首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 31 毫秒
1.
Electrospinning is recognized as a simple and easy method to produce fibers with nanoscale diameters. However, the methods for controlling the shape, structure, and uniformity of electrospun fibers have not yet been fully investigated. In this research, the electrospinning jet behavior, corresponding nanofiber deposition, and average fiber diameter are examined for various nozzle diameters. Fluctuations in the sequence of drop growing, electrospinning, and/or termination of electrospinning are analyzed. We propose two different fluctuations according to nozzle diameter. The multi-jet ejections, that are closely related to the amount of nanoweb deposition and the deposition pattern, are explored.  相似文献   

2.
In this study, we describe the first reported preparation of rosin in fiber form through use of an electrospinning technique utilizing various solvent systems. The polymer concentration of the formed fiber was studied by using various solvents such as chloroform, ethanol, N-N dimethylformamide (DMF), tetrahydrofuran (THF), acetone, and methylene chloride (MC). An electrospray of the solution resulted in the beaded form of the rosin. By varying the polymer concentration with MC, we were then able to obtain uniform fibers. However, the fibers exhibited large diameter. We believe that it is possible to reduce the diameter of the rosin fibers through appropriate selection of electrospinning parameters. In addition, the morphological transitions from beads, to beaded fiber, to fiber were studied at different polymer concentrations. We propose a possible physical cross linking mechanism for the formation of rosin fibers during the electrospinning process. Our results demonstrate the feasibility of producing fiber nanostructures of rosin by using an electrospinning technique.  相似文献   

3.
Yang X  Li L  Yuan L  Li S  Luo S  Liu Y  Peng L 《Optics letters》2011,36(23):4656-4658
We introduce the electrospinning method into fabricating oxygen-sensitive submicrometer scale optical fiber. Uniform tris (4,7-diphenyl-1,10-phenathroline) ruthenium(II) dichloride ([Ru(dpp)(3)](2+)Cl(2))-doped fibers with a diameter of 900 nm are obtained by electrospinning the organic silicon sol solution derived from tetraethyl orthosilicate and n-Octyltriethoxysilane (C(14)H(32)O(3)Si). The experimental results show that the single gel fiber exhibits excellent optical and sensing properties. A laser with a wavelength of 452 nm can be efficiently launched into the fiber and guide along the fiber to excite the fluorescence. Then, we find that [Ru(dpp)(3)](2+)-gel fiber has favorable optical and sensing characteristics, and the Stern-Volmer plots are linear in the full concentration range of O(2) (0-100 vol.?%). The ratio of I(0)/I(100), where I(0) and I(100) respectively represent the fluorescence intensities of the fiber exposed to 100% N(2) and 100% O(2), as the sensitivity of the fiber is 3.5. Simultaneously, the fiber can make a quick response within 100 ms. This method provides an effective and convenient way to fabricate highly uniform nanoscale or microscale optical waveguides for photonic devices.  相似文献   

4.
Electrospinning, a technology capable of fabricating ultrafine fibers (microfibers and nanofibers), has been investigated by various research groups for the production of fibrous biopolymer membranes for potential medical applications. In this study, poly(hydroxybutyrate-co-hydroxyvalerate) (PHBV), a natural, biocompatible, and biodegradable polymer, was successfully electrospun to form nonwoven fibrous mats. The effects of different electrospinning parameters (solution feeding rate, applied voltage, working distance and needle size) and polymer solution properties (concentration, viscosity and conductivity) on fiber diameter and morphology were systematically studied and causes for these effects are discussed. The formation of beaded fibers was investigated and the mechanism presented. It was shown that by varying electrospinning parameters within the processing window that was determined in this study, the diameter of electrospun PHBV fibers could be adjusted from a few hundred nanometers to a few microns, which are in the desirable range for constructing “biomimicking” fibrous scaffolds for tissue engineering applications.  相似文献   

