Ar原子和K+离子序列双光双电离光电子角分布的非偶极效应

基于多组态Dirc-Fock方法和密度矩阵理论,?给出了原子序列双光双电离光电子角分布的计算表达式,开发了相应的计算程序.?利用该程序计算了Ar原子和K+离子np?(n?=?2,?3)壳层的光电离截面、电偶极和非偶极角各向异性参数,?进一步给出了光电子的角分布情况.?结果表明:?在序列双光双电离中两次光电离过程相互影响...     

类钠离子光电子角分布的非偶极效应

基于密度矩阵理论和多组态Dirac-Fock方法,系统地研究了不同入射光子能量下类钠离子(20 Z92)3s,2p_(1/2)和2p_(3/2)子壳层的光电离过程,讨论了辐射场与电子相互作用的多极项对光电子角分布的影响,并给出了光电子角分布的偶极和非偶极参数.结果表明,非偶极项对光电子角分布的影响不仅与入射光子能量有关,而且与靶离子的原子序数、被电离电子的壳层等有着密切的关系.总体上,非偶极项对2p_(1/2,3/2)子壳层光电子角分布的影响大于对3s子壳层光电子角分布的影响;电偶极近似下,入射光子能量、靶离子核电荷数对s子壳层光电子角分布轮廓影响不大,对p子壳层光电子角分布影响较大,在高能光子入射下,低Z离子的p子壳层光电子角分布出现反常的角分布情况;考虑非偶极项之后,p子壳层的反常光电子角分布消失.     

Al原子K壳层光电离的理论研究

基于多组态Dirac-Fock理论方法及其相应的GRASP2K和修改后的RATIP2012程序包,计算了极化光子入射Al原子K壳层光电离截面,并利用最新发展的RPI-E计算程序研究了K壳层光电子角分布,重点讨论了辐射场的非偶极项对光电离截面和光电子角分布的影响.结果表明,在入射光子5000 e V能量范围内,辐射场的非偶极效应对光电离总截面的影响可以忽略不计.随着入射光子能量的增加,辐射场的非偶极效应对光电子角分布的影响越来越大,入射光子能量在5000 eV,一级非偶极参数γ的数值达到1.5.     

Ar原子序列双光双电离产生光电子角分布的理论计算

基于多组态Dirc-Fock方法和密度矩阵理论,给出了原子序列双光双电离光电子角分布的计算表达式,发展了相应的计算程序.利用该程序对Ar原子3p壳层序列双光双电离过程进行了理论研究,给出了光电离的总截面、磁截面、剩余离子取向以及光电子角分布的各向异性参数与入射光子能量的函数关系.结果显示在光电离截面的Cooper极小位置附近取向参数出现极大值,而光电子角分布的各向异性参数在该位置附近出现极小值.进一步给出了33.94和55.34 eV光子能量下序列双光双电离过程中第一步的Ar原子和第二步的Ar^+离子3p壳层光电子角分布,分析了序列双光双电离光电子角分布与单光电离光电子角分布的差异.将计算结果与文献已有的数据进行了比较,具有很好的一致性.本文的研究结果对揭示光与物质相互作用的非线性动力学机制具有重要的参考价值.     

极紫外阿秒脉冲在高次谐波产生过程中引起的非偶极效应

当红外强激光和极紫外(XUV)阿秒脉冲共同作用于原子分子时，电离出去的电子通常会吸收和辐射激光光子而发生能量扩展.讨论了由于XUV阿秒脉冲的短波长与扩展后的电子波包尺度可相比拟时在高次谐波产生过程中引起的非偶极效应.采用H⁺₂作为模型分子，并把分子轴置于激光场的传播方向，通过解二维含时薛定谔方程并比较考虑非偶极效应和采用偶极近似两种方法计算得到的结果，两者相比，前者的谐波强度降低，谐波频率向低级次稍有移动，电子能谱的能带内出现了更多的光电子峰.在相同的光电子能量处，两种方法计算得到的信号强度相差2—5倍.并且这种非偶极效应随着红外基频光光强的增大而增强，随阿秒脉冲波长的增大而减弱. 关键词： 非偶极效应 光场空间不均匀性 阿秒脉冲 高次谐波产生     

多通道光离化的光电子干涉效应及空间角分布

利用光电子角分布成像光谱技术原理,以钠原子为例利用双光子共振三光子电离方法研究了从钠原子的4D态双能级电离后所产生的光电子角分布的状态.分析、讨论了多通道电离过程中所产生光电子的干涉效应.分析了光电子的空间角分布各部分的物理意义.结果表明该干涉图谱能够清楚地描绘出光电子能量和空间角分布状态.     

