Electron－rich Polynuclear Transition Metal Clusters：Ⅱ．Synthetic and Structural Studies of Some Polynuclear Coinage Metal Cluster Compounds

Ｅｌｅｃｔｒｏｎ－ｒｉｃｈＰｏｌｙｎｕｃｌｅａｒＴｒａｎｓｉｔｉｏｎＭｅｔａｌＣｌｕｓｔｅｒｓ：Ⅱ．ＳｙｎｔｈｅｔｉｃａｎｄＳｔｒｕｃｔｕｒａｌＳｔｕｄｉｅｓｏｆＳｏｍｅＰｏｌｙｎｕｃｌｅａｒＣｏｉｎａｇｅＭｅｔａｌＣｌｕｓｔｅｒＣｏｍｐｏｕｎｄｓＨ...     

Structures and Vibrational Spectra of C_2 and LaC_2~ Clusters

ＳｔｒｕｃｔｕｒｅｓａｎｄＶｉｂｒａｔｉｏｎａｌＳｐｅｃｔｒａｏｆＣ２ａｎｄＬａＣ＋２Ｃｌｕｓｔｅｒｓ＊ＷＵＺｈｉ－ｊｉａｎ，ＭＥＮＧＱｉｎｇ－ｂｏａｎｄＺＨＡＮＧＳｉ－ｙｕａｎ＊＊（ＣｈａｎｇｃｈｕｎＩｎｓｔｉｔｕｔｅｏｆＡｐｐｌｉｅｄＣｈｅｍｉｓ...     

A New Advance in Preparation of Mo-S(O) Clusters

ＡＮｅｗＡｄｖａｎｃｅｉｎＰｒｅｐａｒａｔｉｏｎｏｆＭｏ－Ｓ（Ｏ）Ｃｌｕｓｔｅｒｓ￥ＹａｏＹｕａｎ－Ｇｅｎ；ＷｕＬｉｎｇ；ＺｈｕＹｏｎｇ－Ｂａｏ；ＬｕＳｈａｏ－Ｆａｎｇ；（ＦｕｊｔａｎＩｎｓｔｉｔｕｔｅｏｆＲｅｓｅａｒｃｈｏｎｔｈｅＳｔｒｕｃｔｕｒｅ...     

Study on the Magnetic Properties of MoFe_3S_4 Single Cubane－like Clusters Containing R_2dtc Ligands

ＳｔｕｄｙｏｎｔｈｅＭａｇｎｅｔｉｃＰｒｏｐｅｒｔｉｅｓｏｆＭｏＦｅ_３Ｓ_４ＳｉｎｇｌｅＣｕｂａｎｅ－ｌｉｋｅＣｌｕｓｔｅｒｓＣｏｎｔａｉｎｉｎｇＲ_２ｄｔｃＬｉｇａｎｄｓＬＩＵＱｉｕ－Ｔｉａｎ；ＤＥＮＧＹｕ－Ｈｅｎｇ；ＣＨＥＮＣｈａｎｇ－Ｎｅｎｇ（?..     

Quasi－aromaticity in Cluster Chemistry Ⅲ． Localized Molecular Orbital Study on Electron－rich Cobalt－sulfur Cluster Compounds ［Co_6（μ_3－X）_8L_6］~（n＋） （X＝S，Se；L＝PPh_3，PEt_3，CO；n＝0，1）

Ｑｕａｓｉ－ａｒｏｍａｔｉｃｉｔｙｉｎＣｌｕｓｔｅｒＣｈｅｍｉｓｔｒｙＩＩＩ．ＬｏｃａｌｉｚｅｄＭｏｌｅｃｕｌａｒＯｒｂｉｔａｌＳｔｕｄｙｏｎＥｌｅｃｔｒｏｎ－ｒｉｃｈＣｏｂａｌｔ－ｓｕｌｆｕｒＣｌｕｓｔｅｒＣｏｍｐｏｕｎｄｓ［Ｃｏ_６（μ_３－Ｘ）_...     

Asymmetric Synthesis of Chiral Clusters Induced by Chiral Phase-Transfer Catalyst

ＡｓｙｍｍｅｔｒｉｃＳｙｎｔｈｅｓｉｓｏｆＣｈｉｒａｌＣｌｕｓｔｅｒｓＩｎｄｕｃｅｄｂｙＣｈｉｒａｌＰｈａｓｅ－ＴｒａｎｓｆｅｒＣａｔａｌｙｓｔＷＵＳｈｕｌｉｎＤＩＮＧＥｒｒｕｎＬＩＱｉｎｇｓｈａｎＹＩＮＹｕａｎｑｉ１）（ＳｔａｔｅＫｅｙＬａｂｏｒａ...     

