56,57,60CoFe NMR/ON,hyperfine anomalies and γ-factors of cobalt isotopes

The results of NMR/ON measurements on^56'57'60Co isotopes in iron are presented. To avoid the uncertainties caused by local demagnetizing field inhomogenities the measurements on two cobalt isotopes in one sample have been carried out. The values of nuclear-factor ratios ⁵⁷/ ⁶⁰ = 1.805 (20), ⁶⁰/ ⁵⁶ = 0.761 (20), ⁵⁶/ ⁵⁷ = 0.726 (20) and hyperfine anomalies⁵⁶⁶⁰ = -0.036 (10),^{60 57} = 0.017 (10) and⁵⁷⁵⁶ = 0.018 (10) have been calculated from the experimental results.     

Hyperfine interactions of interstitial12B in Fe,V and Ta studied by use of the asymmetric β decay

Magnetic hyperfine fields and spin-lattice relaxation times of interstitial and substitutional¹²B nuclei in Fe are studied in a temperature range, 100 K<T<1200 K, by use of the asymmetric decay from the spin polarized nuclei and NMR detection. In order to infer information regarding the location of¹²B nuclei and expansion in the nearest Fe surrounding following recoil implantation, hyperfine interactions of¹²B in non-magnetic bcc V and Ta crystals are studied.     

(n, γ)-Induced point defects in InP and InSb studied by β-radiation detected nuclear magnetic resonance

Polarized¹¹⁶In (I=1,T _1/2=14.1 s) nuclei were produced by capture of polarized thermal neutrons in undoped InP and InSb and in InSbTe single crystals. As a consequence of the nuclear reaction charged and paramagnetic point defects were produced with a rate of about 0.8 per absorbed neutron. Spin-lattice relaxation rates of the¹¹⁶In probe nuclei were measured at temperatures between 1.3 K and 90 K, as well as NMR line profiles and magnetic field dependences of the nuclear polarization up to 0.63 T. Electric field gradients, produced by the defects, could be determined, and defect induced additional relaxation processes were observed. Further, characteristic phonon frequencies and spin-phonon coupling constants for the undisturbed crystal lattices could be derived.     

Structural, static and dynamic magnetic properties of dextran coated γ-Fe(2)O(3) nanoparticles studied by (57)Fe NMR, M?ssbauer, TEM and magnetization measurements

The structural and magnetic properties and spin dynamics of dextran coated and uncoated γ-Fe(2)O(3) (maghemite) nanoparticles have been investigated using high resolution transmission electron microscopy (HRTEM), (57)Fe nuclear magnetic resonance (NMR), M?ssbauer spectroscopy and dc magnetization measurements. The HRTEM observations indicated a well-crystallized system of ellipsoid-shaped nanoparticles, with an average size of 10 nm. The combined M?ssbauer and magnetic study suggested the existence of significant interparticle interactions not only in the uncoated but also in the dextran coated nanoparticle assemblies. The zero-field NMR spectra of the nanoparticles at low temperatures are very similar to those of the bulk material, indicating the same hyperfine field values at saturation in accord with the performed M?ssbauer measurements. The T(2) NMR spin-spin relaxation time of the nanoparticles has also been measured as a function of temperature and found to be two orders of magnitude shorter than that of the bulk material. It is shown that the thermal fluctuations in the longitudinal magnetization of the nanoparticles in the low temperature limit may account for the shortening and the temperature dependence of the T(2) relaxation time. Thus, the low temperature NMR results are in accord with the mechanism of collective magnetic excitations, due to the precession of the magnetization around the easy direction of the magnetization at an energy minimum, a mechanism originally proposed to interpret M?ssbauer experiments in magnetic nanoparticles. The effect of the surface spins on the NMR relaxation mechanisms is also discussed.     

