Conducting polymers as driving electrodes for Polymer-Dispersed Liquid-Crystals display devices: On the electro-optical efficiency

Intrinsically conducting polymer (ICP) thin films are used as driving electrodes for Polymer-Dispersed Liquid-Crystals (PDLC) display devices. In order to investigate the electro-optical efficiency of these organic electrodes, three different kinds of conducting polymers, i.e. polyaniline doped with 10-camphorsulfonic acid (PANI(HCSA)), polypyrrole doped with dodecylbenzenesulfonic acid (PPY(DBSA)), and polyethylenedioxythiophene doped with polystyrenesulfonate (PEDOT(PSS)), were prepared or purchased, and coated either on glass or plastic substrates. Optical absorption studies in the UV-Vis range of the conducting polymer-coated substrates were first performed showing the presence of conducting species for the three types of polymers. The electrical characteristics of the resulting films were measured with the four-probes technique. PANI(HCSA) exhibits a higher conductivity ( ) compared to PPY(DBSA) ( ), and PEDOT(PSS) ( ). It is also shown that for a given conducting polymer, its electrical conductivity decreases when a plastic substrate is used. These observations have been related to significant morphological changes observed by scanning electron microscopy (SEM). A mixture of Norland Optical Adhesive 65 and nematic liquid-crystal E7 in the weight ratio (35:65) was used as precursor of the PDLC material. Better electro-optical responses (transmission properties, drive voltages and switching times) of PDLC films were obtained for devices prepared with (PPY(DBSA))-based electrodes. The electro-optical performances of the PDLC display devices also depend on the nature of the ICP substrate used.Received: 25 September 2002, Published online: 29 July 2003PACS: 73.61.Ph Polymers; organic compounds - 42.79.Kr Display devices, liquid-crystal devices - 82.35.Cd Conducting polymers - 42.70.Df Liquid crystals F. Roussel: rfred@purple.univ-littoral.fr     

Monte Carlo simulation of particle aggregation and gelation: II. Pair correlation function and structure factor

Diffusion-limited cluster aggregation and gelation are studied using lattice and off-lattice Monte Carlo simulations. The pair correlation function g(r) and the structure factor S(q) of the particle gels were investigated as a function of the volume fraction ( ) and time. At volume fractions below , the gel structure is fractal on small length scales with . g(r) shows a weak minimum at the correlation length ( ), before reaching the average concentration at large length scales. The cut-off function of g(r) varies during the aggregation process, but at a given , where is the gel time, it is a universal function of . At high volume fractions, the structure is dominated by excluded-volume interactions, while at low volume fractions, it is determined by the connectivity.Received: 27 April 2004, Published online: 26 October 2004PACS: 64.60.Ak Renormalization-group, fractal, and percolation studies of phase transitions - 02.70.Uu Applications of Monte Carlo methods     

Exact effective force between star-polymers in a $\Theta$-solvent

We re-examine here the computation of the effective force between two star-polymers of respective numbers of branches f₁ and f₂, immersed in a common -solvent. Such a force originates essentially from the repulsive three-body interactions. To achieve this, we take advantage of some established results using renormalization theory for three-dimensional star-polymers, or conformal invariance for two-dimensional ones. We first show that, in dimension d = 3, the force, , decreases with the center-to-center distance r as , with the exact universal amplitude . Second, in dimension d = 2, we find that the force decays more slowly as , with the exact universal amplitude . For high distances compared to the gyration radius, , of a single polymer chain at the -point, an exponential decay of the force is expected.Received: 3 February 2004, Published online: 24 May 2004PACS: 61.25.Hq Macromolecular and polymer solutions; polymer melts; swelling - 05.20.-y Classical statistical mechanics     

Miscible displacement of non-Newtonian fluids in a vertical tube

The influence of rheology on the miscible displacement of a viscous fluid by a less viscous, Newtonian one in a vertical tube is studied experimentally as a function of the flow velocity. For Newtonian displaced fluids the transient residual film thickness is nearly of the tube radius at large viscosity ratios between the two fluids in agreement with experimental and numerical results from the literature. For shear-thinning fluids with a zero yield stress (mostly xanthan-water solutions), decreases down to of the radius for the most concentrated solutions. For fluids with a non-zero yield stess, further decreases down to 24-25% of the radius. The orders of magnitude of these values can be obtained through numerical simulations (commercial code) for the various types of fluids. Instabilities of the film at its boundary develop downstream and lead to a reduction of the final thickness of the film at longer times: this reduction is larger for lower viscosity ratios and larger velocities.Received: 15 February 2003, Published online: 8 July 2003PACS: 47.20.Gv Hydrodynamic stability: Viscous instability - 83.60.Wc Rheology: Flow instabilities     

