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1.
In this Letter we report the synthesis, characterization, and electrochemical investigation of a 3,4-ethylenedioxythiophene (EDOT) derivative covalently linked to the nucleobase uracil. The successful electrochemical polymerization of this derivative has provided modified electrodes with a novel functional poly(3,4-ethylenedioxythiophene) derivative. Recognition experiments in aqueous media have shown the specific recognition of the complementary base adenine. The electrochemical detection of the selective binding of nucleobases to this PEDOT derivative in aqueous media can be of particular interest for electrochemical sensor applications in physiological media. 相似文献
2.
L.J. del Valle D. Aradilla F. Sepulcre E. Armelin F. Estrany 《European Polymer Journal》2007,43(6):2342-2349
Cell adhesion and proliferation in poly(3,4-ethylenedioxythiophene), an electroactive polythiophene derivative generated by anodic polymerization, has been investigated. Results show that epithelial cells Hep-2 present significant activity on the surface of poly(3,4-ethylenedioxythiophene) electrodeposited on stainless steel electrodes, no sign of cytotoxicity being detected for this conducting polymer. Indeed, seeded and cultured cells bound better to poly(3,4-ethylenedioxythiophene) than to uncoated stainless steel, the latter substrate being used as a control. Furthermore, the electrochemical characteristics of poly(3,4-ethylenedioxythiophene) covered with cells was determined in different biological media using cyclic voltammetry experiments. Results reveal a significant increase in the electroactivity of this material when it is covered with a cellular monolayer. The overall of the results evidences not only the biocompatibility of poly(3,4-ethylenedioxythiophene) with Hep-2 cells but also their electrocompatibility. 相似文献
3.
Raúl Blanco 《Tetrahedron letters》2008,49(13):2056-2059
A convenient and straightforward procedure has been developed for the preparation of functionalized 3,4-ethylenedithiathiophene (EDTT) derivatives by using a new bromomethyl-EDTT derivative as a versatile synthon. Based on this procedure a novel EDTT derivative endowed with 9,10-anthraquinone moieties has been synthesized and electrochemically polymerized to yield a donor-acceptor PEDTT derivative. 相似文献
4.
Lind JU Acikgöz C Daugaard AE Andresen TL Hvilsted S Textor M Larsen NB 《Langmuir : the ACS journal of surfaces and colloids》2012,28(15):6502-6511
A versatile procedure is presented for fast and efficient micropatterning of multiple types of covalently bound surface chemistry in perfect register on and between conductive polymer microcircuits. The micropatterning principle is applied to several types of native and functionalized PEDOT (poly(3,4-ethylenedioxythiophene)) thin films. The method is based on contacting PEDOT-type thin films with a micropatterned agarose stamp containing an oxidant (aqueous hypochlorite) and applying a nonionic detergent. Where contacted, PEDOT not only loses its conductance but is entirely removed, thereby locally revealing the underlying substrate. Surface analysis showed that the substrate surface chemistry was fully exposed and not affected by the treatment. Click chemistry could thus be applied to selectively modify re-exposed alkyne and azide functional groups of functionalized polystyrene substrates. The versatility of the method is illustrated by micropatterning cell-binding RGD-functionalized PEDOT on low cell-binding PMOXA (poly(2-methyl-2-oxazoline)) to produce cell-capturing microelectrodes on a cell nonadhesive background in a few simple steps. The method should be applicable to a wide range of native and chemically functionalized conjugated polymer systems. 相似文献
5.
Jong Seob Choi 《European Polymer Journal》2010,46(3):389-15196
Highly conductive and transparent poly(3,4-ethylenedioxythiophene) (PEDOT) thin films can be prepared effectively via vapor-phase polymerization (VPP) with the addition of imidazole (Im) based derivatives. The addition of Im that has one and/or two alkyl substituents significantly improved the electrical conductivity of PEDOT thin films. In an effort to develop a facile PEDOT micro-patterning method, we investigated ink-jet printing and soft lithography. The procedure of oxidant patterning with a weak base followed by VPP of a 3,4-ethylenedioxythiophene (EDOT) monomer provides an effective and simple method for micro-patterning of an intrinsic conductive polymer (ICP). 相似文献
6.
