常压下液氮窄缝池沸腾实验研究

采用玻璃钢 (FRP)制成的矩形窄缝 ,对三种不同的间隙尺寸 ,分加热面与水平面呈 0°,4 5°,90°,135°,180°五种角度 ,以液氮为工质进行了 15组池沸腾实验。得出结论 :液氮在窄缝中的沸腾传热有明显的强化换热效果 ;加热面所处角度不同 ,在相同热负荷下壁面过热度亦不同 ,滑移汽泡和微液膜蒸发机理在通道中发挥的作用也相应不同。该研究对于有限空间传热强化的机理和实际应用都有一定的参考价值和指导意义。     

Temperature dependence of the elastic modulus of crystalline regions of Poly(ethylene terephthalate)

The temperature dependence of the elastic modulus E₁ of crystalline regions of poly(ethylene terephthalate) (PET) in the direction parallel to the chain axis has been investigated by x-ray diffraction. The axial chain contraction coefficient is constant from 25°C to 200°C, and correspondingly the value of E₁ (108 GPa) remain unchanged up to 215°C. This is in contrast with the temperature dependence of E₁ values of various polymers previously reported. It is considered for PET that the axial thermal molecular motions which cause the decrement of E₁ do not take place in the crystalline regions, and that the force constant of bond stretching and that of bond angle bending are constant over both the temperature and the stress range studied. It is reasonable to conclude that the mechanical structure of drawn PET is composed of the series model.     

Abnormal residual stress in nanostructured Al thin films grown on Ti/glass substrates

The residual stress and micro-structural properties of nanostructured Al thin films prepared by electron beam evaporator are studied. The films were grown on Ti/glass substrates at normal and oblique angles of inclination. The average aspect ratio of Al nanorods produced at an oblique angle of incidence of 85°, increased from 2.2 to 6.0, as the thickness of the films increased from 100 nm to 600 nm. The column tilt angle of Al nanorods was observed to be in close agreement with the theoretical value. The XRD pattern of nanostructured Al thin films showed (111) planes oriented parallel to the substrate surface. The crystallite size was observed to be ～9 nm for all the films produced at oblique angle deposition (OAD). Abnormal residual stresses were determined in the films produced at OAD. The nanocrystalline films produced at normal angle, exhibited tensile residual stress, while, the residual stresses in the films produced at oblique angles of inclination (α = 65°, 75°), were observed to be compressive. Residual stress-free nanocolumnar Al films (Al nanorod films) were observed, when they were grown at an oblique angle of inclination of 85°.     

Track revelation and optical properties of pentaerythritol tetrakis (allyl carbonate) plastic for application as nuclear track detector: effects of gamma radiations

The etching conditions of an indigenously prepared thin film of pentaerythritol tetrakis(allyl carbonate) (PETAC) were standardised for the use as a nuclear track detector. The optimum etching times in 6?N NaOH at 70°C for the appearance of fission and alpha tracks recorded in this detector from a ²⁵²Cf solid source were found to be 30 min and 1.50?h, respectively. The experimentally determined values for the bulk and track-etch rates for this detector in 6?N NaOH at 70°C were found to be 1.7?±?0.1 and 88.4?±?10.7?µm/h, respectively. From these results, the important track etching properties such as the critical angle of etching, the sensitivity and the fission track registration efficiency were calculated and compared with the commercially available detectors. The activation energy value for bulk etching calculated by applying Arrhenius equation to the bulk etch rates of the detector determined at different etching temperatures was found to be 0.86?±?0.02?eV. This compares very well with the value of about 1.0?eV reported for most commonly used track detectors. The effects of gamma irradiation on this new detector in the dose range of 200–1000?kGy have also been studied using bulk etch rate technique. The activation energy values for bulk etching calculated from bulk etch rates measurements at different temperatures were found to decrease with the increase in gamma dose indicating scission of the detector due to gamma irradiation. The optical band gap of this detector was also determined using UV–visible spectrometry and the value was found to be 4.37?±?0.05?eV.     

Heat transfer performance of a toluene loaded two-phase thermosyphon

Large dimension thermosyphons are efficient heat transfer components in heat recovery systems. Their performance limits depend on the following parameters: geometrical (length, diameter, inclination angle), physical (fluid, fill charge), thermal (temperature, heat flux).An experimental investigation was carried out with a large dimension, closed, two-phase thermosyphon which correspond to a device used in industrial recuperators. A vertical or inclinded steel thermosyphon, 3 m long and 27 mm inner diameter, was tested at temperatures varying from 100°C to 300°C with toluene as the working fluid. The lower part of the pipe was electrically heated along a variable length and the upper zone was cooled with an air stream whose flow rate and temperature were controlled. The maximum heat flux was measured as a function of temperature for different liquid fill charges and inclination angles. From these experimental data, boiling and condensation heat transfer coefficients were deduced. It was observed that the critical heat flux depends little on the fill ratio unless the charge is less than 20% for which a local dry-out occurs. The optimal fill charge was found to be between 20% and 50%. Experimental data have been compared with existing theories. The inclination effects have been taken into account with an empirical formula.     

