Polarization catastrophe in the polaronic Wigner crystal

We consider a three dimensional Wigner crystal of electrons lying in a host ionic dielectric. Owing to their interaction with the lattice polarization, each localized electron forms a polaron. We study the collective excitations of such a polaronic Wigner crystal at zero temperature, taking into account the quantum fluctuations of the polarization within the Feynman harmonic approximation. We show that, contrary to the ordinary electron crystal, the system undergoes a polarization catastrophe when the density is increased. An optical signature of this instability is derived, whose trend agrees with the experiments carried out in Nd-based cuprates. Received 4 July 2002 Published online 17 September 2002     

Melting of a Wigner crystal in an ionic dielectric

The melting of a Wigner Crystal of electrons placed into a host polar material is examined as a function of the density and the temperature. When the coupling to the longitudinal optical modes of the host medium is turned on, the WC is progressively transformed into a polaronic Wigner crystal. We estimate the critical density for crystal melting at zero temperature using the Lindeman criterion. We show that above a certain critical value of the Fr?hlich electron-phonon coupling, the melting towards a quantum liquid of polarons is not possible, and the insulator-to-metal transition is driven by the ionization of the polarons (polaron dissociation). The phase diagram at finite temperature is obtained by making use of the same Lindeman criterion. Results are also provided in the case of an anisotropic electron band mass, showing that the scenario of polaron dissociation can be relevant in anisotropic compounds such as the superconducting cuprates at rather moderate e-ph couplings. Received 13 August 1999     

Analytical approach to the quantum-phase transition in the one-dimensional spinless Holstein model

We study the one-dimensional Holstein model of spinless fermions interacting with dispersion-less phonons by using a recently developed projector-based renormalization method (PRM). At half-filling the system shows a metal-insulator transition to a Peierls distorted state at a critical electron-phonon coupling where both phases are described within the same theoretical framework. The transition is accompanied by a phonon softening at the Brillouin zone boundary and a gap in the electronic spectrum. For different filling, the phonon softening appears away from the Brillouin zone boundary and thus reflects a different type of broken symmetry state.     

Magnetism and phase separation in the ground state of the Hubbard model

We discuss the ground state magnetic phase diagram of the Hubbard model off half filling within the dynamical mean-field theory. The effective single-impurity Anderson model is solved by Wilson's numerical renormalization group calculations, adapted to symmetry broken phases. We find a phase separated, antiferromagnetic state up to a critical doping for small and intermediate values of U, but could not stabilize a Néel state for large U and finite doping. At very large U, the phase diagram exhibits an island with a ferromagnetic ground state. Spectral properties in the ordered phases are discussed. Received 9 January 2002 Published online 25 June 2002     

Femtosecond ionization of magnesium clusters grown in ultracold helium droplets

Magnesium clusters grown in helium droplets and ionized with femtosecond laser pulses have been studied by high resolution mass spectrometry. For moderate laser intensities the abundance spectra show characteristic features indicating electronic shell effects. Compared to clusters of s¹-electron metals additional shell closures appear resulting from an electron rearrangement. Irradiation with higher laser intensities leads to a decomposition of the magnesium clusters into atomic ions. Due to charge exchange with the surrounding helium matrix mainly singly and doubly charged magnesium ions remain. In addition, the occurrence of MgHe_N ⁺-complexes is observed. Their abundance depends on the shape of the laser field, i.e. the laser width and the optical delay when applying the pump-probe technique. Received 2 January 2001     

Overhauser shift of the electron spin-resonance line of Si:P at the metal-insulator transition: II. 29 Si contribution