Blobs,channels and “cigars”: Morphologies of liquids at a step

We have studied the equilibria of liquid droplets wetting a step edge with an opening angle by a combination of analytical and numerical methods. Depending on the wetting properties of the substrate walls and on the liquid volume, different locally or globally stable liquid morphologies are found. Complete spreading of the liquid along the bottom edge of the step is observed at equilibrium contact angles satisfying . If the contact angle exceeds a threshold value the liquid exists in a blob-like configuration. Surprisingly, we find an intermediate regime at a sufficiently high liquid volume and in a range of contact angles , in which cigar-shaped configurations arise in addition to the blob. We close the paper by a detailed discussion of the stability of this novel liquid morphology.PACS: 47.55.Dz Drops and bubbles - 61.30.Hn Surface phenomena: alignment, anchoring, anchoring transitions, surface-induced layering, surface-induced ordering, wetting, prewetting transitions, and wetting transitions - 68.08.Bc Wetting     

The effect of thermal fluctuations on Schulman area elasticity

We study the elastic properties of a two-dimensional fluctuating surface whose area density is allowed to deviate from its optimal (Schulman) value. The behavior of such a surface is determined by an interplay between the area-dependent elastic energy, the curvature elasticity, and the entropy. We identify three different elastic regimes depending on the ratio between the projected (frame) and the saturated areas. We show that thermal fluctuations modify the elastic energy of stretched surfaces ( ), and dominate the elastic energy of compressed surfaces ( ). When the elastic energy is not much affected by the fluctuations; the frame area at which the surface tension vanishes becomes smaller than and the area elasticity modulus increases.Received: 14 July 2002, Published online: 19 August 2003PACS: 87.16.Dg Membranes, bilayers, and vesicles - 68.03.Cd Surface tension and related phenomena - 05.70.Np Interface and surface thermodynamicsP. Pincus: Also at Physics and Materials Departments and Program in Biomolecular Science and Engineering, UCSB.     

Irreversible adsorption from dilute polymer solutions

We study irreversible polymer adsorption from dilute solutions theoretically. Universal features of the resultant non-equilibrium layers are predicted. Two broad cases are considered, distinguished by the magnitude of the local monomer-surface sticking rate Q: chemisorption (very small Q) and physisorption (large Q). Early stages of layer formation entail single-chain adsorption. While single-chain physisorption times are typically micro- to milli-seconds, for chemisorbing chains of N units we find experimentally accessible times , ranging from seconds to hours. We establish 3 chemisorption universality classes, determined by a critical contact exponent: zipping, accelerated zipping and homogeneous collapse. For dilute solutions, the mechanism is accelerated zipping: zipping propagates outwards from the first attachment, accelerated by occasional formation of large loops which nucleate further zipping. This leads to a transient distribution of loop lengths s up to a maximum size after time t. By times of order the entire chain is adsorbed. The outcome of the single-chain adsorption episode is a monolayer of fully collapsed chains. Having only a few vacant sites to adsorb onto, late-arriving chains form a diffuse outer layer. In a simple picture we find for both chemisorption and physisorption a final loop distribution and density profile whose forms are the same as for equilibrium layers. In contrast to equilibrium layers, however, the statistical properties of a given chain depend on its adsorption time; the outer layer contains many classes of chain, each characterized by a different fraction of adsorbed monomers f. Consistent with strong physisorption experiments, we find the f values follow a distribution .Received: 13 January 2003, Published online: 8 July 2003PACS: 82.35.-x Polymers: properties; reactions; polymerization - 05.40.-a Fluctuation phenomena, random processes, noise, and Brownian motion - 68.08.-p Liquid-solid interfaces     

Boltzmann-Uehling-Uhlenbech calculation of total reaction cross-section and fragmentation cross-section