5.
A poly(amic acid) (PAA) solution in xylene was prepared for electrospinning in order to fabricate fibers. However, jet breaking occurred at the point of the occurrence of whipping instability, resulting in forming micro-particles. This was an exceptional jet behavior compared with the general electro-spraying process that occurs directly from the surface of the polymer droplet. It is important to understand the mechanism of electrospinning and the instability of PAA in order to form fibers for mat deposition. Thus, the behavior of the jet breaking was clearly observed by a high-speed camera and the dynamic behavior of the jet was explored by an image analysis technique. Furthermore, polyacrylonitrile (PAN) was added to the PAA/xylene solution with various concentrations to change the elongation viscosity. Uniform diameter fibers were obtained by increasing the content of PAN to the level that the drag force between the polymer chains increased enough to overcome the drawing force. As a result the optimum content ratio of the PAA/PAN mixed solution to obtain the desired fiber spinning and deposition was determined as being 5:5.  相似文献   

6.
Electrospinning is a straightforward method to produce micro/nanoscale fibers from polymer solutions typically using an operating voltage of 10 kV–30 kV and spinning distance of 10 cm–20 cm. In this paper, polyvinyl pyrrolidone (PVP) non-woven nanofibers with diameters of 200 nm–900 nm were prepared by low-voltage near-field electrospinning with a working voltage of less than 2.8 kV and a spinning distance of less than 10 mm. Besides the uniform fibers, beaded-fibers were also fabricated and the formation mechanism was discussed. Particularly, a series of experiments were carried out to explore the influence of processing variables on the formation of near-field electrospun PVP nanofibers, including concentration, humidity, collecting position, and spinning distance.  相似文献   

7.
A simple and low-cost method is suggested to fabricate nanochannels via Near-Field Electrospinning (NFES). In this process, orderly and patterned nanofibers direct-written by NFES are used as sacrificial templates. Well-defined nanochannels are available after the removal process of both sacrificial fibers and material coating over the fibers. The sacrificial fiber, controlled by NFES, dominates the channel geometry. The channel width ranges from 133 nm to 13.54?μm while the applied voltage increases from 1.2 kV to 2.5 kV. Complicated wave-shape and grid pattern channels are presented under a corresponding movement of substrate. This method integrates electrospinning with conventional MEMS fabrication technology and has a potential in micro/nano manufacturing.  相似文献   

8.
Elastin isolated from fresh bovine ligaments was dissolved in a mixture of 1,1,1,3,3,3-Hexafluoro-2-propanol and water were electrospun into fiber membranes under different processing conditions. Fiber mats of randomly and aligned fibers were obtained with fixed and rotating ground collectors and fibrils were composed by thin ribbons whose width depends on electrospinning conditions; fibrils with 721 nm up to 2.12 μm width were achieved. After cross-linking with glutaraldehyde, α-elastin can uptake as much as 1700 % of PBS solution and a slight increase on fiber thickness was observed. The glass transition temperature of electrospun fiber mats was found to occur at ~80 °C. Moreover, α-Elastin showed to be a perfect elastomeric material, and no mechanical hysteresis was found in cycle mechanical measurements. The elastic modulus obtained for random and aligned fibers mats in a PBS solution was 330±10 kPa and 732±165 kPa, respectively. Finally, the electrospinning and cross-linking process does not inhibit MC-3T3-E1 cell adhesion. Cell culture results showed good cell adhesion and proliferation in the cross-linked elastin fiber mats.  相似文献   

9.
黄军超  汪凌珂  段怡菲  黄亚峰  刘亮  李唐 《物理学报》2019,68(5):54205-054205
光纤热噪声是限制光纤传感、测量系统性能的最终因素.但是低频区域呈1/f谱特性的光纤热噪声的形成机制迄今仍然存在争论.实验研究了光纤1/f热噪声水平与光纤内杂质离子浓度和光纤施加张力的关系,验证了这类热噪声来源于光纤内部的机械耗散引起的长度自发抖动,符合热机械噪声的理论假设.  相似文献   

