Elastic constants of LaB6 at room temperature

Measurements have been made of the transit times of pulses of longitudinal and transverse ultrasonic waves propagating in single crystal LaB₆ at room temperature. A unique set of values for the three independent elastic constants has been calculated from the resultant velocities and is; C₁₁ = (45.33 ± 0.11) × 10¹¹dynecm^-2, $\text{C}{}_{12}\text{= (1.82 ± 0.17) × 10}{}^{11}\text{dyne}\text{cm}{}^2$ and C₄₄ = (9.01 ± 0.05) × 10¹¹dyne/cm². The Debye temperature of LaB₆ from these measurements is 773 K, which agrees relatively well with the X-ray Debye temperature, however, differs much from the calorimetric and electrical resistance Debye temperatures.     

The influence of excess oxygen on the elastic properties of non-stoichiometric SrO crystals

Measurements have been carried out of the elastic constants of SrO in the virgin undoped state and of the changes produced in them by equilibrium doping with oxygen at ? 1200°C and oxygen partial pressure of 0.95 atm. The method used was Papadakis' pulse-echo overlap technique in conjunction with thermogravimetric analysis (T.G.A.) to determine mass and density changes due to oxygen doping.The values obtained for C₁₁, C₁₂ and C₄₄ of the virgin crystal at 23°C are

$\text{C}{}_{11}\text{= 17.60 ± 0.03 × 10}{}^{11}\text{dynes/cm}{}^2$

;

$\text{C}{}_{12}\text{= 4.808 ± 0.007 × 10}{}^{11}\text{dynes/cm}{}^2$

;

$\text{C}{}_{44}\text{= 5.577 ± 0.008 × 10}{}^{11}\text{dynes/cm}{}^2$

.(These values are in very good agreement with those of Son and Bartels [2].)Values for $\text{δC}{}_{11}\text{C}{}_{11}$ and $\text{δC}{}_{44}\text{C}{}_{44}$ were found to be ?1.74% and ?0.86% respectively. Accurate valu $\text{δC}{}_{12}\text{C}{}_{12}$ could not be obtained because of sample size limitations after quenching. However, C₁₂ was shown to definitely increase due to doping.Analysis of the results indicate that the elastic modulus changes can only be attributed to the formation of cation vacancies during doping. Analysis of the T.G.A. behavior indicates that this cation vacancy formation is probably associated with the presence of various tripositive cation and uninegative anion species depending upon the impurity concentrations of the sample. This implied impurity-controlled cation vacancy concentration is consistent with the earlier observed extrinsic nature of cation diffusion in SrO at 1200°C.     

X-ray compressibility measurements of the graphite intercalates KC8 and KC24

The isothermal compressibilities of pristine graphite and stages 1 and 2 potassium-graphite have been measured at room temperature. Diamond anvil X-ray diffraction techniques were employed to determine the c-axis lattice constant as a function of hydrostatic pressure up to 12 kbar. The compressibilities $\text{k}{}_{\mathrm{c}}\text{?}\text{1}\text{C}{}_{33}$ were found to be (2.73±0.09)×10^-12, (2.13±0.09)×10^-12, (5.3±0.8)×10^-12 and $\text{(1.6±0.2)×10}{}^{-12}\text{cm}{}^2\text{dyn}$ for graphite, KC₈, stage 2 KC₂₄ and stage 3 KC₂₄, respectively. The compressibility of KC₈ was comparable to that of RbC₈ deduced from neutron scattering experiments.     

Infrared bands of 12C2HD

The rotational structure of about 40 bands of ¹²C₂HD observed in the region 6000?600 cm^?1 has been measured and interpreted with the purpose of determining a comprehensive set of molecular constants for this isotopic variety of acetylene. Combining these data with the results for ¹²C₂H₂ and ¹²C₂D₂, a reevaluation of the equilibrium internuclear distances for the acetylene molecule has been made: $\text{r}{}_{\mathrm{e}}\text{(CH) = 1.06215 ± 17 × 10}{}^{\mathrm{?5}}\text{A}\text{?}$ and $\text{r}{}_{\mathrm{e}}\text{(CC) = 1.20257 ± 9 × 10}{}^{\mathrm{?5}}\text{A}\text{?}$ were obtained. This paper presents all the molecular constants derived in this study.     