The electron-spin resonance (ESR) line of delocalised electrons shifts upon saturation due to the hyperfine interaction with the dynamically polarized nuclear spins. The ²⁹ Si part of the Overhauser shift of the ESR line of phosphorus doped silicon (Si:P) is separated in the concentration range 2.7 ... 7.3×10 ¹⁸ / cm ³ covering the metal-insulator transition. The Overhauser shift profiles, recorded versus ²⁹ Si nuclear magnetic resonance (NMR) frequency, are asymmetric. Their dependence on temperature and ESR saturation compares reasonably with simulations. Time and NMR frequency dependence of the dynamic nuclear polarization is studied in detail. No pronounced variation of the ²⁹ Si Overhauser shift profiles with P concentration is observed, but the maximum value of the shift profile decreases with increasing P concentration. In contrast to standard ²⁹ Si NMR results, these measurements reveal the behaviour of the ²⁹ Si nuclei close to the P doping sites. Received 8 November 2001     

Canted antiferromagnetism and magnetoelastic coupling in metallic Ho0.1Ca0.9MnO3

Ho0.1Ca0.9MnO3 is a canted antiferromagnet with the magnetic space group Pn ' ma '. The magnetic structure is a superposition C x F y A z of the three types of order allowed in Pn ' ma '. In the Ca-rich corner of the system Ho _1-x Ca x MnO ₃ the title compound has a strong magnetoelastic distortion , the highest metallic conductivity and a ferromagnetic component F y close to the maximum in the series. Among the areas ab, bc, ca calculated from the lattice constants only ca shows a strong magnetoelastic effect below T N = 106 K. The x-, y-, z-spin components depend differently on the temperature. This gives rise to spin rotation which is particularly strong close to T N. MnO ₆ octahedra have short bond lengths with a temperature independent average . They are practically regular at room temperature and show a Jahn-Teller distortion of 3.5% in the magnetically ordered state. Above T N we find small polaron conductivity. The presence of the Jahn-Teller distortion due to the only small abundance (10%) of Mn ³⁺ in the t _2g ³ e g configuration is attributed to delocalised e g electrons. In the magnetically ordered state the averaged magnetic moment of Mn is reduced appreciably from the paramagnetic value due to spin disorder. Received 21 January 1999     

Localization properties of two interacting particles in a quasi-periodic potential with a metal-insulator transition

We study the influence of many-particle interactions on a metal-insulator transition. We consider the two-interacting-particle problem for onsite interacting particles on a one-dimensional quasiperiodic chain, the so-called Aubry-André model. We show numerically by the decimation method and finite-size scaling that the interaction does not modify the critical parameters such as the transition point and the localization-length exponent. We compare our results to the case of finite density systems studied by means of the density-matrix renormalization scheme. Received 28 June 2001     

Enhancement of magnetoresistance in cobaltites by manganese substitution: the oxide La 0.8 Sr 0.2 Co 1-x Mn x O 3

The substitution of manganese for cobalt in the perovskite La _0.8 Sr _0.2 CoO ₃ has been studied. A significant increase of the magnetoresistance (MR) is obtained, reaching 60% at 5 K under 7 T for . This behavior originates from a spectacular increase of the resistivity correlated to a significant decrease of ferromagnetism by Mn doping. This enhancement of magnetoresistance can be interpreted by the growth of ferromagnetic clusters in the insulating matrix, by applying a magnetic field. Received 7 May 1999     

Interplay of structural, magnetic and transport properties in thelayered Co-based perovskite LnBaCo 2 O 5 (Ln = Tb, Dy, Ho)

The oxygen deficient cobaltites LnBaCo₂O₅ (Ln = Tb, Dy, Ho) exhibit two successive crystallographic transitions at T _N ∼340 K and at T _CO ∼210 K. Whereas the first transition (P4/mmm to Pmmm) is related to the long-range antiferromagnetic ordering of the Co ions (spin ordering), the second transition (Pmmm to Pmmb) corresponds to the long-range ordering of the Co²⁺ and Co³⁺ species (charge ordering) occurring in 1:1 ratio in the structure. The charge ordered (CO) state was directly evidenced by the observation of additional superstructure peaks using neutron and electron diffraction techniques. The CO state was also confirmed indirectly from refinement of high resolution neutron diffraction data as well as from resistivity and DSC measurements. From the refined saturated magnetic moment values only, ∼3.7 and ∼2.7 , the electronic configuration of the Co ions in LnBaCo₂O₅ remains conjectural. Two pictures, with Co³⁺ ions either in intermediate spin state ( t ⁵ _2g e ¹ _g ) or in high spin state ( t ⁴ _2g e ² _g ), describe equally well our experimental data. In both cases, the observed magnetic structure can be explained using the qualitative Goodenough-Kanamori rules for superexchange. Finally, in contrast to the parent Ln = Y compound [Vogt et al. , Phys. Rev. Lett. 84, 2969 (2000)], we do not report any spin transition in LnBaCo₂O₅ (Ln = Tb, Dy, Ho). Received 13 December 2000     

