A generalized rheological model of thixotropic materials

Summary A generalization of the rheological model of thixotropic materials, presented previously, was carried out. In the generalized rheological equation of state the yield stress depending on the structural parameter was introduced. In the generalized rate equation the difference in the destruction and recovery rates of the material structure was taken into account. A procedure leading to the determination of nine rheological parameters of the generalized model was worked out. The model was checked experimentally for a thixotropic paint.

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Zusammenfassung Eine früher dargestellte Theorie thixotroper Stoffe wird verallgemeinert, wobei eine von dem Strukturparameter abhängige Fließspannung eingeführt wird. Weiterhin wird der Unterschied zwischen der Zerstörungs-und der Wiederaufbaugeschwindigkeit der Stoffstruktur berücksichtigt. Eine Methode zur Bestimmung der neun benötigten Stoffparameter wird ausgearbeitet. Das Modell wird am Beispiel einer thixotropen Farbe experimentell geprüft.

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Notation a rheological parameter in eq. [26], s^–1 - A rheological parameter in eq. [16] - b rheological parameter in eq. [26] - c function in eq. [21] - averaged value of functionc in eq. [28] - c function in the rate equation [23], defined by eq. [21] - G function [1] defining material of the rate type - h function [2] determining the state of thixotropic fluid - k rheological parameter in the Herschel-Bulkley equation [17] or, in special case, in eq. [8], Ns ⁿ /m² - K function in eq. [18], Ns ^m /m² - m rheological parameter in eq. [18] or, in special case, in eq. [10] - n rheological parameter in the Herschel-Bulkley model [17] or, in special case, in eq. [8] - s rheological parameter in eq. [16] - t time, s - x arbitrary real variable - rheological parameter in eq. [9], s - shear rate, s^–1 - structural parameter, defined by eq. [2] - substantial derivative of structural parameter, s^–1 - _e function [6] describing the equilibrium curve in the coordinate system ( ) - ₀ initial value of structural parameter (att = 0) - natural time function of the thixotropic material, defined by eq. [22] - shear stress, N/m² - substantial derivative of shear stress, N/m² s - _e function describing equilibrium flow curve in the coordinate system ( ) - ₀ equilibrium yield stress, defined by eq. [12], N/m² - _y function of structural parameter describing the yield stress - function in eq. [11] Notation used in the algorithm:(Appendix) i,j,k integer - k _e (i) ordinal number of the experimental point at which the line of _i = const intersects the equilibrium flow curve - l _i number of the experiments of the type stepchange of the shear rate - l _j number of experimental points in one experiment of the type step-change of the shear rate - n _e number of experimental points on the equilibrium flow curve - n _k number of experimental points on the line of constant - n _y number of lines of constant - t(j) measured time interval (from the moment of the step-change of shear rate) - abscissa of the experimental point of ordinal numberk on the line of _i = const, in the coordinate system ( ) - abscissa of the experimental point of ordinal numberi on the equilibrium flow curve, in the coordinate system ( ) - shear rate at which the experiment of the type step-change of shear rate was carried out - _e (i) ordinate of the experimental point of ordinal numberi on the equilibrium flow curve, in the coordinate system ( ) - _y (i) value of yield stress at = _i - _s (i,j) experimental value of shear stress at constant value of shear rate (2i) for time intervalt(j) - (i,k) ordinate of the experimental point of ordinal numberk on the line of _i = const, in the coordinate system ( ) - ₀ the admissible value of the difference between the experimental and theoretical value of shear stress With 4 figures and 1 table     

Distribution of eddy viscosity and mixing length in a non-Newtonian flow of a solid particle-gas suspension

The present work concerns the study of the radial distribution of eddy viscosity and mixing length and their dependence upon the Reynolds number and the concentration of the solid phase in a non-Newtonian flow of a suspension of solid particles in a gas. The investigated systems have a pseudoplastic character and the deviation from Newtonian behaviour increases with an increase in the concentration of the dispersed phase. Relations are presented for the eddy viscosity and mixing length in the flow of pseudoplastic fluids. From the analysis of results it follows that the mixing length and eddy viscosity increases with an increase in the Reynolds number. In contrast, an increase in the concentration of the solid phase and consequently of the pseudoplasticity causes a decrease in the investigated quantities. The radial distribution of the mixing length and the eddy viscosity is characterized by a maximum, after which the investigated quantities vary only slightly. This enables the area of the core of the turbulent flow to be defined. E Non-dimensional eddy viscosity - K fluid consistency defined by Ostwald-De Waele's formula (power law) - K fluid consistency, eq. (12) - L mixing length - L _t non-dimensional mixing length - N ⁺ position parameter, eq. (3) - n power-law index - n ⁺ Reichardt's position parameter, eq. (4) - n slope of the dependence ln _w = f[ln (8w/D)] - R pipe radius - r radial distance from the pipe axis - Re=D W /µ Reynolds number - U ⁺ non-dimensional local mean axial velocity, eq. (2) - u ^* = w (/8)^0.5 friction velocity - non-dimensional local mean axial velocity - local mean axial velocity - u turbulence velocity component - mean axial velocity at pipe axis - w average velocity over cross-section of pipe - loading ratio of solid to air, i.e. ratio of mass flow rates of solids to air - Y _m ⁺ =Rⁿ u^2–n /K 8^n–1 non-dimensional distance of pipe centre from the wall - y distance from pipe wall - y ⁺ non-dimensional distance from pipe wall, eq. (5) - friction factor - µ _L laminar part of viscosity - µ _t eddy viscosity - density - shear stress - _w shear stress on the wall     