The Experimental Evaluation of Decay Rate Variations of 57Co by the Δλ/λ Method

The measurement of the relative changes / of the radioactive decay by the electron capture process is a direct experimental way to determine the relative changes of the electron charge density on the nucleus. Here we present the results of the experiment with ⁵⁷Co, where the differences of the decay rate were determined for different chemical states of ⁵⁷Co. We analyzed the experimental time dependences of the activity of ⁵⁷Co by means of the direct approximation method and the specialized optimization tool – a genetic algorithm. Using these methods improved the accuracy of the final / values between ⁵⁷Co and ⁵⁷Co(Pd), ⁵⁷CoCl₂,⁵⁷CoS, ⁵⁷CoSO₄7H₂O, which are in good agreement with theoretical considerations reflecting the electron charge rearrangement and screening effects.     

Characterization of Mango Juice by High‐Resolution NMR,Hyphenated NMR,and Diffusion‐Ordered Spectroscopy

Abstract

The application of nuclear magnetic resonance (NMR) spectroscopy, hyphenated NMR, and diffusion‐ordered spectroscopy (DOSY) to the characterization of mango juice, as an example of a complex food mixture, is described. The compositional changes taking place as a function of ripening were followed, and selected metabolites were quantified by integration of the corresponding NMR peaks. In this way, an overall view of the metabolite changes is obtained, enabling the study of the biochemical mechanisms involved in the ripening process. More than 50 compounds were identified by 1D‐ and 2D‐NMR, but many ambiguous assignments remain due to spectral overlap or insufficient coupling information. The use of Liquid Chromatography (LC‐NMR) and LC‐NMR/Mass Spectrometry (MS) enables a fuller characterization of the soluble pectin fraction to be made; its dependence on ripening stage is discussed. Finally, DOSY adds information on the M_r of many metabolites, including the pectin fractions of ripe and unripe mango juices, and enables further peak assignments to be made.     

Deuteron disintegration, thermonuclear and nuclear fission reactions induced by γ-quanta in D-saturated palladium and dense deuterium gas with synthesis of new structures

The results obtained by investigating the chemical composition and structure of Pd sample sur-faces, chamber components, and a new synthesized object (NSO) are presented. The NSO is produced in the chamber with a high-pressure (about 3 kbar) deuterium gas under irradiation by γ-quanta with an energy of 8.8 MeV. The measured concentrations of chemical elements arisen from nuclear reactions initiated by γ-quanta have made it possible to develop the phenomenological approach to describing the process whereby deuterium atoms are heated by the protons and neutrons of a deuteron photofission reaction, hot D-D fusion, Oppenheimer reactions, and palladium nuclear fission. The coefficient of the process efficiency greatly exceeds unity. A new type of reactors (deuterated nuclear fission reactor) is proposed.     

Neutrino Energy Loss by Electron Capture on Nucleus ^56Mn, ^56Fe, ^56Co and ^56Ni in Strong Electron Screening

Based on the p-f shell model, the neutrino energy loss rates for nucleus ^56Mn, ^56Fe, ^56Co and ^56Ni in the electron capture process are canvassed in and not in a strong electron screening. The results show that the neutrino energy loss rates for ^56Mn, ^56Fe, ^56Co and ^56Ni decrease about 15%, 10%, 60% and i order of magnitude correspondingly at the temperature T9 = 15 and even debase 2 orders of magnitude at the temperature T9 = 1.     

Direct measurement of the resonance strengths and branching ratios of low-energy(p, γ) reactions on Mg isotopes

Proton capture reactions on Mg isotopes are significant in the Mg-Al cycle in stellar H-burning.In particular,the resonance strengths and branching ratios of low-energy resonances in Mg(p,y)26 A1 reactions determine the production of ~(26)Al,which is one of the most important long-lived radioactive nuclei in nuclear astrophysics.In this article,we report our first experiment using the intense proton beam of approximately 2 mA provided by the JUNA accelerator ground laboratory and a new technique that can minimize the composition change of targets under intense beam irradiation.The resonance strengths and branching ratios of E=214,304,and 326 keV resonances in the reactions of ~(24)Mg(p,γ)~(26)Al,~(25)Mg(p,γ)~(26)Al,and ~(26)Mg(p,γ)~(27)Al,respectively,were measured with high accuracy.The success of this experiment provides a good calibration for the nuclear astrophysical experiment at the Jinping underground laboratory.     

