Removal cross sections for 14.6 MeV neutrons

This paper reports on the determination of removal cross sections for different materials as paraffin, lead, graphite, concrete, and wood. The experimentally determined values of removal cross sections concerning these materials are respectively: 0.072±0.001, 0.089±0.003, 0.067±0.006, 0.071±0.003 and 0.0360±0.0005 cm^–1.     

Total cross sections for electron scattering from molecules: NH3 and H2O

By developing the semi-empirical formula recently obtained for total cross sections of electron scattering from diatomic molecules in the intermediate- and highenergy range, we calculate the total cross sections for electron scattering from molecules (NH₃ and H₂O) over an incident energy range of 10–1000 eV. The total cross sections have also been calculated by using the complex optical potential and the additivity rule. Compared with other available experimental and calculating data, excellent agreements have been achieved. The developed semi-empirical formula reflects that total cross sections for electron scattering from NH₃ and H₂O in the intermediate- and high-energy range quantitatively depend on the bond length.     

Absolute cross sections for electron scattering from furan

We report results of measurements and calculations of absolute cross sections for electron scattering from furan molecules (C(4)H(4)O). The experimental absolute differential cross sections (DCSs) for elastic electron scattering were obtained for the incident energies from 50 eV to 300 eV and for scattering angles from 20[ordinal indicator, masculine] to 110[ordinal indicator, masculine], by using a crossed electron-target beam setup and the relative flow technique for calibration to the absolute scale. The calculations of the electron interaction cross sections are based on a corrected form of the independent-atom method, known as the screening corrected additivity rule (SCAR) procedure and using an improved quasifree absorption model. The latter calculations also account for rotational excitations in the approximation of a free electric dipole and were used to obtain elastic DCSs as well as total and integral elastic cross sections which are tabulated in the energy range from 10 to 10 000 eV. All SCAR calculated cross sections agree very well with both the present and previously published experimental results. Additionally, calculations based on the first Born approximation were performed to calculate both elastic and vibrationally inelastic DCSs for all the modes of furane, in the energy range from 50 eV to 300 eV. The ratios of the summed vibrational to elastic DCSs are presented and discussed. Finally, the present results for furan are compared with previously published elastic DCSs for the tetrahydrofuran molecule and discussed.     

Elastic electron scattering cross sections of oriented and aligned molecules

Elastic differential electron scattering cross sections of oriented methyl iodide are calculated using the independent atom model. Results are presented for two specific orientations of the ICH₃ molecule for the purpose of comparison with the fictitious molecule IC, similarly oriented, at electron energies of 600 eV and 40 keV. Cross sections are also calculated for IC with a large angular momentum. In a comparison of the results for different orientations of the angular momentum vector, including random orientation, large differences between the cross sections are evident. This sensitivity to the plane of rotation of the molecule suggests the possibility of determining the degree of alignment of the angular momenta of a beam of such molecules by electron diffraction.     

Anomalous neutron Compton scattering cross sections in ammonium hexachlorometallates

The authors have performed neutron Compton scattering measurements on ammonium hexachloropalladate (NH(4))(2)PdCl(6) and ammonium hexachlorotellurate (NH(4))(2)TeCl(6). Both substances belong to the family of ammonium metallates. The aim of the experiment was to investigate the possible role of electronic environment of a proton on the anomaly of the neutron scattering intensity. The quantity of interest that was subject to experimental test was the reduction factor of the neutron scattering intensities. In both samples, the reduction factor was found to be smaller than unity, thus indicating the anomalous neutron Compton scattering from protons. Interestingly, the anomaly decreases with decreasing scattering angle and disappears at the lowest scattering angle (longest scattering time). The dependence of the amount of the anomaly on the scattering angle (scattering time) is the same in both substances (within experimental error). Also, the measured widths of proton momentum distributions are equal in both metallates. This is consistent with the fact that the attosecond proton dynamics of ammonium cations is fairly well decoupled from the dynamics of the sublattice of the octahedral anions PdCl(6) (2-) and TeCl(6) (2-), respectively. The hypothesis is put forward that proton-electron decoherence processes are responsible for the considered effect. Decoherence processes may have to do rather with the direct electronic environment of ammonium protons and not with the electronic structure of the metal-chlorine bond.     

Activation cross sections for some isotopes of Ti and Mo with 14.7 MeV neutrons

The (n,p) and (n,2n) reaction cross sections on natural Ti and Mo targets have been measured forE _n =14.73±0.05 MeV neutrons using the activation technique. The induced gamma-ray activities of the irradiated samples and their monitor foils were measured by using an HPGe detector. The cross sections were compared with previous results. The experimental uncertainties are between 3% and 8% in most cases.     