Superconducting order in low-dimensional boson-fermion model: absence of finite-temperature transition

We present the application of the McBryan and Spencer method to a model describing a mixture of hard-core bosons and fermions interacting each others via a hybridization coupling. We prove upper bounds for some correlation functions at finite temperature and then rule out the possibility of long-range order of superconducting type in one and two dimensions. Received 21 August 2002 Published online 19 November 2002     

Cyclotron resonance of polarons in ternary mixed crystals

Rayleigh-Schr?dinger perturbation theory and an improved Wigner-Brillouin perturbation theory has been used to study the cyclotron resonance of the polarons in ternary mixed crystals in the zero-temperature limit. The interaction between an electron and two branches of longitudinal optical phonon modes is taken into account in the framework of the random-element-isodisplacement model. The numerical results for several ternary mixed crystals show that the polaronic cyclotron energy and mass split successively twice related to the higher and lower branches of longitudinal optical phonon modes of ternary mixed crystals. A non-linear dependence of the polaronic cyclotron energy and mass on the composition x is found. Received 19 March 2002 / Received in final form 21 March 2003 Published online 20 June 2003 RID="a" ID="a"e-mail: xxliang@imu.edu.cn     

Fluctuation-induced magnetotransport of superconductors in the quasiballistic regime

We study the fluctuation-induced magnetotransport of a two-dimensional superconductor in the quasiballistic regime, where ξ _GL(T) ≪ ℓ (ℓ is the electron mean free path and ξ _GL(T) is the Ginzburg-Landau coherence length). The magnetoconductivity is evaluated in the nonlocal fluctuation regime thereby extending the existing theory valid in the local limit. We show that the Maki-Thompson (MT) and density-of-states (DOS) contributions strongly compensate each other and their sum is negligible in comparison with the Aslamazov-Larkin (AL) term. The hierarchy of the fluctuation contributions to the magnetoconductivity in the high-field limit is also qualitatively discussed. Received 10 July 2002 / Received in final form 21 November 2002 Published online 7 May 2003     

Surface and interface optical phonon modes and electron-phonon interaction in a multi-shell spherical system

Within the framework of the dielectric continuum model, interface optical(IO) and surface optical(SO) phonon modes and the Fr?hlich electron-IO (SO) phonon interaction Hamiltonian in a multi-shell spherical system were derived and studied. Numerical calculation on CdS/HgS/H₂O and CdS/HgS/CdS/H₂O spherical systems have been performed. Results reveal that there are two IO modes and one SO mode for the CdS/HgS/H₂O system, one SO mode and four IO modes whose frequencies approach the IO phonon frequencies of the single CdS/HgS heterostructure with the increasing of the quantum number l for CdS/HgS/CdS/H₂O. It also showed that smaller l and SO phonon compared with IO phonon, have more significant contribution to the electron-IO (SO) phonon interaction. Received 16 October 2001 and Received in final form 23 January 2002 Published online 25 June 2002     

Optical and electrical properties of hydrogenated yttrium nanoparticles

We studied the effect of hydrogen in yttrium nanoparticles on a quartz substrate, using optical spectroscopy and electrical resistance measurements. Pulsed laser deposition is used to obtain the Y clusters in an UHV environment. We show, that these clusters are highly sensitive to monoatomic H₁ produced from ambient hydrogen gas pressures, ranging from 10^-5 to 50 mbar with our experimental arrangement. The changes of optical and electrical properties due to the chemical reaction within the particles are sufficient to consider this material as a possible sensor for low concentrations of hydrogen. Received 29 November 2000     

