Effect of some environmental ligands and fertilizers on humic acid complexation with strontium

The effect of some environmental ligands and certain fertilizers on the complexation of strontium with humic acid wasinvestigated colorimetrically and radiometrically. The results indicate that Na₂-EDTA, Na₃-citrate and NaCl compete to complex strontium in solution with the sequence: chloride < citrate < EDTA while Na₃-phosphate has the reverse behavior. In the case of nitrogen containing fertilizers, the results show that urea, Mg-ammonium nitrate and ammonium nitrate increase the availability of strontium to plants and microorganisms.     

Transport processes in the sorption of colored ions by peat particles

A three-step model has been proposed for the adsorption of Astrazone Blue dye (Basic Blue 69) on peat. The initial rate of uptake of dye ions due to physical adsorption and chemisorption (ion exchange) has been correlated using a surface mass transfer coefficient. These coefficients have been determined and expressed in the dimensionless mass transfer form, Sh/Sc^0.33, as a function of agitation, initial dye concentration, peat particle size range, dye solution temperature, and mass of peat.     

Effect of some chelating ligands on the potential response of the chalcocite copper ion-selective electrode

The effects of diethylenetriamine, triethylenetetramine, tetraethylenepentamine, aminoacetic acid, iminodiacetic acid, nitrilotriacetic acid, ethylenediaminediaminetetraacetic acid, diethylenetriaminepentaacetic acid and triethylenetetraminehexaacetic acid on the behaviour of the synthetic chalcocite (copper(I) sulphide) copper-selective electrode are described. The effects of those ligands on the electrode response at different pH values is explained on the assumption that copper(I) ions contribute to the potential indicated. Copper(I) ions originate from the membrane phase and participate in exchange and redox reactions. The effects of oxygen and temperature are reported. The electrode response can be predicted on the basis of copper(II) equilibria in solution, only if the conditions are such that there is no interference from copper(I) ions.     

Effect of environmental conditions on 109Cd(II) sorption to MnO2

The sorption of Cd(II) from aqueous solution on MnO₂ was investigated under ambient conditions. Experiments were carried out as a function of contact time, solid content, pH, ionic strength, foreign ions, fulvic acid and temperature. The results indicated that the sorption of Cd(II) was strongly dependent on pH and ionic strength. At low pH, the sorption of Cd(II) was dominated by outer-sphere surface complexation and ion exchange with Na⁺/H⁺ on MnO₂ surfaces, whereas inner-sphere surface complexation was the main sorption mechanism at high pH. The Langmuir, Freundlich and Dubinin–Radushkevich models were used to simulate the sorption isotherms at three different temperatures. The thermodynamic data (ΔG ⁰, ΔS ⁰, ΔH ⁰) calculated from the temperature dependent sorption isotherms suggested that the sorption of Cd(II) on MnO₂ was an spontaneous and endothermic process.     

Effect of nano-filler dispersion on the thermal, mechanical and water sorption properties of green environmental polymer

Partially exfoliated nanocomposite（2） has been synthesized by intercalation of poly（propylene carbonate）（PPC） into commercial clay,Cloisite 20B（PPC/C-20B）.Nanocomposite 2 was characterized phiso-chemically and exhibited high thermal,mechanical and anti-water sorption properties as compared to PPC and intercalated nanocomposite（1） of PPC/C-20B having same amount of clay.TGA results revealed that the thermal decomposition temperature(T_d,50%) of 2 increased significantly,being 40 K and 17 K higher than that of pure PPC and 1,respectively,while DSC measurements indicated that the nano-filler dispersion of 2 increased the glass transition temperature from 21℃to 31℃.Accordingly,2 showed high elastic modulus,hardness and anti-water absorption capacity.These thermal,mechanical and anti-water absorption improvements are of great importance for the application of PPC as packaging and biomaterials.     

Effect of environmental conditions on the sorption of radiocobalt from aqueous solution to treated eggshell as biosorbent

Carbonate hydroxylapatite (CHAP), prepared from eggshell waste, was used to remove ⁶⁰Co(II) from aqueous solutions. The sorption of ⁶⁰Co(II) on CHAP as a function of contact time, pH, ionic strength and foreign ions in the absence and presence of humic acid and fulvic acid under ambient conditions was studied. The sorption of ⁶⁰Co(II) on CHAP was strongly dependent on pH and ionic strength. The thermodynamic parameters (ΔH ⁰, ΔS ⁰, ΔG ⁰) of ⁶⁰Co(II) sorption on CHAP were calculated from the temperature-dependent sorption isotherms, and the results indicated that the sorption process of ⁶⁰Co(II) on CHAP was endothermic and spontaneous. At low pH, the sorption of ⁶⁰Co(II) was dominated by outer-sphere surface complexation and ion exchange with Na⁺/H⁺ on CHAP surfaces, whereas inner-sphere surface complexation was the main sorption mechanism at high pH. Experimental results also indicated that CHAP was a suitable low-cost adsorbent for pre-concentration and solidification of ⁶⁰Co(II) from large volumes of aqueous solutions.     

