Loss due to magnetic-rotation hysteresis in bismuth calcium vanadium iron garnet

The field and temperature dependences of the loss due to magnetic-rotation hysteresis have been determined by the rotational-moment method in a (Bi_0.32Ca_2.68Fe_3.66V_1.34O₁₂) single crystal. In the temperature range between –183 and +25 °C, the loss increases with increasing field, reaching a maximum at 2500–6000 Oe; then it decreases, vanishing completely in high fields. The loss behavior can be described well at all temperatures studied by an exponential dependence on the field.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, Vol. 12, No. 2, pp. 65–69, February, 1969.     

Growth and magnetic behavior of bismuth substituted yttrium iron garnet nanoparticles

Crystal growth and the magnetic properties of bismuth substituted yttrium iron garnet (Bi-YIG) nanoparticles were studied with particular focus on the bismuth composition dependence of the magnetic properties of the particles and the effects of annealing on the garnet phase formation. The Bi-YIG nanoparticles of 47–67 nm in size can be chemically synthesized when they are annealed at 650–850 °C. Both the lattice constant and the magnetization of the garnet nanoparticles linearly increase when the bismuth composition in the Bi-YIG particles increases. We have found that chemically synthesized nanoparticles transform from the amorphous to the garnet phase when annealed at temperatures below 650 °C, while the onset of magnetic moment of iron in the garnet nanoparticles is observed slightly above 650 °C. According to Mössbauer effect measurements, the hyperfine fields of ⁵⁷Fe at the tetrahedral and octahedral sites in the garnet are 39 and 48 T, respectively.     

High-temperature dynamics of surface magnetism in iron thin films

Finite-temperature magnetic properties of iron thin films are investigated by computer simulation over a broad range of temperatures up to the point of the ferromagnetic–paramagnetic phase transition. The coupled dynamics of atoms and magnetic moments is treated using the large-scale spin–lattice dynamics (SLD) algorithm. We investigate surface and bulk magnetic properties of iron, and how these properties vary as a function of temperature, film thickness and surface crystallography. We find that magnetization at surfaces is enhanced at low temperatures and suppressed at higher temperatures, in agreement with experimental observations. The effective Curie temperature of a film decreases as a function of thickness. Short-range magnetic order and non-vanishing spin–spin spatial correlations are found above the Curie temperature. The spin autocorrelation functions exhibit slower oscillations with longer decoherence times near the surface. We also find that the directional spin disorder has a significant effect on the surface strain.     

Reversible-adsorption-induced variation of domain width in iron garnet films

It has been found using the Faraday-effect magneto-optic method that the width of magnetic domains of the labyrinth domain structure in bismuth-containing iron garnet films with perpendicular anisotropy changes considerably after the adsorption of methanol molecules. A maximum change in domain width of 50% has been observed in methanol saturated vapor. This effect is reversible. A decrease in domain width under adsorption has been attributed to a decrease in the effective constant of the perpendicular magnetic anisotropy of the film caused by the adsorption of methanol molecules.     

Layered structure of epitaxial yttrium iron garnet films

The layered structure of yttrium iron garnet films, ranging in thickness from 0.7 to 4.1 μm, grown epitaxially on single-crystal gallium-gadolinium garnet substrates, was investigated by x-ray spectral microanalysis. The ferrite films were chemically etched layer by layer in a mixture of orthophosphoric and sulfuric acids at T=353–423 K. It was established that the chemical composition of the films varies over the thickness because of the nonuniform distribution of gadolinium, gallium, lead, and platinum ions; the film-substrate transitional layer and the surface layer of the film differ most greatly with respect to the composition and magnetic properties. It was shown that the thickness of the transitional layers and their negative effect on the magnetic characteristics of ferrite films decrease appreciably if at the time of immersion of the substrate and pulling of epitaxial structure out of the fluxed solution the substrate holder together with a special mixer rotate at a rate of 50 rpm and the pulling velocity is 20 cm/min. Zh. Tekh. Fiz. 69, 62–64 (December 1999)     

Wavelength modulation spectroscopy of epitaxial iron garnet films

Derivative absorption and reflectance spectra are reported for epitaxially grown iron garnet films and compared with derivative absorption results for bulk yttrium gallium garnet dilutely doped with Fe³⁺ Results are briefly discussed in terms of crystal field transitions, charge transfer excitons, and charge transfer bands all involving the iron 3d electrons.     

