Hilbert-Enskog-Chapman expansion in the turbulent kinetic theory of gases. I

Giving up the assumption of molecular chaos, we get a hierarchy of equations, instead of the Boltzmann equation, governing the motion of a dilute gas. The Hilbert-Enskog-Chapman expansion methods for the hierarchy are studied in this paper and its continuations.     

A kinetic theory of spectral line shapes

The methods of kinetic theory are used to describe the radiation from an atom immersed in a gas of perturbing particles. It is shown that the line shape can be expressed in terms of a one-particle distribution function. The appropriate BBGKY hierarchy of equations is derived. This hierarchy is then truncated by assuming that only two-body collisions are important. The resulting equations are solved to obtain a non-Markovian kinetic equation which describes the combined effects of Doppler and pressure broadening. When the Markovian assumption is applied, a generalized linear Boltzmann equation is obtained which describes the line shape in the region where the impact limit is valid and which also describes the phenomenon of collisional narrowing.This research was supported in part by the Advanced Research Projects Agency of the Department of Defense, monitored by Army Research Office-Durham under Contract No. DA-31-124-ARO-D-139.     

Lorentz lattice gases: Basic theory

We present several ballistic models of the Lorentz gas in two-dimensional lattices with deterministic and stochastic deflection rules, and their corresponding Liouville equations. Boltzmann-level-equation results are obtained for the diffusion coefficient and velocity autocorrelation function for models with stochastic deflection rules. The long-time behavior of the mean square displacement is briefly discussed and the possibility of abnormal diffusion indicated. Even if the diffusion coefficient exists, its low-density limit may not be given correctly by the Boltzmann equation.     

Fluid dynamic limits of kinetic equations. I. Formal derivations

The connection between kinetic theory and the macroscopic equations of fluid dynamics is described. In particular, our results concerning the incompressible Navier-Stokes equations are based on a formal derivation in which limiting moments are carefully balanced rather than on a classical expansion such as those of Hilbert or Chapman-Enskog. The moment formalism shows that the limit leading to the incompressible Navier-Stokes equations, like that leading to the compressible Euler equations, is a natural one in kinetic theory and is contrasted with the systematics leading to the compressible Navier-Stokes equations. Some indications of the validity of these limits are given. More specifically, the connection between the DiPerna-Lions renormalized solution of the classical Boltzmann equation and the Leray solution of the Navier-Stokes equations is discussed.This paper is dedicated to Joel Lebowitz on his 60th-birthday.     

Hilbert-Enskog-Chapman expansion in the turbulent kinetic theory of gases. II

This is a continuation of the article (I) with the same title. [Tian-quan Chen, preceding articleJ. Stat. Phys. 25, 491 (1981).] We carry on with the Enskog-Chapman expansion here.     

A unified approach for deriving kinetic equations in nonequilibrium statistical mechanics. I. Exact results

A unified method for deriving exact kinetic equations for dynamical quantities of a many-body system is presented. The well-known results of Mori and Zwanzig are recovered as special cases. Furthermore, it is shown that they differ only by the way in which the system is prepared at the initial time. Connections between this method and others recently developed are also discussed.     

Solution of a linearized kinetic model for an ultrarelativistic gas

A linearized model of the Boltzmann equation for a relativistic gas is shown to be reducible, in the ultrarelativistic limit and for (1 + 1)-dimensional problems, to a system of three uncoupled transport equations, one of which is well known. A general method for solving these equations is recalled, with a few new details, and applied to the solution of two boundary value problems. The first of these describes the propagation of an impulsive change in a half space and is shown to give an explicit example of the recently proved result that no signal can propagate with speed larger than the speed of light, according to the relativistic Boltzmann equation. The second problem deals with steady oscillations in a half space and illustrates the meaning of certain recent results concerning the dispersion relation for linear waves in relativistic gas.     

A reinterpretation of dense gas kinetic theory

In dense gas kinetic theory it is standard to express all reduced distribution functions as functionals of the singlet distribution function. Since the singlet distribution function includes aspects of correlated particles as well as describing the properties of freely moving particles, it is here argued that these aspects should more clearly be distinguished and that it is the distribution function for free particles that is the prime object in terms of which dense gas kinetic theory should be expressed. The standard equations of dense gas kinetic theory are rewritten from this point of view and the advantages of doing so are discussed.     

Symmetric linear collision operators in kinetic theory

We consider a class of equilibrium time correlation functions, in fluids, between local physical quantities. We investigate whether the symmetry these correlation functions display with respect to these quantities on theN-particle level also exists on the one-particle (kinetic) level. In this context we derive a new symmetric kinetic operator for a dense, hard sphere fluid.     

Multiscale derivation of an augmented Smoluchowski equation

Smoluchowski and Fokker-Planck equations for the stochastic dynamics of order parameters have been derived previously. The question of the validity of the truncated perturbation series and the initial data for which these equations exist remains unexplored. To address these questions, we take a simple example, a nanoparticle in a host medium. A perturbation parameter ε, the ratio of the mass of a typical atom to that of the nanoparticle, is introduced and the Liouville equation is solved to O(ε²). Via a general kinematic equation for the reduced probability W of the location of the center-of-mass of the nanoparticle, the O(ε²) solution of the Liouville equation yields an equation for W to O(ε³). An augmented Smoluchowski equation for W is obtained from the O(ε²) analysis of the Liouville equation for a particular class of initial data. However, for a less restricted assumption, analysis of the Liouville equation to higher order is required to obtain closure.     