Reexamination of the I2 spectrum near the B(3Π0u+) state dissociation limit

The disagreement of Danyluk and King's (Chem. Phys.25, 343 (1977)) rotational constants for levels lying near the dissociation limit of B-state I₂ with the mechanical behavior predicted by near-dissociation theory is investigated. The discrepancies are shown to be much too large to be explained by either the neglect of centrifugal distortion effects in the original analysis or by rotational or spin-rotation coupling to a nearby repulsive 1_u state. These differences are therefore attributed to experimental error, a conclusion which is confirmed by more recent experimental results. A reanalysis of the best available data for levels near the dissociation limit of B-state I₂ then yields improved values for the B-state dissociation limit $\text{D}$ = 20 043.16 (±0.02) cm^?1 of the vibrational index at dissociation v_$\text{D}$ = 87.32 (±0.04) and of the long-range potential constant $\text{C}{}_5\text{= 2.88 (±0.03) × 10}{}^5\text{cm}{}^{\mathrm{?1}}\text{A}\text{?}{}^5$. This in turn implies a slightly improved ground-state dissociation energy of $\text{D}$₀ = 12 440.18 (±0.02) cm^?1.     

Pulsed magnetic field study of Fe2+ in some fluosilicates

Pulsed field experiments up to 450 kOe have been performed on FeSiF_6.6H₂O. We interpret the data: (i) in terms of spin hamiltonian constants: D = 12.3± 0.2 cm^-1 (E = 0.54cm^-1 being known from EPR data); (ii) in terms of axial-crystal-field parameters: $\text{δ}\text{λ}\text{=}\text{orbital trigonal splitting/spin-orbit coupling}\text{= 15 ± 2; λ = -100 ± 7cm}{}^{\mathrm{?1}}$. The magnetic axis is found to deviate from the cristallographie c axis by an angle 1° < θ < 2°. The adiabatic cooling obtained during the pulse is discussed.Similar experiments on Fe_0.15Zn_0.85SiF_6.6H₂O and Fe_0.30Zn_0.70SiF_6.6H₂O single crystals are reported; in both cases we measure $\text{D}\text{g}{}_{\mathrm{\parallel }}\text{= 6.0 ± 0.1cm}{}^{-1}$. Using EPR data, we obtain D = 14.3cm^-1, λ ～ ?75cm^-1, δ ～ 195cm^-1; using Mössbauer data, we obtain D = 15.3cm^-1, λ ～ ?88cm^-1, δ ～ 185cm^-1.     

Electron paramagnetic resonance of 61Ni+ in CuGaS2

EPR of ⁶¹Ni⁺ doped CuGaS₂ at 4.2 K leads to the following experimental data: $\text{g = 1.918 ± 0.006 A  < 12 × 10}{}^{-4}\text{cm}{}^{-1}\text{, g}{}_{\mathrm{\perp }}\text{= 2.328±0.006 A}{}_{\mathrm{\perp }}\text{= (65±2) × 10}{}^{-4}\text{cm}{}^{-1}$. High axial field splitting of ²T₂ state stabilizes the center against Jahn-Teller interaction. Covalency reduction factor k is 0.76.     

Vibronic properties of the F+ centre in strontium oxide

The shape and moments of the F⁺ absorption band in SrO have been measured between 4.2K and 300K. Analysis of the moments gives the effective frequency of the vibrational modes interacting with the centre as $\text{h}\text{?}\text{ω = 236 ± 20 cm}{}^{-1}$, and the Huang-Rhys factors for cubic and non-cubic modes as S_C = 3 ± 1 and S_NC = 4 ± 1 respectively.     

Accurate determination of the 17O16O + n coupling constant and spectroscopic factor

We have measured ¹⁶O¹⁷O elastic cross sections at 22 MeV between 65°–140° to ± 1 %. The observed oscillatory interference between Coulomb scattering and the neutron transfer process is analyzed using exact finite-range DWBA. A model-independent value of $\text{C}\text{?}{}^2\text{= 0.82 ± 0.07}$ is obtained for the coupling constant of the 1d_{$\text{5}\text{2}$} neutron in ¹⁷O. We also present an analysis of data on magnetic electron scattering from ¹⁷O, which yields precise information on the magnitude and the radial shape of the $\text{1}\text{d}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}$ neutron bound-state wave function. With this we relate the coupling constant to the spectroscopic factor and find S = 1.04 ± 0.11. We show that the magnetic electron scattering data alone yield S = 1.04 ± 0.10. Combining these results with earlier work we recommend $\text{C}\text{?}{}^2\text{= 0.79 ± 0.04}$ and S = 1.03 ± 0.07 as best values. This spectroscopic strength corresponds to (91 ± 7) % of the full single-particle value.     