, and have been calculated via the BUU model with soft EOS and 0.8 times of . The density distribution without any adjustable parameters which comes from the RMF model has been introduced into the BUU calculation to replace the normally used one-parameter square-type distribution. The calculated results can reproduce the experimental data well for both halo- and stable-nuclei-induced reactions. Here or is calculated as the difference between of halo nucleus and core nucleus, by assuming . It indicates that this assumption works very well at high energy in the BUU calculation. More experimental measurements are necessary to test the validity of this assumption at intermediate energy.Received: 12 June 2003, Revised: 29 September 2003, Published online: 27 April 2004PACS: 24.10.-i Nuclear reaction models and methods - 25.60.Dz Interaction and reaction cross-sections - 25.60.Gc Breakup and momentum distributions - 27.20. + n      

Can the glass transition in bulk polymers be modeled by percolation picture?

Recent observations (Eur. Phys. J. E 9, 135 (2002)) showed that the vitrification process, which sets in during the linear bulk methyl methacrylate (MMA) polymerization carried out below glass transition temperatures, can be modelled by static percolation picture. To generalize this observation for different kind of bulk linear or crosslinked polymers not enough data are present in the literature. To cover partly this deficit we studied the glass transition of MMA and styrene (Sty) crosslinking copolymerization in varying ratios of MMA and Sty. Both the fluorescence intensity I and the lifetime of pyrene (Py) used as a nanosecond in situ fluoroprobe were monitored during the gelation time. Both I and increase dramatically as a result of the reduced mobility of the probes trapped in the glassy regions, appearing near the glass transition point. The average size of the glassy regions just below, and the strength of the infinite network formed upon the connection of the glassy regions above the glass transition point obey power law relations. The data around were interpreted on the basis of the percolation theory and we observed that the corresponding exponents and give static percolation values independent of the polymer composition.Received: 9 July 2004, Published online: 1 October 2004PACS: 64.60.Ak Renormalization-group, fractal, and percolation studies of phase transitions - 64.70.Pf Glass transitions - 82.35.Jk Copolymers, phase transitions, structure     

A precise measurement of the tau lifetime

The tau lepton lifetime has been measured with the events collected by the DELPHI detector at LEP in the years 1991-1995. Three different methods have been exploited, using both one-prong and three-prong decay channels. Two measurements have been made using events in which both taus decay to a single charged particle. Combining these measurements gave . A third measurement using taus which decayed to three charged particles yielded These were combined with previous DELPHI results to measure the tau lifetime, using the full LEP1 data sample, to be .Received: 12 November 2003, Revised: 1 June 2004, Published online: 20 July 2004     

Jet production in charged current deep inelastic <Emphasis Type="Italic">e</Emphasis><Superscript> + </Superscript><Emphasis Type="Italic">p</Emphasis> scatteringat HERA

The production rates and substructure of jets have been studied in charged current deep inelastic e ⁺ p scattering for Q ² > 200 GeV² with the ZEUS detector at HERA using an integrated luminosity of 110.5 pb^-1. Inclusive jet cross sections are presented for jets with transverse energies GeV and pseudorapidities in the range . Dijet cross sections are presented for events with a jet having GeV and a second jet having GeV. Measurements of the mean subjet multiplicity, , of the inclusive jet sample are presented. Predictions based on parton-shower Monte Carlo models and next-to-leading-order QCD calculations are compared to the measurements. The value of , determined from at for jets with GeV, is . The mean subjet multiplicity as a function of Q ² is found to be consistent with that measured in NC DIS.Received: 5 June 2003, Published online: 10 October 2003     

Search for anomalous weak dipole moments of the $\tau$ lepton

The anomalous weak dipole moments of the lepton are measured in a data sample collected by ALEPH from 1990 to 1995 corresponding to an integrated luminosity of 155 pb^-1. Tau leptons produced in the reaction at energies close to the mass are studied using their semileptonic decays to , , or . The real and imaginary components of both the anomalous weak magnetic dipole moment and the CP-violating anomalous weak electric dipole moment, , , and , are measured simultaneously by means of a likelihood fit built from the full differential cross section. No evidence of new physics is found. The following bounds are obtained (95% CL): , , , and .Received: 25 September 2002, Published online: 29 August 2003     

