Control of spectral lines weakly absorbed by atmosphere in continuous wave chemical HF lasers

The behavior of two lines P _1-0(11) and P _2-1(8) weakly absorbed by the atmosphere is experimentally investigated in the spectra of cw chemical multikilowatt HF lasers of five types that differ in size and construction scheme of the nozzle array. It is shown that the intensity of these lines can be controlled within certain limits by varying the gas-dynamic regime of the laser operation, the chemical composition of the active medium, the orientation of the optical axis of the cavity and the cavity feedback factor, and the construction of the nozzle array.     

Analysis of mode-locked internally frequency doubled broad-band continuous wave lasers

Closed-form analysis of pulse evolution in the transient regime in an actively modelocked internally frequency doubled broad-band continuous wave laser is presented. The analysis enables investigation of the effect of nonlinear crystal inside the laser cavity on mode-locked pulse parameters at the fundamental frequency. It is shown that the presence of internal second harmonic crystal broadens the fundamental mode-locked pulse while accelerating the approach of the system to steady-state. The dependence of pulse parameters on the bandwidth of the tuning element, modulation depth of the active mode-locker and conversion efficiency of the frequency doubler is presented in detailed graphical form.     

基于BWO连续太赫兹波成像系统的无损检测

介绍了一种基于返波管（BWO）的太赫兹波成像系统。BWO连续太赫兹波成像是一种新的无损检测方法。实验过程中把样品放在X-Z二维电控平移台上进行扫描成像,透过样品的太赫兹波强度信息由热释电探测器接收,然后经过电脑成像。给出了应用0.71THz的连续太赫兹波对打孔铝板、公交卡、校园卡的内部结构和对隐藏在信封内硬币等物体和信封内纸片上的铅字迹的成像实验研究事例,并且测知该系统能够分辨出直径最小为1.5mm的小孔。这项工作揭示了使用BWO连续太赫兹波成像系统在无损检测和安全检查领域是有效的。     

The use of diode array detectors in conjunction with continuous wave gas lasers for anti-Stokes Raman spectroscopy

The Raman spectrum of any molecule consists of two mirror-image signals, th e Stokes and anti-Stokes Raman spectra. In most cases, unless highly specific sampling conditions are used, the anti-Stokes signal is much weaker than that of the Stokes. The recent application of intensified diode array detectors to Raman spectroscopy has produced a marked increase in the sensitivity of the technique which makes a study of the anti-Stokes spectrum potentially more rewarding than it has been to date. The present study has shown that, although of limited use for general purposes, there are some specific instances where the anti-Stokes spectrum can be of considerable practical use. Such applications are to extend the operating range of the Raman spectrometer, to study photodegradable samples and for the analysis of samples which exhibit strong fluorescence.     

Modelling of excited state absorption and upconversion in erbium germanosilicate continuous wave fibre lasers

The effects of upconversion and pump excited state absorption (ESA) on a three-manifold continuous wave (CW) laser are investigated by solving the laser and pump differential equations subject to two-point boundary conditions. This technique is applied to erbium germanosilicate fibre lasers in low-finesse cavities. First, the three-manifold laser problem in a low-finesse cavity is solved analytically, without ESA and upconversion. This shows that the finite value of the upper pump manifold decay rate causes the extracted power to saturate, and it also shows that pump threshold is strongly influenced by the cavity reflectivity. Next, upconversion and ESA are included. This leads to a study of the extracted power and pump threshold as functions of fibre length and outcoupling. This simulation is numerical and is successfully anchored to experiment.     

Development of a 3-D, multi-nuclear continuous wave NMR imaging system

The development of a 3-D, multi-nuclear continuous wave NMR imaging (CW-NMRI) system is described and its imaging capability is demonstrated on a range of materials exhibiting extremely short T(2) relaxation values. A variety of radiofrequency resonators were constructed and incorporated into a new gradient and field offset coil assembly, while the overall system design was modified to minimise microphonic noise which was present in an earlier prototype system. The chemically combined (27)Al in a high temperature refractory cement was imaged, and the CW-NMRI system was found to be sensitive to small differences in (27)Al content in these samples. The penetration of (23)Na in salt water into samples of ordinary Portland cement (OPC) was investigated, with enhanced uptake observed for samples with larger pore size distributions. The solid (13)C component in a carbonated cement sample was also imaged, as were the (7)Li nuclei in a sample of powdered Li(2)CO(3). A spatial resolution of 1mm was measured in an image of a rigid polymeric material exhibiting a principal T( *)(2) value of 16.3 micros. Finally, a high-resolution 3-D image of this rigid polymer is presented.     