Neutron diffraction study of ammonium tartrate (NH4)2C4H4O6

A neutron diffraction study of ammonium tartrate has been carried out. Using the diffractometer in symmetrical setting, intensities of 750 reflections have been measured. The positions of all the hydrogen atoms have been determined. A good agreement is noticed between the present neutron and the earlier x-ray heavy atom parameters. The tartrate ion consists of two nearly identical planar halves, with an interplanar angle of 62°. Tre structure is stabilized by a net-work of hydrogen bonds. Details of hydrogen bonding and the ammonium ions environment are discussed.     

Flow patterns and heat-transfer characteristics of a top heat mode closed-loop oscillating heat pipe with check valves (THMCLOHP/CV)

The aim of this research was to investigate the flow patterns and heat transfer of a top heat mode closed-loop oscillating heat pipe with check valves (THMCLOHP/CV). In this study, the heat pipe was made of a high-quality glass capillary tube with an inner diameter of 2.4 mm bent into 10 meandering turns. The number of check valves was 2 and the tube was filled with R141b at a filling ratio of 50% of internal volume of the tube. The combined lengths of the evaporator, adiabatic and condenser sections were equal to 50 mm. The pipe was operated at the top heat mode, and the angles of inclination were 20°, 40°, 60°, 80°, and 90°. The heat applied at the evaporator section was controlled at 85°Cto 105°C, and 125°C. The results show that in the evaporator section, bubbles are produced and grow as a result of the continuous nucleate boiling. They coalesced and their volume expanded. Similarly, in the condenser section the vapor plug condensate caused the bubbles to collapse and accumulate as a liquid mass at the lower section of the U-bend tube. A new slug then developed and the bubbles coalesced in an upward flow. Heat flux increased when the evaporator temperature and inclination angle increased causing the average length of the vapor plug to decrease and the average velocity of vapor plug to increase. The maximum heat flux occurred at an evaporator temperature of 125°C and an inclination angle of minus 90°.     

冲击下花岗岩界面动态摩擦特性实验研究

 为研究岩石界面动态摩擦性能,对房山花岗岩进行了冲击速度42.2~130.6 m/s、倾斜角为20°和30°的横剖试样斜撞击实验。倾斜角为20°的为对比实验,研究不发生滑动时的界面性能;在倾斜角为30°的实验中,靶和飞片撞击界面发生相对滑动,用于研究发生界面滑动时的动态摩擦性能。基于此,研究了正应力在317~685 MPa、界面相对滑移速度在2.76~24.88 m/s时花岗岩界面滑动态摩擦状态。其结果可以初步揭示地震过程板块动态摩擦过程摩擦强度急剧降低的现象。     

Turbulent convective heat transfer in an inclined tube filled with sodium

Turbulent free convection of liquid sodium in a straight thermally insulated tube with a length equal to 20 diameters and with end heat exchangers ensuring a fixed temperature drop is investigated experimentally. The experiments are performed for a fixed Rayleigh number Ra = 2.4 × 10⁶ and various angles of inclination of the tube relative to the vertical. A strong dependence of the power transferred along the tube on the angle of inclination is revealed: the Nusselt number in the angular range under investigation changes by an order of magnitude with a maximum at the angle of 65° with the vertical. The characteristics of large-scale circulation and turbulent temperature pulsations show that convective heat transfer is mainly determined by the velocity of large-scale circulation of sodium. Turbulent pulsations are maximal for small angles of inclination (α = 20°–30°) and reduce the heat flux along the channel, although in the limit of small angles (vertical tube), there is no large-scale circulation, and the convective heat flux, which is an order of magnitude larger than the molecular heat flux, is ensured only by small scale (turbulent) flow.     

The specific heat of bulk amorphous arsenic

The specific heat of bulk amorphous arsenic deposited from the vapor at 415°K has been measured between 1.8 and 20°K. A comparison with compacted amorphous As films deposited at room temperature reveals appreciable differences in the form of C/T³. The results indicate a relative increase in the density of low frequency vibrational modes in the bulk amorphous As. The specific heat measurements support x-ray and Raman scattering studies that suggest variations in the local structure of amorphous As prepared under different deposition conditions. A comparison with neutron scattering measurements in bulk amorphous As also indicates an underestimate of the low frequency density of states.     

