双电子传输层结构硫硒化锑太阳电池的界面特性优化

硫硒化锑薄膜太阳电池因其制备方法简单、原材料丰富无毒、光电性质稳定等优点,成为了光伏领域的研究热点.经过近几年的发展,硫硒化锑太阳电池的光电转换效率已经突破10%,极具发展潜力.本文针对硫硒化锑太阳电池中n/i界面引起的载流子复合进行了深入研究.发现硫硒化锑太阳电池的界面特性会受到界面电子迁移能力和能带结构两方面的影响.界面电子迁移率的提高能使电子更有效地传输至电子传输层,实现器件短路电流密度和填充因子的有效提升.在此基础上,引入ZnO/Zn_1-xMg_xO双电子传输层结构能够进一步优化硫硒化锑太阳电池性能.其中,Zn_1-xMg_xO能级位置的改变可以同时调节界面和吸光层的能级分布,在Zn_1-xMg_xO导带能级为-4.2 eV,对应Mg含量为20%时,抑制载流子复合的效果最为明显,硫硒化锑太阳电池也获得了最佳的器件性能.在去除缺陷态的理想情况下,双电子传输层结构硫硒化锑太阳电池在600 nm厚时获得了20.77%的理论光电转换效率,该研究结果为硫硒化锑太阳电池...     

太阳电池光电灵敏度测量仪的设计及应用

论述了太阳电池光电灵敏度测量仪的设计方案,并用自行搭建的太阳电池光电灵敏度测量仪测出了不同比例聚噻吩P3HT(poly(3-hexylthiophene))与C60的衍生物PCBM([6,6]-phenyl C61-butyric acid methyl ester)共混体系太阳电池的光电灵敏度,分析了其光电灵敏度变化的原因.     

Elastic properties of nanostructured materials with layered grain boundary structure

Atomistic calculations of the elastic constants for a bulk nanostructured material that consists of a layered structure where alternating layers meet along high angle grain boundaries and where atoms interact via a Lennard-Jones potential are presented. The calculations of the elastic constants were performed in the frame of homogeneous deformations for a wide range of layer widths ranging from 2.24 up to 74.62 nm. The results showed that the relaxation of the atomic structure affects the elastic constants for the cases where more than 5% of atoms are located in the GB region. Also it was found that the way that external stresses are applied on the system affects the values of the obtained elastic properties, with the elastic constants related to the characteristic directions of the grain boundary being the most affected ones. The findings of this work are of interest for the fabrication methods of nanostructured materials, the measurement methods of their elastic properties as well as multiscale modeling schemes of nanostructured materials.     

Determination of the energy diagram of a dielectric-semiconductor structure from the photocharging spectra of the dielectric

The Ge-GeO₂ and Si-SiO₂ structures are investigated by the method of optical charging of traps in the dielectric. It is shown that by measuring the photocharging spectrum in a wide temperature range, one may obtain information on the boundaries of delocalized states of the dielectric as well as on the dimensions of the tails of fluctuation localized states.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, pp. 36–40, May, 1982.     

Dependence of the structure and nagnetic properties of FeTaN films on nitrogen concentration

The structural morphology and magnetic properties of thin FeTaN films with a high Ta content (10 wt %) prepared by annealing compounds deposited by reactive rf magnetron sputtering in an Ar + N gas mixture are studied. The dependence of the properties of FeTaN films on their nitrogen content and annealing temperature were established. The deposition and thermal treatment regimes favoring the preparation of thin nanostructural FeTaN films with high soft magnetic characteristics [B _s = 1.6 T, H _c = 0.2 Oe, and μ₁ (1 MHz) = 3400] were determined.     

管间界面特性对周向超声导波传播特性的影响

采用界面弹簧模型对圆管结构的管间界面特性进行描述, 推导出含弱界面的圆管结构中声波沿周向传播时的位移场及应力场的数学表达式. 在此基础上采用导波的模式展开分析方法, 给出了与管间界面特性及激励源密切相关的周向超声导波模式展开系数的解析表达式. 数值分析了管间界面特性的变化对周向超声导波的频散和声场产生的影响. 理论与数值分析结果表明, 通过选择适当的驱动频率及周向导波模式, 可使周向超声导波的相速度及圆管外表面的位移场随管间界面特性的变化表现出非常敏感且单调的性质. 这一结果有助于采用周向超声导波方法准确定征圆管结构的管间界面特性.     

