Lactone polymers. V. Viscoelastic properties of poly-ε-caprolactone and poly-ε-thiocaprolactone

The viscoelastic properties of crystalline poly-ε-caprolactone and poly-ε-thiocaprolactone have been characterized and compared by stress relaxation and dynamic mechanical studies. The glass transition temperature of poly-ε-thiocaprolactone was shown to be -40°C at 1 Hz and appeared to be independent of the degree of crystallinity. The rate of viscoelastic relaxation for each polymer was independent of linear strain rate of a decade range. The density of each polymer over a wide temperature range was used to reduce the individual time-dependent modulus values to an arbitrary reference temperature. This reduction of stress relaxation data to a standard mechanical state obviated the requirement of vertical shift factors for construction of the respective master curves. The distribution of relaxation times was correlated with the glass transition and the crystalline melt temperature range for each polymer.     

New data on (γ, n), (γ, 2n), and (γ, 3n) partial photoneutron reactions

Systematic discrepancies between the results of various experiments devoted to determining cross sections for total and partial photoneutron reactions are analyzed by using objective criteria of reliability of data in terms of the transitional photoneutron-multiplicity function F _i = σ(γ, in)/σ(γ, xn), whose values for i = 1, 2, 3, ... cannot exceed by definition 1.00, 0.50, 0.33, ..., respectively. It was found that the majority of experimental data on the cross sections obtained for (γ, n), (γ, 2n), and (γ, 3n) reactions with the aid of methods of photoneutron multiplicity sorting do not meet objective criteria (in particular, F ₂ > 0.50 for a vast body of data). New data on the cross sections for partial reactions on ¹⁸¹Ta and ²⁰⁸Pb nuclei were obtained within a new experimental-theoretical method that was proposed for the evaluation of cross sections for partial reactions and in which the experimental neutron yield cross section σ ^expt(γ, xn) = σ(γ, n) + 2σ(γ, 2n) + 3σ(γ, 3n) + ..., which is free from problems associated with determining neutron multiplicities, is used simultaneously with the functions F _i ^theor calculated within a combined model of photonuclear reactions.     

Zur (γ,p)- und (γ,np)-Reaktion am Argon 40

Argon gas has been irradiated with 34 MeV bremsstrahlung. The yields of the reactions A⁴⁰(γ, p) Cl³⁹ and A⁴⁰ (γ, np) Cl³³ were determined relative to C¹²(γ, n) by β-counting. The resulting upper limits for the cross sections integrated to 28 MeV are 160 MeVmbarns for (γ, p), and 35 MeV mbarns for (γ, np). This does not confirm the anomalously high A⁴⁰ (γ, p)-cross section reported in the literature.     

РЕАКЦИЯ (γ, р) НА ИНДИИ

Иамеряется энергети ческое и угловое расп ределение φотопрото нов из индия, облучаемого γ-квантами с энергией E_γ=17,6 Мэв u 14,8 Мзв. При сравнении энерге тического и углового распределения было о бнару-жено, что значительная час ть протонов образует ся при эвапорации и лишь около 3% прямым φо тоэφφектом. Из энергетического р аспределения найден ы энергии возбуждени я E _β ^* ядра¹¹⁴Cd, 3,8; 4,9; 5,6; 6,3 и. 7,6 Мэв.     

РЕАКЦИЯ (γ, р) НА КОБАЛЬ ТЕ

- , Li(, ) ( =17,6. 14,8 MeV). , u . , gQ=0,74+-0,16 MeV ⁵⁸Fe E ^* : 6,76; 6,44; 5,90; 5,47; 4,98; 4,35; 3,50; 3,20 MeV. , .     

РЕАКЦИЯ (γ, р) НА КАДМИИ И ОЛОВЕ

, , , -. [3], . . , , ; . , . , . , . , , .

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(, p) Reaction on cadmium and tin

A study is made of the nuclear photoeffect on Sn and Cd where, in contrast to most of the experiments with this effect up to now, discrete rays were used. The paper complements paper [3], the experimental arrangement of which it has taken over. Several interesting results were obtained — particularly the discreteness of the energy spectrum and the unconventional form of the angular distribution. With tin, the top proton shell of which is completely occupied, the shape of the energy spectrum corresponds to the Wilkinson theory of gigant resonance; with cadmium the energy spectrum is similar to the evaporation spectrum. The angular distributions of the photoprotons of both elements do not satisfy the commonly used relations corresponding to existing theories of nuclear photoeffect. They can, however, be described quite well by empirical equations which contain associated Legendre polynomials of different orders. With both elements the results have features of both a direct and a collective process. The paper gives results, a satisfactory explanation of which would require a new theory including both types of processes.

