Structural organization of syndiotactic polystyrene films crystallized in the α form

Syndiotactic polystyrene films were obtained by melt crystallization in the α form. Samples with different crystallinity were produced by varying the thermal treatment of the melt. The structural organization was analyzed by x rays, transport properties, and Fourier transform infrared measurements. The α form is characterized by chains in zigzag planar conformation; it is transformed in dichloromethane into a crystalline form having the chains in a helical conformation. The vapor activity for this transition was obtained for all the crystalline samples. The fraction of impermeable phase, derived from sorption measurements, was consistently found to be higher than the fraction of crystalline phase derived from x rays. This led to the suggestion that in these samples, besides the crystalline phase, there is also a fraction of mesophase, impermeable to dichloromethane vapors at low activity. At activity higher than a critical value this phase becomes permeable, allowing the conformational transition. At activity a = 1, in liquid dichloromethane, the crystalline phase also becomes permeable, and complete transformation into the helical structure is observed.     

Another representation of the β form of the inhomogeneous Picard-Fuchs equation

In this letter we give another representation of the β form in the inhomogeneous Picard-Fuchs equation for open topological string for some one-parameter Calabi-Yau hypersurfaces in weighted projective spaces. Furthermore, the corresponding domain wall tensions calculated by using these β forms are consistent with the results that appear in literature. The β form is essential for the calculation of the D-brane domain wall tension, and a convenient choice of β forms should simplify the calculation. The freedom of the choice of β forms shows some symmetries in Calabi-Yau space.     

Exact asymptotic form for the β function in quantum electrodynamics

It is shown that the asymptotic form of the Gell-Mann-Low function in quantum electrodynamics can be determined exactly: β(g) = g for g → ∞, where g = e ² is the running fine-structure constant. This solves the problem of electrodynamics at small distances L (for which dependence g ∞ L ^?2 holds) and completely eliminates the problem of “zero charge.”     

Molecular Dynamics of Structural Organization in Binary Fluids with Fixed Particles

We have numerically studied the structural organization in binary immiscible fluids with fixed particles.the particles that have a finite excluded volume and a selective affinity for one fluid component have a significant influence on the organization process,where the hydrodynamic flows induced by the interface motion are suppressed and the domain growth is slowed down at late stages.Two different cases with weak and strong preferential interactions are considered,and the results show that the particles in the former can be left in the unfavourable phase during the process but are permanently surrounded by the favourable phase in the latter.The study indicates that the system would develop into a dynamical steady state and the final domain size might be dependent not only on the number of particles but also on the preferential interaction strength.     

Is the dynamics of polystyrene films consistent with their glass transition temperature?

Experiments in the past 1.5 decades have found that the glass transition temperature of polymer films can be noticeably different from the bulk when the film thickness is decreased below ∼100  nm. On the other hand, many dynamic measurements have found results inconsistent with the observed change in the glass transition temperature. One frequently cited reason is that the dynamic properties being probed may not be directly related to the glass transition. Viscosity is a property traditionally used to characterize the dynamic slowing down occurring to a material at the glass transition. In this paper, we report experimental result showing that the viscosity of polystyrene films supported by oxide-coated silicon decreases with decreasing film thickness, consistent with the observed glass transition temperature of the films.     

Structural origin of perpendicular magnetic anisotropy in Ni–W thin films

The magnetic properties and microstructure of electrodeposited Ni–W thin films (0–11.7 at% W in composition) were studied. The film structures were divided into three regions: an FCC nanocrystalline phase (0–2 at% W), a transition region from FCC nanocrystalline to amorphous phase (2–7 at% W), and an amorphous phase (>7 at% W). In the transition region, (4–5 at% W) films with perpendicular magnetic anisotropy (PMA) were found. The saturation magnetization, magnetic anisotropy field, perpendicular magnetic anisotropy and perpendicular coercivity for a typical Ni–W film (4.5 at% W) were 420 kA/m, 451 kA/m, 230 kJ/m and 113 kA/m, respectively. The microstructure of Ni–W films with PMA is composed of isolated columnar crystalline grains (27–36 nm) with the FCC phase surrounded by the Ni–W amorphous phase. The appearance of the interface between the magnetic core of Ni crystalline grains and the Ni–W non-magnetic boundary layer seems to be the driving mechanism for the appearance of PMA. The origin of PMA in Ni–W films is mainly attributed to the magnetoelastic anisotropy associated with in-plane internal stress and positive magnetostriction. The secondary source of PMA is believed to be the magnetocrystalline anisotropy of 〈1 1 1〉 columnar grains and its shape magnetic anisotropy. It is concluded that Ni–W electrodeposited films (4–5 at% W) may be applicable for perpendicular magnetic recording media.     