Dynamics of living polymers

We study theoretically the dynamics of living polymers which can add and subtract monomer units at their live chain ends. The classic example is ionic living polymerization. In equilibrium, a delicate balance is maintained in which each initiated chain has a very small negative average growth rate (velocity) just sufficient to negate the effect of growth rate fluctuations. This leads to an exponential molecular weight distribution (MWD) with mean . After a small perturbation of relative amplitude , e.g. a small temperature jump, this balance is destroyed: the velocity acquires a boost greatly exceeding its tiny equilibrium value. For the response has 3 stages: (1) Coherent chain growth or shrinkage, leaving a highly non-linear hole or peak in the MWD at small chain lengths. During this episode, lasting time , the MWDs first moment and monomer concentration m relax very close to equilibrium. (2) Hole-filling (or peak decay) after . The absence or surfeit of small chains is erased. (3) Global MWD shape relaxation after . By this time second and higher MWD moments have relaxed. During episodes (2) and (3) the fast variables ( ) are enslaved to the slowly varying number of free initiators (chains of zero length). Thus fast variables are quasi-statically fine-tuned to equilibrium. The outstanding feature of these dynamics is their ultrasensitivity: despite the perturbations linearity, the response is non-linear until the late episode (3). For very small perturbations, , response remains non-linear but with a less dramatic peak or hole during episode (1). Our predictions are in agreement with viscosity measurements on the most widely studied system, -methylstyrene.Received: 23 September 2003PACS: 82.35.-x Polymers: properties; reactions; polymerization - 05.40.-a Fluctuation phenomena, random processes, noise, and Brownian Motion - 87.15.Rn Biomolecules: structure and physical properties; Reactions and kinetics; polymerization     

New experimental limits on violations of the Pauli exclusion principle obtained with the Borexino Counting Test Facility

The Pauli exclusion principle (PEP) has been tested for nucleons (n,p) in and nuclei, using the results of background measurements with the prototype of the Borexino detector, the Counting Test Facility (CTF). The approach consisted of a search for , n, p and/or s emitted in a non-Paulian transition of 1P- shell nucleons to the filled 1S _1/2 shell in nuclei. Similarly, the Pauli-forbidden decay processes were searched for. Due to the extremely low background and the large mass (4.2 tons) of the CTF detector, the following most stringent up-to-date experimental bounds on PEP violating transitions of nucleons have been established: , , , , and , all at C.L.Received: 18 June 2004, Published online: 1 October 2004PACS: 11.30.-j, 24.80. + y, 23.20.-g, 27.20. + nG. Bellini: SpokesmanL. Cadonati: Now at Massachusetts Institute of Technology, NW17-161, 175 Albany St. Cambridge, MA 02139O. Dadoun: Marie Curie fellowship at LNGS Correspondence to: A. Derbin. On leave of absence from St. Petersburg Nuclear Physics Inst. - Gatchina, RussiaM. Deutsch: DeceasedR. Ford: No w at Sudbury Neutrino Observatory, INCO Creighton Mine, P.O.Box 159 Lively, Ontario, Canada, P3Y 1M3B. Freudiger: Marie Curie fellowship at LNGS. Now at Institute for Nuclear Physics, Forschungszentrum Karlsruhe, Postfach 3640, 76021 KarlsruheS. Gazzana: GLIMOSV.V. Kobychev: Now at Institute for Nuclear Research, Prospekt Nauki 47, MSP 03680, Kiev, UkraineG. Korga: On leave of absence from KFKI-RMKI, Konkoly Thege ut 29-33 H-1121 Budapest, HungaryC. Lendvai: Marie Curie fellowship at LNGSP. Lombardi: Detector installation managerA. Martemianov: DeceasedV. Muratova: On leave of absence from St. Petersburg Nuclear Physics Inst. - Gatchina, RussiaL. Niedermeier: Marie Curie fellowship at LNGSL. Papp: On leave of absence from KFKI-RMKI, Konkoly Thege ut 29-33 H-1121 Budapest, HungaryR.S. Raghavan: Present Address: Department of Physics, Virginia Polytechnic Institute and State University, Blacksburg VA 24061G. Ranucci: Project managerC. Salvo: Operational manager Correspondence to: O. SmirnovA. Sonnenschein: Center for Cosmological Physics, University of Chicago, 933 E.56^th St., Chicago, IL 60637     