Helical flow of molten polymers in a cylindrical annulus

Summary The paper is concerned with an analytical investigation of helical flow of a non-Newtonian fluid through an annulus with a rotating inner cylinder. The shear dependence of viscosity is described by a power law and the temperature dependence by an exponential function.Velocity and temperature profiles, energy input and shear along the stream lines, pressure drop, and torque are presented for the range of input parameters encountered in polymer extrusion.The results of the study can be applied to a mixing element in a screw extruder and for a device to control extrudate temperature and output.Nomenclature a thermal diffusivity [m²/s] - b temperature coefficient [K^–1], see eq. [4] - c heat capacity [J/kg K] - h slot width [m] - I ₁,I ₂,I ₃ invariants of the rate of deformation tensor, see eq. [5] - k thermal conductivity [J/m s K] - l, L = 1/h length of the slot - l _T ,l _K thermal and kinematic entrance length - m power law exponent, see eq. [3] - M torque [m N] - p pressure [N/m²] - P dimensionless pressure gradient, see eq. [24] - P _R,P _RZ dimensionless components of the shear stress tensor, see eq. [25] and eq. [26] - r, R = r/r _wa radial coordinate - r _wa, r_wi outer and inner radius of annulus [m] - t time [s]; dwell time in the annulus - T temperature [K] - v , v_r, V_z velocity components [m/s] - v ₀ angular velocity at inner wall [m/s] - average velocity inz-direction [m/s] - V , V_R, V_Z dimensionless velocity components,v /v₀, v_r/v₀, v_z/v₀ - V _z velocity ratio, helical parameter - Y coordinate inr-direction, see eq. [20] - z, Z = z/h Pe axial coordinate - deformation - rate of deformation tensor [s^–1] - apparent viscosity [N s/m²], see eq. [3] - dimensionless temperature,b (T – T ₀) - azimuth coordinate - ratio of radii,r _wi/r_wa - density [kg/m³] - , kl shear stress tensor [N/m²] - fluidity [m²w/Nw s], see eq. [4] - Gf Griffith number, see eq. [12] - Pe Péclet number, see eq. [13] - Re Reynolds number, - 0 initial state, reference state - equilibrium state - e entrance - wi, wa at surface of inner or outer wall - r, R, z, Z, coordinates - i, j radial and axial position of nodal point in the grid - k, l tensor components Presented at Euromech 37, Napoli 6. 20–23. 1972.With 15 figuresDedicated to Prof. Dr.-Ing. G. Schenkel on his 60th birthday     

An approximate theoretical analysis and experimental verification of turbulent entrance region flow of drag reducing fluids

Summary Entry lengths for pipe flows of moderately drag reducing fluids are determined using momentum integral technique. It is shown theoretically that the entry lengths for drag reducing fluids could be significantly larger than the Newtonian fluids flowing turbulently under otherwise identical conditions. The experimental data from the literature bear out the theoretical calculations.

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Zusammenfassung Mit Hilfe der Impuls-Methode wird die Einlauflänge in einer Rohrströmung für Flüssigkeiten mit mäßig starker Widerstandsverminderung berechnet. Es wird vorausgesagt, daß die Einlauflänge für derartige Flüssigkeiten erheblich größer sein kann als für newtonsche Flüssigkeiten unter sonst identischen Bedingungen. Aus der Literatur entnommene experimentelle Daten bestätigen diese theoretischen Berechnungen.

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Nomenclature A ₁ Coefficient in eq. [7] - A Slope of logarithmic velocity profile - a Exponent in eq. [10] - B Intercept function for logarithmic velocity profile - De Deborah number, - f Friction factor - F Function, eq. [30] - G Function given in eq. [11] - Static pressure, dynes/cm² - q Index of power law velocity profile - R Pipe radius, cm - r Radial distance, cm - R Core radius, cm - Re Reynolds number - Axial velocity, cm/s - u _c Core velocity, cm/s - u ⁺ Dimensionless velocity, eq. [5] - u ^* Friction velocity, , cm/s - Radial velocity, cm/s - V Average velocity, cm/s - x Axial distance, cm - x _e Entry length, cm - y Distance from the wall, cm - y ⁺ Dimensionless distance, eq. [5] - y _I ⁺ Dimensionless viscous sublayer thickness - coefficient in eq. [17] - exponent of Reynolds number in eq. [17] - shear rate, s^–1 - boundary layer thickness, cm - _fl fluid relaxation time, s - µ fluid viscosity, gm/cm s - v kinematic viscosity, cm²/s - _l laminar sublayer thickness, dimensionless - fluid density, gm/cm³ - shear stress, dynes/cm² - _w shear stress at the wall, dynes/cm² - ₁, ₂, ₃, ₄ functions in eq. [27] - ~ time averaged quantities - — dimensionless quantity With 3 figures and 1 table     

Rheological properties of reactive polymer melts.

A new method for describing the rheological properties of reactive polymer melts, which was presented in an earlier paper, is developed in more detail. In particular, a detailed derivation of the equation of a first-order rheometrical flow surface is given and a procedure for determining parameters and functions occurring in this equation is proposed. The experimental verification of the presented approach was carried out using our data for polyamide-6.Notation E Dimensionless reduced viscosity, eq. (34) - E ₀ Newtonian asymptote of the function (36) - E power-law asymptote of the function (36) - E _{= 1} the value ofE at = 1 - k degradation reaction rate constant, s^–1 - k ₁ rate constant of function (t), eq. (26), s^–1 - k ₂ rate constant of function (t), eq. (29), s^–1 - K(t) residence-time-dependent consistency factor, eq. (22) - M _w weight-average molecular weight - M _x x-th moment of the molecular weight distribution - R gas constant - S _x M _x /M _w - t residence time in molten state, s - t _j thej-th value oft, s - T temperature, K - % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xd9vqpe0x% c9q8qqaqFn0dXdir-xcvk9pIe9q8qqaq-xir-f0-yqaqVeLsFr0-vr% 0-vr0db8meaabaqaciGacaGaaeqabaWaaeaaeaaakeaaieGaceWFZo% Gbaiaaaaa!3B4E!\[\dot \gamma \] shear rate, s^–1 - _i thei-th value of , s^–1 - _r =1 the value of at = 1, s^–1 - ^* reduced shear rate, eq. (44), s^–1 - dimensionless reduced shear rate, eq. (35) - viscosity, Pa · s - shear-rate and residence-time dependent viscosity, Pa · s - zero-shear-rate degradation curve - degradation curve at - _{t0 (t)} zero-residence-time flow curve - Newtonian asymptote of the RFS - instantaneous flow curve - power-law asymptote of the RFS - _0,0 zero-shear-rate and zero-residence-time viscosity, Pa · s - _E=1 value of viscosity atE=1, Pa · s - ^* reduced viscosity, eq. (43), Pa · s - zero-residence-time rheological time constant, s - density, kg/m³ - (t),(t) residence time functions     

Thermal effects in the capillary rheometer

Summary The effect of viscous heating in a capillary rheometer is analysed for a power-law fluid by means of a perturbation expansion based upon a boundary-layer-core structure. This expansion is found to complement the eigenfunction series solution obtained by earlier investigators. A similar analysis is presented for the work-of-expansion effect. These two thermal effects are superimposed together with a third perturbation effect due to the pressure dependence of viscosity.On the basis of the present theory, earlier work in this area is discussed and, in some cases, apparent inaccuracies or inconsistencies are pointed out. A means is indicated for correcting data on the basis of the present theory.