The Electronic Structures and Catalytic Activities of Triruthenium Ketenylidene Clusters Supported on Oxides

ＴｈｅＥｌｅｃｔｒｏｎｉｃＳｔｒｕｃｔｕｒｅｓａｎｄＣａｔａｌｙｔｉｃＡｃｔｉｖｉｔｉｅｓｏｆＴｒｉｒｕｔｈｅｎｉｕｍＫｅｔｅｎｙｌｉｄｅｎｅＣｌｕｓｔｅｒｓＳｕｐｐｏｒｔｅｄｏｎＯｘｉｄｅｓＬＩＺｈｉ－ｒｕ；ＸＩＡＯＦｅｎｇ－ｓｈｏｕ；ＺＨＡＮＧＹ...     

Quasi－aromaticity in Cluster Chemistry Ⅱ． Localized Molecular Orbital Studies on 〔Co_6（CO）_（14）〕~（4－） and 〔Ni_2Co_4（CO）_（14）〕~（2－） Cluster Anions

Ｑｕａｓｉ－ａｒｏｍａｔｉｃｉｔｙｉｎＣｌｕｓｔｅｒＣｈｅｍｉｓｔｒｙⅡ．ＬｏｃａｌｉｚｅｄＭｏｌｅｃｕｌａｒＯｒｂｉｔａｌＳｔｕｄｉｅｓｏｎ〔Ｃｏ_６（ＣＯ）_（１４）〕~（４－）ａｎｄ〔Ｎｉ_２Ｃｏ_４（ＣＯ）_（１４）〕~（２－）ＣｌｕｓｔｅｒＡｎｉ?..     

Preparation and Characterization of Macroporous Resin Immobilized Pd－Cu Bimetallic Cluster Catalysts

ＰｒｅｐａｒａｔｉｏｎａｎｄＣｈａｒａｃｔｅｒｉｚａｔｉｏｎｏｆＭａｃｒｏｐｏｒｏｕｓＲｅｓｉｎＩｍｍｏｂｉｌｉｚｅｄＰｄ－ＣｕＢｉｍｅｔａｌｌｉｃＣｌｕｓｔｅｒＣａｔａｌｙｓｔｓＷｕＳｈｉｈｕａ；ＺｈｕＣｈａｎｇｙｉｎｇ；ＨｕａｎｇＷｅｉｑｉｎｇ，...     

Structural Features and Interrelation of Two New Trinuclear Mo－S Cluster Compounds

ＳｔｒｕｃｔｕｒａｌＦｅａｔｕｒｅｓａｎｄＩｎｔｅｒｒｅｌａｔｉｏｎｏｆＴｗｏＮｅｗＴｒｉｎｕｃｌｅａｒＭｏ－ＳＣｌｕｓｔｅｒＣｏｍｐｏｕｎｄｓＬｕＳｈａｏ－Ｆａｎｇ；ＷｕＱｉａｎｇ－Ｊｉｎ；ＣｈｅｎＨｏｎｇ－Ｂｉｎｇ；ＹｕＲｏｎｇ－Ｍｉｎ；Ｈｕａｎ...     

Syntheses，Structures and Spectroscopic Properties of Mo（W）－Cu－S－Cluster Compounds with Dialkyldithiocarbamate Ligands

Ｓｙｎｔｈｅｓｅｓ，ＳｔｒｕｃｔｕｒｅｓａｎｄＳｐｅｃｔｒｏｓｃｏｐｉｃＰｒｏｐｅｒｔｉｅｓｏｆＭｏ（Ｗ）－Ｃｕ－Ｓ－ＣｌｕｓｔｅｒＣｏｍｐｏｕｎｄｓｗｉｔｈＤｉａｌｋｙｌｄｉｔｈｉｏｃａｒｂａｍａｔｅＬｉｇａｎｄｓＣａｏＲｏｎｇ；ＬｅｉＸｉｎ－Ｊｉ...     

