Structural response of aluminum core–shell particles in detonation environment

Natural aluminum particles have the core–shell structure. The structure response refers to the mechanical behavior of the aluminum particle structure caused by external influences. The dynamic behavior of the structural response of aluminum core–shell particles before combustion is of great importance for the aluminum powder burning mechanism and its applications. In this paper, an aluminum particle combustion experiment in a detonation environment is conducted and analyzed; the breakage factors of aluminum particles shell in detonation environment are analyzed. The experiment results show that the aluminum particle burns in a gaseous state and condenses into a sub-micron particle cluster. The calculation and simulation demonstrate that the rupture of aluminum particle shell in the detonation environment is mainly caused by the impact of the detonation wave. The detonation wave impacts the aluminum particles, resulting in shell cracking, and due to the shrinkage-expansion of the aluminum core and stripping of the detonation product, the cracked shell is fractured and peeled with the aluminum reacting with the detonation product.     

Second harmonic generation in composites of ellipsoidal particles with core–shell structure

We study the enhancement of the second-harmonic generation (SHG) coefficient in a random composite consisting of ellipsoidal particles with a core–shell structure in a linear dielectric host. The material making up the ellipsoidal core is assumed to be dielectric, but with a nonlinear susceptibility for SHG. The coating material is assumed to be metallic with a linear susceptibility. The effective SHG coefficient is derived and its expression is related to various local field factors. The numerical calculations of the effective SHG response per unit volume of nonlinear material can be greatly enhanced at certain frequencies. For coated ellipsoidal particles, the core–shell structure and the particle shape allow for tuning of the resonance through the choice of material parameters and/or the ratio of the core to shell volume fraction and the depolarization factor of the particles.     

Synthesis of core–shell nanoparticles with a Pt nanoparticle core and a silica shell

A method to prepare a core–shell structure consisting of a Pt metal core coated with a silica shell (Pt(in)SiO₂) is described herein. A silica shell was grown on poly(vinylpyrrolidone) (PVP)-stabilized Pt nanoparticles 2–3 nm in size through hydrolysis and condensation reactions of tetraethyl orthosilicate (TEOS) in a water/ethanol mixture with ammonia as a catalyst. This process requires precise control of the reaction conditions to avoid the formation of silica particles containing multiple Pt cores and core-free silica. The length of PVP molecules, water content, concentration of ammonia and Pt nanoparticles in solution were found to significantly influence the core–shell structure. By optimizing these parameters, it was possible to prepare core–shell particles each containing a single Pt nanoparticle with a silica layer coating approximately 10 nm thick.     

Motion of charged particles in a NUTty Einstein–Maxwell spacetime and causality violation

We investigate the motion of electrically charged test particles in spacetimes with closed timelike curves, a subset of the black hole or wormhole Reissner–Nordström-NUT spacetimes without periodic identification of time. We show that, while in the wormhole case there are closed worldlines inside a potential well, the wordlines of initially distant charged observers moving under the action of the Lorentz force can never close or self-intersect. This means that for these observers causality is preserved, which is an instance of our weak chronology protection criterion.     

Polarizability of a donor impurity in dielectrically modulated core–shell nanodots

Simultaneous effects of the quantum confinement and electric field on the donor states in ZnS/CdSe core–shell nanodots surrounded by a wide-gap dielectric material are investigated. The results show a pronounced blue-shift of the binding energy due to the dielectric confinement. While in smaller dots the electron is located in the core even for off-center impurities, for increased outer radius it becomes squeezed almost entirely into the shell material. Therefore, the impurity states could be tuned by properly tailoring the heterostructure parameters (size, impurity position) and the dielectric environment, as well as by varying the electric field strength.     

Preparation of Cu–Ag core–shell particles with their anti-oxidation and antibacterial properties

Cu–Ag core–shell particles were fabricated from Cu particles and silver sulphate with the environmental-friendly TA (tartaric acid, C₄H₆O₆) as reducing and chelating agent in an aqueous system. The influences of [TA]/[Ag] and [Ag]/[Cu] molar ratios on the formation of Ag coatings on the Cu particles were investigated. The SEM images and SEM–EDS analyses showed that [TA]/[Ag] = 0.5 and [Ag]/[Cu] ≥0.2, the Cu particles were coated with uniform Ag nanoparticles. XRD analyses revealed that for these Cu–Ag particles heated at 250 °C, the oxidation of Cu was significantly reduced. Both anti-Staphylococcus aureus (Gram-positive) and anti-Escherichia coli (Gram-negative) characteristics of this Cu–Ag composite particles showed satisfactory antibacterial ability. The characteristics of the composite Cu–Ag particles were discussed in detail.     

Combustion waves in composite solid material of shell–core type

In this article, an asymptotic and numerical analysis of combustion wave propagation in shell–core composite solid energetic material is undertaken based on the diffusional–thermal model with an overall Arrhenius reaction step. Flame speed and structure are found for a broad range of parameter values. Two different regimes of flame propagation are identified. In the weak recuperation regime, the temperatures of the shell and core are monotonic functions of the coordinates, and they differ only slightly in the reaction zone of the flame. In the strong recuperation regime, the temperature of the shell is significantly higher than that of the core and has a sharp peak in the reaction zone with the maximum value exceeding the adiabatic flame temperature for pure energetic material. It is found that the highest level of flame acceleration in the composite material can be attained in the strong recuperation regime. The competition of these flame propagation regimes may lead to the coexistence of multiple combustion waves travelling with different velocities. The stability is investigated of combustion waves in the practically important strong recuperation regime.     