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Zusammenfassung Es wird der Effekt der Erwärmung einer Potenzflüssigkeit infolge viskoser Reibung in einem Kapillar-Rheometer mittels einer Störungsrechnung untersucht, die auf der Unterteilung der Strömung in eine Grenzschicht und einen Kern basiert. Diese Störungsentwicklung ergänzt eine früher von anderen Autoren gefundene Reihenentwicklung mit Hilfe von Eigenfunktionen. Eine ähnliche Untersuchung wird für die thermische Ausdehnungsarbeit durchgeführt. Diese beiden thermischen Effekte sind zusammen einem dritten Störeffekt superponiert, der von der Druckabhängigkeit der Viskosität herrührt.Aufgrund der vorgelegten Theorie werden verschiedene auf diesem Gebiet früher durchgeführte Arbeiten diskutiert, und es werden in einigen Fällen offensichtliche Ungenauigkeiten und Folgewidrigkeiten aufgedeckt. Schließlich wird eine Methode zur Korrektur von Meßdaten mit Hilfe der vorliegenden Theorie angegeben.

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Nomenclature a tube radius - b ; evaluated atT ₀ andp = 0 when used in perturbation expansion - C _p specific heat - f - f ^* - h defined by eq. [15] - k thermal conductivity - L tube length - m defined by eq. [8] - m ₀ m(T₀, 0) - n power-law index - p pressure - Pe C _p W a/k Peclet number - Pr C _pa/k Prandtl number - Q volumetric flow rate - Q ₀ unperturbed value ofQ in specified-p formulation - r radial coordinate - Re W a/ _a Reynolds number - T temperature - T ₀ inlet temperature - u radial velocity component - u ₀ 0 unperturbed radial velocity - w axial velocity component - w ₀ /W(1 – ) unperturbed axial velocity - W Q/(a ²) average axial velocity - W ₀ Q ₀/(a ²) - z axial coordinate - (3n + 1)/n - ^* ; evaluated atT ₀ andp = 0 when used in perturbation expansion - 4^1-n - ^* - (n + 1)/n - ... shear rate - 4W/a apparent shear rate - p total pressure drop - T _a W ²/k characteristic temperature difference - T _b total bulk-temperature rise - ^* T - r/a - shear viscosity - _a m₀ - (1 –)/ ^1/3 - —p/z - ₀ ... unperturbed value of - z-averaged value of - µ ^{n + 1}/n - z/(a Pe) - _L L/(a Pe) - mass density - _w shear stress at wall - streamfunction - ^*T₀ (absolute temperature scale) - ( )₁ leading-order effect due to viscous heating - ( ) ₁ ^* leading-order effect due to work-of-expansion Note: in specified-p formulation,W gets replaced byW ₀ in definition of Pe, Re, and. With 7 figures and 7 tables     

The rheology of polymeric liquid crystals

The molecular theory of Doi has been used as a framework to characterize the rheological behavior of polymeric liquid crystals at the low deformation rates for which it was derived, and an appropriate extension for high deformation rates is presented. The essential physics behind the Doi formulation has, however, been retained in its entirety. The resulting four-parameter equation enables prediction of the shearing behavior at low and high deformation rates, of the stress in extensional flows, of the isotropic-anisotropic phase transition and of the molecular orientation. Extensional data over nearly three decades of elongation rate (10^–2–10¹) and shearing data over six decades of shear rate (10^–2–10⁴) have been correlated using this analysis. Experimental data are presented for both homogeneous and inhomogeneous shearing stress fields. For the latter, a 20-fold range of capillary tube diameters has been employed and no effects of system geometry or the inhomogeneity of the flow-field are observed. Such an independence of the rheological properties from these effects does not occur for low molecular weight liquid crystals and this is, perhaps, the first time this has been reported for polymeric lyotropic liquid crystals; the physical basis for this major difference is discussed briefly. A Semi-empirical constant in eq. (18), N/m² - c rod concentration, rods/m³ - c ^* critical rod concentration at which the isotropic phase becomes unstable, rods/m³ - C interaction potential in the Doi theory defined in eq. (3) - d rod diameter, m - D semi-empirical constant in eq. (19), s^–1 - D _r lumped rotational diffusivity defined in eq. (4), s^–1 - rotational diffusivity of rods in a concentrated (liquid crystalline) system, s^–1 - D _ro rotational diffusivity of a dilute solution of rods, s^–1 - f distribution function defining rod orientation - F tensorial term in the Doi theory defined in eq. (7) (or eq. (19)), s^–1 - G tensorial term in the Doi theory defined in eq. (8) - K _B Boltzmann constant, 1.38 × 10^–23 J/K-molecule - L rod length, m - S scalar order parameter - S tensor order parameter defined in eq. (5) - t time, s - T absolute temperature, K - u unit vector describing the orientation of an individual rod - rate of change ofu due to macroscopic flow, s^–1 - v fluid velocity vector, m/s - v velocity gradient tensor defined in eq. (9), s^–1 - V mean field (aligning) potential defined in eq. (2) - x coordinate direction, m - Kronecker delta (= 0 if = 1 if = ) - _r ratio of viscosity of suspension to that of the solvent at the same shear stress - _s solvent viscosity, Pa · s - ^* viscosity at the critical concentrationc ^*, Pa · s - v ₁, v₂ numerical factors in eqs. (3) and (4), respectively - deviatoric stress tensor, N/m² - volume fraction of rods - ⁰ constant in eq. (16) - ^* volume fraction of rods at the critical concentrationc ^* - average over the distribution functionf(u, t) (= d ²u f(u, t)) - gradient operator - d ²u integral over the surface of the sphere (|u| = 1)     

Rotationsviskosimetrie mit kugelförmigen Spindeln

Zusammenfassung Die Rheodynamik der stationären viskometrischen Drehströmung um eine rotierende Kugel wird mit Methoden der Variationsrechnung untersucht. Neben iterativen numerischen Lösungsmethoden, die zu exakten Resultaten führen, wird auch eine approximative Ein-Gradienten-Lösung konstruiert, die durch Quadraturen dargestellt wird. Ausgehend von dieser analytischen Approximation werden einfache Methoden zur Auswertung von Experimentaldaten vorgeschlagen, die mit Hilfe von Eintauch-Rotationsviskosimetern mit kugelförmigen Meßspindeln gewonnen wurden.

