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A series of ethylene-norbornene copolymers were synthesised using VO (OEt) Cl_2/Al_2Et_3Cl_3 catalytic system and their structure was characterized by ~1H-NMR, ~1H-~1HCOSY NMR and ~(13)C-NMR. Assignments of NMR spectra were given and discussed indetail. 相似文献
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用电荷转移络合物(CTC)自稳定沉淀聚合法合成出纳米尺寸马来酸酐-醋酸乙烯酯交联型共聚物微球,直径大约在150 nm左右.将少量这种新型纳米级共聚物微球添充到尼龙6(PA6)/线性低密度聚乙烯(LLDPE)体系中;发现纳米级微球颗粒的二乙烯基苯的双键以及酸酐基团分别能与两相发生化学反应,在尼龙6/聚乙烯体系中微球大部分出现在两相界面处,分析表明这些界面处的纳米级微球颗粒能够有效降低球状聚乙烯分散相的尺寸,使分散相粒径稳定在一个较小值(接近1μm),起到类似“分散相稳定剂”的作用.纳米级共聚物微球含量在1.75%左右时,各项性能得到较明显的提升.在拉伸强度与杨氏模量降低10%左右的情况下,冲击强度提高1.35倍,吸水百分率从纯尼龙64.9%下降到最小只有1.2%左右.对其增韧机理进行了初步探讨. 相似文献
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ZHANG Qing xin FU Peng peng ZHANG Hong fang MO Zhi shen ** State Key Laboratory of Polymer Physics Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun P. R. China 《高等学校化学研究》2002,18(3):358-363
IntroductionNylon 66,one of the most successfulcommercial polyamides,has been widely usednowadays as an engineering plastic in many fields.The development of the structure of nylons is acontinuing area of their technological and scientificstudy.The structure of nylon 66 during thephotoinduced decomposition process has beenstudied by resonance Raman[1] ,and the effect oftranscrystalline layers have been investigated[2— 4] .Moreover,the crystallization and meltingbehavior[5] have been learned … 相似文献
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MELTING CRYSTALLIZATION BEHAVIOR OF NYLON 66 总被引:2,自引:0,他引:2
Qing-xin Zhang Zhi-shen Mo State Key Laboratory of Polymer Physics & Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun China 《高分子科学》2001,(3):237-246
Analysis of isothermal and nonisothermal crystallization kinetics of nylon 66 was carried out using differentialscanning calorimetry (DSC). The commonly used Avrami equation and that modified by Jeziorny were used, respectively, tofit the primary stage of isothermal and nonisothermal crystallizations of nylon 66, In the isothermal crystallization process,mechanisms of spherulitic nucleation and growth were discussed. The lateral and folding surface free energies determinedfrom the Lauritzen-Hoffman treatment are σ= 9.77 erg/cm~2 and σ_e= 155.48 erg/cm~2, respectively; and the work of chainfolding is q = 33.14 kJ/mol. The nonisothermal crystallization kinetics of nylon 66 was analyzed by using the Mo methodcombined with the Avrami and Ozawa equations. The average Avrami exponent n was determined to be 3.45, Theactivation energies (ΔE) were determined to be -485.45 kJ/mol and -331.27 kJ/mol, respectively, for the isothermal andnonisothermal crystallization processes by the Arrhenius and the Kissinger methods. 相似文献