David Aradilla Francesc Estrany Denise S. Azambuja María T. Casas Carlos A. Ferreira 《European Polymer Journal》2010,46(5):977-983
Exfoliated nanocomposites formed by poly(3,4-ethylenedioxythiophene) and different concentrations of non-modified montmorillonite (bentonite), which range from 1% to 10% w/w, have been prepared by anodic electropolymerization in aqueous solution. Analyses of the electrochemical and electrical properties reveal that the electroactivity of the nanocomposites is higher than that of the individual homopolymer, while the electrical conductivity of the two systems is practically identical. On the other hand, the exfoliated distribution of the clay in the polymeric matrix and the morphology of the prepared materials have been characterized using transmission electron microscopy, X-ray diffraction and atomic force microscopy. The overall of the results represents a significant improvement with respect to other nanocomposites constituted by conducting polymers and clays, including those involving poly(3,4-ethylenedioxythiophene), and evidences the reliability of the preparation procedure employed in this work. 相似文献
7.
James F. Ponder Jr. Shawn A. Gregory Amalie Atassi Abigail A. Advincula Joshua M. Rinehart Guillaume Freychet Gregory M. Su Shannon K. Yee John R. Reynolds 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2023,135(1):e202211600
Herein, a route to produce highly electrically conductive doped hydroxymethyl functionalized poly(3,4-ethylenedioxythiophene) (PEDOT) films, termed PEDOT(OH) with metal-like charge transport properties using a fully solution processable precursor polymer is reported. This is achieved via an ester-functionalized PEDOT derivative [PEDOT(EHE)] that is soluble in a range of solvents with excellent film-forming ability. PEDOT(EHE) demonstrates moderate electrical conductivities of 20–60 S cm−1 and hopping-like (i.e., thermally activated) transport when doped with ferric tosylate (FeTos3). Upon basic hydrolysis of PEDOT(EHE) films, the electrically insulative side chains are cleaved and washed from the polymer film, leaving a densified film of PEDOT(OH). These films, when optimally doped, reach electrical conductivities of ≈1200 S cm−1 and demonstrate metal-like (i.e., thermally deactivated and band-like) transport properties and high stability at comparable doping levels. 相似文献
8.
Sadik Cogal 《Analytical letters》2018,51(11):1666-1679
Poly(3,4-ethylenedioxythiophene) was deposited on a reduced graphene oxide-decorated glassy carbon electrode through an electrochemical polymerization. The resulting glassy carbon electrode-reduced graphene oxide-poly(3,4-ethylenedioxythiophene) electrode was applied as an electrochemical biosensor for the determination of dopamine in the presence of ascorbic acid and uric acid. The material deposited on glassy carbon electrode was investigated in terms of morphology and structural analysis. The comparison of electrochemical behavior of the glassy carbon electrode-reduced graphene oxide-poly(3,4-ethylenedioxythiophene) electrode with the glassy carbon electrode-graphene oxide, glassy carbon electrode-reduced graphene oxide, and glassy carbon electrode-poly(3,4-ethylenedioxythiophene) electrodes exhibited high electrocatalytic activity for dopamine detection. Electrochemical kinetic parameters of glassy carbon electrode-reduced graphene oxide-poly(3,4-ethylenedioxythiophene), including the charge transfer coefficient α (0.49) and electron transfer rate constant ks (1.04), were determined and discussed. The glassy carbon electrode-reduced graphene oxide-poly(3,4-ethylenedioxythiophene) electrode was studied for the determination of dopamine by differential pulse voltammetry and exhibited a linear range from 19.6 to 122.8?µM with a sensitivity of 3.27?µA?µM?1?cm?2 and a detection limit of 1.92?µM. The developed biosensor exhibited good selectivity toward dopamine with high reproducibility and stability. 相似文献
9.