Analysis of the Raman spectrum of SF6

The Raman active fundamentals ν₁(A1g), ν₂(Eg), ν₅(F2g), and the overtone 2ν₆ of SF₆ have been investigated with a higher resolution and the band origins were estimated to be: ν₁ = 774.53 cm^?1, ν₂ = 643.35 cm^?1, ν₅ = 523.5 cm^?1, and 2ν₆ = 693.8 cm^?1. Raman and infrared data have been combined for estimation of several anharmonicity constants. The ν₆ fundamental frequency is calculated as 347.0 cm^?1. From the analysis of the ν₂ Raman band, the following rotational constants of both the ground and upper states have been calculated:

$\text{B}{}_0\text{= 0.09111 ± 0.00005}\text{cm}{}^{\mathrm{?1}}\text{; D}{}_0\text{= (0.16±0.08)10}{}^{\mathrm{?7}}\text{cm}{}^{\mathrm{?1}}$

;

$\text{B}{}_2\text{= 0.09116 ± 0.00005}\text{cm}{}^{\mathrm{?1}}\text{; D}{}_2\text{= (0.18±0.04)10}{}^{\mathrm{?7}}\text{cm}{}^{\mathrm{?1}}$

.     

Coupling constants for several light nuclei from a dispersion analysis of nucleon and deuteron scattering amplitudes

A forward dispersion relation cannot be applied to charged particle scattering amplitudes unless the influence of the Coulomb interaction is explicitly considered. Earlier studies have shown how Coulomb effects can be taken into account when direct (s-channel or bound-state) poles are investigated. In this paper we extend the Coulomb modification to include I = 0 exchange (u-channel) processes as well. We then apply a forward dispersion relation to empirical d + α, p + d and n + d elastic scattering amplitudes which contain both direct and exchange poles with and without Coulomb effects. We obtain detailed and model-independent information on the following vertices: ⁶Li-α-d (S- and D-state) ⁴He-d-d, ³He-d-p, ³H-d-n and d-p-n. From the coupling constants we calculate the asymptotic normalization (spectroscopic factors) C²₁ of the corresponding cluster wave functions, which become: $\text{C}{}^2{}_0\text{(}{}^6\text{Li}\text{, α}\text{d}\text{) = 4.62 ± 0.23}$, $\text{C}{}^2{}_2\text{(}{}^6\text{Li}\text{, α}\text{d}\text{) = (1 ± 6) × 10}{}^{\mathrm{?4}}$, C²₀(α, dd) < 2, $\text{C}{}^2{}_0\text{(}{}^3\text{He, dp}\text{) = 3.5 ± 0.4}$, $\text{C}{}^2{}_0\text{(}{}^3\text{H, dn}\text{) = 2.6 ± 0.3}\text{and}\text{C}{}^2{}_0\text{(}\text{d, np}\text{) = 1.66 ± 0.1}$.     