Asymptotic Expansion of β Matrix Models in the One-cut Regime

We prove the existence of a 1/N expansion to all orders in β matrix models with a confining, offcritical potential corresponding to an equilibrium measure with a connected support. Thus, the coefficients of the expansion can be obtained recursively by the “topological recursion” derived in Chekhov and Eynard (JHEP 0612:026, 2006). Our method relies on the combination of a priori bounds on the correlators and the study of Schwinger-Dyson equations, thanks to the uses of classical complex analysis techniques. These a priori bounds can be derived following (Boutet de Monvel et al. in J Stat Phys 79(3–4):585–611, 1995; Johansson in Duke Math J 91(1):151–204, 1998; Kriecherbauer and Shcherbina in Fluctuations of eigenvalues of matrix models and their applications, 2010) or for strictly convex potentials by using concentration of measure (Anderson et al. in An introduction to random matrices, Sect. 2.3, Cambridge University Press, Cambridge, 2010). Doing so, we extend the strategy of Guionnet and Maurel-Segala (Ann Probab 35:2160–2212, 2007), from the hermitian models (β = 2) and perturbative potentials, to general β models. The existence of the first correction in 1/N was considered in Johansson (1998) and more recently in Kriecherbauer and Shcherbina (2010). Here, by taking similar hypotheses, we extend the result to all orders in 1/N.     

Peculiarities of α → β transformation in the Pd-In-Ru-H system

A precise X-ray diffractometry method is employed to investigate a Pd-In-Ru alloy foil subjected to electrolytic hydrogenation. It is revealed that an increase in the scattering volume of the sample and its multiphase disintegration are caused by the α → β transformation. The basic characteristics of the given transformation are established.     

Considering collective degrees of freedom in the β decay of odd nuclei

The β decay of around 30 odd nuclei was calculated within the dynamic collective model using expressions for the reduced matrix elements of the weak-interaction Hamiltonian for U-type and V-type β decay obtained earlier by the authors. All of the many-phonon states of the yrast band of an even-even core contributing to the formation of the excited states of nuclei were taken into account. For β transitions with an intensity of >1%, the calculated logft values differ from the experimental values by no more than 0.2.     

Nonperturbative effect in the β functions and the equations of motion for the string

We study systematically how to calculate the β functions nonperturbatively in the sigma model which describes the string propagation in arbitrary background fields. In particular, we calculate explicity the β functions for a tachyon and massless background fields up to the three-string tree interactions and also the four-tachyon tree interactions.     

Electromagnetic form factors of Λ_c in the space-like momentum region

We studied the electromagnetic form factors(EMFFs) of Λ_c and the contributions of the quark and diquark currents to the EMFFs of Λ_c in the space-like region in the Bethe–Salpeter equation approach with instantaneous approximation. In this picture, baryon Λ_c can be regarded as a two-body c(ud) system. We found that for different values of parameters the contribution of quark and diquark currents to the EMFFs of Λ_c is very different,while their total contribution to the EMFFs of Λ_c is similar. The EMFFs of Λ_c are similar to those of other baryons(proton, Ξ~-, and Σ~+) with a peak at ω = 1, where ω = v′·v is the velocity transfer between the initial state(with velocity v) and the final state(with velocity v′) of Λ_c.     