Innovative structure for dye solar cells

In this work we present a computer aided design software, called TiberCAD, to simulate dye sensitized solar cells (DSC). DSCs are particularly interesting devices due to their high efficiency (more than 12% on small area and 8% on large area) and long stability. In our model a drift-diffusion set of equations for the different charge carriers coupled to Poisson equation has been implemented within finite element method. The model takes into account also trap assisted transport for electrons in the mesoporous titanium dioxide with a phenomenological model derived from multi-trapping model. An application of the code presents an innovative topology for a DSC using a 3D geometry. A cell where contacts and illuminated surface are completely decoupled.     

Anionic nonconjugated polyelectrolyte as an anode interfacial layer for polymer solar cells

Since the most high-performing donor polymers in polymer solar cells (PSCs) possessed the deep highest occupied molecular orbital (HOMO) level, interfacial engineering on anode contact is becoming increasingly important. Herein, we demonstrated efficient PSCs using an anionic poly(styrene sulfonate) (PSS) as an anode interfacial layer (AIL). With the formation of the dipole layer, the effective work function (WF) of indium tin oxide (ITO) electrode is significantly increased from 4.8 to 5.3 eV, providing favorable energetic alignment to the quasi-Fermi level of various donor polymers. Moreover, by incorporating cationic polyelectrolytes as a cathode interfacial layer, a pair of electric dipole layers induces a strong built-in electric field across the photoactive layer to drive efficient sweep-out of photogenerated charges. Consequently, the device with PSS AIL exhibited high power conversion efficiencies of 9.2 and 14.8% in PTB7-Th:PC₇₁BM- and PM6:Y6-based PSCs, respectively, both of which are higher than those of the devices with PEDOT:PSS.     

Engineering the electronic band structure for multiband solar cells

Using the unique features of the electronic band structure of GaN(x)As(1-x) alloys, we have designed, fabricated and tested a multiband photovoltaic device. The device demonstrates an optical activity of three energy bands that absorb, and convert into electrical current, the crucial part of the solar spectrum. The performance of the device and measurements of electroluminescence, quantum efficiency and photomodulated reflectivity are analyzed in terms of the band anticrossing model of the electronic structure of highly mismatched alloys. The results demonstrate the feasibility of using highly mismatched alloys to engineer the semiconductor energy band structure for specific device applications.     

Effect of rapid thermal oxidation on structure and photoelectronic properties of silicon oxide in monocrystalline silicon solar cells

This paper concerns the topic of surface passivation properties of rapid thermal oxidation on p-type monocrystalline silicon wafer for use in screen-printed silicon solar cells. It shows that inline thermal oxidation is a very promising alternative to the use of conventional batch type quartz tube furnaces for the surface passivation of industrial phosphorus-diffused emitters. Five minutes was the most favorable holding time for the rapid thermal oxidation growth of the solar cell sample, in which the average carrier lifetime was increased 19.4 μs. The Fourier transform infrared spectrum of the rapid thermal oxidation sample, whose structure was Al/Al-BSF/p-type Si/n-type SiP/SiO₂/SiN_x/Ag solar cell with an active area of 15.6 cm², contained an absorption peak at 1085 cm⁻¹, which was associated with the Si–O bonds in silicon oxide. The lowest average reflectance of this sample is 0.87%. Furthermore, for this sample, its average of internal quantum efficiency and conversion efficiency are respectively increased by 8% and 0.23%, compared with the sample without rapid thermal oxidation processing.     