The ground state of methane 12CH4 through the forbidden lines of the ν3 band

High resolution spectra of the ν₃ band of methane, ¹²CH₄, were recorded by using a “third generation vacuum Fourier interferometer”; a large pressure range (from 0.009 to 10 Torr) with a sample path fixed at eight meters was used, enabling observation of transitions with intensity ratios as low as $\text{1}\text{10 000}$. More than 350 forbidden transitions of the ν₃ band, including about 125 transitions of the Q⁺ branch, were unambiguously identified. Of the 277 transitions retained for computations, one-hundred have 11 ≤ J ≤ 16. From combination difference relations using pairs of transitions having the same upper state energy level (forbidden-allowed and forbidden-forbidden pairs were used), 276 independent differences between ground state energy levels could be determined with uncertainties of about 0.001 cm^?1.These data yielded the following values for the ground state structure constants of ¹²CH₄ along with their standard deviations (in cm^?1): $\text{β}{}^{\mathrm{o}}\text{hc}\text{=5.2410356±0.0000096}$, $\text{γ}{}^{\mathrm{o}}\text{hc}\text{=(?1±0.00074) 10}{}^{\mathrm{?4}}$, $\text{π}{}^{\mathrm{o}}\text{hc}\text{=(5.78±0.18) 10}{}^{\mathrm{?9}}$, $\text{?}{}^{\mathrm{o}}\text{hc}\text{=(?1.4485±0.0023) 10}{}^{\mathrm{?6}}$, $\text{?}{}^{\mathrm{o}}\text{hc}\text{=(1.768±0.126) 10}{}^{\mathrm{?10}}$, $\text{ξ}{}^{\mathrm{o}}\text{hc}\text{=(?1.602±0.067) 10}{}^{\mathrm{?11}}$, Thus, for the first time, the scalar constant π⁰ has been evaluated and ir values have been obtained for the two tetrahedral constants ?⁰ and ξ⁰; furthermore, these values are in very good agreement with the ones recently determined from radiofrequency data, i.e., in cm^?1: $\text{?}{}^{\mathrm{o}}\text{hc}\text{=(?1.45061±0.00014) 10}{}^{\mathrm{?6}}$, $\text{?}{}^{\mathrm{o}}\text{hc}\text{=(1.7634±0.0068) 10}{}^{\mathrm{?10}}$, $\text{ξ}{}^{\mathrm{o}}\text{hc}\text{=(?1.5432±0.0040) 10}{}^{\mathrm{?11}}$ From these values, the 276 differences can be reproduced with an overall rms deviation equal to 0.0009 cm^?1.Finally, the ground state energies of ¹²CH₄ have been calculated for J ≤ 16.     

Diffusion of water in additively colored potassium iodide crystals

The diffusion of water into additively colored potassium iodide has been studied in the range 15–45°C. Penetration depths, measured by decrease in the F-band absorption, increase with $\text{t}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$. The diffusion coefficient, D = 0·58 exp (?6496/T) cm² sec^?1 agrees very well with that determined by other workers. The Henry's law constant, $\text{K =}\text{C}{}_0\text{p}{}_{\mathrm{w}}\text{= 1·3 × 10}{}^9\text{exp}\text{(+4882/T)}\text{cm}{}^{\mathrm{?3}}\text{torr}{}^{\mathrm{?1}}$ implies a water concentration of C₀ ? 10¹⁷ molecules per cm³ in the surface of KI crystals in equilibrium with an environment at 25°C and 35 per cent relative humidity. The large C₀ makes penetration very rapid. Diffusion occurs by interstitial migration of water molecules with an entropy of activation of 9.4 cal/mol deg and an enthalpy of activation of 12·9 kcal/mol.     

Vibrational spectra and force constants of symmetric tops: High resolution spectra of monoisotopic H3SiCl in the 2200-cm−1 region and rovibrational analysis of the ν1 and ν4 fundamentals

The gas phase infrared spectra of monoisotopic H₃Si³⁵Cl and H₃Si³⁷Cl have been studied in the $\text{ν}{}_1\text{ν}{}_4$ region near 2200 cm^?1 with a resolution of 0.012 and 0.04 cm^?1, respectively, and rotational fine structure for ΔJ = ±1 branches has been resolved. In addition, some information on ν₃ + ν₄ of H₃Si³⁵Cl near 2750 cm^?1 has been obtained. ν₁ and ν₄ are weakly coupled by Coriolis x, y resonance, $\text{B}\text{Ω}{}_{14}\text{ζ}{}_{14}\text{～ 2 × 10}{}^{\mathrm{?3}}\text{cm}{}^{\mathrm{?1}}$, only the upper states K′ = 2, l = 0 and K′ = 1, l = ?1 being substantially affected. Local perturbation due to rotational l(±1, ±1)-type resonance with ν₃ + ν₅⁺¹ + ν₆⁺¹ and ν₃ + ν₅⁺¹ + ν₆^?1 is revealed in the ΔK = +1 and ?1 branches, respectively. From a fit of the experimental line positions, standard deviations of 1.4 and 3.8 × 10^?3 cm^?1, respectively, to a model with five interacting levels conventional excited state parameters and interaction constants have been obtained. In $\text{H}{}_3\text{Si}{}^{35}\text{Cl}\text{H}{}_3\text{Si}{}^{37}\text{Cl}$ the fundamentals are ν₁, $\text{2201.94380(15)}\text{2201.9345(7)}$ and ν₄, $\text{2209.63862(8)}\text{2209.6254(2)}\text{cm}{}^{\mathrm{?1}}$, respectively. Q branches of the “hot” band (ν₃ + ν₄) ? ν₃ and of ν₄ of the ²⁹Si and ³⁰Si species have been detected.     