Measurement of isolated prompt photon production in photon-photon collisions at $\sqrt{s_{\rm ee}} = 183$-209 GeV

For the first time at LEP the production of prompt photons is studied in the collisions of quasi-real photons using the OPAL data taken at centre-of-mass energies between 183 GeV and 209 GeV. The total inclusive production cross-section for isolated prompt photons in the kinematic range of transverse momentum GeV and pseudorapidity is determined to be . Differential cross-sections are compared to the predictions of a next-to-leading-order (NLO) calculation.Received: 6 May 2003, Published online: 4 November 2003     

Surface and bulk interchange energy in binary mixtures of chain molecules

The interchange (interaction) parameter, controlling the phase behaviour of a binary mixture, is determined for the bulk and the surface of binary mixtures of different types of chain molecules, using surface tensiometry and a mean-field theory. For all mixtures and concentrations studied an identical behaviour is observed at the surface, depending only on the square of the reduced chain length mismatch , where and are the difference in and average of the number of carbons of the two components.Received: 21 December 2003, Published online: 25 March 2004PACS: 61.30.Hn Surface phenomena: alignment, anchoring, anchoring transitions, surface-induced layering, surface-induced ordering, wetting, prewetting transitions, and wetting transitions - 68.35.Md Surface thermodynamics, surface energies - 68.03.Cd Surface tension and related phenomena     

An analysis of the time-dependent CP asymmetryin $B \to \pi \pi$ decays in the standard model

Measurements of the time-dependent CP-asymmetry in the decay and its charge conjugate by the BELLE and BABAR collaborations currently yield and , characterizing the direct and mixing-induced CP-asymmetries, respectively. We study the implication of these measurements on the CKM phenomenology taking into account the available information in the quark mixing sector. Our analysis leads to the results that the ratio |P _c /T _c | involving the QCD-penguin and tree amplitudes and the related strong phase difference in the decays are quite substantial. Using the isospin symmetry to constrain |P _c /T _c | and , where parameterizes the penguin-induced contribution, we present a fit of the current data including the measurements of and . Our best-fits yield , , , , and . At 68% C.L., the ranges are , , , and . Currently en vogue dynamical approaches to estimate the hadronic matrix elements in decays do not provide a good fit of the current data.Received: 5 April 2004, Published online: 14 July 2004A.Ya. Parkhomenko: On leave of absence from Department of Theoretical Physics, Yaroslavl State University, Sovietskaya 14, 150000 Yaroslavl, Russia.     

Deformation of adhering elastic tubes

Deformation of an elastic tube adhering onto a substrate due to van der Waals attractive force is investigated by means of numerical minimization and scaling theory. The onset of the deformation is determined by the critical value of , where is the bending constant, is the depth of the van der Waals potential, and N is the size of the tube. For a significantly deformed tube, we found a scaling behavior of the bending energy, which is explained within the shell theory.Received: 11 September 2003, Published online: 2 March 2004PACS: 68.35.-p Solid surfaces and solid-solid interfaces: Structure and energetics - 68.55.-a Thin film structure and morphology - 81.07.De Nanotubes     

Lifetime vibrational interference during the NO 1s-1π* resonant excitation studied by the NO+(A 1Π → X 1Σ+) fluorescence

Dispersed fluorescence from fragments formed after the de-excitation of the 1s^-1π^* resonances of N^*O and NO^* has been measured in the spectral range of 118–142 nm. This range is dominated by lines of atomic nitrogen and oxygen fragments and by the bands in the NO⁺ ion which result from the participator Auger decay of the 1s^-1π^* resonances. Ab-initio calculations of the transition probabilities between vibrational levels during the reaction NO N^*O ⇒ NO were used to explain the observed intensity dependence for the fluorescence bands on the exciting-photon energy across the resonances and on both v^′ and v^′′ vibrational quantum numbers. The multiplet structure of the 1s^-1π^* resonance and lifetime vibrational interference explain the observed exciting-photon energy dependence of the fluorescence intensity. A strong spin-orbit coupling between singlet and triplet states of NO⁺ is proposed to reduce additional cascade population of the state via radiative transitions from the and states and to explain remaining differences between measured and calculated integral fluorescence intensities.