     

The isomeric ratios in some photonuclear reactions (γ, n), (γ, p), (γ, 2n), and (γ, np) induced by bremsstrahlungs with end-point energies in the Giant Dipole Resonance region

We have determined the isomeric ratios in photonuclear reactions ¹¹⁶Cd(γ, n)^{115m, g} Cd, ¹³⁸Ce(γ, n)^{137m, g} Ce, ¹⁵³Eu(γ, n)^{152m, g} Eu, ⁹⁶Mo(γ, p)^{95m, g} Nb, ¹¹⁸Sn(γ, p)^{117m, g} In, ⁸⁹Y(γ, 2n)^{87m, g} Y, ¹⁰⁶Cd(γ, np)^{104m, g} Ag, and ¹¹²Sn(γ, np)^{110m, g} In induced by bremsstrahlungs with end-point energies in the Giant Dipole Resonance (GDR) region. The targets were irradiated at electron accelerator Microtron MT-25 of the Flerov Laboratory of Nuclear Reactions, Joint Institute for Nuclear Research, Dubna. Gamma spectra of irradiated samples were measured with a spectroscopic system consisting of 8192-channel analyzer and high-energy resolution (180 keV at gamma ray 1332 keV of ⁶⁰Co) semiconductor detector CANBERRA. The results were discussed and compared with those of other authors. The article is published in the original.     

Pressure-volume-temperature relations of a poly-ε-caprolactam and its nanocomposite

The equation of state of a poly-ε-caprolactam melt, PA-6, of molar mass M _n = 22 kg/mol was investigated in a Gnomix apparatus (Gnomix Inc., Boulder, Colorado) between 300 and 560 K, and pressures up to 150 MPa. Corresponding measurements were performed with addition of 1.6 wt% of montmorillonite exfoliated particles. Reductions in specific volume of about 1.0 and 1.4%, respectively, at 10 and 150 MPa, are observed. For the melt, excellent agreement between experiment and the results from lattice-hole theory is found for both systems. Addition of the nanoparticles reduced the hole (free volume) fraction by 14%. Evidently, the hole fraction is a sensitive indicator of structural changes. It is noteworthy that such a small quantity of added nanoparticles increases the tensile strength by about 14% and modulus by 26%, at a cost of reduction in the elongation at break by about 25%. For a treatment of the PNC, and as an approximation, our earlier model of a particulate composite was adopted. To calculate the binary interaction parameters it was assumed that: (1) the clay particles are in form of flat disks, 100 nm diameter and 1 nm thick; (2) the hard core segments of polymer and of solid occupy the same lattice volume, i.e. v ^* ₁₁ = v ^* ₂₂; (3) the energetic interactions of polymer with solid are given by the geometric average between the two self-interactions. These assumptions lead to the following results ('11' represents polymer-polymer, '22' represents clay-clay and '12' represents polymer-clay interactions): ε ^* ₁₁= 32.09; ε ^* ₁₂ = 313.54 and ε ^* ₂₂ = 3063 (kJ/mol) v ^* ₁₁ = 24.89; v ^* ₁₂ = 33.53 andv ^* ₂₂ = 24.89 (ml/mol)     

Sonochemical degradation of poly- and perfluoroalkyl substances – A review

Poly- and perfluoroalkyl substances (PFAS) have received considerable attention from environmental scientists and engineers because of their stability and widespread. Sonochemical process has been widely used in the environmental field to remove pollutants due to its advantages in terms of operational simplicity, no secondary pollutant formation and safety. Currently, many studies have reported sonochemical degradation of various PFAS in laboratory settings and showed excellent removal potential. This article reviewed the effects of different power densities, ultrasonic frequencies, temperatures, atmosphere conditions, additives, and initial concentration and chemical properties of PFAS on the sonochemical degradation of PFAS. Sonochemical methods combined with conventional techniques for PFAS removal were elaborated as well. Additionally, this article discussed the challenges and prospects of using sonochemical approaches for PFAS remediation.     