Investigation of the antineutrino angular distribution in experiments on the β decay of polarized neutrons

Since the emission of γ grays unavoidably accompanies β decay, the final state after the β decay of a neutron includes a photon along with a proton, an electron, and an antineutrino, i.e., four particles, rather than three. Therefore, when only the electron and proton momenta are detected and the γ-ray momentum is not detected in an experiment, the antineutrino momentum cannot be uniquely reconstructed, and only its mean value over a γ-ray momentum distribution determined from corresponding calculations can be considered. The γ grays are significant for finding the asymmetry parameter B of the antineutrino angular distribution from experiments on the β decay of polarized neutrons, where the electron momentum p directed along the x axis and the projection of the proton momentum P _x onto the x axis are detected, and the neutron polarization vector ξ is parallel or antiparallel to x. Since the γ rays are not detected in such experiments, the antineutrino kinematics are not uniquely specified by the observables p and P _x and can be reconstructed only on the average, so that the antineutrino momentum distribution averaged over a γ-ray momentum distribution is considered. Thus, the exact value of B cannot be obtained from these experiments, but the true value of B can be estimated on the average by considering the mean (most likely) value 〈B〉 and the dispersion (rms deviation) ΔB. The unavoidable uncertainty in the estimate of B amounts to several percent and is thus significant for present-day experiments, which are intended to obtain the value of B to a very high accuracy of ∼ (0.1–1)%. If electromagnetic interactions are taken into account, measurements of the electron and proton momentum distributions can also be used to obtain g _A, i.e., the axial β-decay amplitude, to high accuracy. Zh. éksp. Teor. Fiz. 116, 1505–1522 (November 1999)     

The parametric orbits and the form invariance of three-body in one-dimension

In this paper, the differential equations of motion of a three-body interacting pairwise by inverse cubic forces(“centrifugal potential”) in addition to linear forces (“harmonical potential”) are expressed in Ermakov formalism in two-dimension polar coordinates, and the Ermakov invariant is obtained. By rescaling of the time variable and the space coordinates, the parametric orbits of the three bodies are expressed in terms of relative energy H1 and Ermakov invariant. The form invariance of the transformations of two conserved quantities are also studied.     

Structural and optical properties of ZnSe x Te1−-x solid solutions in thin-film form

Solid solutions of ZnSe _x Te_1–x (0. 1 x 1) were synthesized by vacuum fusion of stoichiometric proportions of ZnSe and ZnTe. X-ray diffraction data revealed that they have polycrystalline cubic zinc-blende structure. The calculated unit cell lattice constant (a) for the different compositions in powder form vary linearly, with molecular fractionx following Vegard's law:a(x) = 6.165 – 0.485x. Thin films of ZnSe _x Te_1–x (0.1 x 1) solid solutions deposited onto glass or quartz substrates by thermal evaporation in a vacuum of 10^–4 Pa were found to be polycrystalline with a preferred (1 1 1) orientation. The obtained data were confirmed by electron diffraction. The optical studies showed that ZnSe _x Te_1–x polycrystalline films of different compositions have two direct transitions with corresponding energy gapsE _g andE _g + _so The variations in bothE _g andE _g + _so, withx indicate that ZnSe _x Te_1–x solid solution belongs to an amalgamation-type following quadratic equations with bowing parameters 1.251 and 1.275, respectively.     

Variation in the structural state of the α-phase in the Pd-In-H system during the β → α transformation

Increasing the concentration of indium atoms and hydrogen was found in the α-phase of the foil of a Pd-In alloy (with 5.3 and 5.0 at % In) after its electrolytic hydrogenation and 500-h relaxation. It is shown that the structural variations in the foil during the β → α transformation are nonmonotonic.     

Parametric magnon–phonon instability in the structure of YIG films

The effects of parametric magnon–phonon instability and the self-modulation of magnetostatic and fast magnetoelastic waves are revealed. It is found that instabilities are caused by the decay of the initial waves stimulated by high-Q acoustic resonances. Decays of the first and the second order (three- and four-magnon–phonon decays) are observed. Their characteristics and existing conditions are determined. Magnetostatic wave decays have both upper and lower thresholds. It is shown that magnetoelastic waves become stable above the upper thresholds. The existence of the upper threshold is due to several competing decay scenarios.     

Peculiarities of the ferromagnetic resonance in multilayer CoFeZr-α-Si films

The static magnetic properties and ferromagnetic resonance spectra of multilayer CoFeZr-α-Si films with different numbers and thicknesses of magnetic and nonmagnetic layers have been investigated. It is established that the shape of the ferromagnetic resonance spectrum and the resonant fields H _res depend on the thickness of nonmagnetic layers and their total number. The character of changes in the spectrum makes it possible to estimate the quality of layers and interfaces.