Exchange coupling in ultrathin epitaxial yttrium iron garnet films

Magnetic exchange coupling has been observed for ultrathin films of yttrium iron garnet (Y₃Fe₅O₁₂ or YIG). Single-crystalline YIG films were prepared on yttrium aluminium garnet (Y₃Al₅O₁₂ or YAG) substrates by pulsed laser deposition. (111) and (110) oriented substrates were used. Film thicknesses were varied from 180 ? to 4600 ?. Epitaxial growth of YIG on YAG was obtained in spite of the lattice mismatch of 3%. Magnetic hysteresis loops recorded for ultrathin YIG films have a “bee-waist” shape and show a coupling between two different magnetic phases. The first phase is magnetically soft YIG. A composition study by secondary ion mass spectroscopy shows the second phase to be Y₃Fe_5-xAl_xO₁₂ due to the interdiffusion of Fe and Al at the film/substrate interface. This compound is known to be magnetically harder and to have weaker magnetization than YIG. The coupling of the two phases leads to a hysteresis loop displacement at low temperatures. This displacement varies differently with film thickness for two substrate orientations. Assuming an interfacial coupling, the maximal interaction energy is estimated to be about 0.17 erg/cm² at 5 K for (111) oriented sample. Received 3 June 2002 / Received in final form 7 October 2002 Published online 27 January 2003 RID="a" ID="a"Presently at LPM, Université H. Poincaré, BP 239, 54506 Vandœuvre-lès-Nancy e-mail: popova@lpm.u-nancy.fr     

Bias-field-induced spiral dynamic domains induced in iron garnet films

The induction of an Anger state (AS) in a multidomain magnetic medium by a static bias magnetic field is observed. The properties of the spiral dynamic domains in the induced AS are substantially different from those of previously studied spiral domains. Pis’ma Zh. éksp. Teor. Fiz. 65, No. 1, 60–64 (10 January 1997)     

Optical isolators using Bi-substituted rare-earth iron garnet films

Using Bi-substituted rare-earth iron garnet film, (GdBi)₃ (FeAlGa)₅O₁₂ or (YbTbBi)₃ Fe₅O₁₂, grown by liquid phase epitaxy technique, we have fabricated a compact, low cost and high performance optical isolator for near-infrared wavelength region, in comparison with conventional isolator using yttrium iron garnet (YIG) single crystal as Faraday rotator. Typical insertion loss and isolation of developed isolators are 0.6 dB and 35 dB respectively at =1.31 m and the size is 6×6 mm. The isolators, which could be used in the wavelength range of 1.31 to 1.55 m, are also fabricated with insertion loss of less than 1.1 dB and isolation of more than 35 dB.     

Evolution of magnetoresistance effect in iron–bismuth films

A unique time-dependent magnetotransport behavior has been observed in Fe–Bi films. Approximately one month was required to stabilize resistance after samples were fabricated. Initially, the as-prepared Fe–Bi films exhibit both ordinary magnetoresistance (MR) and anisotropic magnetoresistance. Fe precipitation changes the microstructure. Eventually, an isotropic and negative MR, like a giant MR effect was observed; it arises from electronic transport between Fe granules separated by Bi.     

Structure and properties of deposited yttrium iron garnet films

Ferromagnetic resonance (FMR) and vibrating-sample magnetometer techniques were used to study the nature of the structural characteristics of yttrium iron garnet films deposited through either liquid phase epitaxy or laser evaporation on a (111)-oriented gallium gadolinium garnet substrate. It was proved that, based on the experimentally observed cubic magnetic anisotropy, deposited films should be considered to be single crystals. However, the absence of the FMR domain branch in a nonsaturated film and the shape of the magnetization curve indicate that a deposited film when demagnetized does not have a domain structure, as would be expected for a single-crystal film. According to the model proposed, a deposited film consists of close-packed single-crystal fragments with equal crystallographic orientation, the boundaries between which are in a partially atomically disordered state. As a result, such a film is both locally and macroscopically anisotropic, like a continuous single crystal. This film can split into domains only within a fragment (as is the case in a magnetic granular polycrystal); however, this does not happen, because the linear dimensions of a submicroscopic fragment are smaller than the equilibrium domain width.     