A General Formula of Flow Equations for Harry-Dym Hierarchy

In this paper, we derive a general formula of the flow equtions for the Harry-Dym hierarchy. And three applications in n-reduction, (2+1)-dimensional generalization, and Kupershmidt reduction, are considered.     

A kinetic derivation of extended irreversible thermodynamics

The basic postulates of the extended irreversible thermodynamics are derived from the kinetic model for a dilute monoatomic gas. Using the Grad 13-moment method to solve the full nonlinear Boltzmann equation for molecules conceived as soft spheres we obtain the microscopic expressions for the entropy flux, the entropy production, and the generalized Pfaffian for the extended definition of entropy as required by such a theory. Some of the physical implications of these results are discussed.Member, Colegio Nacional.     

Hydrodynamics from kinetic models of conservative economies

In this paper, we introduce and discuss the passage to hydrodynamic equations for kinetic models of conservative economies, in which the density of wealth depends on additional parameters, like the propensity to invest. As in kinetic theory of rarefied gases, the closure depends on the knowledge of the homogeneous steady wealth distribution (the Maxwellian) of the underlying kinetic model. The collision operator used here is the Fokker-Planck operator introduced by J.P. Bouchaud and M. Mezard [Wealth condensation in a simple model of economy, Physica A 282 (2000) 536-545], which has been recently obtained in a suitable asymptotic of a Boltzmann-like model involving both exchanges between agents and speculative trading by S. Cordier, L. Pareschi and one of the authors [S. Cordier, L. Pareschi, G. Toscani, On a kinetic model for a simple market economy, J. Stat. Phys. 120 (2005) 253-277]. Numerical simulations on the fluid equations are then proposed and analyzed for various laws of variation of the propensity.     

Generalized enskog theory for homogeneous systems

We propose a generalization of the Enskog equation for homogeneous dense systems including the complete three-particle dynamics. To this end the time derivative of the one-particle distribution is represented in the thermodynamic limit as the sum of three terms describing the effect of the initials-particle correlations, collisions withins-particle clusters, and coupling ofs-particle clusters to the surrounding gaseous medium, respectively. The analysis of casess=2 ands=3 is performed both for hard spheres and for a smooth, repulsive interaction. On assuming the equilibrium structure and spatial dependence of terms reflecting the effect of the medium, we obtain fors=2 the Enskog equation, and fors=3 a new equation, going beyond the Enskog theory. Apart from the Enskog collision term it contains additional contributions, and can be shown to reduce to the Choh-Uhlenbeck equation in the long-time, low-density limit.     

Analysis of structure function equations up to the seventh order

We examine balances of structure function equations up to the seventh order N = 7 for longitudinal, mixed and transverse components. Similarly, we examine the traces of the structure function equations, which are of interest because they contain invariant scaling parameters. The trace equations are found to be qualitatively similar to the individual component's equations. In the even-order equations, the source terms proportional to the correlation between velocity increments and the pseudo-dissipation tensor are significant, while for odd N, source terms proportional to the correlation of velocity increments and pressure gradients are dominant. Regarding the component equations, one finds under the inertial range assumptions as many equations as unknown structure functions for even N, i.e. can solve for them as function of the source terms. On the other hand, there are more structure functions than equations for odd N under the inertial range assumptions. Similarly, there are not enough linearly independent equations in the viscous range r → 0 for orders N > 3.     

Additive Invariant Functionals for Dynamical Systems

We consider the problem of defining completely a class of additive conservation laws for the generalized Liouville equation whose characteristics are given by an arbitrary system of first-order ordinary differential equations. We first show that if the conservation law, a time-invariant functional, is additive on functions having disjoint compact support in phase space, then it is represented by an integral over phase space of a kernel which is a function of the solution to the Liouville equation. Then we use the fact that in classical mechanics phase space is usually a direct product of physical space and velocity space (Newtonian systems). We prove that for such systems the aforementioned representation of the invariant functionals will hold for conservation laws which are additive only in physical space; i.e., additivity in physical space automatically implies additivity in the whole phase space. We extend the results to include non-degenerate Hamiltonian systems, and, more generally, to include both conservative and dissipative dynamical systems. Some applications of the results are discussed.     

On nonlinear stationary half-space problems in discrete kinetic theory

We show that every steady discrete velocity model of the Boltzmann equation on the real line, _i·(d/dx)f ⁱ=C ⁱ(f), which satisfies anH-theorem and for which all _i0, has solutions on the half-line (0, ) which take prescribed non-negativef ⁱ(O) if _i>0 and approach a certain manifold of Maxwellians asx. Such solutions give the density distribution in a Knudsen boundary layer in the discrete velocity case.     

Nonequilibrium fluctuations in μ space

The properties of fluctuations in space in or outside thermal equilibrium are obtained by solving hierarchies of equations derived either from the Liouville or the Master equation. In particular we study the one-, two-, etc., time correlation functions that describe the spatial and temporal behavior of the fluctuations in space. Explicit solutions are obtained for a dilute gas. The Langevin approach is briefly discussed. Our results are compared with those obtained in the extensive literature, which is reviewed in some detail.     

On the kinetic theory of a dense gas of rough spheres

The revised Enskog equation for a dense gas of rough spheres is considered. TheH theorem and the conservation equations are discussed.