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丙烯-乙烯共聚物/乙烯-1-辛烯共聚物层状复合材料的力学性能研究 总被引:3,自引:0,他引:3
利用自主设计的一套可进行微层共挤出的口模,分别制备了2层、16层、32层和64层丙烯-乙烯共聚物(PPE)/乙烯-1-辛烯共聚物(POE)交替层状复合材料。研究了制得的层状复合材料的应力-应变行为,利用等效盒子模型(equivalent box model)描述了层状复合材料与相应的常规PPE/POE共混材料力学行为的区别.通过对共挤出材料和共混材料的拉伸数据进行分析后发现,具有层状结构特别是多层结构的共挤出材料具有比共混材料更为优异的屈服和断裂伸长性能. 相似文献
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In this paper, a new type of organophilic montmorillonites, co-treated by octadecylammonium and aminoundecanoic acid, were synthesized and applied to prepare nylon 66/montmorillonite nanocomposites via melt compounding in a twin extruder. WAXD and TEM characterization indicate that a disordered structure was derived and the montmorillonite platelets dispersed in nanoscale in the nylon 66 matrix. The nanocomposites with co-treated montmorillonite display comparatively higher strength and modulus compared to nylon 66 matrix. 相似文献
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聚酯-聚酯多嵌段共聚物序列结构研究 总被引:2,自引:2,他引:2
利用对苯二甲酸乙二酯-己内酯多嵌段共聚物质子谱中各官能团的特征共振吸收峰计算证明两种吸收强度关系式反映了软链段和硬链段中相应官能团的数量关系,从而进一步肯定了所提出的链化学结构,在此基础上又直接利用各种官能团对其质子谱中特征吸收峰的强度贡献,计算得到多嵌段共聚物中软硬链段数,软硬链段平均长度,分子量和硬链段重量百分数的表示式。本文最后一部分用三素组的几率计算方法对多嵌段共聚物的质子谱和~(13)C谱分析讨论,所得有关链结构的数量关系是合理的,进一步证实了质子谱的直接计算法。 相似文献
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均相催化剂制备的乙丙共聚物的组成均匀性研究 总被引:1,自引:0,他引:1
均相催化剂制备的乙丙共聚物的组成均匀性研究徐君庭范志强王齐封麟先(浙江大学高分子科学与工程学系杭州310027)关键词均相催化剂,乙丙共聚物,组成均匀性在高聚物的制备过程中,由于多种活性中心的存在、活性中心随时间的变化及聚合条件的波动等因素使得... 相似文献
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采用溶液共混-共沉淀的办法获得尼龙6及聚酰胺嵌段共聚物/尼龙6共混体系粉末,样品在260℃下熔融之后经程序降温的方法得到非淬火样品,然后分别在190℃下高温退火不同时间(0~48 h),采用示差扫描量热仪(DSC)、广角X射线衍射仪(WAXD)、偏光显微镜(POM)等表征手段研究热处理对体系晶体熔融行为和结晶结构的影响.结果表明,(1)在相同的热历史条件下,嵌段共聚物的存在影响了尼龙6的结晶行为及结晶结构;(2)退火处理对两种样品有着不同的影响,对于尼龙6体系,退火处理促进了非晶相向晶相的转变,大大提高样品的结晶完善程度和结晶度;对于共混体系,退火处理同样促进了非晶相向晶相的转变,同时形成新的α型和γ型结晶,体系的结晶完善程度明显提高,退火48 h后,结晶度比原始样品提高约84%. 相似文献
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尼龙66/蒙脱土复合材料结晶行为的研究 总被引:8,自引:0,他引:8
在密炼机中采用熔融共混法制备蒙脱土重量分数为 2 5 %、4 5 %的尼龙 6 6 /蒙脱土复合材料 .通过DSC法对非等温结晶行为及在 2 2 8~ 2 4 0℃范围内的等温结晶行为进行研究 ,并与纯尼龙 6 6进行比较 .从其等温和非等温结晶行为的研究表明 ,蒙脱土起成核剂的作用 ,它的填入使尼龙 6 6结晶速率提高 ,但填料与基体间的相互作用使其链段运动困难 ,结晶活化能提高 ;在研究的填料含量变化范围内 ,结晶行为变化不大 ,并且找到该复合材料在 2 2 8~ 2 34℃范围结晶对温度的不敏感区 ;对非等温结晶过程分析 ,刘结平 莫志深方程是适用的 ,而Ozawa方程则是不适用的 . 相似文献
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John Hee Hong S. Ramasundaram A. Anand Prabu Kap Jin Kim Jun Ho Yang 《Polymer Degradation and Stability》2008,93(2):392-400
