超声波抗垢强化传热技术的研究进展

换热设备的污垢一直是普遍存在且难以解决的问题。在对国内外超声波抗垢强化传热技术的研究进行简要描述与总结的基础上，本文认为超声波抗垢强化传热是一种先进的节能环保技术，具有非常广阔的应用前景，并指出了存在的问题与研究方向。其中声学参数的选择以及因地制宜的应用方法是该技术的关键，有必要进一步结合丰富的实验进行深入的理论分析与研究。     

超声波强化超滤过程

本文综述了超声波强化超滤的实验方法，超声波对越滤膜结构的影响及超声波强化清洗超滤膜等方面的研究进展，论述了超声波强化超滤的作用机理，声冲流和空化作用在超声波强化超滤中起到主要作用。     

松香脂液的超声波清洗

本文介绍在松香加工工艺中，应用超声地脂液进行处理，使时脂液和悬浮在脂液中的细微杂质粒子得以充分洗涤和更快分离，从而达到提高松香质量的目的。     

超声波显像管振动清洗机的研制

本文介绍一种无需任何清洗液且有别于常规超声波清洗机理的超声波显像管振动清洗机。从理论上分析说明超声波干振动清洗的机理和方法，阐明各超声参量的选取标准和超声振动系统中应注意的问题。     

超声波清洗设备的目前发展方向

超声波清洗设备的发展方向目前有二个：一个是从单缸机到多缸机或自动化的超声清洗生产线;另一个是,从低频超声清洗机到高频超声清洗机。     

超声波对多聚糖结构特性的影响

本文以灵芝为主要对象研究了多糖结构和微晶束结构及其稳定性和抗解性，通过对加超声能量场，对结晶结构施加强烈的机构冲击，使稳定性和抗解性消弱。     

光学零件超声波清洗的应用现状及其发展

本文在概述超声波清洗机理之后，着重介绍了光学零件超声波清洗的应用现状及光学零件超声波清洗用的清洗剂、脱水剂、干化剂等清洗辅料的几个进展阶段，以及当前清洗辅料的研究动态及面临课题。     

氨水降膜吸收传热传质强化的研究进展

综述了近年来应用于氨水降膜吸收性能强化的研究成果,总结了氨水降膜吸收的强化方法,分析了氨水降膜吸收过程中的影响因素,指出研究中的一些不足,并对该领域未来的研究方向进行了讨论,指出采用物理处理、化学处理和纳米技术三种强化手段相结合的方法是未来强化吸收可能的发展趋势。     

纳米流体应用于强化传热的研究进展及面临的挑战

纳米流体是近年来新兴的一种强化传热工质,其在强化传热领域有着广阔的应用前景,然而目前对纳米流体强化传热应用的研究还存在一些障碍。本文从纳米流体的制备和传热特性方面总结了近几年的研究进展,并提出了研究过程中需要克服的几个问题,以促进今后进一步的研究工作。     

强化管型对超声波除垢影响的实验研究

结垢问题长久存在于电力、化工、石油等领域,将超声波应用在除垢上具有十分显著的优势。为研究不同管道内结垢和超声波除垢情况,本文采用实验方法,针对三种不同形状(圆管、波纹管和横纹管)管道进行结垢和超声波除垢研究。结果表明,波纹管内结垢量较其它两根管较少,而横纹管的超声波除垢效率最高。由此,可为工程实际中特殊管道的除垢及传统圆管可否进行管型改进提供一定的理论依据。     

Investigations in ultrasound-assisted anticoagulant production by marine Bacillus subtilis ZHX

Anticoagulants are the main drugs for the prevention and treatment of thromboembolism. However, most of the present anticoagulants have shortcomings and novel anticoagulants are in great demand. Marine microorganisms are an important source of new drugs. Therefore, in this study, ultrasound was applied to enhance anticoagulant accumulation by marine Bacillus subtilis ZHX. Ultrasound parameters were optimized by single-factor experiments exploring the effects of ultrasound power, duration, duty cycle and the cell growth phases. The optimum conditions were exponential prophase (5 h) with 25 kHz frequency, 140 W power, and a 40% duty cycle for 5 min. The maximum anticoagulant activity (55.36 U/mL) was 1.73 times that of the control group, and the fermentation time was shortened by 3 h. Under optimal conditions, ultrasound increased the carbon utilization by Bacillus subtilis ZHX without significant changes in morphology, favoring cell growth and anticoagulant production. However, excessive ultrasound caused intracellular damage, which inhibited biomass accumulation, decreasing anticoagulant activity and even leading to cell rupture. This is the first report on the use of ultrasound to enhance anticoagulant production by Bacillus, and it provides useful information for scaling-up the process.     

