Enhancement of activated decay of metastable states by resonant pumping

We consider the effect of a high-frequency pumping cost on the escape rate of a classical underdamped Brownian particle out of a deep potential well. The energy dependence of the oscillation frequency(E) is assumed to be weak on the scale of thermal energy,_E(0)T(0)T/V₀ (0)[_E(0) is the derivative of(E) atE= 0,V ₀ is the barrier height,V ₀ T]. The quadratic-in- contribution to the decay rate is calculated in two different regimes: (1) for the case of resonance of the pumping frequency with the nth harmonic of the internal motion at an energye, when = n(e); (2) for a rollout region of the basic resonance near the bottom of the potential well, when ¦-(0)¦ and is the damping coefficient. In the latter case the absorption spectrum and the enhancement of the decay rate are calculated as functions of two reduced parameters, the anharmonicity of the potential,v _E (0)T/, and the resonance mismatch, [ —(0)]/. It is shown that the effect of the pumping increases with diminishing ¦v¦ and at small v is proportional tov ^–1. In this regime, the dependence on is stepwise: the pumping contribution is large for v > 0 and small for v < 0. In the frame of our theory, the decay rate is invariant against the simultaneous alternation of the signs of andv. The spectrum of the energy absorption has the standard Lorentzian shape in the absence of anharmonicity,v=0, and with increasing of ¦v¦ shifts and widens retaining its bell-shape form.     

Kinetic theory of adsorption and desorption

In this paper we use stochastic methods to discuss adsorption and desorption. The paper derives generalized coefficients of sticking and accomodation depending on surface temperatureT _s and gas temperatureT _g and shows, that for additive Markov processes, these kinetic coefficients are identical. Furthermore, exact solutions of the kinetic equations for certain simple transition probabilitiesP(, ) are found and an approximation method for more complicatedP(, ) is given. The comparison of the theory with experimental results for noble gas-metal systems indicate a quadratic relationship between the first moment of the transition probabilityP(, ) and the well depth of the physisorption system.     

Absolutely continuous invariant measures for one-parameter families of one-dimensional maps

Given a one-parameter familyf (x) of maps of the interval [0, 1], we consider the set of parameter values for whichf has an invariant measure absolutely continuous with respect to Lebesgue measure. We show that this set has positive measure, for two classes of maps: i)f (x)=f(x) where 0<4 andf(x) is a functionC ³-near the quadratic mapx(1–x), and ii)f (x)=f(x) (mod 1) wheref isC ³,f(0)=f(1)=0 andf has a unique nondegenerate critical point in [0, 1].     

Natural boundaries for area-preserving twist maps

We consider KAM invariant curves for generalizations of the standard map of the form (x, y)=(x+y, y+f(x)), wheref(x) is an odd trigonometric polynomial. We study numerically their analytic properties by a Padé approximant method applied to the function which conjugates the dynamics to a rotation +. In the complex plane, natural boundaries of different shapes are found. In the complex plane the analyticity region appears to be a strip bounded by a natural boundary, whose width tends linearly to 0 as tends to the critical value.     

Ergodic states in a non commutative ergodic theory

Using the Godement mean of positive-type functions over a groupG, we study -abelian systems { , } of aC*-algebra and a homomorphic mapping of a groupG into the homomorphism group of . Consideration of the Godement mean off(g)U _g withf a positive-type function overG andU a unitary representation ofG first yields a generalized mean-ergodic theorem. We then define the Godement mean off(g) ( _g (A)) withA and a covariant representation of the system { , } for which theG-invariant Hilbert space vectors are cyclic and study its properties, notably in relation with ergodic and weakly mixing states over . Finally we investigate the discrete spectrum of covariant representations of { , } (i.e. the direct sum of the finite-dimensional subrepresentations of the associated representations ofG).On leave of absence from Istituto di Fisica G. Marconi Piazzale delle Scienze 5 — Roma.     

Spouge's Conjecture on Complete and Instantaneous Gelation

We investigate the stochastic counterpart of the Smoluchowski coagulation equation, namely the Marcus–Lushnikov coagulation model. It is believed that for a broad class of kernels, all particles are swept into one huge cluster in an arbitrarily small time, which is known as a complete and instantaneous gelation phenomenon. Indeed, Spouge (also Domilovskii et al. for a special case) conjectured that K(i, j)=(ij) , >1, are such kernels. In this paper, we extend the above conjecture and prove rigorously that if there is a function (i, j), increasing in both i and j such that _j=1 1/(j(i, j))< for all i, and K(i, j)ij(i, j) for all i, j, then complete and instantaneous gelation occurs. Evidently, this implies that any kernels K(i, j)ij(log(i+1)log(j+1)) , >1, exhibit complete instantaneous gelation. Also, we conjuncture the existence of a critical (or metastable) sol state: if lim _i+j ij/K(i, j)=0 and _{i, j=1} 1/K(i, j)=, then gelation time T _g satisfies 0<T _g<. Moreover, the gelation is complete after T _g.     

