Shock wave structure in a diatomic gas based on a kinetic model

The structure of a normal (direct) shock in a gas for the parameters corresponding to nitrogen is investigated with allowance for the rotational degrees of freedom on the basis of a model kinetic equation. For various Mach numbers the structure is compared with both the known experimental results and the solutions of the Navier-Stokes approximation within the framework of two-temperature hydrodynamics. The possibility of assuming the constancy of the fraction of excited rotational degrees of freedom is studied.     

Slip and Macroparameter Jumps of a Polyatomic Gas with Rotational Degrees of Freedom on a Weakly Curved Spherical Surface

The problem of the slip of a temperature-inhomogeneous polyatomic gas along a spherical surface of small curvature is solved. The solution is obtained using the half-space moment method on the basis of a previously proposed model kinetic equation which takes into account the rotational degrees of freedom of the polyatomic gas. Both the first- and second-order (in the Knudsen number) slip coefficients and the polyatomic gas macroparameter jump coefficients on the phase interface are obtained. These coefficients are given as functions of the tangential momentum accommodation coefficients, the translational and rotational energy accommodation coefficients, and the Prandtl number. The kinetic coefficients are calculated for certain polyatomic gases.     

Spherical flow of a diatomic gas from an evaporating drop

The spherical expansion of gas from an evaporating drop is investigated on the basis of the numerical solution to a model kinetic equation for a gas with rotational degrees of freedom. Examples considered are the stationary evaporation of a drop with given temperature into the vacuum and evaporation of a drop into a gas-filled space under the condition of an energy balance on the drop surface.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 4, pp. 184–187, July–August, 1980.     

Effect of Temperature on Slip Coefficients of Molecular Gases

Results obtained by accurate analytical methods applied to the problem of molecular-gas slip over a rigid spherical surface are reported. The Boltzmann equation is modified to take into account rotational degrees of freedom in the BGK model is used as a master kinetic equation. The calculated slip coefficients are shown to depend on the Prandtl number and on the gas temperature. Slip coefficients for several molecular gases are plotted as functions of temperature. __________ Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 47, No. 1, pp. 58–65, January–February, 2006.     

Influence of excitation of internal degrees of freedom of molecules on the process of weak evaporation or condensation

A study is made of the process of weak evaporation (or condensation) with allowance for excitation of vibrational and rotational degrees of freedom of diatomic molecules. The solution to the corresponding Knudsen layer problem is obtained on the basis of a model kinetic equation of the type of the Morse equation [1]. A relation is obtained that establishes the connection between the rate of evaporation (or condensation) and the parameters of the surface and the gas above it. The boundary conditions of slip for the equations of gas dynamics are analyzed. The results are compared with the evaporation or condensation in the case of a monatomic gas. The introduction of accommodation coefficients for an evaporating surface is considered.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 6. pp. 98–110, November–December, 1979.     

转动非平衡玻尔兹曼模型方程统一算法与全流域绕流计算应用

基于过去开展稀薄自由分子流到连续流气体运动论统一算法框架,采用转动惯量描述气体分子自旋运动,确立含转动非平衡效应各流域统一玻尔兹曼模型方程.基于转动能量对分布函数守恒积分,得到计及转动非平衡效应气体分子速度分布函数方程组,使用离散速度坐标法对分布函数方程所依赖速度空间离散降维;应用拓展计算流体力学有限差分方法,构造直接求解分子速度分布函数的气体动理论数值格式;基于物面质量流量通量守恒与能量平衡关系,发展计及转动非平衡气体动理论边界条件数学模型及数值处理方法,提出模拟各流域转动非平衡效应玻尔兹曼模型方程统一算法.通过高、低不同马赫数1:5～25氮气激波结构与自由分子流到连续流全飞行流域不同克努森数（9×10-4～10）Ramp制动器、圆球、尖双锥飞行器、飞船返回舱外形体再入跨流域绕流模拟研究,将计算结果与有关实验数据、稀薄流DSMC模拟值等结果对比分析,验证统一算法模拟自由分子流到连续流再入过程高超声速绕流问题的可靠性与精度.      

GAS-KINETIC UNIFIED ALGORITHM FOR BOLTZMANN MODEL EQUATION IN ROTATIONAL NONEQUILIBRIUM AND ITS APPLICATION TO THE WHOLE RANGE FLOW REGIMES

基于过去开展稀薄自由分子流到连续流气体运动论统一算法框架,采用转动惯量描述气体分子自旋运动,确立含转动非平衡效应各流域统一玻尔兹曼模型方程.基于转动能量对分布函数守恒积分,得到计及转动非平衡效应气体分子速度分布函数方程组,使用离散速度坐标法对分布函数方程所依赖速度空间离散降维;应用拓展计算流体力学有限差分方法,构造直接求解分子速度分布函数的气体动理论数值格式;基于物面质量流量通量守恒与能量平衡关系,发展计及转动非平衡气体动理论边界条件数学模型及数值处理方法,提出模拟各流域转动非平衡效应玻尔兹曼模型方程统一算法.通过高、低不同马赫数1：5～25氮气激波结构与自由分子流到连续流全飞行流域不同克努森数（9×10^-4～10）Ramp制动器、圆球、尖双锥飞行器、飞船返回舱外形体再入跨流域绕流模拟研究,将计算结果与有关实验数据、稀薄流DSMC模拟值等结果对比分析,验证统一算法模拟自由分子流到连续流再入过程高超声速绕流问题的可靠性与精度.     