端面抽运Tm，Ho∶YLF连续激光器的参数优化与实验研究

研究了激光二极管端面抽运Tm,Ho∶YLF连续激光器的输出特性,并对激光器的参数进行了优化.在考虑能量传递上转换的前提下,通过准三能级速率方程推导出了连续抽运Tm,Ho∶YLF激光器输出功率与抽运功率关系的表达式.对激光晶体的粒子掺杂浓度、晶体长度、激光束腰半径与抽运光束腰半径比值以及输出镜透过率等激光器参数进行了优化.实验上得到了激光输出功率随抽运功率的变化关系,并将其与理论结果进行了比较,发现比较吻合,从而验证了理论模型的合理性. 关键词： Tm Ho∶YLF晶体 速率方程 能量传递上转换 参数优化     

Syntheses of BaCO3 nanostructures by ultrasonic method

BaCO₃ nanostructures were synthesized by the reaction of Ba(CH₃COO)₂ and sodium hydroxide or tetramethylammonium hydroxide (TMAH) by a sonochemical method. Reaction conditions, such as the concentration of the Ba²⁺ ion, aging time and power of the ultrasonic device played important roles in the size, morphology and growth process of the final products. The BaCO₃ nanostructures were characterized by scanning electron microscopy (SEM), X-ray powder diffraction (XRD), and the Infrared spectroscopy (IR).     

激光调频连续波测距的精度评定方法研究

基于双光纤光路等光频重采样原理,提出了一种距离精度的评定方法.通过推导噪声背景下等光频重采样信号中距离参量的克拉美-罗下边界,得到了影响系统测距精度的两个重要因素:信噪比和扫描带宽,并进行了实验验证.实验表明,该评价方法并不会受到任何距离估算方法的影响,根据此方法可以选择一个最优的距离估算方法.通过对两个影响精度的因素进行仿真分析可知,在扫描带宽为2.2 nm时,若将测量光路的信噪比提升至70 dB以上,系统可获得低于10μm的测距精度.该精度评定方法可为后续改善调频连续波测距系统性能提供理论参考.     

Laser ultrasonic anomalous wave propagation imaging method with adjacent wave subtraction: Application to actual damages in composite wing

Laser ultrasonic wave propagation imaging methods have great potential for integrated structural health management and non-destructive evaluation. However, application of these techniques to complex structures in the field is difficult because they give rise to complicated wave propagation patterns. We developed an anomalous wave propagation imaging method with adjacent wave subtraction using laser ultrasonic scanning to solve this problem. The proposed method is suitable for non-destructive evaluation of complex structures because it highlights the propagation of anomalous waves related to structural discontinuities, and suppresses complex incident waves without the need of pre-stored reference data. In this study, the method was applied to a real composite wing subjected to bending and impact tests. The method enhanced the visibility of the anomalous waves related to damages such as stringer tip debonding, skin-spar debonding, and invisible impact damage. Based on these anomalous waves, variable time window amplitude mapping was performed to show the damage location, size, and shape resemble to the actual damage. Comparisons showed that the methods performed better than the ultrasonic A-scan in terms of damage detection and sizing accuracy. The presence of structural elements such as spars, stringers, ribs, and surface-mounted PZT elements did not adversely affect the inspection. The proposed wing test setup with a built-in ultrasonic propagation imaging system for automatic NDE could be easily expanded throughout a hanger for maintenance inspection.     

Mole-controlled growth of Y-doped ZnO nanostructures by hydrothermal method

We investigated the mole-controlled growth of Y-doped ZnO (YZO) nanostructures by the hydrothermal synthesis techniques. Through controlling the aqueous solution's mole concentration, we could modify the morphological and structural properties of YZO. The shape of YZO becomes a nanometer-sized rod when using a relatively low mole concentration, whereas the morphology is changed to be flat and mosaic when using a relatively high mole concentration. Since the aqueous solution's mole concentration decides the amount of hydroxide, we ascribe the mole-controlled morphological changes to the alteration of chemical potential during the hydrothermal chemical reaction.     

Preparation and properties of ZnO nanostructures by electrochemical anodization method

ZnO thin films with diverse nanostructures, including nanodot, nanowire and nanoflower, have been fabricated on zinc foils by a simple and rapid electrochemical anodization method. The ZnO thin films reveal very strong visible emission that is ascribed to the transition between V_OZn_i and valence band. Under the dc or ac electric field, the electroinduced surface wettability conversion from the superhydrophobic to hydrophilic state was observed and the generation of surface defective sites on ZnO films under electric field was used to explain the transition mechanism. This work provides a simple and rapid method for synthesizing different ZnO nanostructures in large scale, and electric field can be used to modulate the wettability of ZnO nanostructures.     

Direct detection of acetylene in air by continuous wave cavity ring-down spectroscopy

Diode laser-based continuous wave cavity ring-down spectroscopy (cw-CRDS) in the near-infrared region has been used to measure the mixing ratio of acetylene (C₂H₂) in ambient air. Detection limits of 120 parts per trillion by volume (pptv) for 20 min and 340 pptv for 70 s acquisition time were achieved without sample pre-concentration, measuring on a C₂H₂ absorption line at 6565.620 cm^?1 (～1523 nm). Several indoor and outdoor air samples were collected at different locations in the Helsinki metropolitan area and analyzed using static-cell measurements. In addition, flow measurements of indoor and outdoor air have been performed continuously over several days with a time resolution of down to one minute. Baseline acetylene levels in the range of 0.4 to 3 parts per billion by volume (ppbv), with a maximum around midday and a minimum during the night, were measured. Sudden high mixing ratios of up to 60 ppbv were observed in outdoor air during daytime on a minute time scale. In general, the indoor mixing ratios were found to be higher than those in outdoor air. The acetylene levels correlated with the ambient CO levels and with outdoor temperature.     