Preparing copper catalyst by ultrasound-assisted chemical precipitation method

In this paper, preparing copper catalyst by ultrasound-assisted chemical precipitation method is investigated. The used equipment is JP-020 ultrasonic cleaner, power and frequency are 180 W and 40 kHz respectively. Under the action of ultrasound, CuSO₄·5H₂O is reduced by ascorbic acid to obtain copper. The products are characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and catalytic performance test. The results show that the morphology of copper products is rod-like and irregular granular. Copper catalyst has good catalytic oxidation performance for dyes methylene blue, crystal violet, alizarin red and Rhodamine B. The catalytic efficiency of 10 mg catalyst copper to 6 mg/L methylene blue reaches 98.1%, and the catalytic efficiency of the catalyst increases with the increase of catalyst dosage and the decrease of dye solution concentration. In addition, the new preparation techniques for Cu-based catalysts based on coprecipitation method are compared. Finally, the development trend of the new technology of copper-based catalyst preparation based on coprecipitation method is pointed out.     

Study on ultrasound-assisted oxidative desulfurization for crude oil

The existence of sulfur compounds in crude oil will bring many problems such as corrosion, catalyst poisoning and pollution to the petroleum processing process. Therefore, how to reduce the sulfur content as much as possible in the process of crude oil processing has become an important research topic in the petroleum processing industry. In this paper, ultrasonic-oxidative desulfurization is studied. The effects of reaction temperature, reaction time, amount of oxidant and demulsifier on desulfurization rate are investigated. And the effect of oxidative desulfurization and single oxidative desulfurization under ultrasonic treatment are compared. It is found that the addition of ultrasonic treatment can enhance the desulfurization effect of desulfurizer, the desulfurization efficiency can be increased by about 10% under ultrasonic treatment (100 W, 70 kHz); ultrasonic wave plays an auxiliary role in the system, it can promote heterogeneous reactions, improve the activity of oxidants, and promote the degradation of macromolecular compounds. Finally, physical desulfurization, chemical desulfurization and biological desulfurization technologies are compared.     

Mechanistic investigations in ultrasound-assisted biodegradation of phenanthrene

This study has addressed the biodegradation of polycyclic aromatic hydrocarbon, phenanthrene using Candida tropicalis. Optimization using central composite statistical design yielded optimum experimental parameters as: pH = 6.2, temperature = 33.4 °C, mechanical shaking = 190 rpm and % inoculum = 9.26% v/v. Sonication of biodegradation mixture at 33 kHz and 10% duty cycle in log phase (12 h per day for 4 days) resulted in a 25% enhancement in phenanthrene removal. Profiles of specific growth rate (µ) and specific degradation rate (q) versus initial substrate concentration were fitted to Haldane substrate inhibition model. Both µ and q showed maxima for initial concentration of 100 mg L⁻¹. Kinetic analysis of degradation profiles showed higher biomass yield coefficient and smaller decay coefficient in presence of sonication. Expression of total intracellular proteins in control and test experiments were analyzed using SDS–PAGE. This analysis revealed overexpression of enzyme catechol 2,3-dioxygenase (in meta route metabolism) during sonication which is involved in ring cleavage of phenanthrene. Evaluation of cell viability after sonication by flow cytometry analysis revealed > 80% live cells. These effects are attributed to enhanced cellular transport induced by intense microturbulence generated by sonication.     

功率超声在结晶过程中应用的进展

功率超声在结晶过程中的应用研究促进了结晶技术的发展,丰富了功率超声学和相关学科相互交叉的学术内容。以实例陈述了超声强化溶液结晶过程在化工、食品和制药行业中的应用,从熔融结晶和电结晶两方面阐述了超声改善金属结晶,综述了高分子材料和生物大分子等聚合物结晶过程中超声波的应用,总结了超声波对纳米晶型材料制备和性能的影响,着重说明了功率超声在食品冷冻中冰结晶过程的研究现状和发展方向。最后,总结了超声对结晶的强化机理。     

Kinetics of ultrasound-assisted lipase-catalyzed glycerolysis of olive oil in solvent-free system

This work reports experimental kinetic data of solvent-free glycerolysis of olive oil using a commercial immobilized lipase (Novozym 435) under the influence of ultrasound irradiation. The experiments were performed in a mechanically stirred reactor under ultrasound irradiation, evaluating the effects of temperature (50-70 °C), enzyme concentration (2.5-10 wt%) and glycerol to oil molar ratio (0.8:1-3:1). Results show that ultrasound-assisted lipase-catalyzed glycerolysis might be a potential alternative route to conventional methods, as high contents of reaction products, especially monoglycerides, were achieved at mild irradiation power supply (∼130 W) and temperature, in a relatively short reaction time (2 h) and low enzyme content (7.5 wt%). To completeness, two simplified kinetic modeling approaches, based on the ordered-sequential bi bi mechanism and reaction stoichiometry, were employed to represent the experimental data, thus allowing a better understanding of the reaction kinetics.     