Synthesis and structure of a novel MoFe_4S_4 cubane-like cluster (Me_3PhCH_2N)_2[MoFe_4S_4(SC_6H_(11))_7]

Ｉｔｉｓｗｅｌｌｋｎｏｗｎｔｈａｔｉｎｎａｔｕｒｅｔｈｅａｃｔｉｖａｔｉｏｎａｎｄｒｅｄｕｃｔｉｏｎｏｆｄｉｎｉｔｒｏｇｅｎｉｎａｉｒｔｏａｍｍｏｎｉａａｒｅｃａｔａｌｙｚｅｄｂｙｎｉｔｒｏｇｅｎａｓｅａｔａｍｂｉｅｎｔｔｅｍｐｅｒａｔｕｒｅａｎｄｐｒｅｓｓｕｒｅ.ＴｈｅｍａｉｎｃｏｍｐｏｎｅｎｔｓｏｆｔｈｅａｃｔｉｖｅｃｌｕｓｔｅｒｏｆＭｏＦｅｐｒｏｔｅｉｎｉｎｎｉｔｒｏｇｅｎａｓｅａｒｅＭｃｌｕｓｔｅｒ(ＭｏＦｅ7Ｓ9ｃｌｕｓｔｅｒ)ａｎｄＰｃｌｕｓｔｅｒ(Ｆｅ8Ｓ8ｃｌｕｓｔｅｒ)[1].Ｉｎｔｈｅｌ…     

Synthesis and Crystal Structure of〔( PPh_3)( CH_3 COS) _2 NiB_(10) H_(10)〕·0 .4( C_5 H_(12))

１　ＩＮＴＲＯＤＵＣＴＩＯＮＷｅｈａｖｅｓｈｏｗｎａｎｉｎｔｅｒｅｓｔｉｎｅｘｏｐｏｌｙｈｅｄｒａｌｃｙｃｌｉｚａｔｉｏｎｏｆｍｅｔａｌｌｉｇａｎｄｓｔｏｃｌｕｓｔｅｒ．ＡｓｅｒｉｅｓｏｆｍｅｔａｌｌａｂｏｒａｎｅｃｏｍｐｏｕｎｄｓｃｏｎｔａｉｎｉｎｇｆｉｖｅｍｅｍｂｅｒｅｄｒｉｎｇｓｓｕｃｈａｓＭ－Ｏ－Ｃ－Ｏ－ＢａｎｄＭ－Ｓ－Ｃ－Ｏ－Ｂａｒｅｓｙｎｔｈｅｓｉｚｅｄａｎｄｃｈａｒａｃｔｅｒｉｚｅｄ．Ｔｈｅｇｒｏｕｐｓｏｆｃｙｃｌｉｚａｔｉｏｎｉｎｃｌｕｄｅａｃｅｔａｔｅ〔１〕,ｂｅｎｚｏａｔ…     

Synthesis and Crystal Structure of Mixed Mo－W Cubane－type Cluster Compound ［Mo_2W_2S_4（μ－OAc）_2（dtp）_3（dtpH）］·CH_2Cl_2

Ｓｙｎｔｈｅｓｉｓ　ａｎｄ　Ｃｒｙｓｔａｌ　Ｓｔｒｕｃｔｕｒｅ　ｏｆ　Ｍｉｘｅｄ　Ｍｏ－Ｗ　Ｃｕｂａｎｅ－ｔｙｐｅ　Ｃｌｕｓｔｅｒ　Ｃｏｍｐｏｕｎｄ　［Ｍｏ_２Ｗ_２Ｓ_４（μ－ＯＡｃ）_２（ｄｔｐ）_３（ｄｔｐＨ）］·ＣＨ_２Ｃｌ_２ＣｈｅｎＱｉｕ－Ｈｕ?..     

Research on Reactivities of MoCluster． A Selective Substitution Reaction of the Bridging（dtp） Ligand and Structure of Tetranuclear Molybdenum Cluster Compound ［Mo_4S_4（μ－O_2CC_6H_5）_2（dtp）_4］

ＲｅｓｅａｒｃｈｏｎＲｅａｃｔｉｖｉｔｉｅｓｏｆＭｏＣｌｕｓｔｅｒ．ＡＳｅｌｅｃｔｉｖｅＳｕｂｓｔｉｔｕｔｉｏｎＲｅａｃｔｉｏｎｏｆｔｈｅＢｒｉｄｇｉｎｇ（ｄｔｐ）ＬｉｇａｎｄａｎｄＳｔｒｕｃｔｕｒｅｏｆＴｅｔｒａｎｕｃｌｅａｒＭｏｌｙｂｄｅｎｕｍＣ...     

