13,8 Μ-Dublett von orientierten Schichten aus CH2-Kettenmolekeln

Ohne Zusammenfassung     

Crystal structure of Μ2, η2, Σ2-nitrato-η2, Σ2-nitrato-bis(1-ethyltetrazole-N4)copper(II) Cu(C3H6N4)2(NO3)2 = [Cu(C3H6N4)2(NO3)(NO3)2/2]∞

The complex compound of copper(II) nitrate with 1ethyltetrazole (ettz), Cu( C₃H₆N₄)₂(NO₃)(NO₃)_2/2] is studied by Xray diffraction analysis (“Syntex P2₁” automatic diffractometer, CuK_a radiation, graphite monochromator, 6/26 scan mode with V_min = 3.91 deg/min, the total number of data collected 3544 l_hkb including 3141 nonextinct l_hkl > 0, a correction for absorption (Μ = 25.08 cm^-1) applied by integrating over the crystal faces). The parameters of the orthorhombic unit cell (space group Pccn) are a = 15.436(3), b = 20.198(5), c = 19.587(3) Å, V_cell = 6107(2) Å^{3, Z} = 16, d_calc = 1.670 g/cm³. The two crystallographically independent copper atoms have a distorted octahedral environment (coordination node is CuN₂O₄), coordination number (CN) is 6 = 4 + t2. In the equatorial plane, two nitrogen atoms of ettz and two oxygen atoms of NO ₃ ^? groups are trans to each other; Cu-N = 1.983(8), C-O_{NO 3} ^? = 1.978(7) Å (average). The nitrato groups fulfill chelate and bridging functions, complementing the coordination polyhedra of the copper atoms to distorted octahedra, where Cu-O_{NO 3} ^? = 2.517(7) Å (average). The compound has a chain structure; the chains stretching along [001] are packed pairwise according to the hexagonal law.