10.
In recent years drug-loaded nanofibers prepared using solution electrospinning methods have been actively studied. However, there are a number of problems connected to their solution electrospinning with respect to medical applications because of the hazards associated with the residual solvents. To avoid the use of solvents in this study we prepared and evaluated drug-loaded polylactide (PLA) fiber webs using a laser-electrospinning (LES) type of a melt electrospinning process. The structures and properties of the obtained drug-loaded PLA fiber webs were evaluated by scanning electron microscopy, fluorescence microscopy, wide-angle X-ray diffraction and UV–vis spectrometry. As shown by the various characterization techniques, we employed LES to prepare PLA nanofiber webs with average fiber diameters of 4.21 and 0.67?μm. Additionally, the webs were loaded with argatroban, a thrombin inhibitor, resulting in amorphous structures for both the argatroban and the PLA matrix. An in-vitro investigation of the drug release behavior of the webs revealed that higher release rates occurred for the fiber samples with the small fiber diameters, particularly in comparison with melt spun fibers with an average diameter of 150?μm. Overall, we expect that the herein described drug-loaded PLA nanofiber webs can be applied as medical materials with drug delivery system functions.  相似文献   

11.
易军 《物理学报》2017,66(17):178102-178102
将块体材料制备成微纳米纤维时,其力学性能会得到进一步的提高,甚至具备块体材料所没有的力学行为.非晶态材料可经过熔体拉丝一次性成型而得到所需尺寸的均匀纤维,纤维表面质量好,其制备过程相对简单且节能.由于非晶材料短程有序、长程无序的结构,具备优异的力学性能,所以非晶纤维有着广泛的应用前景和基础研究价值.本文对能制备成非晶纤维且有优异力学性能的材料做了简单介绍,对非晶纤维的制备方法及其成型物理机制、非晶纤维的力学行为及其物理机制进行了综述,最后总结了非晶纤维的制备和力学行为的研究中存在的问题,对非晶纤维的发展前景做了展望.  相似文献   

12.
Electrospinning is regarded as an effective method to generate nanoscale fibers. However, we believe that the mechanism of the formation of nanoscale fibers by Electrospinning has not yet been fully investigated. In this study, the jet behavior under various conditions was observed with a high-speed camera with short exposure periods. The behaviors of stable and unstable jets were compared. The effect of bending instability on the deposition pattern of jets was examined at different voltages and concentrations. In addition, the diameters of nanoscale fibers were analyzed as a function of sampling position.  相似文献   

13.
Ultrafine fibers were electrospun from Polyacrylonitrile and N,N-dimethylformamide solution to be used as a precursor for carbon nanofibers. An electrospinning set-up was used to collect fibers with diameter ranging from 104 nm to 434 nm. Morphology of fibers and its distribution were investigated by varying Berry's number, charge density, spinning angle, spinneret diameter and collector area. A more systematic understanding of process parameters was obtained and a quantitative relationship between electrospinning parameters and average fiber diameter was established by using response surface methodology. It was concluded that; Berry's number, charge density and spinneret diameters played an important role to the diameter of nanofibers and its standard deviation. Spinning angle and collector area had no significant impact. Based on response surface methodology the optimum Polyacrylonitrile average fiber diameter of 280 nm and 28 nm standard deviation, were collected at 1.6 kV/cm charge density, 8 Berry's number and 0.9 mm spinneret diameter.  相似文献   

14.
Electrospun nanofibers with designed or controlled structures have drawn much attention. In this study, we report an interesting new closed-loop structure in individual cerium nitrate/polyvinyl alcohol(Ce(NO_3)_3/PVA) and Na Cl/PVA fibers,which are fabricated by electrospinning with a nail collector. The electrospinning parameters such as voltage and Ce(NO_3)_3(or Na Cl) concentration are examined for the formation of the closed-loop structure. The results suggest that the increase of the spinning voltage or addition of Ce(NO_3)_3(or Na Cl) is favorable for the formation of the closed-loop structure, and the increase of loop numbers and the decrease of loop size. Further analyses indicate that the formation mechanism of the closed-loop fibers can be predominantly attributed to the Coulomb repulsion in the charged jets.  相似文献   

15.
It has been successfully developed by the electrospinning technology that AgCl nanoparticles were incorporated into polymer fiber. In this paper, we chose poly(vinyl pyrrolidone) (PVP) because it was not only a good material for electrospinning but also it was excellent capping reagent of various metal nanoparticles. The silver ions interacted with the carbonyl groups in the PVP molecules. The formation of AgCl nanoparticles inside the PVP were carried out via the reaction of silver ions and HCl. TEM proved that most of the AgCl nanoparticles were uniformly dispersed in the PVP fibers.  相似文献   

16.

