Use of Langevin equations for calculating turbulent transfer coefficients

Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No.2, pp. 47–54, March–April, 1992.     

A model for the viscoelastic behavior of polymers at finite strains

Summary A constitutive model is derived for the isothermal nonlinear viscoelastic response in polymers, which do not possess the separability property. The model is based on the concept of transient networks, and treats a polymer as a system of nonlinear elastic springs (adaptive links), which break and emerge due to micro-Brownian motion of chains. The breakage and reformation rates for adaptive links are assumed to depend on some strain energy density. The viscoelastic behavior is described by an integral constitutive equation, where the relaxation functions satisfy partial differential equations with coefficients depending on the strain history. Adjustable parameters of the model are found by fitting experimental data for a number of polymers in tension at strains up to 400 per cent. To validate the constitutive relations, we consider loading with different strain rates, determine adjustable parameters at one rate of strains, and compare prediction of the model with observations at another rate of strains. Fair agreement between experimental data and results of numerical simulation is demonstrated when the rates of strains differ by more than a decade. Received 1 July 1997; accepted for publication 7 October 1997     

Comparison between uniaxial and biaxial elongational flow behavior of viscoelastic fluids as predicted by differential constitutive equations

Behavior of polymer melts in biaxial as well as uniaxial elongational flow is studied based on the predictions of three constitutive models (Leonov, Giesekus, and Larson) with single relaxation mode. Transient elongational viscosities in both flows are calculated for three constitutive models, and steady-state elongational viscosities are obtained as functions of strain rates for the Giesekus and the Larson models.Change of elongational flow behavior with adjustable parameter is investigated in each model. Steady-state viscosities _E and _B are obtained for the Leonov model only when the strain-hardening parameter is smaller than the critical value _cr determined in each flow. In this model, uniaxial elongational viscosity _E increases with increasing strain rate , while biaxial elongational viscosity _B decreases with increasing biaxial strain rate _B . The Giesekus model predictions depend on the anisotropy parameter . _E and _B increase with strain rates for small _B while they decrease for large . When is 0.5, _E in increasing, but _B is decreasing. The Larson model predicts strain-softening behavior for both flows when the chain-contraction parameter > 0.5. On the other hand, when is small, the steady-state viscosities of this model show distinct maximum around = _B = 1.0 with relaxation time . The maximum is more prominent in _E than in _B .     

Finite multiplicative plasticity for small elastic strains with linear balance equations and grain boundary relaxation

This paper is concerned with the formulation of a phenomenological model of finite elasto-plasticity valid for small elastic strains for initially isotropic polycrystalline material. As a basic we assume the multiplicative split of the deformation gradient into elastic and plastic part. A key feature of the model is the introduction of an independent field of 'elastic' rotations which eliminate the remaining geometrical nonlinearities coming from finite elasticity in the presence of small elastic strains. In contrast to micro-polar theories an evolution equation for is presented which relates to making use of a new device found by the author to perform the polar decomposition asymptotically. The model is shown to be invariant under both change of frame and rotation of the so called intermediate configuration. The corresponding equilibrium equations at frozen plastic and viscoelastic configuration constitute then a linear, elliptic system with nonconstant coefficients which makes this model amenable to a rigorous mathematical analysis. The introduced hysteresis effects within the elastic region are related to viscous elastic rotations of the grains of the polycrystal due to internal friction at the grain boundaries and constitute as such a rate dependent transient texture effect. The inclusion of work hardening will be addressed in future work. Received March 07, 2002 / Published online February 17, 2003 RID="*" ID="*"Communicated by Kolumban Hutter, Darmstadt     

Evaluation by means of stress relaxation (after a step strain) experiments of the viscoelastic behavior of polymer melts in uniaxial extension

 As is widely acknowledged, morphology in most materials is far more sensitive to extensional than to shear deformations but, unfortunately, due to the experimental difficulties involved, there are no non-destructive, morphology probing techniques in such flows, i.e., the equivalent of stress relaxation and oscillatory experiments in shear flows. This paper tries to overcome some of those drawbacks by proposing an experimental technique that allows stress relaxation experiments after a step strain in uniaxial extension to be performed. The benefits of this technique are twofold: (a) while the deformation is small enough for the response to be in the linear viscoelastic regime it constitutes a probe of the microstructure of the material and (b) it allows the departure to the non-linear regime to be studied, useful, for example, for the definition of the damping function in uniaxial extensional flow or for the study of the response of materials to fast transient flows with a strong extensional component, such as contraction flows. In this work the proposed technique, which requires a correction to the apparent (theoretical) strain rate in order to allow the calculation of the true Hencky strains attained during the strain step, is tested and validated for two polyisobutylene melts. Received: 9 April 2001 Accepted: 26 July 2001     

Equations for calculating the viscosity coefficient of nitrogen and hydrogen in the gaseous and liquid states

An equation for describing experimental data on the viscosity of gases and liquids is presented, taking into consideration the peculiarities of the configuration of isochoric sections of the viscosity coefficient surface. The effectiveness of the equation is demonstrated for nitrogen and hydrogen.Translated from Zhurnal Prikladnoi Mekhaniki i Tekhnicheskoi Fiziki, No. 3, pp. 118–121, May–June, 1971.     

Method of calculating the bending modes in an inhomogeneous viscoelastic system

International Applied Mechanics -     

On the use of stretched-exponential functions for both linear viscoelastic creep and stress relaxation

The use of the stretched-exponential function to represent both the relaxation function g(t)=(G(t)-G _∞)/(G ₀-G _∞) and the retardation function r(t) = (J _∞+t/η-J(t))/(J _∞-J ₀) of linear viscoelasticity for a given material is investigated. That is, if g(t) is given by exp (?(t/τ)^β), can r(t) be represented as exp (?(t/λ)^µ) for a linear viscoelastic fluid or solid? Here J(t) is the creep compliance, G(t) is the shear modulus, η is the viscosity (η^?1 is finite for a fluid and zero for a solid), G _∞ is the equilibrium modulus G _e for a solid or zero for a fluid, J _∞ is 1/G _e for a solid or the steady-state recoverable compliance for a fluid, G ₀= 1/J ₀ is the instantaneous modulus, and t is the time. It is concluded that g(t) and r(t) cannot both exactly by stretched-exponential functions for a given material. Nevertheless, it is found that both g(t) and r(t) can be approximately represented by stretched-exponential functions for the special case of a fluid with exponents β=µ in the range 0.5 to 0.6, with the correspondence being very close with β=µ=0.5 and λ=2τ. Otherwise, the functions g(t) and r(t) differ, with the deviation being marked for solids. The possible application of a stretched-exponential to represent r(t) for a critical gel is discussed.     

Some applications of the method of moments for the homogeneous Boltzmann and Kac equations

Using the method of moments, we prove that any polynomial moment of the solution of the homogeneous Boltzmann equation with hard potentials or hard spheres is bounded provided that a moment of order strictly higher than 2 exists initially. We also give partial results of convergence towards the Maxwellian equilibrium in the case of soft potentials. Finally, exponential as well as Maxwellian estimates are introduced for the Kac equation.     

On the equivalence of simplest non-linear rheological equations for viscoelastic polymer media

Some equivalence conditions are formulated for non-linear models of polymer melts and solutions that are analogous to known conditions for three-constant linear rheological equations. The resulting model is analysed in simple shear and elongational flows. The kinematics of finite elastoviscous strains is considered in an appendix.