Studies on Chem icalCom position ofIron-m olybdenum Cofactor fromNitrogenase by Fluorescence Analysis

ＩｎｔｒｏｄｕｃｔｉｏｎＮｉｔｒｏｇｅｎａｓｅｆｒｏｍａｖａｒｉｅｔｙｏｆＮ２－ｆｉｘｉｎｇｏｒｇａｎｉｓｍｓｉｓｃｏｍｐｏｓｅｄｏｆｔｗｏ－ｃｏｍｐｏｎｅｎｔｐｒｏｔｅｉｎ，ＭｏＦｅ－ｐｒｏｔｅｉｎａｎｄＦｅ－ｐｒｏｔｅｉｎ．Ｆｅ－ｐｒｏｔｅｉｎｃｏｎｔａｉｎｓａｓｉｎｇｌｅＦｅ４Ｓ４－ｃｌｕｓｔｅｒ，ｗｈｉｃｈｈａｓｔｈｅｆｕｎｃｔｉｏｎｏｆｔｒａｎｓｆｅｒｉｎｇｅｌｅｃｔｒｏｎｓｆｒｏｍｄｏｎｏｒｔｏＭｏＦｅ－ｐｒｏｔｅｉｎ．ＭｏＦｅ－ｐｒｏｔｅｉｎｃｏｎｔａｉｎｓＰ－ｃｌｕｓｔｅｒｐａｉ…     

Synthesis and Crystal Structure of (η~5 EtO(O)CC_5H_4)RuCoMo(μ_3-S)(CO)_8

１　ＩＮＴＲＯＤＵＣＴＩＯＮＩｎｔｈｅｄｅｖｅｌｏｐｍｅｎｔｏｆｔｒａｎｓｉｔｉｏｎｍｅｔａｌｃｌｕｓｔｅｒｓ,ａｇｒｅａｔｍａｎｙｔｅｔｒａｈｅｄｒｏｎ－ｔｙｐｅｃｈｉｒａｌｃｌｕｓｔｅｒｓｈａｖｅｂｅｅｎｓｙｎｔｈｅｓｉｚｅｄ．Ｏｎｅｉｍｐｏｒｔａｎｔｒｅａｓｏｎｉｓｔｈａｔｓｕｃｈｃｌｕｓｔｅｒｓｃａｎｂｅｐｏｔｅｎｔｉａｌｌｙｕｓｅｄａｓａｓｙｍｍｅｔｒｉｃｃａｔａｌｙｓｔｓｉｎｔｈｅｐｒｏｃｅｓｓｗｈｉｃｈｉｓｔｒｕｌｙｃｌｕｓｔｅｒ－ｃａｔ－ａｌｙｚｅｄ〔１,２〕．Ｈｏｗｅｖｅｒ,ｔ…     

Synthesis and Crystal Structure of μ_4－alkyne Cluster Complex（μ_4－η~2－C_2Ph_2）Co_4（CO）_8（μ－CO）_2

ＳｙｎｔｈｅｓｉｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆμ_４－ａｌｋｙｎｅＣｌｕｓｔｅｒＣｏｍｐｌｅｘ（μ_４－η~２－Ｃ_２Ｐｈ_２）Ｃｏ_４（ＣＯ）_８（μ－ＣＯ）_２ＳｏｎｇＬｉ－Ｃｈｅｎｇ;ＳｈｅｎＪｉｎ－Ｙｕ;ＨｕＱｉｎｇ－Ｍｅｉ;Ｈｕａｎｇ...     

Nonorthogonal Tight-binding Study of the Geometries and Electronic Properties of Ge_n(n=2—20)Clusters

ＩｎｔｒｏｄｕｃｔｉｏｎＳｔｕｄｉｅｓｏｎｃｌｕｓｔｅｒｓｏｆｇｒｏｕｐⅣｅｌｅｍｅｎｔｓ（Ｃ,Ｓｉ,Ｇｅ,ＳｎａｎｄＰｂ）ｈａｖｅｒｅｃｅｉｖｅｄｍｕｃｈａｔｅｎｔｉｏｎｉｎｔｈｅｌａｓｔｄｅｃａｄｅｆｏｒｔｈｅｉｒｐｏｔｅｎｔｉａｌａｐｐｌｉｃａ...     

Study on Infrared Spectra and Chemical Bonding of the Cluster Anion ［Cl_2FeS_2MoS_2Cu（PPh_3）_2］~－

ＳｔｕｄｙｏｎＩｎｆｒａｒｅｄＳｐｅｃｔｒａａｎｄＣｈｅｍｉｃａｌＢｏｎｄｉｎｇｏｆｔｈｅＣｌｕｓｔｅｒＡｎｉｏｎ［Ｃｌ_２ＦｅＳ_２ＭｏＳ_２Ｃｕ（ＰＰｈ_３）_２］~－ＫｏｎｇＸｉａｎ－Ｌｉｎｇ；ＣｈｅｎＺｈｉ－Ｄａ；ＳｈｅｎｇＴｉａｎ－Ｌｕ；ＷｕＸｉ...