Modelling čerenkov radiation of relativistic particles in crystals

From the aspects of classical mechanics and electrodynamics, an analysis has been performed of the possible influence of the kind of charged particle trajectory on the erenkov radiation spectrum in a crystal. Results of the analytical computation are compared with the data of a computer experiment. It is shown that the influence of the particle trajectory on the erenkov radiation spectrum is insignificant in the optical frequency band. The expected effect is possible when utilizing crystals with a superlattice and by observation of radiation in the xray frequency range.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 2, pp. 62–67, February, 1988.The authors are grateful to S. A. Vorob'ev for supporting the research and to Yu. L. Pivovarov for stimulating and useful discussions.     

Synthesis of NiAu alloy and core–shell nanoparticles in water-in-oil microemulsions

NiAu alloy nanoparticles with various Ni/Au molar ratios were synthesized by the hydrazine reduction of nickel chloride and hydrogen tetrachloroaurate in the microemulsion system. They had a face-centered cubic structure and a mean diameter of 6–13 nm, decreasing with increasing Au content. As Au nanoparticles did, they showed a characteristic absorption peak at about 520 nm but the intensity decreased with increasing Ni content. Also, they were nearly superparamagnetic, although the magnetization decreased significantly with increasing Au content. Under an external magnetic field, they could be self-organized into the parallel lines. In addition, the core–shell nanoparticles, Ni₃Au₁@Au, were prepared by the Au coating on the surface of Ni₃Au₁ alloy nanoparticles. By increasing the hydrogen tetrachloroaurate concentration for Au coating, the thickness of Au shells could be raised and led to an enhanced and red-shifted surface plasmon absorption.     

Polar optical phonons in core–shell semiconductor nanowires

We obtain the long-wavelength polar optical vibrational modes of semiconductor core–shell nanowires by means of a phenomenological continuum model. A basis for the space of solutions is derived, and by applying the appropriate boundary conditions, the transcendental equations for the coupled and uncoupled modes are attained. Our results are applied to the study of the GaAs–GaP core–shell nanowire, for which we calculate numerically the polar optical modes, analyzing the role of strain in the vibrational properties of this nanosystem.     

Speed of particles and a relativity of locality in κ-Minkowski quantum spacetime

The last decade of research on κ-Minkowski noncommutative spacetime has been strongly characterized by a controversy concerning the speed of propagation of massless particles. Most arguments suggested that this speed should depend on the momentum of the particle strongly enough to be of interest for some ongoing experimental studies. But the only explicit derivations of worldlines in κ-Minkowski predicted no momentum dependence for the speed of massless particles. We return to this controversy equipped with the recent understanding that in some quantum spacetimes coincidences of events assessed by an observer who is distant from the events can be artifactual. We therefore set up our investigation in such a way that we never rely on the assessment of coincidences of events by distant observers. This allows us to verify explicitly that in κ-Minkowski simultaneously-emitted massless particles of different momentum are detected at different times, and establish a linear dependence of the detection times on momentum.     

Size-dependent thermal stresses in the core–shell nanoparticles

The thermal stress in a magnetic core–shell nanoparticle during a thermal process is an important parameter to be known and controlled in the magnetization process of the core–shell system. In this paper we analyze the stress that appears in a core–shell nanoparticle subjected to a cooling process. The external surface temperature of the system, considered in equilibrium at room temperature, is instantly reduced to a target temperature. The thermal evolution of the system in time and the induced stress are studied using an analytical model based on a time-dependent heat conduction equation and a differential displacement equation in the formalism of elastic displacements. The source of internal stress is the difference in contraction between core and shell materials due to the temperature change. The thermal stress decreases in time and is minimized when the system reaches the thermal equilibrium. The radial and azimuthal stress components depend on system geometry, material properties, and initial and final temperatures. The magnitude of the stress changes the magnetic state of the core–shell system. For some materials, the values of the thermal stresses are larger than their specific elastic limits and the materials begin to deform plastically in the cooling process. The presence of the induced anisotropy due to the plastic deformation modifies the magnetic domain structure and the magnetic behavior of the system.     

Surface/interface effects on the formation of misfit dislocation in a core–shell nanowire

The misfit strain within the core of a two-phase free-standing core–shell nanowire resulting in the generation of an edge misfit dislocation or an edge misfit dislocation dipole at the core–shell interface is considered theoretically within both the classical and surface/interface elasticity approaches. The critical conditions for the misfit dislocation generation are studied and discussed in detail with special attention to the non-classical surface/interface effect. It is shown that this effect is significant for fine cores of radius smaller than roughly 20 interatomic distances. The positive and negative surface/interface Lamé constants mostly make the generation of the misfit dislocation easier and harder, respectively. Moreover, the positive (negative) residual surface/interface tensions mostly make the generation of the misfit dislocation harder (easier). The formation of individual misfit dislocation is energetically more preferential in finer two-phase nanowires, while the formation of misfit dislocation dipole is more expectable in the coarser ones.     