Mean-Field Critical Behavior for the Contact Process

The contact process is a model of spread of an infectious disease. Combining with the result of ref. 1, we prove that the critical exponents take on the mean-field values for sufficiently high dimensional nearest-neighbor models and for sufficiently spread-out models with d>4:()– _c as _c and ()( _c–)^–1 as _c, where () and () are the spread probability and the susceptibility of the infection respectively, and _c is the critical infection rate. Our results imply that the upper critical dimension for the contact process is at most 4.     

Intersection properties of simple random walks: A renormalization group approach

We study estimates for the intersection probability,g(m), of two simple random walks on lattices of dimensiond=4, 4– as a problem in Euclidean field theory. We rigorously establish a renormalization group flow equation forg(m) and bounds on the -function which show that, ind=4,g(m) tends to zero logarithmically as the killing rate (mass)m tends to zero, and that the fixed point,g*, ind=4– is bounded by const' g*const. Our methods also yield estimates on the intersection probability of three random walks ind=3, 3–. For =0, these results were first obtained by Lawler [1].     

An algebraic approach to quantum field theory and commutation relations for energy momentum in the framework of general relativity

We present a consistent set of commutation relations (C.R.) for a quantum system immersed in a classical gravitational field. The gravity field is described by metric tensorg _ik (x) andg ₀₀(x) with coordinate gaugeg _i0=0. The Hamiltonian of the system is found to be a linear function of [–g ₀₀(x)]^1/2. Its properties we define by C.R. avoiding explicit expression in terms of fields, as well as its splitting into free and interaction parts. In this way a consistent set of C.R., which are equally simple for a flat and curvilinear space, can be established. To stress the main idea of our approach, we consider the simple but still nontrivial example of a scalar electrodynamics immersed in a gravity field. The electromagnetic current operator we define by its C.R. and not explicitly. An interesting feature of this approach is that the Poisson equation follows from the consistency of the C.R. The C.R. for the energy and momentum operators of the system in a gravity field are established which generalize the usual Poincare group generators C.R. For example, we find (i/hc ²)[H _(x) ,H _(x) ]=P _– , whereH _(x) is the Hamiltonian of the system, which is a linear functional of (x)[–g ₀₀(x)]^1/2 andP _s(x) represents the momentum-density operator [averaged with the classical functions(x)].     

Observed difference between the probabilities of recoilless resonance absorptionf′ and reemissionf″ of gamma-quanta in single crystals of Na2[Fe(CN)5NO]·2 H2O

The recoilless absorption probability factor,f, and recoilless reemission,f, both measured on Na₂[Fe(CN)₅NO]·2 H₂O single crystals using the black filter technique, were found to be different. Unexpectedly, the results found weref>f. In the calculation off, selfabsorption in the scatterer, non-ideality of the black filter and the influence of non-resonant scattering processes have all been taken into account. By varying the scattering geometry for the incoming and outgoing -beam relative to the crystallographic axes only a change in the reemitted valuesf _a, f_b, f_c could be detected because of the long lifetime of the excited nucleus (10^–7 s) relative to the lattice vibration frequencies (10¹² Hz).     

Multifractal Power Law Distributions: Negative and Critical Dimensions and Other “Anomalies,” Explained by a Simple Example

Divergence of high moments and dimension of the carrier is the subtitle of Mandelbrot's 1974 seed paper on random multifractals. The key words divergence and dimension met very different fates. Dimension expanded into a multifractal formalism based on an exponent and a function f(). An excellent exposition in Halsey et al. 1986 helped this formalism flourish. But it does not allow divergent high moments and the related inequalities f()<0 and <0. As a result, those possibilities did not flourish. Now their time has come for diverse reasons. The broad 1974 definitions of and f allow <0 and f()<0, but the original presentation demanded to be both developed and simplified. This paper shows that both multifractal anomalies occur in a very simple example, which has been crafted for this purpose. This example predicts the power law distribution. It generalizes and f() beyond their usual roles of being a Hölder exponent and a Hausdorff dimension. The effect is to allow either f or both f and to be negative, and the apparent anomalies are made into sources of new important information. In addition, this paper substantially clarifies the subtle way in which randomness manifests itself in multifractals.     

Long-range correlations at depinning transitions

Semi-infinite systems are considered with long-range surface fields B _z ^–(1+r) for large distancesz from the surface. The influence of such fields on the global phase diagram and on the critical singularities of depinning transitions is studied within Landau theory. For |B|0, the correlation length diverges as b ^–1/2 withb=|Bln|B^–(1+r). For finiteB, t ^v withv =(2+r)/(2+2r) wheret measures the distance from bulk coexistence. In the latter case, a Ginzburg criterion leads to the upper critical dimensiond ^*=(2+3r)/(2+r).     