Rotation-vibration analysis of the Coriolis-coupled ν5g, ν6g, ν8g and ν9 bands of H2CCO

Medium resolution infrared grating spectra of gaseous ketene, H₂CCO were recorded between 1000 and 400 cm^?1, both at instrument temperature (40°C) and with cooling (?40°C). Interferometric Fourier spectra were also measured at ?70°C with resolution 0.22 cm^?1 between 450 and 330 cm^?1. The K structure of the fundamentals ν₅, ν₆, ν₈, and ν₉ was assigned. These fundamentals are coupled by a-axis Coriolis interactions. These couplings were analysed on the symmetric top basis for setting up the perturbation matrix and by utilizing the K-dependent Coriolis shifts of levels. A preliminary analysis of the Coriolis intensity anomalies was also undertaken.Band center values from combination differences are $\text{ν}{}_5{}^0\text{= 587.30 (27)}$ and $\text{ν}{}_6{}^0\text{= 528.36 (39)}\text{cm}{}^{\mathrm{?1}}$. Synthetic spectra indicate the band origins of ν₈ and ν₉ to be close to 977.8 and 439.0 cm^?1, respectively. Estimates of Coriolis coupling constants obtained from synthetic spectra are $\text{ζ}{}_{58}{}^{\mathrm{a}}\text{= + 0.33 (5)}$, $\text{ζ}{}_{68}{}^{\mathrm{a}}\text{= + 0.714 (20)}$, $\text{ζ}{}_{59}{}^{\mathrm{a}}\text{= ? 0.774 (20)}$, and $\text{ζ}{}_{69}{}^{\mathrm{a}}\text{= ? 0.30 (2)}$. Approximate ratios of unperturbed vibrational transition moments obtained from spectral simulations are $\text{M}{}_8{}^0\text{:±iM}{}_5{}^0\text{:±iM}{}_6{}^0\text{:M}{}_9{}^0\text{≈ +2:?9:+10:+0.5}$.     

Third order elastic constants of rubidium chloride

The third order elastic constants of RbCl, determined by measurements of the static stress dependence of ultrasonic waves, are found to be (in units of 10¹²$\text{dynes}\text{cm}{}^2$)

$\text{C}{}_{111}\text{= ?6.71 ± 0.1 C}{}_{123}\text{= 0.05 ± 0.07}$

$\text{C}{}_{112}\text{=?0.18 ± 0.04 C}{}_{144}\text{= 0.11 ± 0.02}$

$\text{C}{}_{166}\text{=?0.17 ± 0.01 C}{}_{456}\text{= 0.4 ± 0.01}$

. The calculation of third order constants using a rigid ion Born model is briefly discussed, and results are compared to the measurements. The comparison qualitatively supports the model, but no quantitative evaluation of the repulsive interaction is possible.     