Influence of some cations on the sorption ability of modified clinoptilolites

The influence of some cations on the exchange ability of chemically treated clinoptilolites has been studied. The natural clinoptilolites were treated by NaOH, NH₄OH, NaCl and KCl. The modified clinoptilolites surface characteristics and ion exchange ability were studied as well.     

Study of uranium sorption and desorption on some Turkish clays

The sorption and desorption of uranium on two different clay samples which are obtained from the deposit located in Turgutlu and Kula have been studied by application of a batch technique. The two types of clay materials are Ca-montmorillonite. The uranium concentration range was between 200–3000 ppm. Experimental procedures are outlined and results for uranium contacted with montmorillonite are reported and discussed. The sorption/desorption isotherms were reversible and non-linear for this concentration range. The relative importance of test parameters e.g., pH, clay particle size, temperature, ground water composition, contact — time, solid/water ratio which require definition in order to arrive at meaningful distribution coefficients were carried out. The sorption coefficients varied between 0.65–1.45 and 0.45–1.14 for Kula clay and for Turgutlu clay, respectively. The data could be fitted to Freundlich and Langmuir isotherms. The quantity of the sorbed and desorbed uranium ions was much lower than its theoretical CEC's. This was attributed to a blocking of montmorillonite's CEC by uranium islands sorbed in interlayer. The results have shown that the test parameters can have a marked effect on sorption and the present work provides further evidence of the need to take account of the presence of such materials in safety assessment modeling.     

The sorption of some radiocations on microporous titanosilicate ETS-10

The microporous titanosilicate ETS-10 synthesized from gel with following molar composition: 1.0 Na₂O: 1.49 SiO₂ : 0.2 TiO₂ : 0.6 KF : 1.28 HCl : 39.5 H₂O was subjected to sorption of radioactive cations ¹¹⁵Cd²⁺, ²⁰⁴Hg²⁺, ⁶⁰Co²⁺ and ¹³⁷Cs⁺ (M) from aqueous solution, in the absence of ionic competition. The uptake of these cations on the ETS-10 was compared by means of the distribution coefficient (K_d) versus contact time and sorption capacity (R) at equilibrium. The FT-IR spectra of M-ETS-10 sorption products exhibit a modification of the absorption band, principally at 381 cm^-1.     

Studying the sorption kinetics on peat ions of iron(III) and copper(II) from wastewater

The sorption kinetics on the peat of copper(II) and iron(III) ions from model solutions are studied. The sorption process takes place quickly and is almost complete after 20 minutes. Based on the processing of the experimental absorption curves of the equations of chemical kinetics and diffusion it is established that the sorption process is in the diffusion mode. The stage of the chemical interaction of the metal ions with the functional groups of peat also contributes to the overall speed of the process. The efficiency of the sorption process is determined and the possibility of Using peat as a sorbent for purifying wastewater from the copper( II) and iron(III) ions at industrial sites is shown.     

Effects of some complex-forming ligands on the potential of antimony pH-sensors

The E vs. pH relationship for oriented monocrystalline antimony electrodes was studied in various ionic media, containing no buffer or one of several common buffer substances, and the stability of the electrode potential with time was investigated. Several makes of commercially available polycrystalline antimony electrodes were also studied. The results indicate that tris(hydroxymethyl)aminomethane may be used for calibration of antimony electrodes, but most other commonly used buffer substances, e.g., orthophosphate, yield erroneous results. Monocrystalline antimony electrodes are preferable to polycrystalline ones, especially when measurements are made in unstirred solutions. The long-term stability of monocrystalline electrodes is superior to that of polycrystalline ones.     

Strontium and cesium sorption of some Anatolian zeolites

Zeolite samples of Tertiary age obtained from different areas of Anatolia (Turkey) are classified as Clinoptilolite, Analcime or Heulandite and we have investigated their sorption capacity for Cs⁺ and Sr²⁺ ions from aqueous solutions. Quantitative analysis of the zeolite samples untreated and treated with chloride salts of Cs⁺ or Sr²⁺ in aqueous solutions, for Na, Mg, Al, Si, P, K, Ca, Ti, Mn and Fe were performed using EDXRF. Chemical analysis indicated that the Clinoptilolite type zeolite from the deposits of Cankiri-Corum Basin of Anatolia is the best sorber for Sr and Cs ions.Presented at the Sixth International Seminar on Inclusion Compounds, Istanbul, Turkey, 27–31 August, 1995.     