Effect of inelastic collisions on the first-order slip coefficients for a diatomic gas with rotational degrees of freedom

When solving problems of inhomogeneous gas dynamics in the slip regime, it is necessary to know the boundary conditions for the velocity, temperature, heat fluxes, etc., that is, the boundary conditions for the gas macroparameters. In particular, such problems arise in developing the theory of thermophoresis of moderately large aerosol particles [1].The problem of monatomic and molecular (di- and polyatomic) gas slip along a boundary surface is considered in many publications (see, for example, [2–8]). The first-order effects include the isothermal and thermal gas slips characterized by the coefficients C_m and K_TS, respectively.In contrast to a monatomic gas, the molecules of diatomic and polyatomic gases have internal degrees of freedom, which considerably complicates the kinetic equation [9]. The lack of reliable models for the intermolecular interaction potential predetermines the need to construct model kinetic equations [10].In this study, for a diatomic gas whose molecules have rotational degrees of freedom, we propose a model kinetic equation obtained by developing the approach described in [6]. With the use of this model equation, the problem of diatomic gas slip along a plane surface is solved. As a result, for diatomic gases the coefficients C_m and K_TS, which depend on the thermophysical gas parameters and the intensity of inelastic collisions, are obtained.Translated from Izvestiya Rossiiskoi Academii Nauk, Mekhanika Zhidkosti i Gaza, No. 6, 2004, pp. 176–182. Original Russian Text Copyright © 2004 by Poddoskin.     

Poiseuille flow and thermal creep in a capillary tube on the basis of the kinetic R-model

Flow of a diatomic rarefied gas in a capillary tube of infinite length and an arbitrary cross-section under a given small pressure gradient (Poiseuille flow) or a small temperature gradient (thermal creep) is studied on the basis of a kinetic model that takes account for the rotational degrees of freedom of molecules (R-model). Numerical investigation is carried out for flows between parallel flat plates and in a circular capillary tube at the gas parameters corresponding to nitrogen. The main calculated quantity is the gas flow rate through a tube cross-section. The results are compared with the corresponding data obtained on the basis of the S-model.     

Approximating kinetic equation for weakly nonequilibrium states of polyatomic gases

The aim of the present paper is to construct an approximate kinetic equation that, first, takes into account correctly the possibility of excitation of both rotational and vibrational degrees of freedom of the molecules and, second, is valid for any law of intermolecular interaction.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 2, pp. 183–187, March–April, 1982.We thank M, Ya. Alievskio for helpful consultations.     

Influence of internal degrees of freedom on flow of a rarefied gas over a flat plate

Flow of a rarefied gas over a flat plate has been investigated numerically by a number of authors, using both the kinetic model equations (e.g., 1, 2]) and the Boltzmann equation [3, 6], In most cases a solution was found for a monatomic gas. The appreciable influence of the molecule structure on local and total aerodynamic characteristics and on the flow field over a flat plate at small angles of attack was noted in [1, 5, 7], where the authors examined various models for the rotational molecular degrees of freedom. In the present paper a two-point repulsion center model with constant collision cross section is used to investigate the influence of internal degrees of freedom of the molecule in flow over a plate, positioned parallel to (angle of attack = 0), and transverse to ( = 90 °) a rarefied gas stream. The data are compared with those calculated for a monatomic gas and from experimental results.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 6, pp. 151–156, November–December, 1978.     

Intense Condensation of a Molecular Gas

The kinetic problem of intense subsonic condensation of a polyatomic gas on a plane surface is solved by the method of semispatial moments. The contribution of the internal degrees of freedom to the total heat capacity is taken into account. The domains of existence of the Boltzmann equation solution are determined for the given method. Analytic expressions for calculating the gas concentration behind the Knudsen layer depending on the Mach number and temperature are derived for the cases of mon-, di-, and triatomic gases.     

Rotational relaxation of nitrogen in a viscous shock layer at low reynolds numbers

The viscous shock-layer model is used to examine relaxation of rotational degrees of freedom of molecular nitrogen in flow of a rarefied gas near the stagnation flow line around a sphere. It is shown that in the strongly smeared shock-wave region the rotational degrees of freedom can exhibit substantial nonequilibrium, leading to the increase of temperature and an increase of shock-layer thickness as compared with the equilibrium values. The influence of rotational relaxation on the shock-wave structure is discussed, and boundaries are found for the flow regions when rotational relaxation plays on important role,A comparison is made between the results of numerical calculations and experimentally obtained density profiles available in the literature near the stagnation line in flow of a rarefied gas over a sphere [1, 2]. Quite good agreement is obtained between the results of the calculation and experimental data over a wide range of Reynolds numbers.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 4, pp. 172–175, July–August, 1977.     