The electrochemical recognition and trace-level detection of bactericide carbendazim (MBC) in paddy water and commercial juice were realized using carboxylic group functionalized poly(3,4-ethylenedioxythiophene) (PC4-EDOT-COOH) film electrode. PC4-EDOT-COOH film was prepared by one step, low-cost, and green electrosynthesis in aqueous microemulsion system and characterized by FT-IR, cyclic voltammetry, UV–vis and SEM. In comparison with poly(3,4-ethylenedioxythiophene) (PEDOT) and poly(hydroxymethylated-3,4-ethylenedioxylthiophene) (PEDTM), PC4-EDOT-COOH exhibited the best electrochemical recognition towards MBC and the recognition mechanism was proved by quantitative calculation. Sensing parameters such as pH values, accumulation potential, accumulation time, supporting electrolyte, and scan rate on the current response of MBC were discussed. In addition, the sensor can be applied to quantification of MBC in the concentration range of 0.012–0.35 μM with a low detection limit of 3.5 nM (S/N = 3). Moreover, PC4-EDOT-COOH film electrode showed good stability, high selectivity, and satisfactory anti-interference ability. Satisfactory results indicated that PC4-EDOT-COOH film is a promising sensing platform for the trace-level analysis of bactericide residue carbendazim in agricultural crops and environment. 相似文献
10.
A dipyrromethane functionalized monomer, 5-(4-tert-butylphenyl)dipyrromethane (DP), was synthesized to examine the spectral differences of its copolymer and blend with 3,4-ethylenedioxythiophene. Electrochemical polymerization, copolymerization, and blending of DP were achieved in LiClO4/Acetonitrile. Spectral and electrochromic properties of products were investigated. Spectral properties of copolymer and blend revealed great differences from each other and also from their corresponding homopolymers. Effect of monomer feed ratio on the spectral properties of copolymer was also investigated. 相似文献
11.
《高分子科学》2016,(5)
Two pairs of amino-acid functionalized poly(3,4-ethylenedioxythiophene)(PEDOT) derivatives, namely, poly(N-(tert-butoxycarbonyl)-L-methionyl(3,4-ethylenedioxythiophene-2'-yl)methylamide)(L-PEDOT-Boc-Met) and poly(N-(tertbutoxycarbonyl)-D-methionyl(3,4-ethylenedioxythiophene-2'-yl)methylamide)(D-PEDOT-Boc-Met); poly(L-methionyl(3,4-ethylenedioxythiophene-2'-yl)methylamide)(L-PEDOT-Met) and poly(D-methionyl(3,4-ethylenedioxythiophene-2'-yl)methylamide)(D-PEDOT-Met) were synthesized via chemical oxidative polymerization of corresponding monomers. The structural characterization, spectroscopic properties and thermal stability of these monomers and polymers were systematically explored by FTIR spectra, Raman spectra, XRD spectra, UV-Vis spectra and thermogravimetric analysis. As chiral electrode materials, these polymers were employed to successfully recognize 3,4-dihydroxyphenylalanine(DOPA) enantiomers by cyclic voltammetry(CV) in sulphuric acid solution. The measurement results reveal that the tendency was hetero-chiral interaction between L-PEDOT-Met/PVA/GCE and D-DOPA, D-PEDOT-Met/PVA/GCE and L-DOPA, respectively. Also, the mechanism of chiral discrimination was discussed. All the results implied that the combination of electrochemical molecular recognition technology and chiral PEDOT materials can be a promising approach for chiral recognition and may open new opportunities for facile, biocompatible, sensitive and robust chiral assays in biochemical applications. 相似文献
12.
Natarajan Senthilkumar Hak-Su Kang Dae-Won Park Youngson Choe 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(5):484-490
In this study, polymeric nanocomposites of poly(3,4-ethylenedioxythiophene): poly(styrene sulfonate) (PEDOT:PSS) and functionalized multi-walled carbon nanotubes (MWCNTs) were spin coated on a pre-patterned ITO glass and used as a hole conducting layer in organic photovoltaic cells. The multi-layered ITO/MWCNT-PEDOT:PSS/CuPc/C60/Al devices were fabricated to investigate the current density-voltage characteristics and power conversion efficiency. The power conversion efficiency obtained from the device with a concentration of 1.0 wt% MWCNT in the PEDOT:PSS layer was increased twice as those adopted from device without MWCNT doping in the PEDOT:PSS layer and current density-voltage characteristics was also improved well with incorporation of MWCNTs. 相似文献
13.