Effect of carbon support on the hydrogen sorption of platinum

The hydrogen sorption of carbon-supported platinum catalysts, studied by the potentiodynamic method, differs significantly from that of unsupported platinum. The difference depends on the preparation method and on the nature of the support. Possible explanations are suggested as (i) some kind of interaction between metal and support atoms during impregnation, (ii) high dispersity (amorphous structure) and (iii) hydrogen spillover onto the carbon support.

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Pt/C, . . (I) , (II) ( ), (III) .

     

Effect of peat humus acids on the structure of sizing starch gels

Influence of peat humus acid microadditions on the structure of starch gels for sizing cotton yarn is studied by rheology.     

Impact of environmental conditions on the sorption behavior of 60Co(II) on illite

In this work, a naturally occurring illite was characterized by using FT-IR and XRD technique to determine its surface functional groups and crystal structure. Sorption of ⁶⁰Co(II) on illite as a function of contact time, pH, ionic strength, foreign ions, humic substances and temperature was studied under ambient condition using batch technique. The results indicated that the sorption of ⁶⁰Co(II) on illite is strongly affected by pH values (2–9) and ionic strength. A positive effect of humic substances on ⁶⁰Co(II) sorption was found at pH < 7.0, whereas a negative effect was observed at pH > 7.0. At low pH, the sorption of ⁶⁰Co(II) was dominated by outer-sphere surface complexation and ion exchange with Na⁺/H⁺ on illite surfaces, whereas inner-sphere surface complexation was the main sorption mechanism at high pH. The Langmuir and Freundlich models were used to simulate the sorption isotherms of ⁶⁰Co(II) at three different temperatures of 298.15, 323.15 and 343.15 K. The thermodynamic parameters (ΔH ⁰, ΔS ⁰ and ΔG ⁰) calculated from the temperature dependent sorption isotherms indicated that the sorption process of ⁶⁰Co(II) on illite was endothermic and spontaneous.     

Impact of environmental conditions on the sorption behavior of Pb(II) onto attapulgite

This paper examined the application of attapulgite as an adsorbent for the removal of Pb(II) from heavy metal-contaminated water under various conditions. The sorption results indicated that the sorption of Pb(II) on attapulgite was strongly dependent on ionic strength at pH < 7.0. Outer-sphere surface complexation or ion exchange may be the main sorption mechanism of Pb(II) on attapulgite at low pH values. No drastic difference of Pb(II) sorption was observed at pH 7.0–10.0, and the sorption at pH > 10.0 was mainly dominated by inner-sphere surface complexation. The sorption of Pb(II) on attapulgite was affected by foreign ions in solution at pH < 7.0, and was not affected by foreign ions at pH > 7.0. The thermodynamic parameters (ΔH°, ΔS° and ΔG°) were evaluated from the temperature-dependent sorption isotherms, and the results indicated that the sorption process of Pb(II) on attapulgite was spontaneous and endothermic in nature.     

NMR elucidation of some pentacycloundecane derived ligands

The complete NMR elucidation of four pentacycloundecane (PCU) derived ligands is reported. 2D NMR techniques are used to overcome the problem of major overlapping of methine signals on the cage skeleton. One of the cage ligands is chiral and the ¹³C NMR signals of the leucinol side “arms” to the cage appear to be split into two or more peaks indicating either impurities or conformational differences. Impurities were ruled out and the only logical explanation for this unusual observation appears to be conformational effects due to different positions of the two relative bulky side chains or “arms”. The rigid cage skeleton is known for through space deshielding of signals in close proximity to oxygen atoms attached to the cage skeleton. The leucinol side chains in closer proximity to the cage ether bridge would experience a larger shielding effect causing those carbon atoms to be shifted upfield with respect to the corresponding atoms in other conformations. The intrinsic chiral nature of the cage could also play a role in this case to perhaps enhance the observed effect. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Water vapor sorption and desorption behavior of some keratins

Summary Sorption and desorption isotherms of water vapor in a number of keratin substrates including excised human stratum corneum, guinea pig and neonatal rat corneum and human hair have been obtained and the data compared to the information available on wool. An attempt was made to analyze the data according to the BET and D'Arcy-Watt equations, Flory-Huggins polymer solution theory and Zimm's clustering function. The results suggest strong binding between the sorbate and keratins in the low relative vapor pressure range, reflecting a sorption process on primary reactive sites (Langmuir) which proceeds up to 0.2-0.3 relative vapor pressure. More confirmation is obtained from isosteric heat of sorption measurements. Extensive clustering and multilayer formation occur in the higher relative vapor pressure range.With 10 figures