Effect of 60Co γ-irradiation on structural and optical properties of thin films of Ga10Se80Hg10

Thin films of Ga₁₀Se₈₀Hg₁₀ have been deposited onto a chemically cleaned Al₂O₃ substrates by thermal evaporation technique under vacuum. The investigated thin films are irradiated by ⁶⁰Co γ-rays in the dose range of 50–150 kGy. X-ray diffraction patterns of the investigated thin films confirm the preferred crystallite growth occurs in the tetragonal phase structure. It also shows, the average crystallite size increases after γ-exposure, which indicates the crystallinity of the material increases after γ-irradiation. These results were further supported by surface morphological analysis carried out by scanning electron microscope and atomic force microscope which also shows the crystallinity of the material increases with increasing the γ-irradiation dose. The optical transmission spectra of the thin films at normal incidence were investigated in the spectral range from 190 to 1100 nm. Using the transmission spectra, the optical constants like refractive index (n) and extinction coefficient (k) were calculated based on Swanepoel’s method. The optical band gap (E_g) was also estimated using Tauc’s extrapolation procedure. The optical analysis shows: the value of optical band gap of investigated thin films decreases and the corresponding absorption coefficient increases continuously with increasing dose of γ-irradiation.     

Structure of the proton emitter La studied by proton and γ-ray spectroscopy

Proton radioactivity from ¹¹⁷La was re-investigated with much improved statistics and precision. Only the ground-state proton decay (Ep=813(3) keV, T1/2=20.1(25) ms) was observed, no evidence for a previously reported isomeric proton decay was found. Prompt γ rays in ¹¹⁷La were identified using the Recoil-Decay Tagging method. Overall the data indicate that the proton-emitting state is associated with a Kπ=3/²⁺ configuration, in agreement with all the published proton-decay calculations and predictions for the ground-state configuration of ¹¹⁷La calculated in the framework of either adiabatic or non-adiabatic particle models. However, this is not in agreement with the most recent state-of-the-art quasi-particle non-adiabatic model calculations which predict a Kπ=7/²⁻ configuration.     

The characterisation of atomic structure and glass-forming ability of the Zr–Cu–Co metallic glasses studied by molecular dynamics simulations

In the present work, the glass formation process and structural properties of Zr₅₀Cu_50-xCo_x (0 ≤ x ≤ 50) bulk metallic glasses were investigated by a molecular dynamics simulation with the many body tight-binding potentials. The evolution of structure and glass formation process with temperature were discussed using the coordination number, the radial distribution functions, the volume–temperature curve, icosahedral short-range order, glass transition temperature, Voronoi analysis, Honeycutt–Andersen pair analysis technique and the distribution of bond–angles. Results indicate that adding Co causes similar responses on the nature of the Zr₅₀Cu_50-xCo_x (0 ≤ x ≤ 50) alloys except for higher glass transition temperature and ideal icosahedral type ordered local atomic environment. Also, the differences of the atomic radii play the key role in influencing the atomic structure of these alloys. Both Cu and Co atoms play a significant role in deciding the chemical and topological short-range orders of the Zr₅₀Cu_50-xCo_x ternary liquids and amorphous alloys. The glass-forming ability of these alloys is supported by the experimental observations reported in the literature up to now.     

Characterization of K2CO3/Co–MoS2 catalyst by XRD,XPS, SEM,and EDS

MoS₂, Co–MoS₂ and K₂CO₃/Co–MoS₂ catalysts have been characterized by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). XRD analysis indicates that Co–MoS₂ is a primary phase in K₂CO₃/Co–MoS₂ catalyst and the diffraction lines of Co–MoS₂ are not changed by the addition of K₂CO₃. Co₉S₈ phase is not present at Co/Mo mole ratio of 0.5 using a co-precipitation method for preparation of cobalt–molybdenum catalyst. The binding energies (BEs) of chemical species present on the surface of the catalysts are compared through the course of catalyst preparation. K₂CO₃/Co–MoS₂ catalyst has been investigated as a function of dispersion of K on the surface and exposure to a mixture of carbon monoxide and hydrogen (syngas) by scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS). The distribution of potassium on the surface of the K-promoted catalyst is not uniform.     