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Summary The rotational viscometric flow around a rotating sphere has been studied by variational methods. The exact numerical, as well as an approximate analytical solutions are given. Employing the analytical approximation, a simple method of evaluating viscometric data from immersional (portable) viscometers with a rotating sphere is proposed.

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A Achsenschnitt durch den Bereich der Strömung - B - b, c anpaßbare empirische Konstanten - C Kalibrierungsoperator - D Schergeschwindigkeit der viskosimetrischen Strömung - D _ij Komponenten des Deformationsgeschwindigkeitstensors - D _I, _I Stoffkonstanten der VF des Ellis-Modells - g metrischer Koeffizient - H() Funktional der Ein-Gradienten-Approximation, Gl. [27] - J[] energetisches Potential - J _a[] Ein-Gradienten-Approximation fürJ - K Konsistenzkoeffizient, Parameter der VF des Potenzmodells - m Parameter des Ellis-Modells - M Drehmoment - n Parameter des Potenzmodells - n, n Differentialindices der VF, Gl. [20c, d] - n*,n** Differentialindices der RC, Gl. [9], [13] - r, , z polare Zylinderkoordinaten - R Spindelhalbmesser - rheometrischer Operator - S Spindeloberfläche - U(D) energetische Funktion nachBird, Gl. [20e] - v _i physikalische Komponenten der Geschwindigkeit - Z() transformierte VF, Gl. [20f] - (n) durch Gl. [35] definierte Funktion - k Verhältnis der Radien von Spindel und Wand - ( durch Gl. [43] definierte Funktion - natürliche (Radial-)Koordinate - Schubspannung der viskosimetrischen Strömung - _ij Komponenten des Spannungstensors - _S() Spannungsprofil an der Spindeloberfläche - _M Maximalspannung an der Spindeloberfläche - mittlere Spannung an der Spindeloberfläche, Gln. [3], [22] - natürliche (Meridional-) Koordinate - Winkelgeschwindigkeit in der Flüssigkeit - Winkelgeschwindigkeit der Spindelrotation - ( rheometrische Charakteristik Mit 4 Abbildungen und 3 Tabellen     

The chaotic response of a fluttering panel: The influence of maneuvering

The influence of maneuvering on the chaotic response of a fluttering buckled plate on an aircraft has been studied. The governing equations, derived using Lagrangian mechanics, include geometric non-linearities associated with the occurrence of tensile stresses, as well as coupling between the angular velocity of the maneuver and the elastic degrees of freedom. Numerical simulation for periodic and chaotic responses are conducted in order to analyze the influence of the pull-up maneuver on the dynamic behavior of the panel. Long-time histories phase-plane plots, and power spectra of the responses are presented. As the maneuver (load factor) increases, the system exhibits complicated dynamic behavior including a direct and inverse cascade of subharmonic bifurcations, intermittency, and chaos. Beside these classical routes of transition from a periodic state to chaos, our calculations suggest amplitude modulation as a possible new mode of transition to chaos. Consequently this research contributes to the understanding of the mechanisms through which the transition between periodic and strange attractors occurs in, dissipative mechanical systems. In the case of a prescribed time dependent maneuver, a remarkable transition between the different types of limit cycles is presented.Nomenclature a plate length - a _r u _r /h - D plate bending stiffness - E modulus of elasticity - g acceleration due to gravity - h plate thickness - j₁,j₂,j₃ base vectors of the body frame of reference - K spring constant - M Mach number - n 1 + ₀/g - N ₁ applied in-plane force - p–p aerodynamic pressure - P pa ⁴/Dh - q ₀/2 - Q _r generalized Lagrangian forces - R rotation matrix - R ₄ N, a ²/D - t time - kinetic energy - u plate deflection - u displacement of the structure - u _r modal amplitude - v₀ velocity - x coordinates in the inertial frame of reference - z coordinates in the body frame of reference - Ka/(Ka+Eh) - - elastic energy - 2qa ³/D - a/_mh - Poisson's ratio - material coordinates - air density - _m plate density - - _r prescribed functions - _r sin(r z/a) - angular velocity - a/v₀ - skew-symmetric matrix form of the angular velocity     

On the measurement of normal stress differences in steady shear flow

Summary Compared to the similar pressure-distribution cone-and-plate apparatus of Adams and Lodge (4), the new apparatus' improvements include: temperature control of the cone (as well as the plate); increased stiffening of the frame; four (not three) pressuremeasuring holes in the cone/plate region; inclusion of a pressure-measuring hole on the axis under the cone truncation; exclusive use of a vertical free liquid boundary at the cone rim (without a sea of liquid). Temperature control of the rotating cone and of the fixed plate leads to acceptable temperature uniformity in the test liquid for working temperatures within 10°C or 20°C of ambient; the corresponding interval is about 1°C if the cone temperature control is abandoned. Pressure gradients measured using a Newtonian liquid agree with those calculated using Walters' eq. (3). For a viscoelastic liquid, after subtracting inertial contributions, pressure distributions measured at a given shear rate in the cone/plate region do not change when the gap angle is changed from 2° to 3°, showing that the effects of secondary flow are negligible. Values ofN ₃ =N ₁ + 2N ₂ obtained from the gradients of these distributions are believed to be in error by not more than ±1 Pa, in favorable cases. The present most useful ranges are: 10 to 5000 Pa forN ₃; 0.1 to 200 sec^–1 for shear rate; up to 5 Pa s for viscosity; and 5 to 40°C for temperature. As an application, it is shown that adding 0.1% of a high molecular weight polyisobutylene to a 2% polyisobutylene solution doublesN ₃ and has no detectable effect on the viscosity measured at low shear rates with a Ferranti-Shirley viscometer.