Insulator-metal transition shift related to magnetic polarons in La<Subscript>0.67-x</Subscript>Y<Subscript>x</Subscript>Ca<Subscript>0.33</Subscript>MnO<Subscript>3</Subscript>

The magnetic transport properties have been measured for La_0.67-xY_xCa_0.33MnO₃ ( 0 ⩽ x ⩽ 0.14) system. It was found that the transition temperature T _p almost linearly moves to higher temperature as H increases. Electron spin resonance confirms that above T _p , there exist ferromagnetic clusters. From the magnetic polaron point of view, the shift of T _p vs. H was understood, and it was estimated that the size of the magnetic polaron is of 9.7 ∼ 15.4 ? which is consistent with the magnetic correlation length revealed by the small-angle neutron-scattering technique. The transport properties at temperatures higher than T _p conform to the variable-range hopping mechanism. Received 27 August 2002 / Received in final form 2 December 2002 Published online 14 March 2003     

Ferromagnetism in lacunar perovskite manganites Pr 0.7 Sr 0.3 - x x MnO 3 and Pr 0.7 - x x Sr 0.3 MnO 3

Deficiency effects in the A site upon the structural, magnetic and electrical properties in the lacunar perovskite manganite oxides Pr_0.7Sr_{0.3-x x}MnO₃ ( 0 ? x ? 0.3) and Pr_{0.7-x x}Sr_0.3MnO₃ ( 0 ? x ? 0.23) have been investigated. This study focuses on the different parameters which govern the magnetic and electrical properties in such samples. The powder X-ray diffraction patterns for all samples could be indexed either with a rhombohedral perovskite structure and R c space group for x ? 0.2 in strontium deficient samples and for x ? 0.1 for praseodymium deficient ones. For other values of x the samples could be indexed in the orthorhombic structure with Pbnm space group. Magnetic and electrical investigations show that praseodymium and strontium vacancies do not have similar effects on the lacunar compounds. Magnetization measurements versus temperature show that all our samples exhibit a magnetic transition when the temperature decreases. All the praseodymium deficient samples exhibit a paramagnetic-ferromagnetic transition when the temperature decreases while the strontium deficient ones exhibit this transition only for low x values. The magnetic transition temperature shifts to lower values as the strontium deficiency increases (from 265 K for x = 0 to 90 K for x = 0.3) and to higher values with the praseodymium deficiency increase (from 265 K for x = 0 to 315 for x = 0.23). Resistivity measurements as a function of temperature show a semiconducting-metallic transition for all x values in the praseodymium lacunar samples and only for low x values ( 0 ? x ? 0.1) in the strontium lacunar ones when the temperature decreases. Received 12 April 2000 and Received in final form 8 January 2001     

Ground-state properties of the Falicov-Kimball model in one and two dimensions

A new numerical method is used to study the ground-state properties of the spinless Falicov-Kimball model in one and two dimensions. The resultant solutions are used to examine the phase diagram of the model as well as possibilities for valence and metal-insulator transitions. In one dimension a comprehensive phase diagram of the model is presented. On the base of this phase diagram, the complete picture of valence and metal-insulator transitions is discussed. In two dimensions the structure of ground-state configurations is described for intermediate interactions between f and d electrons. In this region the phase separation and metal-insulator transitions are found at low f-electron concentrations. It is shown that valence transitions exhibit a staircase structure. Received 20 October 2000     

Self-energy-functional approach to systems of correlated electrons

The grand potential of a system of interacting electrons is considered as a stationary point of a self-energy functional. It is shown that a rigorous evaluation of the functional is possible for self-energies that are representable within a certain reference system. The variational scheme allows to construct new non-perturbative and thermodynamically consistent approximations. Numerical results illustrate the practicability of the method. Received 13 January 2003 / Received in final form 5 March 2003 Published online 24 April 2003