In-beam implantation of iron into germanium,silicon and diamond studied by the Mössbauer effect

The Mössbauer effect of⁵⁷Fe implanted into diamond structure semiconductors, Ge, Si and C, has been studied by in-beam implantation of⁵⁷Fe ions, which were excited to the 14 keV state by a³⁵Cl beam from a tandem Van de Graaff accelerator. The time between the stopping of the⁵⁷Fe nucleus and the emission of the 14 keV -ray is determined by the lifetime (140 ns) of the 14 keV state. In each material the Mössbauer spectrum exhibits a doublet with velocity coordinates (in mm/s) at room temperature, relative to a sodium ferrocyanide absorber, as follows: diamond (–0.99, 1.10), silicon (–0.80, 0.21), and germanium (–0.88, –0.02). In silicon and germanium crystals the spectra were observed over the temperature range between 13 K and 870 K. The relative line intensities changed dramatically and the positions of the lines shifted systematically with temperature. In addition, channelling studies were made on iron that had been implanted into silicon.     

Research of Effect of ^60Co γ-ray Irradiation on Cell Cycle of SMMC, 7721 Tumor Cell with Flow Cytometery

The resultsMost researchof cell cycle play an important role in resear, ching tumor occurrence, development and treatment. results show that malignant grade and pharmic sensitivity of tumor are relative to cell cycle. The sensitivity of medications is different to different phases of cell cycle of tumor. In general, the cell of M are more sensitivity. On the side, different medications have different action in different cell cycle. The irradiation can change cell cycle proccss and can induce the pattern of changes in cell cycle. For cxamplc, G1 arrest, G2 arrest and S arrest. So, thc research rcsults of tumor cell cycle in different irradiation have not only biological means but also realistic means for selecting chemical therapy medication after radiotherapy.     

Effects of Pre-exposure of Mouse Pituitary with Low-dose ^60Co γ-ray on Male Reproductive Endocrine Capacity Induced by Subsequent High-dose Irradiation

To investigate the effects of pre-exposure of mouse pituitary with low-dose ^60Co γ-ray on male reproductive endocrine capacity induced by subsequent high-dose irradiation, the pituitary of the B6C3F1 hybrid strain male mice were irradiated with 0.05 Gy of ^60Co γ-ray as the pre-exposure dose (D1), and were then irradiated with 2 Gy of ^60Co γ-ray as challenging irradiation dose (D2) at 4 h after per-exposure. Pituitary gonadotroping hormones --follicle-stimulating hormone (FSH) and luterinzing hormone (LH), serum testosterone, testis weight and sperm count were measured at 35th day after irradiation.     

Influence of γ-irradiation on properties of amorphous Fe78B13Si9 alloy studied by Mössbauer spectroscopy and positron annihilation technique

The influence of γ-irradiation on properties of METGLAS 2605S2 and FC3-1 Fe₇₈B₁₃Si₉ has been investigated by Mössbauer spectroscopy, positron annihilation technique as well as bending test. The ductility and orientation of magnetization were changed by γ-irradiation. They probably correlate with the change of microscopic free volume and release of stress in the ribbon, respectively.     

Determination of the Composition and Thickness of Co–Ni/Cr System Films by X-Ray Fluorescence

A procedure of determining the composition and thickness of Co–Ni/Cr two-layer films on Polycor by means of x-ray fluorescence is developed. The correction factors that take into account the effects of the mutual influence of the elements in the given system are calculated. The density of the materials entering into the composition of the films is determined experimentally. The metrological characteristics of the procedure are established.