Stability of {\text{SrCe}}_{{0.9}} {\text{Eu}}_{{0.1}} {\text{O}}_{{3 - \delta }} and {\text{SrZr}}_{{0.2}} {\text{Ce}}_{{0.7}} {\text{Eu}}_{{0.1}} {\text{O}}_{{3 - \delta }} under H2 atmospheres

Previous H₂ permeation tests showed a degradation of H₂ permeation flux with time. To understand the cause of degradation and develop a solution, the stability of $ {\text{SrCe}}_{{0.9}} {\text{Eu}}_{{0.1}} {\text{O}}_{{3 - \delta }} $ and $ {\text{SrZr}}_{{0.2}} {\text{Ce}}_{{0.7}} {\text{Eu}}_{{0.1}} {\text{O}}_{{3 - \delta }} $ samples were studied under dry and wet H₂ atmospheres. Total conductivity of $ {\text{SrCe}}_{{0.9}} {\text{Eu}}_{{0.1}} {\text{O}}_{{3 - \delta }} $ increased with time in dry H₂. The X-ray diffraction pattern of $ {\text{SrCe}}_{{0.9}} {\text{Eu}}_{{0.1}} {\text{O}}_{{3 - \delta }} $ after dry hydrogen atmosphere heat treatments show CeO₂ peaks indicating that $ {\text{SrCe}}_{{0.9}} {\text{Eu}}_{{0.1}} {\text{O}}_{{3 - \delta }} $ decomposes under dry H₂ atmospheres; scanning electron microscopy and energy dispersive X-ray spectroscopy analyses prove that decomposition proceeded along the grain boundaries. $ {\text{SrZr}}_{{0.2}} {\text{Ce}}_{{0.7}} {\text{Eu}}_{{0.1}} {\text{O}}_{{3 - \delta }} $ was investigated and demonstrated greater stability under dry hydrogen atmospheres. However, Zr substitution results in a tradeoff with electrical properties.     

Theoretical study of collision and collision-free radiative lifetimes of {{\text{S}}_2}\left( {{{\text{B}}^3}\Sigma_{\text{u}}^{-} \left( {{\upsilon^{\prime}} = 0 - 9} \right)} \right)

We calculate multireference configuration-interaction wavefunctions and the potential-energy curves for the $ {B^3}\Sigma_u^{-} $ and $ {X^3}\Sigma_g^{-} $ states of the collision-free S₂ molecule and the T-shape collision complex S₂?CHe using cc-pVQZ basis sets. We obtain the transition dipole moments of the $ {{\text{S}}_2}\left( {{B^3}\Sigma_u^{-} \to {X^3}\Sigma_g^{-} } \right) $ and the Franck?CCondon factors between the vibrational levels of this two states. We evaluate the radiative lifetimes of $ {{\text{S}}_2}\left( {{B^3}\Sigma_u^{-} \left( {{\upsilon^{\prime}} = 0 - 9} \right)} \right) $ levels of the collision complex and the collision-free molecule and compare them with the experiments. The collision provides little change in the radiative lifetimes of $ {{\text{S}}_2}\left( {{B^3}\Sigma_u^{-} \left( {{\upsilon^{\prime}} = 0 - 9} \right)} \right) $ according to the previous calculations. We obtain excellent agreement between the theoretical results and the experiments. The data calculated are very useful in the study of the microwave-driven high-pressure sulfur lamp and an S₂ laser pumped by a transverse fast discharge.     

On q-Deformed {\mathfrak{gl}_{\ell+1}}-Whittaker Function II

A representation of a specialization of a q-deformed class one lattice ${\mathfrak{gl}_{\ell+1}}$ -Whittaker function in terms of cohomology groups of line bundles on the space ${\mathcal{QM}_d(\mathbb{P}^{\ell})}$ of quasi-maps ${\mathbb{P}^1 \to \mathbb{P}^{\ell}}$ of degree d is proposed. For ? = 1, this provides an interpretation of the non-specialized q-deformed ${\mathfrak{gl}_{2}}$ -Whittaker function in terms of ${\mathcal{QM}_d(\mathbb{P}^1)}$ . In particular the (q-version of the) Mellin-Barnes representation of the ${\mathfrak{gl}_2}$ -Whittaker function is realized as a semi-infinite period map. The explicit form of the period map manifests an important role of q-version of Γ-function as a topological genus in semi-infinite geometry. A relation with the Givental-Lee universal solution (J-function) of q-deformed ${\mathfrak{gl}_2}$ -Toda chain is also discussed.     