线偏振激光场中原子的多光子电离的光电子角分布研究

非微扰量子电动力学的发展使我们可以利用精确的波函数和非微扰的散射理论来研究多光子电离问题.文章作者及其合作者发展了光电子角分布的处理方法,利用复合相位Bessel函数来表征光电子的跃迁几率幅,将光电子的角分布与复合相位Bessel函数直接联系起来.研究发现,复合相位Bessel函数的性质决定了光电子角分布的主要特点及其随激光强度、频率以及光电子能量的演化.该理论不但证实了实验上已经观测到的各种光电子角分布,而且还预言了实验上尚未观测到的光电子角分布,确立了光电子角分布的标度定律.     

双色驻波场中梯形三能级原子所受整流偶极力的涨落分析

本文基于文献[1]利用双色驻波场作用于三能级原子获得宏观数量个光学波长上符号保持不变的整流偶极力的工作基础上,运用量子回归定理计算了所得整流偶极力在一个光学波长上的涨落.结果表明:原子偶极零点振动与光场幅度梯度相互作用引起的偶极力的涨落D1的值较大,是整流偶极力涨落的主要因素,且其随空间的变化规律与整流偶极力相似;原子偶极与真空零点振动相互作用导致偶极力的涨落Ds较小,几乎可以忽略不计.由于力的起伏所导致的加热效应不利于中性原子的偶极束缚[6].     

Kerr介质中光场与V型三能级原子依赖强度耦合相互作用系统的原子偶极压缩

利用全量子理论,研究了Kerr介质中单模光场与V型三能级原子依赖强度耦合的相互作用系统中原子偶极压缩效应,采用数值计算的方法讨论了Kerr介质常数χ和失谐量Ω对原子偶极压缩的影响.结果表明:Kerr效应对原子偶极压缩效应起着不同程度的减弱作用,适当大小的失谐量Ω有利于原子偶极压缩.     

圆柱腔体光电输运的蒙特卡罗模拟

应用三维并行蒙特卡罗程序JMCT, 计算了特征温度分别为1, 3, 5, 8keV的黑体谱X射线入射到铝、二氧化硅、金的表面的背散射光电产额和电子能谱, 并与文献结果进行对比, 验证了程序的正确性, 进而针对系统电磁脉冲(SGEMP)研究中的典型几何结构——金属圆柱腔体, 模拟计算了其在黑体谱X射线照射下的光电输运过程, 用温度为1keV、注量为1J/m2的黑体谱X射线平行照射圆柱腔侧面, 半个侧面发射光电子, 计算得出了和方位角相关的不同面上发射光电子的光电产额、能谱分布和角分布, 结果表明掠入射的X射线会产生更高的光电产额; 光电子的发射角分布都基本符合余弦角分布的规律。     

Surface spiral waves in a filamentary vortex

Second-order [ O(k(2)), k = omega/c] nondipole effects in soft-x-ray photoemission are demonstrated via an experimental and a theoretical study of angular distributions of neon valence photoelectrons in the 100-1200 eV photon-energy range. A newly derived theoretical expression for nondipolar angular distributions characterizes the second-order effects using four new parameters with primary contributions from pure-quadrupole and octupole-dipole interference terms. Independent-particle calculations of these parameters account for a significant portion of the existing discrepancy between experiment and theory for Ne 2p first-order nondipole parameters.     

