymers were identified by FT-IR,1H-NMR and TGA. The products exhibited weight-average molar masses up to 2.81 x 104g mol−1 in GPC. These poly(aryl ether)s showed very high thermal stability up to 363 °C for 5 % weight loss in TGA under N2. 相似文献