Mechanism of Bi2Sr2CaCu2Ox crystallization and superconducting properties for Bi2Sr2CaCu2Ox/Ag tapes prepared using isothermal partial melting method

The mechanism of Bi₂Sr₂CaCu₂O_x (Bi-2212) crystallization from a partially molten state has been studied by means of thermal analysis, X-ray diffraction (XRD) measurement, and microstructural observation in Bi-2212/Ag tapes. Tapes have been prepared using the isothermal partial melting (IPM) method, under which partial melting and solidification are carried out at the same temperature in an nitrogen atmosphere and 20% oxygen partial pressure (p(O₂)), respectively. The Bi-2212 phase crystallizes by peritectic reaction between (Sr, Ca)CuO₂ (1:1 phase) and the liquid phase at processing temperatures (T_p)≥855°C. At the beginning of Bi-2212 crystallization, only the 1:1 and the liquid phases are present in tapes. The Bi-2212 nucleation occurs in the vicinity of 1:1 grains (homogeneous nucleation). This peritectic reaction progresses by recovery of oxygen in the liquid phase. In contrast, the nucleation of the Bi-2212 phase occurs heterogeneously at T_p≤850°C. The Bi-2212 phase co-exists with four Bi-free phases ((Sr, Ca)₁₄Cu₂₄O₄₁ (14:24 phase), (Sr, Ca)₂CuO₃ (2:1 phase), (Sr, Ca)O (1:0 phase), and the 1:1 phase) and the liquid phase in the early stage of the Bi-2212 crystallization step. Since the precipitation temperature of the Bi-2212 phase is higher than 850°C, the Bi-2212 crystallization progresses by direct precipitation. The crystallization paths affect microstructure and transport critical current density (J_c) of Bi-2212 tapes.     

Effect of Ba substitution for Sr in Bi2Sr2CaCu2O y superconducting films prepared by rf-sputtering method

In order to investigate the effect of the distance between the CuO₂ layer and the SrO layer, d _Cu-Sr, on the superconductivity in the Bi₂Sr₂CaCu₂O _y system, we have substituted Ba for Sr. Bi-(Sr, Ba)-Ca-Cu-O superconducting thin films were prepared by the rf-magnetron sputtering method. Rietveld analysis was employed to estimate d _Cu-Sr. Samples with various d _Cu-Sr were obtained by changing the post-annealing temperature as well as the Ba concentration. T_c was found to increase with increasing d _Cu-Sr.     

Spin correlations in amorphous Bi2Sr2CaCu2Ox

Zero and longitudinal field SR has been used to probe the magnetic state of amorphous Bi₂Sr₂CaCu₂O_x prepared by rapid quenching from the melt. The results suggest quasi-static spin correlations between extremely dilute Cu²⁺ ions.Work performed while at the J J Thomson Physical Laboratory, University of Reading.     

Visualization of magnetic flux penetration and trapping in superconducting Bi2Sr2CaCu2Ox single crystals

Magnetic flux profiles in superconducting Bi₂Sr₂CaCu₂O_x single crystals have been observed using a magnetic garnet film as a magnetic field sensor. Measurements have been performed for the “zero-field-cooled” and “field-cooled” regimes as a function of temperature and magnetic field. An analysis of the observed patterns has revealed some peculiarities in the flux trapping effects. In particular, a nonuniform magnetic structure has been directly observed in the remanent state after “field-cooled” processes.     

Growth of Bi2Sr2Cu1Ox films by laser ablation

The formation and the properties of thin BiSrCuO films grown on MgO single crystal substrates by the pulsed laser ablation of a Bi₂Sr₂Cu₁O₆ target have been studied. The precise influence of the oxygen pressure and substrate temperature on the atomic composition, nature and structure of the grown phases, crystalline quality and superconductivity of the films has been analyzed. In the 600–750°C temperature range and 0.05–0.5 mbar oxygen pressure range, highly textured films of the 2201 phase (Bi₂Sr₂Cu₁O₆ phase) were formed despite large composition deviations (Bi enrichment and Sr depletion) with respect to the ideal composition. A high crystalline quality was evidenced for films grown at low and intermediate pressure and high temperature. χ_min values in the films deduced from channeling experiments were similar to the case of single crystal material. Despite this high crystalline quality, incomplete or very low T_c superconducting transitions were observed in the resistivity measurements.     

Dynamic mixed state in micron-size bridges based on Bi2Sr2CaCu2Ox whiskers

Measurements of the current-voltage characteristics of micron-size bridges made of Bi₂Sr₂CaCu₂O_x single-crystal whiskers are carried out. It is found that, at temperatures below the superconducting transition temperature, the current-voltage characteristics exhibit quasi-periodic voltage jumps with segments of constant differential resistance whose value is proportional to the jump number. For the narrowest bridges (0.5–1 ¼m), up to ten voltage jumps are observed. The result of the experiment is explained by the formation of vortex lines under the current effect.