A novel method of high resolution imaging through random perturbation wave front

A novel method is proposed for eliminating the effect of the traditional optical aberration on high resolution imaging by random perturbation wave front and digital image processing. A random phase mask, whose phase spectrum fluctuation is accordant with Kolmogorov distribution, is positioned near the aperture stop of optical system, making the optical aberration image become random perturbation image, that is, the intermediate image. The blind deconvolution algorithm based on maximum-likelihood estimation technique is used to restore the intermediate image acquired by a digital detector. The effects of optical aberrations and the noise on the restoration image are explored. To demonstrate the validity of the method proposed, the computer simulation and laboratory experiments are carried out for the imaging of the optical system with primary aberration. The results have shown that the present method is well suited for effectively improving the imaging quality of the optical system with certain aberration, thus making the optical system resolution close to or reach the diffraction-limit of the optical system.     

High-power continuous wave green beam generation by use of simple linear cavity with side-pumped module

High-power continuous wave green radiation has been generated by means of type-II phase-matched frequency doubling in a KTP crystal located in a simple linear cavity incorporating a diode side-pumped Nd:YAG laser module. The cavity was designed to make the fundamental beam radius at the KTP crystal smaller than that at the gain medium, as is required for obtaining large mode volume in Nd:YAG crystal and realizing efficient CW intracavity frequency doubling. Output power of 51.2 W is obtained in the experiment with a diode-to-green optical conversion efficiency of 10.3%. The M²-parameters of the laser are measured at different output powers. For the output power of about 47 W, the power fluctuation is measured less than 1%. The experimental results show that the continuous wave green laser system using this simple linear cavity offers good laser performance and output stability.     

DNA折纸结构介导的多尺度纳米结构精准制造

原子及近原子尺度制造在近年来一直是物质科学领域被广泛探讨的前沿问题.当制造和加工的尺度从微米、纳米逐渐走向原子级别时,材料在常规尺度下所具备的性质已无法通过经典理论进行解释,相反地,会在这一尺度下展现出一系列新奇的特性.因而对材料极限制造尺度和颠覆性物性的不断追求始终是科学界共同关注的重点领域.作为一种在纳米尺度下对结构制造单元进行精细操控的先进手段,DNA纳米技术的开发和发展为纳米制造甚至原子制造提供了新的观点和思路,而DNA折纸术作为DNA纳米技术的重要组成部分,正在凭借其在结构制造过程当中的高度可编程性成为纳米尺度下进行各类物质精准制造的独特的解决方案,并可能为不同物质不同材料更小尺度和任意形状的精准构筑带来机遇.本文首先简单概述了DNA折纸术的基本原理和发展历程,然后根据制造策略的不同对DNA折纸结构的纳米制造的相关代表性工作做了总结,并在文末提出了对于DNA折纸结构在原子制造中的可行性的思考和未来发展方向的展望.     

Application of thermal wave imaging and phase shifting method for defect detection in Stainless steel

This paper presents an experimental arrangement for detection of artificial subsurface defects in a stainless steel sample by means of thermal wave imaging with lock-in thermography and consequently, the impact of excitation frequency on defect detectability. The experimental analysis was performed at several excitation frequencies to observe the sample beginning from 0.18 Hz all the way down to 0.01 Hz. The phase contrast between the defective and sound regions illustrates the qualitative and quantitative investigation of defects. The two, three, four and five-step phase shifting methods are investigated to obtain the information on defects. A contrast to noise ratio analysis was applied to each phase shifting method allowing the choice of the most appropriate one. Phase contrast with four-step phase shifting at an optimum frequency of 0.01 Hz provides excellent results. The inquiry with the effect of defect size and depth on phase contrast shows that phase contrast decreases with increase in defect depth and increases with the increase in defect size.     

Formation of carbon nanostructures containing single-crystalline cobalt carbides by ion irradiation method

Carbon nanofibers (CNFs) with a diameter of 17 nm, and carbon nanoneedles (CNNs) with sharp tips have been synthesized on graphite substrates by ion irradiation of argon ions with the Co supplies rate of 1 and 3.4 nm/min, respectively. Energy dispersive X-ray spectrometry, combined with selected area electron diffraction patterns has been used to identify the chemical composition and crystallinity of these carbon nanostructures. The CNFs were found to be amorphous in nature, while the structures of the CNNs consisted of cubic CoC_x, orthorhombic Co₂C and Co₃C depending on the cobalt content in the CNNs. The diameter of the carbide crystals was almost as large as the diameter of the CNN. Compared to the ion-induced nickel carbides and iron carbides, the formation of single-crystalline cobalt carbides might be due to the high temperature produced by the irradiation.