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Zusammenfassung Im Vergleich zu dem ähnlichen Kegel-Platte-Gerät von Adams und Lodge (4) zur Messung der Druckverteilung wurden an dem neuen Gerät die folgenden Verbesserungen vorgenommen: Temperaturregelung an Kegel und Platte, Versteifung des Rahmens, vier (anstatt drei) Druckmeßlöcher im Kegel-Platte-Bereich, ein zusätzliches Druckmeßloch auf der Achse unter der Kegelstumpf-Deckfläche, ausschließliche Verwendung einer vertikalen freien Grenzfläche der Flüssigkeit am Kegelrand (ohne umgebenden Flüssigkeitssee). Die Temperaturregelung des rotierenden Kegels und der festen Platte führt zu einer ausreichenden Temperaturgleichförmigkeit in der Testflüssigkeit für Betriebstemperaturen, die höchstens um 10–20°C von der Umgebungstemperatur abweichen. Dieses Intervall beträgt dagegen nur etwa 1°C, wenn auf die Temperaturregelung am Kegel verzichtet wird. Für newtonsche Flüssigkeiten entsprechen die gemessenen Druckgradienten den mittels der Gleichung von Walters (3) berechneten. Für viskoelastische Flüssigkeiten zeigen sich bei der Änderung des Spaltwinkels von 2° auf 3° nach Abzug der Trägheitsbeiträge keine Änderungen der bei einer bestimmten Schergeschwindigkeit gemessenen Druckverteilung. Dies zeigt, daß Sekundärströmungseffekte vernachlässigbar sind. Es darf angenommen werden, daß die Werte vonN ₃ =N ₁ + 2N ₂, die man aus den Gradienten dieser Verteilungen erhält, unter günstigen Umständen mit einem Fehler von nicht mehr als ±1 Pa behaftet sind. Gegenwärtig liegen die günstigsten Bereiche bei 10 bis 5000 Pa fürN ₃, 0,1 bis 200 s^–1 für die Schergeschwindigkeit, unterhalb von 5 Pa s für die Viskosität und 5 bis 40°C für die Temperatur. Als Anwendung wird gezeigt, daß ein Zusatz von 0,1% hochmolekularen Polyisobutylens zu einer 2%igen Polyisobutylenlösung den Wert vonN ₃ verdoppelt, aber keinen erkennbaren Einfluß auf die (bei geringen Schergeschwindigkeiten mit einem Ferranti-Shirley-Viskosimeter gemessen) Viskosität hat.

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udsf unidirectional shear flow - TCP truncated-cone and plate - N ₁,N ₂ 1st and 2nd normal stress differences in udsf - N ₃ N ₁ + 2N ₂ - : = A is defined by the equationA := B - P ^* hole pressurePw – Pm; Pw, Pm = pressures measured by flush transducer and by hole-mounted transducer - t time - , strain rate, shear rate - (P,t) covariant body metric tensor at particleP and timet - ⁱ , _i covariant and contravariant udsf body base vectors (i = 1, 2, 3) - ^–1 inverse of - R, plate radius, cone/plate gap angle - r ₀,h ₀ radius and height of cone truncation - r,, spherical polar coordinates; cone axis = 0; plate surface = /2 - physical components of stress; for a tensile component - cone angular velocity - p on the plate = /2 - ,T, density, absolute temperature, viscosity - P 0.15 ²(r ² –R ²) (inertial contribution) [2.7] - P _ve contribution [2.8] from flow perturbations of viscoelastic origin - r _i i = 1,2,3,4; values ofr at centers of holes in cone/plate region - P _i () pressure change recorded by transducerTi when cone angular velocity goes from zero to - 1/2 {P _i ()+ P _i (–)} (average for 2 senses of rotation) - rim pressure, from least-squares line through four points - Re Reynolds' number:R ²/ - (P,t)/t With 11 figures and 2 tables     

Zur analytischen Beschreibung des Füllstoffeinflusses auf das Fließverhalten von Kunststoff-Schmelzen

From literature some representative equations have been compiled describing the influence of filler on the viscosity of polymer melts. By application of these on the experimental results obtained from GF-SAN it was found that the relative viscosity _R , i.e. the ratio of the viscosities of the filled and unfilled melt, shows a pronounced dependence on the shear rate but not on the shear stress. Defining _R with constant and not with constant (as it is usually done), an analytical approach is possible independent of Further the influence of pressure, temperature and filler content on the zero-shear viscosity of filled polymer melts may be expressed by a modified Arrhenius equation.

     

A general model for the effective viscosity of pseudoplastic and dilatant fluids

Summary A new and very general expression is proposed for correlation of data for the effective viscosity of pseudoplastic and dilatant fluids as a function of the shear stress. Most of the models which have been proposed previously are shown to be special cases of this expression. A straightforward procedure is outlined for evaluation of the arbitrary constants.

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Zusammenfassung Eine neue und sehr allgemeine Formel wird für die Korrelation der Werte der effektiven Viskosität von strukturviskosen und dilatanten Flüssigkeiten in Abhängigkeit von der Schubspannung vorgeschlagen. Die meisten schon früher vorgeschlagenen Methoden werden hier als Spezialfälle dieser Gleichung gezeigt. Ein einfaches Verfahren für die Auswertung der willkürlichen Konstanten wird beschrieben.