A single step ultrasound-assisted nitrocellulose synthesis from microcrystalline cellulose

Nitrocellulose is a nitrated cellulose polymer with a broad application in industry. Depending on the nitrogen content, this polymer can be used for manufacturing explosives, varnishes, clothes, and films, being considered a product of high value-added. In this work, the use of ultrasound was investigated for the intensification of nitrocellulose synthesis from microcrystalline cellulose. The ultrasound-assisted nitrocellulose synthesis (UANS) was carried out using several ultrasound systems, such as baths and cup horns, allowing the evaluation of the frequency (from 20 to 130 kHz) and delivered power (from 23 to 134 W dm⁻³) to the reaction medium. The following parameters were evaluated: acid mixture (H₂SO₄, H₃PO₄, CH₂O₂ or CH₃COOH with HNO₃, 2 to 14.4 mol L⁻¹), ultrasound amplitude (10 to 70%) and reaction time (5 to 50 min). Better nitrocellulose yield (nitrogen content of 12.5% was obtained from 1 g of microcrystalline cellulose employing a cup horn system operating at 20 kHz, 750 W of nominal power with 60% of amplitude, 25 mL of acid solution (13.6 mL of 18.4 mol L⁻¹ H₂SO₄ + 9.2 mL of 14.4 mol L⁻¹ HNO₃ + 2.2 mL H₂O), at 30 °C for 30 min. At silent conditions (mechanical stirring ranging from 100 to 500 rpm), the nitrogen content was lower than 11.8% which demonstrate the ultrasound effects for nitrocellulose synthesis.     

Effect of ultrasound-assisted resting on the quality of surimi-wheat dough and noodles

In this study, the influence of ultrasound-assisted resting at different power on the rheological properties, water distribution and structural characteristics of dough with 50 % surimi as well as the texture, cooking and microstructure characteristics of the surimi-wheat noodles were investigated. Compared with the fermentation control (FC) noodles, the microstructure, cooking and texture characteristics of noodles (≤24.00 W/L) were significantly (p < 0.05) improved after ultrasonic treating. As the increasing of ultrasonic power, compared to FC, the creep strain, recovery strain, semi-bound water, and free sulfhydryl (SH) contents of surimi-wheat dough decreased at first and then increased significantly (p < 0.05). The α-helix and β-turn content of dough increased at first and then decreased after ultrasonic treatment, while the β-sheet was reversed. The surimi-wheat dough network structure was improved by ultrasonic treatment, with the densest and continuous pore size in 21.33 W/L, but the dough structure was broken and loose (>21.33 W/L), which consisted of the hardness, elasticity, chewiness, resistant and cooked quality of surimi-wheat noodles. This work elucidated the effect of ultrasonic power on the performance of surimi-wheat dough, and the optimal ultrasound power was obtained, thereby improving the nutritional properties and the quality of surimi-wheat noodles.     

Influence of ultrasound-assisted extraction on the pyrolysis characteristics and kinetic parameters of eucalyptus

In this study, the influence of ultrasound-assisted extraction on eucalyptus samples with special focus on pyrolysis characteristics and kinetic parameters was explored. Ultrasound and Soxhlet extraction were used to pretreat samples respectively, then samples were assayed by component analysis, TG-FTIR, and kinetic analysis. Ultrasound-assisted extraction did change the physiochemical characteristics of eucalyptus samples, particularly in regards to the quantity of extractives obtained. In TG and DTG curves, ultrasound-extracted samples reflected lower residual weight ratio (17.77%) and higher maximum weight loss rate (−22.92%/min), and were accompanied by a slight shift in the weight loss rate peak to lower temperature (366 °C). The volatiles produced during pyrolysis and the discrepancies of product distribution between experimental and controlled groups were explored based on TG-FTIR spectra. According to kinetic analysis results, ultrasound-treated samples showed higher activation energy at the primary portion of thermal degradation with an average of 206.09 kJ/mol.