The synthesis of arylated/heteroarylated 3,4-ethylenedioxythiophene derivatives is reported using a straightforward palladium mediated Heck coupling of 3,4-ethylenedioxythiophene with various aryl/heteroaryl halides. 相似文献
14.
Solid-state synthesis of a conducting polythiophene via an unprecedented heterocyclic coupling reaction 总被引:2,自引:0,他引:2
Meng H Perepichka DF Bendikov M Wudl F Pan GZ Yu W Dong W Brown S 《Journal of the American Chemical Society》2003,125(49):15151-15162
Prolonged storage ( approximately 2 years) or gentle heating (50-80 degrees C) of crystalline 2,5-dibromo-3,4-ethylenedioxythiophene (DBEDOT) affords a highly conducting, bromine-doped poly(3,4-ethylenedioxythiophene) (PEDOT), as confirmed by solid-state NMR, FTIR, CV, and vis-NIR spectroscopies. The novel solid-state polymerization (SSP) does not occur for 2,5-dichloro-3,4-ethylenedioxythiophene (DCEDOT), and requires a much higher temperature (>130 degrees C) for 2,5-diiodo-3,4-ethylenedioxythiophene (DIEDOT). X-ray structural analysis of the above dihalothiophenes reveals short Hal.Hal distances between adjacent molecules in DBEDOT and DIEDOT, but not in DCEDOT. The polymerization may also occur in the melt but is significantly slower and leads to poorly conductive material. Detailed studies of the reaction were performed using ESR, DSC, microscopy, and gravimetric analyses. SSP starts on crystal defect sites; it is exothermic by 14 kcal/mol and requires activation energy of approximately 26 kcal/mol (for DBEDOT). The temperature dependence of the conductivity of SSP-PEDOT (sigma(rt) = 20-80 S/cm) reveals a slight thermal activation. It can be further increased by a factor of 2 by doping with iodine. Using this approach, thin films of PEDOT with conductivity as high as 20 S/cm were fabricated on insulating flexible plastic surfaces. 相似文献
15.
New functionalized pyrazolo[3,4‐d]pyrimido[1,2‐b][1,2,4,5]tetrazine derivatives 6a‐q were synthesized via reaction of the hydrazonoyl halides 1a‐q with 5‐amino‐1‐phenyl‐6‐thioxo‐pyrazolo[3,4‐d]pyrimidin‐4‐one 2 and its 2‐methylthio derivative 3 . The mechanism and the regioselectivity of the studied reactions have been discussed. 相似文献
16.
Multilayer films stacked alternately by poly(3,4-ethylenedioxythiophene) and reduced graphene oxide were synthesized electrochemically from a single aqueous solution containing 3,4-ethylenedioxythiophene (EDOT) and graphene oxide (GO) by repeatedly oxidizing EDOT and reducing GO on a conductive substrate. Using the proposed technique, the thickness of the different layers could be easily tuned by varying the electrolysis time, and the number of layers could be increased simply by repeating the sequence of potential steps. 相似文献
17.
Francesc Estrany David Aradilla Ramn Oliver Elaine Armelin Carlos Alemn 《European Polymer Journal》2008,44(5):1323-1330
Multilayered films formed by 3, 5 and 7 alternated layers of poly(3,4-ethylenedioxythiophene) and poly(N-methylpyrrole) have been prepared by chronoamperometry under a constant potential of 1.4 V using a layer-by-layer electrodeposition technique. In order to examine influence of the interface:bulk dimensional ratio, the thickness of the yielded films was reduced from the submicrometric to the nanometric scale by decreasing the polymerization time of each layer from 100 s to 10 s. The electroactivity, electrochemical characteristics and morphologies of the resulting multilayered films have been compared with those obtained for both single-component poly(3,4-ethylenedioxythiophene) films prepared using identical experimental conditions and previously reported multilayered films with thickness within the micrometric scale [Estrany F, Aradilla D, Oliver R, Alemán C. Eur Polym J 2007;43:1876]. 相似文献
18.