Possibility of forming an inverted distribution over the rotational levels of nitrogen in an expanding gas stream

A number of theoretical papers have been devoted to an investigation of the relaxation kinetics of the population of a system of rotational levels of molecules in a stream of gas freely expanding from a sonic nozzle [1–3]. The complexity of the task of constructing models of relaxation and of collisions consistent in accuracy, however, as well as the difficulties in solving the resulting system of kinetic and gas-dynamic equations, lead to the necessity of using substantial approximations. Some disagreement between the experimental data and calculated results [1, 2] requires an evaluation of the accuracy of the various approximations used and further refinement of the theoretical models. In contrast to [1], in order to bring out the possible mutual influence of nonequilibrium energy exchange between the degrees of freedom of nitrogen molecules and the variation of the gas-dynamic parameters, the calculation presented below is based on a numerical solution of a self-consistent system of kinetic and gas-dynamic equations for the populations of rotational states and the temperature, density, and velocity of gas in the stream. Collisional probabilities of rotational transitions, calculated with allowance for the long-range part of the potential of the interaction between molecules [4], are used for this.Translated from Zhurnal Prikladnoi Mekhaniki i Tekhnicheskoi Fiziki, No. 3, pp. 9–16, May–June, 1986.     

Slip coefficients and macroparameter jumps of a diatomic gas with rotational degrees of freedom on a weakly curved spherical surface

Using the half-space moment method, the problem of the slip of a diatomic gas along a rigid spherical surface is solved within the framework of a model kinetic equation previously proposed which takes into account the rotational degrees of freedom of the gas. Second-order slip coefficients (correctionsC _m ^′ , β _R ^′ , and β _R to the isothermal and thermal slip which are linear with respect to the Knudsen number Kn) are obtained. The gas macroparameter jump coefficientsC _v andC _q, which are of the second order in the Knudsen number and characterize the discontinuity of the normal mass and heat fluxes on the gas-rigid phase interface, are calculated. These coefficients are given as functions of the tangential momentum accommodation coefficient, the translational and rotational energy accommodation coefficients, and the Prandtl number. The coefficients are calculated for certain diatomic gases. Moscow. Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No. 1, pp. 163–173, January–February, 2000.     

Analytical solution of the problem of sphere rotation in a rarefied molecular gas

A problem of sphere rotation in a rarefied molecular gas is solved in an isothermal approximation. The particle velocity profile in the rarefied molecular gas entrained by the rotating sphere is obtained with a second-order correction in terms of the Knudsen number. For a rarefied molecular gas, in contrast to a monatomic gas, the particle velocity is demonstrated to depend substantially on the Prandtl number if rotational degrees of freedom of molecules are taken into account.     

Translationally nonequilibrium free jet boundary layer in the wake behind a wedge

Macroscopic equations obtained as a thin-layer version of the 13-moment Grad equations derived from kinetic considerations are used for describing the translationally nonequilibrium monatomic gas flow in a hypersonic free jet boundary layer formed in the wake behind a wedge. This model makes it possible to investigate flows with strong violations of equilibrium with respect to the translational degrees of freedom. A method of constructing the solution of this kinetically justified problem based on the solution of an analogous problem in the Navier-Stokes interpretation is proposed. It is established that for the kinetic variant of the problem considered the gas flow velocity distribution along the separating streamline in a plane orthogonal to the wedge generator coincides with the distribution obtained in solving the Navier-Stokes variant. It is found that taking into account the nonequilibrium nature of the flow with respect to the translational degrees of freedom of the gas particles has no effect on the base pressure and the wake angle.     

Effect of rotational degrees of freedom of molecules on energy flux in attenuated gas

On the basis of model kinetic equations a solution is obtained by a numerical method for the flow of attenuated gas around a sphere. The effect of rotational degrees of freedom on the energy flux to the body is investigated. Values of the ratio between the energy flux Q and its free-molecular value Q* for monatomic and diatomic gases are compared; for the comparison, the dimensionless temperature of the body, the gas velocity at infinity, and the law of viscosity must be the same in the two cases. For sufficiently cold bodies (when the body temperature is below the equilibrium temperature for a diatomic gas) the difference between Q/Q* for monatomic and diatomic gases is insignificant. For a diatomic gas when the body temperature is close to equilibrium, the ratio Q/Q* is found to have a nonmonotonic dependence on the Knudsen force.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 5, pp. 119–124, September–October, 1977.     

Direct Shocks in a Vibrationally Nonequilibrium Gas

Direct shocks in flows of a high-temperature diatomic gas with rotational and vibrational degrees of freedom are considered. Gas-dynamic parameters and populations of molecular vibrational levels behind a shock are studied for the case of disturbance of vibrational equilibrium in an incident flow.