Ion-beam modification of track membrane surface

An ion-beam method to modify the track membrane surface is suggested. An ion gun based on a magnetron sputterer is developed. This gun provides ion energies in the range of 5 eV–1 keV, ion current density up to 0.8 mA/cm², and an ion beam aperture of 90 mm. After the track membrane surface has been irradiated by argon ions with an energy of 50–100 eV, the angle of surface-water contact decreases from 65°–75° to 10°–25°. If the irradiating ion energy is 300–800 eV, the angle of contact increases from 65°–75° to 90°–100°.     

Experimental analysis of conical baffles with rifts on heat transfer and pressure drop

In the present study, convective heat transfer to the air from a heating tube attached to conical baffles with rift was experimentally examined. The air entering the test section first contacts the large surface of the conical baffle. Therefore, the conical baffle both directs the air toward the heating surface and increases the heat transfer surface area. In the experiments, baffles with inclination angles of 45°, 60°, and 80° were used. The baffles were placed on the heating tube at the pitch of 15 mm. The temperature of the heating fluid (water) was kept fixed at 65°C. In addition to the riftless baffles, the experiments were carried out by using baffles with a rift spacing of 1.5 and 3.5 mm so that the boundary layer separation mechanism could be accelerated. Experimental results for eight different velocities of airflow (2–20 m/s) were presented. For the inclination angle of 60°, the increase in the heat transfer of the baffle with rift was 13% at a rift spacing of 1.5 mm and 4% at a rift spacing of 3.5 mm according to the riftless baffle. In addition, for the inclination angle of 60°, the pressure drop values of the riftless and the rift spacing of 1.5 and 3.5 mm were almost the same.     

宽角度反射式相位延迟器的设计

金属增强型反射镜在入射光非正入射的时候,两个不同的偏振态之间会产生不同的相移。利用最优技术设计了一种相位延迟器,其工作波长在640-670nm之间,入射角在40-50°范围内时,反射率>99%且相移为90°±20°。波长在670nm附近时相移对入射角不敏感。膜层厚度误差对相移影响最大。     

赫兹型微裂纹光场调制增强作用的系统研究

通过改变裂纹的倾角、宽度和深度参数,模拟了赫兹型裂纹在不同参数下对光场调制能力的不同. 模拟发现,倾斜角度为20.9°到45°之间的裂纹危害最大,倾角大于45°小于48.2°的裂纹危害也十分大,而倾斜角度为45°时的裂纹危害最小. 对于30°倾角的赫兹型裂纹,一定范围内,赫兹型裂纹深度的增加会导致其光场调制增强能力呈二次方关系增加,但宽度的增加不会使其光场调制增强作用增加. 裂纹深度和宽度的增加可以用来近似裂纹的演化过程,所以裂纹的扩展导致了其光场调制能力的增加,进而导致损伤增长速率的加快,这和e指数损伤增长规律相符. 关键词： 损伤增长 亚表面缺陷 赫兹型裂纹 光场增强     

Influence of the plate inclination angle on rivulet formation and breakdown of non-isothermal liquid film

The influence of the plate inclination angle relative to the horizon on a distance between formed rivulets and breakdown of a falling water film was studied experimentally on a heater of 150×150 mm. Dependences of the distance between rivulets on the heat flux density and plate inclination angle were examined. In experiments two zones of influence of the heat flux on a distance between rivulets were revealed: at θ ≥ 20° distances between the rivulets do not depend on the heat flux, and at θ ≤ 15° they decrease with a rise of the heat flux. Data on film breakdown were generalized with consideration of evaporation effect. It is shown that there is almost no effect of inclination angle on film breakdown in the whole range of studied Reynolds numbers. The work was financially supported by the President of RF (No. NSh-6749.2006.8), Russian Foundation for Basic Research (Grants Nos. 05-08-33325-a, 06-01-00360-a) and SB RAS (Interdisciplinary integration project No. 111).     