Spectral energy characteristics of 6,γ- and 7,γ-dimethyl ethers of chlorine 6 in water-alcohol solutions

Absorption spectra and dispersion of optical rotation (DOR) are measured for monomers of 6,γ- and,7,γ-dimethyl ethers of chlorin e₆ (Ch-6,γ-DME and Ch-7,γ-DME) in 96% ethanol and for associates of them that are polymers and colloidal particles. The optical activity of Ch-6,γ-DME monomers is higher than that of Ch-7,γ-DME monomers, which is linked with more pronounced distortion of the molecular macrocycle for Ch-6,γ-DME in the γ-C₆ local region. The structural and energy parameters of dimeric unit cells of Ch-6,γ-DME and Ch-7,γ-DME polymers are discussed from the standpoint of the Davydov-Tinoko exciton theories. Longwave absorption spectra and DOR are resolved into individual components with the aid of a modified Alentsev-Fock method. Institute of Molecular and Atomic Physics of the National Academy of Sciences of Belarus, 68, F. Skorina Ave., Minsk, 220072, Belarus. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 66, No. 3, pp. 331–337, May–June, 1999.     

γ,p碰撞生两个大P_Tγ的反应截面的QCD预言

我们在γ-p质心系里用微扰QCD方法计算了γ p→2γ_((大P_T))反应的双微分截面(d~2σ)/(dx_Tdx_L),并分析了它的两种可能的背景(γ p→γ q(?)和γ p→γ q(?),文中指出,利用该反应所具备的大_(P_T)光生和直接光子对出射过程的双重特点,可以把这两种背景大大压低,计算结果表明,用QCD预言的γ p→2γ_((大P_T))反应不但具有本底干净的显著特点,而且在相当大的(x_T,x_L)范围内,计算得到的反应截面可以在目前的实验精度下测量。因而,在实验上精确测定此过程,对于检验QCD是有意义的。     

X,γ射线谱仪用的半导体探测器

半导体探测器是六十年代发展起来的一种新型探测器.随着硅、锗单晶性能的提高,硅(锂)[Si(Li )]、锗(锂)[Ge(Li)]及高纯锗[HPGe]探测器的制备工艺日趋完善.与此同时,随着电于学线路的改进,Si(Li),Ge(Li),HPGe探测器及低噪声电子学线路和低温装置所组成的X,γ射线谱仪性能得到迅速提高。逐渐发展成高热率、高能量分辨率的X,γ谱仪,这就使应用γ射线核能谱学增添了新的实验数据,同时使微量及痕量元素分析技术达到了新的水平. 半导体探测器一般又称固体探测器[1],它实质上是由一块半导体材料所组成的电离室.对核谱仪用的探测器的基本要求…     

The influence of the spin-orbital bond on direct photonuclear reactions (γ, n) and (γ, p)

The Courant model for direct photonuclear reactions is modified by using the wave functions of a shell model with spin-orbital bond. It is shown that the introduction of spin-orbital interaction does not influence the cross-section. The changes caused by the spin-orbital bond are apparent only on the angular distribution, which has the Courant forma+bsin² , but with a different value ofb/a, i.e. the anisotropy coefficient. New selection lawsj j, j j±1 are found. The introduction of spin-orbital interaction permits the negative value of the anisotropy coefficient, found in some experimental papers, to be explained in a natural way.

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- - (, n) (, )

: - . , . , - , , a+bsin² , , b/a, . . . j j, j j±1. - , .

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Excerpt from diploma work done at Faculty of Technical and Nuclear Physics in Prague.

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In conclusion the author thanks lecturer J. Kvasnica for the choice of subject and valuable remarks.     

Polarization observables in (γ,NN) reactions

The formalism of ( γ, NN) reactions is given where the incident photon is polarized and the outgoing-nucleon polarization is detected. Sixteen structure functions and fifteen polarization observables are found in the general case, while only eight structure functions and seven polarization observables survive in coplanar kinematics. Numerical examples are presented for the ¹⁶O(γ, np) and ¹⁶O(γ, pp) reactions. The transitions to the ground state of ¹⁴C and ¹⁴N are calculated in a model where realistic short-range and tensor correlations are taken into account for the np pair, while short-range and long-range correlations are included in a consistent way for pp pairs. The effects of the one-body and two-body components of the nuclear current and the role of correlations in cross-sections and polarizations are studied and discussed. Received: 7 June 2001 / Accepted: 26 September 2001     

Two-photon four-level hologram recording in poly-(alkyl-α-cyanoacrylates)

We have investigated the suitability of poly-(alkyl--cyanoacrylates) (p-(alkyl-CAc)) for two-photon four-level holographic recording. It is shown that these materials follow indeed a two-photon four-level mechanism with the second absorption step in the near infrared. Light induces the polymerization of residual monomer in the matrix. The reaction is associated with positive density changes. The sensitivity ofp-(alkyl-CAc) depends strongly on composition and age of the sample. Maximum sensitivities achieved are comparable to the so far best-known two-photon four-level ir-sensitive systems.