Svetlana Laishevkina Natalia Shevchenko Olga Iakobson Anatoly Dobrodumov Vladimir Chelibanov Elena Tomík 《Molecules (Basel, Switzerland)》2022,27(21)
Conductive hydrogels are polymeric materials that are promising for bioelectronic applications. In the present study, a complex based on sulfonic cryogels and poly(3,4-ethylenedioxythiophene) (PEDOT) was investigated as an example of a conductive hydrogel. Preparation of polyacrylate cryogels of various morphologies was carried out by cryotropic gelation of 3-sulfopropyl methacrylate and sulfobetaine methacrylate in the presence of functional comonomers (2-hydroxyethyl methacrylate and vinyl acetate). Polymerization of 3,4-ethylenedioxythiophene in the presence of several of the above cryogels occurred throughout the entire volume of each polyelectrolyte cryogel because of its porous structure. Structural features of cryogel@PEDOT complexes in relation to their electrochemical properties were investigated. It was shown that poly(3,4-ethylenedioxythiophene) of a linear conformation was formed in the presence of a cryogel based on sulfobetaine methacrylate, while minimum values of charge-transfer resistance were observed in those complexes, and electrochemical properties of the complexes did not depend on diffusion processes. 相似文献
19.
Jing Sui Lijuan Zhang Jadranka Travas-Sejdic Paul A. Kilmartin 《Macromolecular Symposia》2010,290(1):107-114
Summary: Hollow microspheres of PEDOT (poly(3,4-ethylenedioxythiophene) ranging from 0.5 to 10 µm have been synthesized by chemically oxidative polymerization of EDOT(3,4-ethylenedioxythiophene) using ammonium persulfate in a catanionic surfactant solution obtained by mixing cetyltrimethylammonium bromide (CTAB) and sodium dodecylbenzenesulfonate (SDBS). The effect of the molar ratio of CTAB to SDBS on the morphology of the PEDOT oxidation products has been investigated using SEM and TEM and by an analysis of the structural properties using UV-visible, FTIR and Raman spectroscopies, elemental analysis and conductivity measurements. The electro-catalytic activity of PEDOT hollow microspheres for the oxidation of ascorbic acid was investigated by cyclic voltammetry in a pH 6 citrate/phosphate buffer solution and compared to the activity of granular PEDOT particles formed in the absence of the catanionic surfactant. 相似文献
20.
Cravino A Neugebauer H Petr A Skabara PJ Spencer HJ McDouall JJ Dunsch L Sariciftci NS 《The journal of physical chemistry. B》2006,110(6):2662-2667
Poly(3,4-ethylenedithiathiophene) (PEDTT) is a polythiophene-like conjugated polymer in which each thiophene ring is functionalized with an ethylenedithia bridge. As such, PEDTT is the sulfur analogue of the well-known poly(3,4-ethylenedioxythiophene) (PEDOT). Substituent effects, namely the presence of sulfur atoms in PEDTT replacing the oxygen atoms of PEDOT, do not provide a simple explanation for the different electronic properties of the two polymers in the neutral state. This paper reports the spectroscopic properties of PEDTT, studied by in situ techniques such as IR-, Vis-, and electron spin resonance (ESR) spectroelectrochemistry. The differences observed upon electrochemical oxidation of PEDTT and PEDOT (e.g., the different infrared active vibrational band patterns in IR spectroelectrochemistry as well as the different nature of the charged states) are even more marked than those observed in the neutral state. These results, with AM1 calculations, indicate conformational effects as a possible explanation for the different electronic and spectroscopic properties of PEDTT and PEDOT. 相似文献