The fiber spinning technique of electrospinning has been optimized in order to prepare unidirectionally aligned and structurally oriented fibers. For this paper, we designed a new device based on a 2D period collector fabrication and electrostatic fields analysis to obtain a large area latticework fibers pattern. The pattern was composed of polyvinylpyrrolidone (PVP)‐based sub‐micron fibers with diameters ranging from 910 nm to 1300 nm, which have potential applications in tissue cell cultures.  相似文献   

17.
We developed a temperature-controlled electrospinning apparatus specially for the polymers/IL system with high viscosity and surface tension and investigated the electrospinning of polyacrylonitrile (PAN)/1-butyl-3-methyl-imidazolium bromide ([BMIM][Br]) solutions. The rheological behaviors, surface tensions and conductivities of PAN/[BMIM]/[Br] solutions at different temperatures indicated that appropriately increasing the temperature is beneficial to their spinnability. It is also shown that PAN/[BMIM]/[Br] with a concentration of 3 wt%, 4 wt% and 5 wt% can be electrospun to fibers by increasing their temperatures to 70°C, 75°C or 85°C, respectively. A rotating drum composed of a dacron mesh was used as a collector in order to avoid the contraction of the wet fibers. This present study provides an alternative method for electrospinning polymer fibers.  相似文献   

18.
We present the synthesis, magnetic and UV spectrometry of NiZn-ferrite nanofiber. The single phase of spinel ferrite was obtained at 600 °C. The NiZn-ferrite fibers fabricated by an electrospinning process were formed as a polygonal grain growth with firing temperature in fiber matrix. It appeared that the saturation magnetization (MS) of NiZn-ferrite nanofiber was dependent on Ni/Zn molar ratio which is similar to that of the inverse spinel ferrites. The NiZn-ferrite fibers showed good DNA adsorption efficiency that can be modified and utilized for DNA separation with magnetic nanofiber as a novel material in clinical applications.  相似文献   

19.
《Composite Interfaces》2013,20(8):775-788
The incorporation of nanotube-covered fibers in continuous fiber/epoxy composites has been shown to influence the mechanical, electrical, and thermal properties of the composite. Increased interlaminar shear stress, flexural strength and modulus have been reported in such composites over composites containing bare fibers. In this study, the microstructure and interfacial shear strength (ISS) of continuous silicon carbide fiber/epoxy composites with and without nanotubes grown from the SiC fiber surface were investigated with micro-Raman spectroscopy (MRS) and microscopy. The fibers with nanotubes grown from the surface were found to have a reduced ISS compared with the bare fibers. Electron microscopy showed good wetting of epoxy in the nanotube forests, but poor attachment of the nanotube forests to the fibers. These results suggest that the mechanism leading to improvements in bulk composite properties is not due to an improvement in the fiber/matrix ISS.  相似文献   

20.
This paper presents an investigation regarding poly(vinyl alcohol)/zirconium acetate (organic–inorganic) (PVA/Zrace) nanofibers prepared by electrospinning which could be used as a precursor for fabricating ceramic metal oxide nanofibers. The effect of some processing variables, including polymer solution concentration, tip to collector distance and applied voltage of electrospinning, and the amount of Zrace and their interactions, on the diameter of the nanofibers were studied. Taguchi experimental design and a statistical analysis (ANOVA) were employed and the relationship between experimental conditions and yield levels determined. It was concluded that to obtain a narrow diameter distribution as well as maximum fiber fineness, a polymer concentration of 10 wt%, tip to collector distance of 18 cm and applied voltage of 20 kV variables were the optimum. Furthermore, it was also concluded that the ratio of Zrace (6 g) to PVA solution (10% wt) played an important role for achieving the minimum fiber diameter. Under these optimum conditions, the diameters of the electrospun composite fibers ranged from 86 nm to 381 nm with a diameter average of 193 nm. The experiments were done with Qualitek-4 software with “smaller is better” as the quality characteristics. The optimized conditions showed an improvement in the fibers diameter distribution and the average fibers diameter showed good resemblance with the result predicted using the Taguchi method and the Qualitek-4 software. The ANOVA results showed that all factors had significant effects on the fibers diameter and distribution, but the effect of PVA concentration and zirconium acetate were more significant than the other factors.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号