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Nomenclature b arbitrary constant inSisko model (eq. [5]) - n arbitrary exponent in eq. [1] - x independent variable - y(x) dependent variable - y ₀(x) limiting behavior of dependent variable asx 0 - y(x) limiting behavior of dependent variable asx - z original dependent variable - arbitrary constant inSisko model (eq. [5]) andBird-Sisko model (eq. [6]) - arbitrary exponent in eqs. [2] and [8] - effective viscosity = shear stress/rate of shear - _A effective viscosity at = _A - _B empirical constant in eqs. [2] and [8] - ₀ limiting value of effective viscosity as 0 - ₀() limiting behavior of effective viscosity as 0 - limiting value of effective viscosity as - () limiting behavior of effective viscosity as - rate of shear - arbitrary constant inBird-Sisko model (eq.[6]) - shear stress - _A arbitrary constant in eqs. [2] and [8] - ₀ shear stress at inBingham model - _1/2 shear stress at = ( ₀ + )/2 With 8 figures     

On the prediction of riblet performance with engineering turbulence models

The paper reports the outcome of a numerical study of fully developed flow through a plane channel composed of ribleted surfaces adopting a two-equation turbulence model to describe turbulent mixing. Three families of riblets have been examined: idealized blade-type, V-groove and a novel U-form that, according to computations, achieves a superior performance to that of the commercial V-groove configuration. The maximum drag reduction attained for any particular geometry is broadly in accord with experiment though this optimum occurs for considerably larger riblet heights than measurements indicate. Further explorations bring out a substantial sensitivity in the level of drag reduction to the channel Reynolds number below values of 15 000 as well as to the thickness of the blade riblet. The latter is in accord with the trends of very recent, independent experimental studies.Possible shortcomings in the model of turbulence are discussed particularly with reference to the absence of any turbulence-driven secondary motions when an isotropic turbulent viscosity is adopted. For illustration, results are obtained for the case where a stress transport turbulence model is adopted above the riblet crests, an elaboration that leads to the formation of a plausible secondary motion sweeping high momentum fluid towards the wall close to the riblet and thereby raising momentum transport.Nomenclature c _f Skin friction coefficient - c _f Skin friction coefficient in smooth channel at the same Reynolds number - k Turbulent kinetic energy - K ⁺ k/ _w - h Riblet height - S Riblet width - H Half height of channel - Re Reynolds number = volume flow/unit width/ - Modified turbulent Reynolds number - R _t turbulent Reynolds numberk ²/ - P _k Shear production rate ofk, _t (U _i /x _j + U _j /x _i ) U _i /x _j - dP/dz Streamwise static pressure gradient - U _i Mean velocity vector (tensor notation) - U Friction velocity, _w/ where _w=–H dP/dz - W Mean velocity - W _b Bulk mean velocity through channel - y ⁺ yU /v. Unless otherwise stated, origin is at wall on trough plane of symmetry - Kinematic viscosity - _t Turbulent kinematic viscosity - Turbulence energy dissipation rate - Modified dissipation rate – 2(k ^1/2/x _j )² - Density - _k , Effective turbulent Prandtl numbers for diffusion ofk and      

Influence of the formation of associations of macromolecules on the rheo-optical properties of their dilute solutions. I. Theory

Assuming the formation of doublets in the flow according to a mass action law, the shear rate and the concentration dependence of the extinction angle, of the birefringence, and of the average coil expansion are calculated for dilute solutions of flexible macromolecules. It is shown that this reversible association process has a strong influence on the measurable parameters in a flow birefringence experiment. c concentration (g/cm³) - h ² mean square end-to-end distance at shear rate - h ₀ ² mean-square end-to-end distance at zero-shear rate - n refractive index of the solution (not very different from the solvent for a very dilute solution) - E mean coil expansion - K ₀,K constant of the mass action law - M molecular weight - R _G gas constant - T absolute temperature - ₁ – ₂ optical anisotropy of the segment - ₀ Deborah number: - Deborah number: - shear rate - ₀, reduced concentration - _s viscosity of the solvent - [] ₀ intrinsic viscosity at zero-shear rate - [] intrinsic viscosity at shear rate - extinction angle - N _a Avodagro's number - _n magnitude of the birefringence     

Fractal-time stochastic processes and dynamic functions of polymeric systems

Dynamic material functions of polymeric systems are calculated via a defect-diffusion model. The random motion of defects is modelled by a fractaltime stochastic process. It is shown that the dynamic functions of polymeric solutions can be approximated by the defect-diffusion process of the mixed type. The relaxation modulus of Kohlrausch type is obtained for a fractal-time defect-diffusion process, and it is shown that this modulus is capable of portraying the dynamic behavior of typical viscoelastic solutions.The Fourier transforms of the Kohlrausch function are calculated to obtain and. A three-parameter model for and is compared with the previous calculations. Experimental measurements for five polymer solutions are compared with model predictions. D rate of deformation tensor - G(t) mechanical relaxation modulus - H relaxation spectrum - I(t) flux of defects - P _n (s) probability of finding a walker ats aftern-steps - P generating function ofP _n (s) - s(t) fraction of surviving defects - , () gamma function (incomplete) - ₀ zero shear viscosity - ^* () complex viscosity - frequency - t _n n-th moment - F[] Fourier transform - f ^* (u) Laplace transform off(t) - , components of ^* - G _f, _f ^* fractional model - G ₃, ₃ ^* three parameter model - complex conjugate ofz - material time derivative ofD     

Asymptotic Nusselt numbers for Newtonian flow through a parallel-plate channel with recycle

General expressions for evaluating the asymptotic Nusselt number for a Newtonian flow through a parallel-plate channel with recycle at the ends have been derived. Numerical results with the ratio of thicknesses as a parameter for various recycle ratios are obtained. A regression analysis shows that the results can be expressed by log Nur^0.83=0.3589 (log)² -0.2925 (log) + 0.3348 forR 3, 0.1 0.9; logNu=0.5982(log)² +0.3755 × 10^–2 (log) +0.8342 forR 10^–2, 0.1 0.9.

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Asymptotische Nusselt-Zahlen für die Newtonsche Strömung durch einen Kanal aus parallelen Platten mit Rückführung

Zusammenfassung In dieser Untersuchung wurden allgemeine Ausdrücke hergeleitet um die asymptotische Nusselt-Zahl für eine Newtonsche Strömung durch einen Kanal aus parallelen Platten mit Rückführung an den Enden berechnen zu können. Es wurden numerische Ergebnisse mit den Dicken-Verhältnissen, als Parameter für verschiedene Rückführungs-verhältnisse, erhalten. Eine Regressionsanalyse zeigt, daß die Ergebnisse wie folgt ausgedrückt werden können: log Nur^0,83=0,3589 (log)² -0,2925 (log) + 0,3348 fürR 3, 0,1 0,9; logNu=0,5982(log)² +0,3755 × 10^–2 (log) + 0,8342 fürR 10^–2, 0,1 0,9.