Nylon 66 (NY66) polymer based products widely used in automotive applications undergo deterioration in their mechanical properties when repeatedly exposed to ethylene glycol (EG) solution. In this study, recycling of glycolyzed NY66 (g-NY66) samples was carried out through melt-compounding with novel isocyanate based chain extenders namely hexamethylene 1,6-dicarbamoyl dicaprolactam (HDC) and tolylene 2,4-dicarbamoyl dicaprolactam (TDC). The recycling efficiency of HDC and TDC on g-NY66 was compared with two commercially available chain extenders 1,1-carbonyl biscaprolactam (CBC) and 1,3-phenylene bis(2-oxazoline) (PBO), and the resultant changes in molecular weight, melt flow, and crystallization behavior in the modified NY66 samples were confirmed from intrinsic viscosity, rheology, and differential scanning calorimetry measurements, respectively. The active ingredients (isocyanate and ?-caprolactam) liberated from HDC and TDC during the melt-compounding process reacted efficiently with the end groups of g-NY66 (-OH and -NH2) resulting in improved molecular weight compared to g-NY66 and the results are reported in detail. 相似文献
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The polyester-polyetber segmented copolymer has been investigated by rheo-optical FTIR during stretehing for the informastion on strain induced crystallizatinn of soft segment chains, hard and soft chain orientation.At room temperature 15℃, the soft segment chains of polyester-polyether being to crystallize at 220% strain and the degree of crystallixation increa(?)e with draw ratio, but there will not be any soft segment chains crystallization above 21℃even at bigber strain. The average orientation of hard segment chains are higher than that of the soft chain at high strain level, both are positive oriented into the stretching direction at allover strain level. This indicates that the b(?)d (?)ent ch(?)ins are dispersed into the elastomeric phase and without forming spherulite. 相似文献
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生物降解高分子——聚己内酯/聚氧乙烯/聚丙交酯三元共聚物水解行为的研究 总被引:5,自引:0,他引:5
以异辛酸亚锡为催化剂 ,通过聚乙二醇醚 (PEG)引发ε 己内酯和L 丙交酯开环聚合 ,制备了PCL/PEO/PLA三元共聚物 .研究了聚合物在 pH7 4磷酸缓冲溶液、37℃条件下的体外降解行为 .采用GPC、1H NMR、DSC和XRD技术研究了聚合物在水解降解过程中分子量、分子量分布、组成、吸水率、结晶性等的变化 .结果表明共聚物的吸水率随聚醚组分含量而增大 ;随水解材料的失重率增大 ,聚醚组分含量下降程度也加大 .此外研究还表明 :聚合物中丙交酯组分含量高时 ,聚合物的结晶结构主要由PLLA形成 .由于聚合物的水解降解首先发生在无定形区和结晶区边缘 ,随着共聚物的降解、结晶性的PLLA低聚物的生成 ,导致了共聚物的分子量呈双峰分布 相似文献
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用反相悬浮聚合法制备了交联度分别为10%、7.5%、5%、1%、0.5%及0.25%的丙烯酰胺-丙烯酸P(AAM-NaAA)交联共聚水凝胶,用HNMR驰豫方法测定了水及聚合物主链上(-CH2CH-)基团中质子的自旋-自旋驰豫时间(T2),并结合质子线型分析,研究了交联凝胶在溶胀态下的内部分子运动,讨论了不同交联度下谱线线宽及驰豫变化的机制。结果表明,由于交联使凝胶内部各向异性相互作用增强,存在有残余的偶极-偶极相互作用,质子语具有特征的超Lorentz线型;质子线宽比非交联态时加大,水及主链的T2随交联度的加大而减小,反映了内部分子运动由强变弱的过程;水的T2驰豫不是单纯的单指数驰豫行为,表明凝胶内部有较强的键合束缚水存在,与DSC实验的结论一致。 相似文献
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