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氢化物-原子荧光法测定土壤中痕量汞 总被引:10,自引:0,他引:10
熊伟 《光谱学与光谱分析》2001,21(3):382-383
采用氢化物冷原子荧光光谱法测定土壤中痕量汞是一种新方法。本文阐述了用王水热浸提,快速测定土壤样品中痕量汞的方法,试验了硼氢化钾浓度对测定汞的影响。用该方法测定污染农田土壤标准物质样品(GBW08303),其测量结果与推荐值相吻合。相对偏差1.4%,回收率87%-105%。该方法简便、简单、准确。 相似文献
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研究了铁(Ⅲ)和钼(Ⅵ)与邻苯二酚在pH 6.20 微酸性介质中反应生成的有色配合物与717型强碱性阴离子交换树脂的交换吸附,探讨了树脂相分光光度法同时测定铁(Ⅲ)和钼(Ⅵ)的实验条件。铁(Ⅲ)和钼(Ⅵ)树脂相有色配合物的最大吸收波长分别为520 nm 和400 nm ,表观摩尔吸光系数ε为4.1×104 L/(m ol·cm )和9.0×104 L/(m ol·cm ),符合Beer定律的范围为0~2.2 m g·L- 1和0~1.6 m g·L- 1。此法用于地下水中微量铁和钼的测定,相对标准偏差为3.3 % 和3.2 % 。 相似文献
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生命起源、全球气候变化等是关系到人类未来命运的重大科学问题,X射线光谱(XRS)可原位测定物质组成与元素形态,在解决重大科学问题、揭示自然规律中发挥了重要作用:(1)在生命起源探索中,通过RNA结构和海洋热液自养体系元素形态分析,揭示了RNA形成机制和生物地球化学规律;(2)在地球早期生命研究中,通过沉积纹层、细胞组构测定,发现了远古生物保存机制与证据;(3)在全球碳循环研究中,通过物相与元素形态分析,揭示了铁源生物有效性与碳汇机制。利用XRS从微纳米尺度原位测定元素三维空间分布与形态,实现活体分析蛋白质信息传递与生物响应过程,探索元素与有机质构效关系,揭示生命起源与生物代谢机制及全球气候变化规律,是XRS未来发展中的重要领域;作为冶金、材料、地质、文物、工矿、生态、环境、医学与生命科学等领域中的重要分析手段,XRS所特有的无损、原位与活体分析特性,已呈现了巨大应用价值,在未来探索重大科学问题、解决关键技术难点的研究中,X射线光谱分析技术必将发挥更大作用。 相似文献
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N─甲基吡咯烷酮两相闭式热虹吸管传热特性的实验研究 总被引:2,自引:0,他引:2
本文报道了用N—甲基吡咯烷酮(C5H9NO3)为工质以光滑管与三维内翅片管为管壳制成的两相闭式逆流热虹吸管的传热特性。实验结果表明在工作温度为220~350℃,热负荷为8.2~17.3kW/m2范围内光滑热虹吸管蒸发段与凝结段换热系数的积分平均值分别约为1700W/m2·℃和1600W/m2·℃。由于三维翅片的强化传热作用,使三维内翅片热虹吸管蒸发段与凝结段换热系数分别比光滑管增大了20%~40%和70%~160%。实验表明N—甲基吡咯烷酮综合传热性能优于萘,可望作为中温热管工质使用。 相似文献
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分光光度法测定荞麦中芦丁含量 总被引:11,自引:1,他引:10
建立一种简单、准确测定荞麦中芦丁含量的分光光度法,讨论最佳试验条件及试剂用量,反应产物在500nm有相对稳定吸收峰,该法灵敏、可靠(ε=7.5×10 ̄4L/mol·cm)。回收率96.40%─105.50%,相对标准偏差小于1.42%。 相似文献
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钨盐涂覆-GFAAS法测定肿瘤患者体内痕量锂 总被引:3,自引:0,他引:3
钨盐涂覆处理石墨管,大幅度提高测定锂的灵敏度。配以(NH4)2SO4基体改进剂,消除生物基体干扰。特征浓度5.53×10-3μg·mL-1/1%,回收率大于93.72%,相对标准偏差小于8.93%。 相似文献
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Thermal conductivity and thermal diffusivity of “ozone-safe” refrigerant R134a in liquid state within the range of temperatures
295.9–354.9 K and pressures from the liquid — vapor equilibrium line up to 4.08 MPa have been studied by high-frequency thermal-wave
method. The experimental uncertainties of the temperature, pressure, thermal conductivity and thermal diffusivity measurement
errors were estimated to be 0.1 K, 3 kPa, 1.5 and 2.5 %, respectively. Values of thermal conductivity and thermal diffusivity
of liquid R134a on saturated line have been calculated. Approximation dependences for thermal conductivity and thermal diffusivity
within the whole studied range of temperatures and pressures as well as on the saturated line have been obtained.
The work was financially supported by the Russian Foundation for Basic Research (grant No. 07-08-00295-a). 相似文献
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Abstract This article presents an experimental investigation where the thermal conductivity and viscosity of silver-deionized water nanofluid is measured and studied. The mixture consists of silver nanoparticles of 0.3, 0.6, and 0.9% of volume concentrations and studied for temperatures between 50°C and 90°C. The transient hot-wire apparatus and Cannon-Fenske viscometer are used to measure the thermal conductivity and kinematic viscosity of nanofluid, respectively. The thermal conductivity increases with the increase in temperature and particle concentrations. A minimum and maximum enhancement of 27% at 0.3 vol% and 80% at 0.9 vol% are observed at an average temperature of 70°C. The viscosity decreases with the increase in temperature and increases with the increase in particle concentrations. The effect of Brownian motion and thermophoresis on the thermo-physical properties is discussed. Thus, an experimental correlation for thermal conductivity and viscosity, which relates the volume concentration and temperature, is developed, and the proposed correlation is found to be in good agreement with the experimental results. 相似文献
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A loop thermosiphon thermal collector was developed for the waste heat recovery power generation with electric capacity of 500 W. The heat collector with heat transfer area of 0.159 m2 (500 mm width and 300 mm depth) was connected to the condenser with a shrunken heat transfer area by a loop. The thermal performance of the apparatus was declined when increasing the water filling rate to 90% as the working fluid occupied the internal volume. In the range of water filling rate between 30% and 60%, the effective thermal conductivity was around100 times of the conductivity of copper. 相似文献