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Nomenclature A₁ shooting value,d(0)/d - A₂ shooting value,d(1)/d - B channel width - Gz Graetz number, U_bW²/L - h _m logarithmic average convective heat transfer coefficient - h _x average local convective heat transfer coefficient - k thermal conductivity - L channel length - Nu average local Nusselt number, 2 h_xW/k - Nu _m logarithmic average Nusselt number, 2h_mW/k - R recycle ratio, reverse volume flow rate divided by input volume flow rate - T temperature of fluid - T _m bulk temperature, Eq. (8) - T ₀ temperature of feed stream - T _s wall temperature - U velocity distribution - U _b reference velocity,V/BW - V input volume flow rate - v dimensionless velocity distribution, U/U_b - W channel thickness - x longitudinal coordinate - y transversal coordinate - Z₁-z₆ functions defined in Eq. (A1) - thermal diffusivity - least squares error, Eq. (A7) - weight, Eqs. (A8), (A9) - dimensionless coordinate,y/W - dimensionless coordinate,x/GzL - function, Eq. (7)     

Flow of second-order fluids over an enclosed rotating disc

Summary This paper is devoted to a study of the flow of a second-order fluid (flowing with a small mass rate of symmetrical radial outflow m, taken negative for a net radial inflow) over a finite rotating disc enclosed within a coaxial cylinderical casing. The effects of the second-order terms are observed to depend upon two dimensionless parameters ₁ and ₂. Maximum values ₁ and ₂ of the dimensionless radial distances at which there is no recirculation, for the cases of net radial outflow (m>0) and net radial inflow (m<0) respectively, decrease with an increase in the second-order effects [represented by T(=₁+₂)]. The velocities at ₁ and ₂ as well as at some other fixed radii have been calculated for different T and the associated phenomena of no-recirculation/recirculation discussed. The change in flow phenomena due to a reversal of the direction of net radial flow has also been studied. The moment on the rotating disc increases with T.Nomenclature , , z coordinates in a cylindrical polar system - z ₀ distance between rotor and stator (gap length) - =/z ₀, dimensionless radial distance - =z/z ₀, dimensionless axial distance - _s = _s/z₀, dimensionless disc radius - V =(u, v, w), velocity vector - dimensionless velocity components - uniform angular velocity of the rotor - , p fluid density and pressure - P =p/(₂ z ₀₂ ² , dimensionless pressure - ₁, ₂, ₃ kinematic coefficients of Newtonian viscosity, elastico-viscosity and cross-viscosity respectively - ₁, _{2 2}/z ₀ ² , resp. ₃/z ₀ ² , dimensionless parameters representing the ratio of second-order and inertial effects - m = , mass rate of symmetrical radial outflow - l a number associated with induced circulatory flow - Rm =m/(z ₀₁), Reynolds number of radial outflow - R _l =l/(z ₀₁), Reynolds number of induced circulatory flow - Rz =z ₀ ² /₁, Reynolds number based on the gap - ₁, ₂ maximum radii at which there is no recirculation for the cases Rm>0 and Rm<0 respectively - ₁(T), ₂(T) ₁ and ₂ for different T - U _1(T) ⁽⁺⁾ = dimensionless radial velocity, Rm>0 - V _1(T) ⁽⁺⁾ = , dimensionless transverse velocity, Rm>0 - U _2(T) ^(–) = , dimensionless radial velocity, Rm=–Rn<0, m=–n - V _2(T) ^(–) = , dimensionless transverse velocity, Rm<0 - C _m moment coefficient     

Viscoelastic swirling flow with free surface in cylindrical chambers

The flow of a viscoelastic liquid driven by the steadily rotating bottom cover of a cylindrical cup is investigated. The flow field and the shape of the free surface are determined at the lowest significant orders of the regular domain perturbation in terms of the angular velocity of the bottom cap. The meridional field superposed on a primary azimuthal field shows a structure of multiple cells. The velocity field and the shape of the free surface are strongly effected by the cylinder aspect ratio and the elasticity of the liquid. The use of this flow configuration as a free surface rheometer to determine the first two Rivlin-Ericksen constants is shown to be promising.Nomenclature R, ,Z Coordinates in the physical domain D - , , Coordinates in the rest stateD ₀ - r, ,z Dimensionless coordinates in the rest stateD ₀ - Angular velocity - Zero shear viscosity - Surface tension coefficient - Density - Dimensionless surface tension parameter - ₁, ₂ The first two Rivlin-Ericksen constants - Stream function - Dimensionless second order meridional stream function - ^* Dimensionless second normal stress function - 2 Dimensionless sum of the first and second normal stress functions - N ₁,N ₂ The first and second normal stress functions - n Unit normal vector - D Stretching tensor - A _n nth order Rivlin-Ericksen tensor - S Extra-stress - u Velocity field - U Dimensionless second order meridional velocity field - V Dimensionless first order azimuthal velocity field - p Pressure - Modified pressure field - P Dimensionless second order pressure field - J Mean curvature - a Cylinder radius - d Liquid depth at rest - D Dimensionless liquid depth at rest - h Free surface height - H Dimensionless free surface height at the second order     