Proton-antiproton annihilation into a \Lambda_{c}^{+} \bar{{\Lambda}}_{c}^{-} pair

The process p $ \bar{{p}}$ $ \rightarrow$ $ \Lambda_{c}^{+}$ $ \bar{{\Lambda}}_{c}^{-}$ is investigated within the handbag approach. It is shown to lowest order of perturbative QCD that, under the assumption of restricted parton virtualities and transverse momenta, the dominant dynamical mechanism, characterized by the partonic subprocess u $ \bar{{u}}$ $ \rightarrow$ c $ \bar{{c}}$ , factorizes in the sense that only the subprocess contains highly virtual partons, namely a gluon, while the hadronic matrix elements embody only soft scales and can be parameterized in terms of helicity flip and non-flip generalized parton distributions. Modelling the latter functions by overlaps of light-cone wave functions for the involved baryons we are able to predict cross-sections and spin correlation parameters for the process of interest.     

Femtosecond relaxation kinetics of highly excited \mathrm{M}_{\mathrm{Na}}^{**} states in CaF2 at 3.2 eV and 4.7 eV

Femtosecond (fs) laser pulses at variable delay times allowed us to track the fast non-radiative transitions between the manifold of highly excited $\mathrm{M}_{\mathrm{Na}}^{**}$ states to the lower lying fluorescent $\mathrm{M}_{\mathrm{Na}}^{*}$ state in CaF₂. Two distinct $\mathrm{M}_{\mathrm{Na}}^{**}$ states of the manifold at 3.16?eV ( $\mathrm{M}_{\mathrm{Na}2}^{**}$ ) and 4.73?eV ( $\mathrm{M}_{\mathrm{Na}3}^{**}$ ) were populated using the second (SH) and third harmonics (TH) of fs laser light at 785?nm. The population kinetics of the fluorescent $\mathrm{M}_{\mathrm{Na}}^{*}$ state in the 2?eV excitation energy range was revealed by depleting its fluorescence centered at 740?nm using fundamental near infrared (NIR) fs laser pulses. The related time constants for $\mathrm{M}_{\mathrm{Na}2,3}^{**}{\sim}{>} \mathrm{M}_{\mathrm{Na}}^{*}$ relaxation amounted to 1.0±0.14?ps and 3.0±0.3?ps upon SH and TH excitation, respectively.     

A stable and easily sintering {\text{BaCe}}_{0.7} {\text{Sn}}_{0.1} {\text{Gd}}_{0.2} {\text{O}}_{3 - \delta } electrolyte for solid oxide fuel cells

${\text{BaCe}}_{0.7} {\text{Sn}}_{0.1} {\text{Gd}}_{0.2} {\text{O}}_{3 - \sigma } $ (BCSG) and ${\text{BaCe}}_{0.8} {\text{Gd}}_{0.2} {\text{O}}_{3 - \sigma } $ (BCG) powders were prepared by solid-state reaction method. After exposure in 5% CO₂?+?5% H₂O?+?90% N₂ at 500 °C for 5 h, the BCSG powders were hardly affected while the BCG powders decomposed into CeO₂ and BaCO₃ phases. Moreover, the relative density of BCSG reaches 97%, while the BCG just displays 91% after sintering at 1,400 °C. The BCSG displays a conductivity of 0.01 S/cm at 700 °C in humid hydrogen, which is quite close to 0.012 S/cm for BCG. A fuel cell with BCSG exhibits 1.02 V for open circuit voltage, 420 mW/cm² for peak performance and 0.23 Ω cm² for interfacial resistance at 700 °C, respectively.     

Magnetotransport properties in \text{ Ni }_{81}\text{ Fe }_{19}\text{/Zr } multi-layers

In this work, we present a study of the magneto transport properties in magnetic multilayered structure $\text{ Ni }_{81}\text{ Fe }_{19}\text{/Zr }$ Ni 81 Fe 19 /Zr . The magnetic $(\text{ Ni }_{81}\text{ Fe }_{19})$ ( Ni 81 Fe 19 ) and non magnetic (Zr) layer thickness $(\mathbf{t}_\mathbf{NiFe}, \mathbf{t}_\mathbf{zr})$ ( t NiFe , t zr ) effects on the magneto resistance (MR) are discussed theoretically in the framework of the Johnson–Camley semi classical approach based on the Boltzmann transport equation. A comparison between calculated and measured MR is obtained. The observed MR ratio oscillates for Zr layer thickness with an average period of 7Å. A generally weak $\text{ MR }(\text{ t }_{\mathrm{NiFe}})$ MR ( t NiFe ) ratio for fixed $\mathbf{t}_\mathbf{zr}$ t zr is obtained and it shows a maxima peak of the MR with a value of 1.8 % located at $\mathbf{t}_\mathbf{NiFe}= 80$ t NiFe = 80 Å.     