Interference effects in 12C(p, γ)13N and direct capture to unbound states

Excitation functions of the capture reaction ¹²C(p, γ₀)¹³N have been obtained at θ_γ = 0° and 90° and E_p = 150–2500 keV. The results can be explained if a direct radiative capture process, E1(s and d → p), to the ground state in ¹³N is included in the analysis in addition to the two well-known resonances in this beam energy range $\text{[E}{}_{\mathrm{p}}\text{= 457(}\text{1}\text{2}{}^{\mathrm{+}}\text{)}$ and 1699 $\text{(}\text{3}\text{2}{}^{\mathrm{?}}\text{) keV]}$. The direct capture component is enhanced through interference effects with the two resonance amplitudes. From the observed direct capture cross section, a spectroscopic factor of C²S(l = 1) = 0.49 ± 0.15 has been deduced for the $\text{1}\text{2}{}^{\mathrm{?}}$ ground state in ¹³N. Excitation functions for the reaction ${}^{12}\text{C(p,γ}{}_1\text{p}{}^1\text{)}{}^{12}\text{C}$ have been obtained at θ_γ = 0° and 90° and E_p = 610–2700 keV. Away from the 1699 keV resonance the capture γ-ray yield is dominated by the direct capture process E1 (p → s) to the $\text{2366 (}\text{1}\text{2}{}^{\mathrm{+}}\text{) keV}$ unbound state. Above E_p = 1 MeV, the observed excitation functions are well reproduced by the direct capture theory to unbound states (bremsstrahlung theory). Below E_p = 1 MeV, i.e., E_p → 457 keV, the theory diverges in contrast to observation. This discrepancy is well known in bremsstrahlung theory as the “infrared problem”. From the observed direct capture cross sections at $\text{E}{}_{\mathrm{p}}\text{? 1 MeV}$, a spectroscopic factor of C²S(l = 0) = 1.02 ± 0.15 has been found for the $\text{2366 (}\text{1}\text{2}{}^{\mathrm{+}}\text{) keV}$ unbound state. A search for direct capture transitions to the $\text{3512 (}\text{3}\text{2}{}^{\mathrm{?}}\text{)}$and $\text{3547 (}\text{5}\text{2}{}^{\mathrm{+}}\text{) keV}$ unbound states resulted in upper limits of C²S(l = 1) ≦ 0.5 and C²S(l = 2) ? 1.0, respectively. The results are compared with available stripping data as well as shell-model calculations. The astrophysical aspect of the ¹²C(p, γ₀)¹³N reaction also is discussed.     

Band contour analysis of compounds with pure isotopes: The E fundamentals of HC35Cl3

The vibration-rotation transitions for v = 1 ← 0 of NO (${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$) have been studied by using the technique of laser magnetic resonance spectroscopy. Five magnetic resonance lines are observed with three CO laser lines in the range from 1859 to 1886 cm^?1. From these, three zero-field transition frequencies, v = 1 ← 0; $\text{R(}\text{3}\text{2}\text{)}$, $\text{P(}\text{7}\text{2}\text{)}$, and $\text{P(}\text{9}\text{2}\text{)}$ are obtained with an accuracy of ±0.0007 cm^?1. The molecular constants which have been determined by borrowing centrifugal constants from a previous infrared work are $\text{B}{}_{02}{}^1\text{= 1.72004 ± 0.00006}\text{cm}{}^{\mathrm{?1}}$, $\text{B}{}_{12}{}^1\text{= 1.70212 ± 0.00010}\text{cm}{}^{\mathrm{?1}}$, and $\text{G(v = 1) ? G(v = 0) (}\text{for}{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{) = 1875.8470 ± 0.0007}\text{cm}{}^{\mathrm{?1}}$.     

Nuclear matrix elements from L/K electron capture ratios in 59Ni decay

Using a recent theoretical method, the ratio of nuclear matrix elements $\text{R = (}{}^{\mathrm{v}}\text{F}{}^0{}_{220}\text{?√}\text{3}\text{2}{}^{\mathrm{A}}\text{F}{}^0{}_{221}\text{/}{}^{\mathrm{v}}\text{F}{}^0{}_{211}\text{)}$ was determined to be either 20.50^+0.35_?0.55 or 25.22^+0.28_?0.17 in the second-forbidden nonunique decay of 8 × 10⁴ y ⁵⁹Ni. These values of R were obtained from a value of L₃/K = 0.008 ± 0.002 found by subtracting the theoretical ratio $\text{(L}{}_1\text{+ L}{}_2\text{)}\text{K}$ = 0.113 (based on Q_PEC = 1070 ± 8 keV) from the total ratio L/K = 0.121 ± 0.002, which was measured with a reactor-produced, doubly-mass-separated ⁵⁹Ni source introduced as gaseous nickel-ocene, (C₅H₅)₂, into a wall-less, anticoincidence, multiwire proportional counter. The 854–1008 eV L and the 8.33 keV K peaks were measured simultaneously.     

Room temperature static lattice dielectric constant of lead telluride by a microwave cavity-perturbation technique

We have measured the room-temperature static lattice dielectric constant of PbTe using a cavity-perturbation technique. The result, ?_s = 800 ± 220, implies a transverse optic phonon frequency $\text{ω}{}_{\mathrm{<mtext>TO</mtext>}}\text{= 23 ±}{}^4{}_3$ cm^-1 in agreement with values extrapolated from low-temperature magnetoplasma measurements but in disagreement with the commonly-quoted neutron-diffraction result of Cochran et al., ω_TO = 31.7 ± 1.3 cm^-1.