光电子的初能量分布与角度分布

本文利用了Nottingham关於透射系数的经验公式,将DuBrige的不考虑反射效应的光电子初能量分布理论加以推广。由於详细地考虑了表面位垒对发射出来的电子所起的折射作用,因此不仅讨论了光电子的初能量分布与法线能量分布,而且也讨论了角度分布。这些讨论都假定发射面是理想的金属表面,没有碎鳞效应;金属内部的电子满足费密-狄喇克(Fermi-Dirac)统计分布;并假定入射光为固定强度的非偏振的单色光。本文中所获得的光电子初能量分布公式相当简单,而且比已往的理论更符合实验结果。光电子的角度分布曲线呈蛋状,大的一端向外,这舆Ives的实验结果相符。如果表面的反射效应不存在,那么角度分布满足馀弦定律。其他如光电流的光谱分布、球形电容器(其中心的小电极为光电阶极)在阻滞场下的伏-安特性曲线的理论公式,以及法线能量分布和理想平行板电容器在阻滞场下的电压-雷流特性曲线的理论公式也都曾加以讨论。     

The angular distribution of neon 2p shell photoelectrons in the 0–20 eV region above threshold

The photoelectron angular distribution parameter β has been measured in the 0–20 eV region above threshold for the neon 2p electrons using a synchrotron light source. Measurements are compared with the Hartree-Fock calculations of Manson and Kennedy.     

Theory of spin polarization phenomena in atomic and molecular photoeffects

A compact invariant expression for the angular distribution of photoelectrons formed as a result of photoionization of axisymmetrically polarized atoms and molecules, including optically active molecules, is derived from the general symmetry considerations and using a recently developed bipolar harmonic reduction technique. In the angular distribution of photoelectrons, as well as in the total photoionization cross section, the dependence on all the geometric parameters is separated completely. The polarization of ionizing radiation can be arbitrary, with the partial polarization being specified by the Stokes parameters. The expression for the angular distribution of photoelectrons escaping from an atomic-molecular system oriented in the first order also determines the structure of the expression for the photoionization cross section of an unpolarized system with allowance for the spin polarization of a photoelectron or a photoion with the spin 1/2. The roles played by circular dichroism, chirality, etc., in the process of photoionization of oriented and aligned systems are analyzed in detail.     

Optical properties in photoelectron diffraction theory

Photoelectron diffraction effects may be strongly influenced by optical properties of the solid. Due to refraction and absorption of light at a surface, the state of polarization of light may be changed and, therefore, the corresponding photoelectron diffraction intensity. In order to include optical properties of solids in photoelectron diffraction theory, a general polarization vector of light is defined taking into account both refraction and absorption of light at the vacuum–solid boundary. In a first step, the radiation field of light inside the solid is approximated macroscopically according to classical electrodynamics. Analytical expressions are derived within a real-angle representation of Fresnel equations to reveal the influence of refraction and absorption of light on the state of polarization of light. A general refractive index in dependence on the incident angle of light is introduced which determines the refractive angle inside the solid (refraction law with real angles) and the order of influence of absorption of light. The general polarization vector is applied in the calculation of dipole transition matrix elements in a multiple-scattering cluster model of photoelectron diffraction, where the process of photoabsorption (dipole transition matrix element) and multiple scattering processes of photoelectrons (scattering path operator) are considered separately. Different analytical and numerical results of photoelectron diffraction effects are presented for light of general polarization incident at general angles taking into account the optical properties of the solid. Examples are shown and discussed in detail for Cu(001) and GaAs(110) surfaces.     

Photoelectron elastic scattering effects in XPS

The photoelectron elastic scattering effects in XPS are reviewed. Using the transport theory approach and Monte-Carlo calculations as well experimental data, the influence of elastic scattering is demonstrated for the escape probability of the photoelectrons from solids, the intensities from bulk and surface systems, the angular intensity dependence including dipole and quadrupole transitions, attenuation lengths from various definitions, mean escape depths, the path-length distribution of photoelectrons in solids, the overlayer thickness determination, in-depth profiling and photoelectron diffractions patterns from single crystals.     

Angular dependence in photoemission: from atoms to surfaces to atoms

Some aspects of atomic and solid-state contributions to the angular dependence of photoemission from core levels, and their relevance and utility in the study of surfaces, are reviewed from a personal and historical perspective. In particular, the role played by dipole angular dependence in photoelectron diffraction and X-ray absorption spectroscopy, and by both dipole and non-dipole effects in X-ray standing wave studies are highlighted.