Luminescence centers in thin films of yttrium oxide and yttrium-aluminum garnet activated with bismuth

Luminescence spectra and photoluminescence excitation spectra of Y₂O₃:Bi and Y₃Al₅O₁₂:Bi thin films were investigated. Luminescence was stimulated by the emission from two types of centers that were associated with the substitution of Bi³⁺ for Y³⁺ in sites of the crystal lattice of Y₂O₃ (Y₃Al₅O₁₂) with point symmetries C₂ and C_3i (D₂ and C_3i). The emission of Bi³⁺ in the site with point symmetry C_3i causes blue luminescence in both Y₂O₃:Bi and Y₃Al₅O₁₂:Bi films with maxima at 3.03 eV and 3.15 eV, respectively, that is related to the ³P₁-¹S₀ transition. The emission of Bi³⁺ in the site with point symmetry C₂ gives green luminescence in Y₂O₃:Bi with the maximum at 2.40 eV that is also related to the ³P₁-¹S₀ transition. The emission of Bi³⁺ in the site with point symmetry D₂ leads to ultraviolet luminescence in Y₃Al₅O₁₂:Bi with the maximum at 3.75 eV that corresponds to the ³P₁-¹S₀ transition. The red luminescence band with the maximum at 1.85 eV in Y₂O₃:Bi is due to the presence of structural defects. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 75, No. 2, pp. 202–207, March–April, 2008.     

Four-magnon decay of magnetostatic surface waves in yttrium iron garnet films

The four-magnon instability of magnetostatic surface waves (MSSWs) in yttrium iron garnet epitaxial films is investigated experimentally. It is shown that four-magnon instability for MSSWs with wave numbers 30–600 cm⁻¹ is a decay instability and develops for values of the wave magnetization close to the threshold level for second-order parametric instability of a homogeneous transverse pump wave. When the supercriticality of the MSSW power is 15–20 dB, the generated parametric spin waves themselves become unstable with respect to the four-magnon interaction, so that kinetic instability develops in the film. It is shown that the pump signal transmitted through the signal and the length of the “nonlinear” part of the film, where a MSSW is capable of exciting parametric spin waves, increase as the pump power is increased. Fiz. Tverd. Tela (St. Petersburg) 38, 330–338 (February 1997)     

Temperature dependence of the exchange interaction constant in iron garnet films

The spin-wave resonance method is used to investigate the temperature dependence of the exchange interaction constant A in iron garnet films. The experimental results are compared with theoretical results based on the theory of second-order phase transitions. It is shown that the temperature dependence A(T) for films of pure yttrium iron garnet is different from A(T) for films exhibiting a point of compensation of the magnetic moment. Pis’ma Zh. éksp. Teor. Fiz. 63, No. 7, 528–532 (10 April 1996)     

Measurement of the refractive index and optical absorption spectra of epitaxial bismuth substituted yttrium iron garnet films at uv to near-ir wavelengths

Refractive-index and optical-absorption spectra of Bi-substituted yttrium iron garnet films, epitaxially grown by liquid-phase epitaxy, have been measured in the spectral regime 0.26 m1.9 m by thin-film interference for 0.52 m and by ellipsometry for0.52 m. The Y_3–x–y Bi _x Pb _y Fe_5–z Pt _z O₁₂ films contain bismuth in the range Ox 1.42, lead in the range 0.01 y0.08 and platinum in the range 0.005<=z0.03. There is satisfactory coincidence between the results from ellipsometry and thin-film interference in the overlapping wavelength region. The materials investigated are the same as reported earlier from this laboratory in ter mof their magnetic and magnetooptic properties.     

Stability of Bose-Einstein condensates of hot magnons in yttrium iron garnet films

We investigate the stability of the recently discovered room-temperature Bose-Einstein condensate (BEC) of magnons in yttrium iron garnet films. We show that magnon-magnon interactions depend strongly on the external field orientation, and that the BEC in current experiments is actually metastable-it only survives because of finite-size effects, and because the BEC density is very low. On the other hand a strong field applied perpendicular to the sample plane leads to a repulsive magnon-magnon interaction; we predict that a high-density room-temperature magnon BEC should then form in this perpendicular field geometry.     

Changes in optical absorption in iron garnet films due to impurity incorporation

The incorporation of impurities in films of Bi-substituted iron garnets grown by liquid phase epitaxy has been studied by successively adding small amounts of SiO₂ and CaCO₃ to the melt before film growth. It is found that very small additions of CaCO₃ to the melt profoundly influences the optical absorption coefficient and the electrical properties. The impurity absorption ofn-type YIG doped with Si⁴⁺ and Pb²⁺ ions is investigated and its wavelength dependence compared to that ofp-type YIG. The optical transitions involved in the impurity absorption of iron garnets are discussed in terms of transition reaction, photon energy and dependence on the impurity concentration. Depending on the photon energy, one or several transitions may give rise to impurity absorption.     

Evolution of spiral dynamic magnetic domains in Anger states of iron garnet films

Dynamic domain structures in the Anger state of iron garnet films are analyzed by a video micrographic technique. Data are obtained on the evolution of individual spiral domains over the lifetime of each domain. A new mechanism for the destruction of this state is discovered. Pis’ma Zh. éksp. Teor. Fiz. 63, No. 6, 453–456 (25 March 1996)