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We have measured the temperature (T) dependence of the transverse relaxation rate (T G –1 ) of the Cu(1) nuclear spin in YBa2Cu3O6.98 (T c=92 K) and YBa2Cu4O8 (T c=82 K). From the scaling ratio ofT G –2 (Cu1) toT G –2 (Cu2), we have estimated the strength of a covalent bonding between the CuO2 plane and the CuO chain to be B0.38×A zz. The experimentalT G –1 (Cu1) in YBa2Cu4O8 was of the same order of magnitude as the estimated one fromT G –1 (Cu2). These results appear to indicate that the electrons in the CuO2 plane fairly spread out of the plane in both compounds.  相似文献   

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The frequencies of allB 1u (z) phonon modes predicted by a group-theoretical analysis were measured and found to agree well with recent lattice dynamical calculations for this compound. We report also the determination of two superconducting gap values in YBa2Cu4O8 through phonon self-energy effects in the normal and superconducting conducting state. The gap-to-T c ratios obtained from an analysis of these effects are 2 1/kT c 2.5 and 5.82 2/kT c 9.2. This coincides with previous results of both phononic and electronic Raman scattering where values of 2.1 and 6.3 were found. We further find anomalous softenings of two phonon modes 40 Kabove T c , which correlate with an observed deviation from the linear temperature dependence of the average plasma frequency p (T).  相似文献   

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通过从头算密度泛函理论研究了YBa2Cu3O7的结构和弹性性质。发现c轴最容易压缩。另外,我们还计算了各种弹性性质与压强的关系,例如弹性模量,剪切模量,杨氏模量,泊松比。最后,我们获得了不同压强下的德拜温度和声速。  相似文献   

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Y2BaCuO5YBa2Cu3O7-x (Y211/Y123) interfaces in melt-processed YBa2Cu3O7-x were studied by high-resolution transmission electron microscopy and energy dispersive X-ray spectroscopy. Yttrium enrichment and barium depletion were observed locally at the Y211/Y123 interfaces where Y123 (001) facets were present. This effect may be interpreted as the result of lattice substitution of Ba by Y near these interfaces. Cation nonstoichiometry was found near Y211/Y123 interfaces where liquid phases (Cu-Ba-O) were present. This chemical disorder introduces numerous point defects in the Y123, and these defects may act as additional pinning sites alongwith stacking faults. A comparison of grain boundary (GB) chemical composition in polycrystalline YBa2Cu3O7-x and YBa2Cu4O8(Y124), studied using nanoprobe parallel-detection electron energy-loss spectroscopy (EELS), is presented. The studies of Y124 show that stoichiometric grain boundaries can also form weak links between superconducting grains. It is suggested that weak-link behavior is determined largely by misorientation at grain boundaries.  相似文献   

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Romano  P.  Di Leo  R.  Nigro  A.  Cucolo  A. M.  Dabrowski  B.  Radaelli  P. G. 《Il Nuovo Cimento D》1994,16(10):1885-1888
Il Nuovo Cimento D - We have realized planar tunnel junctions using both Y123 and Y124 single crystals as base electrodes and Pb as counterelectrode. The crystals, with T c=90 K (Y123) and T c=80 K...  相似文献   

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We report the observation of quantum oscillations in the underdoped cuprate superconductor YBa2Cu4O8 using a tunnel-diode oscillator technique in pulsed magnetic fields up to 85 T. There is a clear signal, periodic in inverse field, with frequency 660+/-15 T and possible evidence for the presence of two components of slightly different frequency. The quasiparticle mass is m(*)=3.0+/-0.3m(e). In conjunction with the results of Doiron-Leyraud et al. for YBa2Cu3O6.5, the present measurements suggest that Fermi surface pockets are a general feature of underdoped copper oxide planes and provide information about the doping dependence of the Fermi surface.  相似文献   

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