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Manipulation of Shell Morphology of Silicate Spheres from Structural Evolution in a Purely Inorganic System 下载免费PDF全文
Dr. Qingmin Ji Dr. Shinsuke Ishihara Dr. Tatyana G. Terentyeva Dr. Kenzo Deguchi Dr. Shinobu Ohki Dr. Masataka Tansho Dr. Tadashi Shimizu Dr. Jonathan P. Hill Dr. Katsuhiko Ariga 《化学:亚洲杂志》2015,10(6):1379-1386
We have investigated the structural transformation of solid silica spheres into various more complex spherical structures including flower‐like, thick or thin nanosheet‐shelled and porous shelled spheres. In the absence of organic additives, sodium salts contained in this inorganic reaction system apparently direct the silica dissolution and regrowth of dissolved silicate at the nanometer‐scale, leading to the formation of a nanosheet network rather than solid aggregates. Subsequent removal of the salts by simple water washing results in voids in the siloxane network and a significant availability of surface silanol groups so that the resulting nanosheets and spheres composed of them possess large surface areas, pore volumes, and morphological flexibility, which can be varied by an applied stimulus. The results represent a rare example of the transformation of a simple silicate structure into a much more complex spherical structure involving a purely inorganic reaction system. 相似文献
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Cover Picture: Assembly of Large Purely Inorganic Ce‐Stabilized/Bridged Selenotungstates: From Nanoclusters to Layers (Chem. Asian J. 5/2015) 下载免费PDF全文
Wei‐Chao Chen Prof. Chao Qin Prof. Yang‐Guang Li Prof. Hong‐Ying Zang Kui‐Zhan Shao Prof. Zhong‐Min Su Prof. En‐Bo Wang 《化学:亚洲杂志》2015,10(5):1081-1081
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Inside Back Cover: An Unconventional Route to Monodisperse and Intimately Contacted Semiconducting Organic–Inorganic Nanocomposites (Angew. Chem. Int. Ed. 15/2015) 下载免费PDF全文
Hui Xu Dr. Xinchang Pang Yanjie He Dr. Ming He Jaehan Jung Prof. Dr. Haiping Xia Prof. Dr. Zhiqun Lin 《Angewandte Chemie (International ed. in English)》2015,54(15):4679-4679
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Inside Back Cover: Direct Patterning and Biofunctionalization of a Large‐Area Pristine Graphene Sheet (Chem. Asian J. 3/2015) 下载免费PDF全文
Daewha Hong KiEun Bae Dr. Duckshin Park Houngkyung Kim Seok‐Pyo Hong Mi‐Hee Kim Dr. Bong Soo Lee Dr. Sangwon Ko Prof. Dr. Seokwoo Jeon Xu Zheng Prof. Dr. Wan Soo Yun Prof. Dr. Yang‐Gyun Kim Prof. Dr. Insung S. Choi Prof. Dr. Jungkyu K. Lee 《化学:亚洲杂志》2015,10(3):767-767
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Inside Back Cover: Catalyst‐Dependent Selectivity in the Relay Catalytic Branching Cascade (Chem. Eur. J. 6/2015) 下载免费PDF全文
Avinash H. Bansode Aslam C. Shaikh Dr. Rahul D. Kavthe Shridhar Thorat Dr. Rajesh G. Gonnade Dr. Nitin T. Patil 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(6):2707-2707
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Inside Back Cover: Porous Liquids: A Promising Class of Media for Gas Separation (Angew. Chem. Int. Ed. 3/2015) 下载免费PDF全文
Dr. Jinshui Zhang Dr. Song‐Hai Chai Dr. Zhen‐An Qiao Dr. Shannon M. Mahurin Dr. Jihua Chen Dr. Youxing Fang Dr. Shun Wan Kimberly Nelson Dr. Pengfei Zhang Prof. Sheng Dai 《Angewandte Chemie (International ed. in English)》2015,54(3):1041-1041
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