Group actions on C*-algebras, 3-cocycles and quantum field theory

We study group extensions , where acts on a C^*-algebraA. Given a twisted covariant representation ,V of the pairA, we construct 3-cocycles on with values in the centre of the group generated byV(). These 3-cocycles are obstructions to the existence of an extension of byV() which acts onA compatibly with . The main theorems of the paper introduce a subsidiary invariant which classifies actions of onV() and in terms of which a necessary and sufficient condition for the the cohomology class of the 3-cocycle to be non-trivial may be formulated. Examples are provided which show how non-trivial 3-cocycles may be realised. The framework we choose to exhibit these essentially mathematical results is influenced by anomalous gauge field theories. We show how to interpret our results in that setting in two ways, one motivated by an algebraic approach to constrained dynamics and the other by the descent equation approach to constructing cocycles on gauge groups. In order to make comparisons with the usual approach to cohomology in gauge theory we conclude with a Lie algebra version of the invariant and the 3-cocycle.     

New proofs of the existence of the Feigenbaum functions

A new proof of the existence of analytic, unimodal solutions of the Cvitanovi-Feigenbaum functional equation g(x) = –g(g(–x)),g(x) 1 - const|x|^r at 0, valid for all in (0, 1), is given, and the existence of the Eckmann-Wittwer functions [8] is recovered. The method also provides the existence of solutions for certain given values ofr, and in particular, forr=2, a proof requiring no computer.     

On X-ray measurements of residual stresses in materials with lattice strain gradient

The non-linear distribution of lattice strain ³¹⁰vs sin² observed on the surface of a polished steel specimen can be interpreted by tri-axial stress state with surface components of stress tensor ₁₁(0)= ₂₂(0) and gradientsg ₁₁= ₁₁/T, g ₃₃= ₃₃/T. The distribution of experimental values is duscussed from the viewpoint of various ways of calculating ₁₁.The authors would like to thank Dr. J. Musil, D. Sc. of the Institute of Physics of Czechoslovak Academy of Sciences for kindly providing the samples which made possible this study.     

The vacuum energy forP(ø)2: Infinite volume limit and coupling constant dependence

LetE(g) be the vacuum energy for theP(ø)₂ Hamiltonian with space cutoffg(x)0 and coupling constant 0. For suitable families of cutoffsg1, the vacuum energy per unit volume converges; i.e., –E(g)/g(x)dx (). We obtain bounds on the dependence of () for large and small . These lead to estimates forE(g) as a functional ofg that permit a weakening of the standard regularity conditions forg. Typical of such estimates is the linear lower bound, –E(g)const g(x)² dx, valid for allg0 provided thatP is normalized so thatP(0)=0. Finally we show that the perturbation series for () is asymptotic to second order.Research partially supported by AFOSR under Contract No. F 44620-71-C-0108.Postal address after September 30, 1972: via A. Falcone 70, 80127, Napoli, Italy.     

Exact expressions for row correlation functions in the isotropicd=2 ising model

We present exact explicit expressions for the row spin-spin correlation functions _{00 n}0 in the isotropicd= 2 Ising model, in terms of elliptic integrals, forn 5. We also give a general structural formula for _{00 n}0.     

Instability in degenerate two-photon running wave laser

The stability of the homogeneously broadened and degenerate two-photon running wave laser is analysed by using the full set of matter-field equations. The stability depends on the relative size of the relaxation constants. For 2k>1+r(k=/,r=/; is the cavity loss of the field and , are the longitudinal and transversal decay constants, respectively) no stable lasing state exists. Forr<k<(1+r)/2 an instability occurs. With the decrease in pumping the stable lasing state loses its stability due to Hopf-bifurcation.     

Unbounded derivations of commutativeC*-algebras

It is shown that an unbounded *-derivation of a unital commutativeC*-algebraA is quasi well-behaved if and only if there is a dense open subsetU of the spectrum ofA such that, for anyf in the domain of , (f) vanishes at any point ofU wheref attains its norm. An example is given to show that even if is closed it need not be quasi well-behaved. This answers negatively a question posed by Sakai for arbitraryC*-algebras.It is also shown that there are no-zero closed derivations onA if the spectrum ofA contains a dense open totally disconnected subset.     

Calculation of the dispersion of the third-order optical nonlinearity in C60 films

Using wave functions determined from ground-state local-density calculations, we have calculated the wave-dispersed free response of the optical nonlinear polarizability ⁽³⁾(–3;,,), for the C₆₀ molecule and ⁽³⁾(–3;,,) i.e. Third-Harmonic Generation (THG) for films using a sum-over-states approach. The influence of screening was determined by applying an external static electric field in separate selfconsistent calculations to evaluate induced dipole moments which was used to determine the static linear and nonlinear polarizabilities. The polarizabilities calculated in the static limit were used to determine an effective screening parameter which was, in turn, used together with an RPA approach to calculate screened wave-dispersed, third-order nonlinear optical properties such as ⁽³⁾(–3;,,) and ⁽³⁾(–3;,,). Comparing evaluated polarizabilities with experimental values we found that the non-resonant free polarizability compares well in absolute magnitude with experimental results. Inclusion of screening results in a polarizability about two orders of magnitude below the experimental values.Paper presented at the 129th WE-Heraeus-Seminar on Surface Studies by Nonlinear Laser Spectroscopies, Kassel, Germany, May 30 to June 1, 1994