Total (elastic + inelastic) cross sections for electron scattering with bound and free germanium and lead atoms

Spherical complex optical potential (SCOP) approach has been used to compute the differential, total (elastic + inelastic) and momentum transfer cross sections for electrons scattering from the bound and free germanium and lead atoms in the energy range from 100–5000 eV. We find that the present calculated differential scattering cross sections (DCS) exhibit all important features (such as forward peaking, dip at middle angles and enhanced backward scattering) observed in other theoretical calculations and experimental measurements. The effect of absorption potential is generally to reduce the elastic cross section.     

On the sudden approximation of cross: computational tests and factorization of cross sections and related scattering phenomena

A sudden approximation recently derived by Cross using a semiclassical treatment of the orbital motion is recast into a form which permits factorization of differential and integral degeneracy averaged cross sections, opacities as a function of final angular momentum quantum number, the scattering amplitude, and the phenomenological cross section which describes spectral line broadening. Calculations are done using an average of initial and final orbital angular momentum quantum numbers for the partial wave parameter for ArN₂, ArTIF, H⁺H₂ and Li⁺H₂. The results indicate that the method is a good approximation for integral cross sections and opacities when the energy sudden approximation is valid and when the coupling of the orbital motion is important.     

Total dissociative electron attachment cross sections of selected amino acids

Total dissociative electron attachment cross sections are presented for the amino acids, glycine, alanine, proline, phenylalanine, and tryptophan, at energies below the first ionization energy. Cross section magnitudes were determined by observation of positive ion production and normalization to ionization cross sections calculated using the binary-encounter-Bethe method. The prominent 1.2 eV feature in the cross sections of the amino acids and the closely related HCOOH molecule is widely attributed to the attachment into the -COOH pi* orbital. The authors discuss evidence that direct attachment to the lowest sigma* orbital may instead be responsible. A close correlation between the energies of the core-excited anion states of glycine, alanine, and proline and the ionization energies of the neutral molecules is found. A prominent feature in the total dissociative electron attachment cross section of these compounds is absent in previous studies using mass analysis, suggesting that the missing fragment is energetic H-.     

Measurements of total cross sections for electron scattering from helium and argon

A time-of-flight (TOF) electron spectrometer has been used to measure absolute total cross sections (TCS) scattered from helium and argon over the energy range from 1 to 50 eV. The TOF spectrometer and experimental procedure are described briefly, and experimental results are presented together with associated errors. The results are found to be in good agreement with other experimental and theoretical data.     

Total photon attenuation cross sections of helium at energies below 10 keV. An assessment of the accuracy of measured and calculated cross sections

Recent measurements and calculations of helium photoionization, photon attenuation and scattering cross sections for energies below 10 keV are critically evaluated and compared with older measurements, calculations and tabulations. Oscillator strength sum rules are used to assess the validity of various results.     

Total one-electron capture cross sections for Ar q+ and I q+ ions in slow collisions on H2 and He

Argon and iodine recoil ions were produced by a 2 GeV U⁷⁵⁺ beam and total one electron capture cross sections are measured for 198 eV/q Ar ^q+ (4≦q≦15) and I ^q+ (5≦q≦27 on He andH ₂. The cross section can be approximately reproduced by 1/2 πR ² according to the classical barrier model. Theq-dependences exhibit significant fluctuations even for high charge states.     

Total dissociative electron attachment cross sections for molecular constituents of DNA

Total cross sections for the dissociative electron attachment process are presented for the DNA bases thymine, cytosine, and adenine and for three compounds used as surrogates for the ribose and phosphate groups, tetrahydrofuran, 3-hydroxytetrahydrofuran, and trimethylphosphate, respectively. Cross section magnitudes are obtained by observation of positive ion production and normalization to ionization cross sections calculated elsewhere using the binary-encounter-Bethe method. The average cross section of the three bases is 3-10 times smaller than the effective cross section per nucleotide reported for single strand breaks in surface-bound supercoiled DNA. Consequently, damage to the bases alone does not appear to account for the major portion of the strand breaks. The presence of an OH group on the ribose surrogate considerably enhances its cross section. Model compounds in which protonation or OH groups are used to terminate bonds may therefore display larger cross sections than in DNA itself.     

Chemical effects on oscillatory cross sections in low energy ion scattering

Oscillatory structure in the scattered ion yield for He⁺ scattering from In has been observed to depend upon the chemical environmental of the In. Fourier analysis of the oscillatory structure indicates two major components whose relative amplitudes vary significantly with chemical environment.     

Evaluation of cross sections for X-ray and high-energy electron scattering from molecular systems

An analytical and computationally efficient formalism for the evaluation of rotationally averaged cross sections for X-ray and high-energy electron scattering from molecular systems is given. Its application for both SCF and CI wave functions is discussed. © 1994 John Wiley & Sons, Inc.