A Rule Governing Crystallization of Configurationally Directional Polymers: The Crystal Structure of the α and β Forms of Polypivalolactone

A “Rule” is proposed for incorporation of polymer chains having directional configuration, e.g. A‐B‐C‐A‐B‐C, into a crystal. Crystallization into a lamella morphology, as in slow crystallization from the melt, will incorporate antiparallel sequences (↑↓↑↓↑↓). Formation of a fiber by drawing the lamellar morphology must produce a different crystal structure containing parallel directional sequences. The drawn fiber must be polymorphic with a disordered aggregation of antiparallel and parallel crystal polymorphs. An example of this rule is found in the crystal structure of polypivalolactone. The melt crystallized α form is monoclinic, P2₁/c with a=9.05Å, b (fiber axis)=5.97Å, c=11.69Å, β=121.4° and consists of planar antiparallel sequences. The molecular conformation is a folded zig‐zag arrangement. On drawing a fiber, a disordered second phase of parallel plus antiparallel sequences is created. The chain conformation is a slightly distorted extended zigzag. The crystal structure of the directionally disordered β form is metrically monoclinic, with a=5.95Å, b=10.32Å, c (fiber axis)=4.94Å, β=101.3°. Examples of several classes of crystalline polymers demonstrating this Rule are presented.     

Brightness enhancement of slow positron beams

A study on the horizontally LPE-grown La, Ga: YIG films is presented. With the spin wave resonance technique the ratio of the saturation magnetizations of the bulk and transient layer has been measured. The average saturation magnetization was determined by means of a vibrating sample magnetometer and the Ga concentration by x-ray fluorescence analysis. These data are compared with the growth rates of both the transient and the bulk layer. A systematic dependence of the magnetization on the growth rate is found.     

DC conductivity and dielectric properties of maize starch/methylcellulose blend films

The transient current, electrical conductivity, dielectric constant (ε′), and dielectric loss factor (ε″) of starch and methylcellulose homopolymers and their blends with various compositions were studied under different conditions. The x-ray diffraction pattern was obtained for individual polymers and 50:50 wt/wt% blend sample to identify both the structure and degree of crystallinity. From transient current, the ionic and electronic transfer number as well as charge carrier density and drift mobility were determined. The values of activation energy in the temperature range 30–90 °C indicate that the conduction mechanism is due to combined electronic and ionic processes, while in the temperature range 100–160 °C, electronic contribution is predominant. The complex dielectric data of the present samples in an extended frequency and temperature range appear as different relaxation processes, which are connected with polymer dynamics.     

Identification of the polymerized orthorhombic phase of C60 fullerene

It is established by x-ray diffraction and Raman scattering that the polymerization of C₆₀ fullerene at 1.5 GPa and 723 K leads to the formation of an orthorhombic phase that is different from the previously identified high-pressure orthorhombic phase. It is determined by a calculation of the optimal packing of linear C₆₀ polymers by the method of atom-atom potentials that the energetically favorable structure of the orthorhombic phase belongs to the space group P n n m and not the previously proposed group I m m m. The computed value of the rotation angle of the polymer chains that corresponds to the minimum packing energy was equal to 61°. The mechanisms leading to the formation of the polymerized phases are discussed on the basis of the results obtained. Pis’ma Zh. éksp. Teor. Fiz. 66, No. 2, 110–114 (25 July 1997)     

An experimental study on flame geometry and radiation flux of line-source fire over inclined surface

An experimental study was performed on line-source fire over an inclined surface (ground) to simulate downhill fire spread behavior. The flame geometry and the thermal radiation to both far-field surroundings and near-field inclined surface were investigated. As a basic configuration for wildland fire over a slope, the buoyancy induced natural convection flow along the inclined surface and the constraint of air entrainment by the inclined surface change the flame geometry as well as its radiation emission. Various surface (ground) inclination angles (from 0°-80°), fire source heat release rates and fuels were considered comprehensively with a total of 126 test conditions. Results showed that the flame perpendicular height decreased, while both the flame parallel length and base drag length along the inclined surface increased, with the increased inclination angle. A dimensional analysis was then performed based on the controlling mechanisms, with the dimensionless heat release rate, the density ratio of fuel vapor to air, along with sinα and cosα involved to represent the components in the parallel and perpendicular directions. The flame geometry parameters were well represented by the proposed dimensional analysis. Both the radiation fluxes to far-field surroundings and to near-field inclined surface decreased with the increased inclination angle. The far-field radiation was found to be well characterized by a model based on the soot volume fraction analysis according to single point source model. Concerning the near-field radiation to inclined surface, an inclined cuboid radiative modeling was developed. The predicting results by the proposed model and the experimental values showed good agreement. The present study has explained the controlling physics and proposed non-dimensional functions for flame geometry and modeling the downslope radiation of the line-source fire over the inclined surface, which facilitates the understanding of the wildland fire spread behavior over a slopping ground in the downhill direction.