Dehnungsverhalten von Polyäthylen-Schmelzen

Zusammenfassung In einem Dehnungsrheometer werden Spannungs-Dehnungs-Diagramme von Polyäthylen-Schmelzen bei 150 °C und bei konstanter Dehnungsgeschwindigkeit gemessen ( zwischen 0,001 und 1 sec^–1). Weiterhin wird der reversible (elastische) Dehnungsanteil bestimmt. Messungen mit einem Dehnungstester für Kunststoff-Schmelzen ergänzen die Ausführungen.Die Ergebnisse zeigen deutlich, daß bei Dehnung mit zunehmender Verformungsgeschwindigkeit die Dehnungsviskosität nicht abnimmt, im Gegensatz zu dem bekannten strukturviskosen Verhalten bei Scherung.Bei Dehnungen bis zu=1 kann das Verhalten unabhängig von beschrieben werden, wenn als viskoelastische Materialfunktion die Dehnungs-Spannviskosität betrachtet wird. In diesem Bereich von gilt dabei die BeziehungT(t)=3 _s (t) mit _s (t) als zeitabhängige Scherviskosität im linear-viskoelastischen Bereich.Bei größeren Dehnungen und nicht zu kleinen Dehnungsgeschwindigkeiten zeigt verzweigtes Polyäthylen eine zusätzliche starke Spannungszunahme. In dem Bereich dieser zusätzlichen Verfestigung ist das Verhalten im wesentlichen eine Funktion der Dehnung und fast unabhängig von . Die zusätzliche Verfestigung scheint eine Folge der Verzweigungsstruktur des verzweigten Polyäthylens zu sein, da bei Linear-PE ein derartiger Verlauf des Spannungs-Dehnungs-Diagramms nicht beobachtet wird.Die Betrachtung des reversiblen Dehnungsanteils _R zeigt bei der ausführlich untersuchten Schmelze I (verzweigtes PE) drei verschiedene Bereiche: Unterhalb einer Grenzdehnungsgeschwindigkeit ist _R =0, unterhalb einer Versuchszeitt ^** ist _R =. Im dazwischenliegenden Bereich treten elastische und viskose Dehnungsanteile auf,= _R + _V , wobei für niedrige gilt, daß _R lg . Die Grenze wird der Frequenz der thermisch aktivierten Platzwechsel zugeordnet,t ^** erscheint als Zeit, innerhalb der die Verhakungen wie fixierte Vernetzungen wirken.In dem Anhang wird der Einfluß der Grenzflächenspannung zwischen PE-Schmelze und Silikonöl auf die Ergebnisse der Dehnungsversuche diskutiert.

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Summary Stress-strain relations for different PE melts are measured at 150 °C in an extensional rheometer under the condition of a constant extensional strain rate ( between 0,001 and 1 sec^–1). Further, the recoverable (elastic) portion _R of the total strain ( in Hencky's measure) is determined and additional measurements with a tensile tester for polymer melts are described.The results show clearly that in extension there is no decrease of the tensile viscosity with increasing deformation rate, in contrast to the well-known pseudoplastic behaviour in shear. Within total strains<1 the tensile behaviour can be described independently from by means of a viscoelastic material function called stressing viscosity . In this range of the relation _T (t)=3 _s (t) holds, where _s (t) is the stressing viscosity in shear in the linear viscoelastic range. For larger tensile strains and not too small branched PB shows a remarkable increase in stress. This work-hardening behaviour is mainly a function of and almost independent from . This additional hardening seems to be due to the branches in branched PE, because linear PE does not show this effect.The discussion of the recoverable tensile strain _R gives three regions of tensile rate: Below a critical there is _R =0. At times shorter thant ^** the equation _R = is valid. Within these limits both elastic and viscous portions of the total strain= _R + _V exist. may correlate with the frequency of the thermally activated position changes of the molecular segments.t ^** is assumed to be the time for the entanglements to act as fixed cross-links.In the appendix the influence of the interface tension between PE melt and silicone oil on the results of the tensile experiments is discussed.

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Vorgetragen auf der Deutschen Rheologen-Tagung, Berlin, 11.-13. Mai 1970.

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An der Weiterentwicklung des Dehnungsrheometers, an der Durchführung und Auswertung der Messungen waren die HerrenB. Kienle, F. Landmesser, M, Reuther undF. Scherr beteiligt. Herr Dr.F.Ramsteiner und HerrH. Schroeck haben sich um die Herstellung der Stränge aus Linear-PE bemüht. Herr Dr.W. Ball besorgte die GPC-Messungen und Herr Dr.P. Simak die Ultrarot-Untersuchung. Den vorgenannten Herren sei für ihre Hilfe beim Zustandekommen dieser Arbeit gedankt. Herrn Dr.H. Baur danke ich für wertvolle Diskussionen.     

Second order gravitational field theories with hilbert gauge

Summary We consider, in the field-theoretical approach, a class of gravitational theories deducible by a variational principle in the unrenormalized pseudo-Euclidean space-time. At first order in the coupling constant f we require the theories to coincide with the Einstein one. Moreover we assume the Hilbert gauge which assure the exclusion of the vector component of the gravitational potential . To get the higher order consistency we substitute the most general energy-momentum tensor for the particle tensorT ^(p) in the field equations. Requiring the latter to be deducible by a variational principle varying the potentials , we get a Lagrangian which, varying the particle coordinates, gives the equations of motion. So we get a class of theories depending on 5 arbitrary parameters. To have observable quantities we have to renormalize. So we realize that, to satisfy the equivalence principle, we have to put one of the arbitrary parameters equal to zero. With this choice the class of theories coincides at second order with general relativity.

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Sommario Si vuole ottenere una classe di teorie gravitazionali deducibili da un principio variazionale, nell'ambito della teoria dei campi e nello spazio-tempo pseudoeuclideo non-rinormalizzato. Si richiede che tali teorie coincidano, al primo ordine nella costante di accoppiamento f, con la teoria di Einstein. Si assume inoltre la gauge di Hilbert al fine di escludere la presenza della componente vettoriale del potenziale . Per ottenere la consistenza al secondo ordine delle equazioni di campo, si sostituisce, in queste ultime, al tensore della particellaT ^(p) il più generale tensore energia-quantità-di-moto . Imponendo alle equazioni di campo di essere deducibili mediante un principio variazionale ove si varino i potenziali , si ottiene una lagrangiana che, ove si varino le coordinate della particella di prova, dà le equazioni di moto. In tal modo si ottiene una classe di teorie dipendenti da 5 parametri arbitrari. Per un confronto con i dati sperimentali è necessario rinormalizzare, onde esprimere quantità osservabili. Si dimostra così che per soddisfare il principio di equivalenza al secondo ordine è necessario porre uno dei 5 parametri uguale a zero e che, con tale scelta, l'intera classe di teorie coincide, al secondo ordine, con la relatività generale.

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Research sponsored by the CNR, Gruppi di ricerca Matematica