Simulation of the absorption spectra of nanometallic Al particles with core–shell structure: size-dependent interband transitions

Nanoaluminum combined with an oxidizing polymer binder is representative of a new class of nanotechnology energetic materials termed “structural energetic materials” that can be laser initiated by near-infrared heating of the Al particles. The visible and near-IR absorption spectra of Al nanoparticles passivated by the native oxide Al₂O₃, embedded in nitrocellulose (NC) binder, are simulated numerically using a model for the metallic dielectric function that incorporates the effects of interband transitions. The effects of oxide thickness, nanoparticle size and size distribution, and particle shape on the absorption characteristics are investigated. The nanoparticle spectra evidence an absorption peak and valley in the 550–1,100 nm range that redshift with decreasing nanoparticle size. Calculations indicate that this peak-valley structure results from interband transitions, and the unusual redshift cannot be explained without using an interband transition onset frequency that varies with nanoparticle size.     

Synthesis and characterization of Co@Ag core–shell nanoparticles

Journal of Nanoparticle Research - A micellar method has been used to prepare silver-coated cobalt (Co@Ag) nanoparticles. The synthesized particles have been deeply characterized by several...     

Ultra-high transmission of photonic nanojet induced modes in chains of core–shell microcylinders

The ultra-high transmission of photonic nanojet induced modes in chains of core–shell microcylinders illuminated by a plane wave is reported. Using high resolution finite-difference time-domain simulation, the periodical focusing of lightwave in straight chains of touching core–shell microcylinders is characterized with the periodicity of photonic nanojets corresponding to the diameter of two microcylinders. The core–shell microcylinders are efficiently coupled to the collimated incident lightwaves. We observe the lightwave with high optical transport of 3 dB in the maxima of transmission spectra for a chain of core–shell microcylinders. The chains of core–shell microcylinders can be assembled inside hollow waveguide and used in a variety of microscopy techniques, biomedical applications, and optical microprobes with subwavelength spatial resolution.     

Simulation of the wave-absorbing model of a carbonyl iron / silver-coated core–shell structure

The microwave-absorbing performances of carbonyl iron powder / silver core–shell composite particles are studied on the basis of the electromagnetic scattering theory and the energy conservation law. In addition, a calculation method for reflection loss of the carbonyl iron powder / silver core–shell composite particles with microwave is proposed. The calculated reflection loss of the carbonyl iron powder / silver core–shell composite particles is compared with the experimental results. The findings show that the trend of reflection loss of the carbonyl iron powder / silver composite particles can be predicted which can subsequently provide a relevant reference for future experiment and calculation of the absorbing mechanism of electromagnetic wave-microscopic carbonyl iron powder / silver core–shell composite particles.     

Characterization of spherical core–shell particles by static light scattering. Estimation of the core- and particle-size distributions

A numerical method is proposed for the characterization of core–shell spherical particles from static light scattering (SLS) measurements. The method is able to estimate the core size distribution (CSD) and the particle size distribution (PSD), through the following two-step procedure: (i) the estimation of the bivariate core–particle size distribution (C–PSD), by solving a linear ill-conditioned inverse problem through a generalized Tikhonov regularization strategy, and (ii) the calculation of the CSD and the PSD from the estimated C–PSD. First, the method was evaluated on the basis of several simulated examples, with polystyrene–poly(methyl methacrylate) core–shell particles of different CSDs and PSDs. Then, two samples of hematite–Yttrium basic carbonate core–shell particles were successfully characterized. In all analyzed examples, acceptable estimates of the PSD and the average diameter of the CSD were obtained. Based on the single-scattering Mie theory, the proposed method is an effective tool for characterizing core–shell colloidal particles larger than their Rayleigh limits without requiring any a-priori assumption on the shapes of the size distributions. Under such conditions, the PSDs can always be adequately estimated, while acceptable CSD estimates are obtained when the core/shell particles exhibit either a high optical contrast, or a moderate optical contrast but with a high ‘average core diameter’/‘average particle diameter’ ratio.     

Interlevel transitions in core–shell nanodots with dielectric environment

The interlevels absorption in spherical CdSe/ZnS and ZnS/CdSe core–shell nanodots is theoretically investigated taking into account the dielectric environment effect. By considering the joint action of the quantum confinement and polarization charges, the influence of the nanosystem geometry upon the energy spectrum and oscillator strength associated to interlevel transitions is studied. We found that: (1) the low dielectric constant environments significantly blueshift the energy levels; (2) the transition matrix elements and oscillator strengths considerably vary with the core–shell radius ratio; (3) the peak position of the interlevels optical absorption is greatly affected by changing of the shell thickness, but for some geometries the absorption spectrum also becomes sensitive to the environment dielectric properties. The possibility of tuning the resonant energies by using the combined effect of the spatial confinement and dielectric mismatch between the dot and the surrounding medium can be useful in the optoelectronic devices applications.