Effect of interfacial interaction on the structure and rheological properties of polyamide-6/clay nanocomposites

A series of polyamide-6 (PA6)/layered silicate (clay) nanocomposites were prepared via direct melt compounding using a conventional single screw extruder, and then the effect of interfacial interaction on the characteristic internal structure and rheological properties of PA6/clay nanocomposites was investigated. XRD diffractograms indicated a large extent of exfoliation of the layered silicate entering into a strong interaction with PA6. The formation of such morphology was further supported by TEM images. In addition, various rheological properties were interpreted in conjunction with morphological characteristics depending on interfacial interaction between PA6 and the layered silicate.     

Effects of silicon nanowires length on solar cells photovoltaic properties

Silicon nanowires (SiNWs) were produced by an electroless method on FZ-Si (100) wafer, in HF/AgNO₃ solution. The influence of etching time and temperature on SiNWs morphology were studied using FESEM images. Optical properties were also investigated by optical absorption spectroscopy and low-temperature photoluminescence at 4.2?K. Considering their role as active regions, photovoltaic properties of SiNWs solar cells were studied for their different lengths. Photovoltaic measurements were taken in 1 sun condition under AM 1.5 illumination supplied by a solar simulator. Measurements indicated a reduction in efficiency as SiNWs length increased, which might be attributed to increased dangling states on nanowires surfaces.     

有机共混结构叠层太阳电池的研究进展

有机太阳电池由于质轻、价廉、柔性,受到人们的广泛关注.单个有机材料只能吸收部分太阳光,叠层结构的太阳电池将不同吸收带隙的有机材料通过中间层连接起来,既能充分吸收太阳光,又能提高太阳电池的开路电压或短路电流.本文综述了近年来有机共混结构叠层太阳电池的研究进展,介绍了各种叠层有机太阳电池的结构、原理及性能,阐述了国内外有机叠层太阳电池研究的现状及存在问题,为高性能有机太阳电池的研究提供有价值的参考.     

The use of laser technology to shape properties of the contacts of silicon solar cells and their structure

The paper presents the results of the investigation of the front contact manufactured using silver pastes (based on experimentally prepared silver powder) on monocrystalline silicon solar cells in order to reduce contact resistance. Various deposition and fabrication techniques were applied to improve the electrical properties of contacts. The aim of the paper was to apply an unconventional method (selective laser sintering) to improve the quality of forming contacts of silicon solar cells. The topography of both the melted/sintered contact and textured silicon was investigated using atomic force microscopy. Resistance of front electrodes was measured using the Transmission Line Model (TLM). Both surface topography and cross section of front contacts were researched using the scanning electron microscopy.     

Dependence of Forbush-decrease magnitudes on parameters of solar eruptions

By data of the 23^rd solar cycle, it is shown that close statistical relations exist between quantitative parameters of dimmings and arcades caused by solar coronal mass ejections (CMEs), on the one hand, and magnitudes of non-recurrent Forbush-decreases of the galactic cosmic ray flux, as well as the propagation time of disturbances from the Sun to the Earth, on the other hand. Parameters of dimmings and arcades, in particular their summarized magnetic flux of the prolonged field at the photospheric level, were calculated by data of the EUV SOHO/EIT telescope in the 195 Å Received results mean that the scale, characteristics, and propagation time of interplanetary disturbances to the Earth are determined to a large degree by measurable parameters of solar eruptions and may be estimated in advance by observations of dimmings and arcades in the EUV range.     

Theoretical study of electronic structure and excited states properties of two dyes for dye-sensitized solar cells

Two conjugated organic dyes comprising the benzo[b]furan moieties as the electron donor and cyanoacetic acid moieties as the electron acceptor/anchoring groups have been investigated using a quantum chemical method. The molecular equilibrium geometries and ground state character were studied using density functional theory. Absorption spectra were obtained using time-dependent density functional theory and semiempirical ZINDO. The nature of absorption spectra was further studied using 2D and 3D real-space analysis; here, 2D real-space analysis showed electron–hole coherence, and 3D real-space analysis showed intramolecular charge transfer during photo-excitation. As important parameters, excited state oxidation potential and driving force energy were obtained to reveal the relationship between molecular structure and performance of two compounds.