Quasi solid state dye-sensitized solar cells based on polyvinyl alcohol (PVA) electrolytes containing \mathbf{I}^{\mathbf{-}}/\mathbf{I}_{\mathbf{3}}^{\mathbf{-}} redox couple

Quasi solid state dye-sensitized solar cells (DSSCs) have been fabricated with electrolytes containing $\text{ I }^{-}/\text{ I }_{3}^{-}$ redox couple using 80 % hydrolyzed polyvinyl alcohol (PVA) doped with potassium iodide (KI) and a mixture of potassium iodide and tetrapropyl ammonium iodide ( $\text{ Pr }_{4}\text{ NI }$ ) salts. The quasi solid state gel polymer electrolytes were prepared using 1:1 ethylene carbonate (EC):propylene carbonate (PC) mixture. The solar cells have the structure of ITO/ $\text{ TiO }_{2}$ /N3-Dye/electrolyte/Pt/ITO. The conductivity of the electrolytes has been calculated from the bulk resistance value determined using the electrochemical impedance spectroscopy. The performance of the DSSCs has been studied by varying the concentration of the doping salts in the electrolyte and incident light intensity. The DSSC fabricated with the KI salt electrolyte containing 9.9 wt% PVA, 39.6 wt% EC, 39.6 wt% PC, 10.9 wt% KI $(+\text{ I }_{2})$ exhibited the best power conversion efficiency of 1.97 %. However, the DSSC with a double-salt electrolyte containing 9.9 wt% PVA: 39.6 wt% EC: 39.6 wt% PC: (6.5 wt% KI: 4.4 wt% $\text{ Pr }_{4}\text{ NI }$ ) ( $+\text{ I }_{2}$ ) exhibited a higher efficiency of 3.27% under $100 \text{ mW/cm }^{2}$ light intensity. The efficiency of this cell increased to 4.59 % under dimmer light of intensity of $54 \text{ mW/cm }^{2}$ .     

Analysis of the \frac{1} {2}^ - and \frac{3} {2}^ - heavy and doubly heavy baryon states with QCD sum rules

In this article, we study the $\frac{1} {2}^ -$ and $\frac{3} {2}^ -$ heavy and doubly heavy baryon states $\Sigma _Q \left( {\frac{1} {2}^ - } \right)$ , $\Xi '_Q \left( {\frac{1} {2}^ - } \right)$ , $\Omega _Q \left( {\frac{1} {2}^ - } \right)$ , $\Xi _{QQ} \left( {\frac{1} {2}^ - } \right)$ , $\Omega _{QQ} \left( {\frac{1} {2}^ - } \right)$ , $\Sigma _Q^* \left( {\frac{3} {2}^ - } \right)$ , $\Xi _Q^* \left( {\frac{3} {2}^ - } \right)$ , $\Omega _Q^* \left( {\frac{3} {2}^ - } \right)$ , $\Xi _{QQ}^* \left( {\frac{3} {2}^ - } \right)$ and $\Omega _{QQ}^* \left( {\frac{3} {2}^ - } \right)$ by subtracting the contributions from the corresponding $\frac{1} {2}^ +$ and $\frac{3} {2}^ +$ heavy and doubly heavy baryon states with the QCD sum rules in a systematic way, and make reasonable predictions for their masses.     

Modeling of Spin Hamiltonian Parameters for Vanadyl-Doped {\bf\hbox{K}_2\hbox{SO}_4{-}\hbox{Na}_2\hbox{SO}_4{-}\hbox{ZnSO}_4} Glass

A full ligand-field energy matrix diagonalization treatment for 3d ¹ ions in tetragonal symmetry is developed on the basis of the two spin?Corbit coupling parameter model, and the contributions of the spin?Corbit coupling of the ligand ions to the optical and electron paramagnetic resonance spectra are included. Spin Hamiltonian parameters of the tetragonal ${\rm V}^{4+}$ center in $\hbox{K}_2\hbox{SO}_4 {-} \hbox{Na}_2\hbox{SO}_4{-}\hbox{ZnSO}_4$ glass are calculated from the complete energy matrix diagonalization and the perturbation theory methods. The results calculated by both methods are not only close to each other but also in good agreement with the experimental values. Furthermore, the compressed defect structure of the ${\rm (VO_6)^{8-}}$ cluster is discussed.     

Muonic Anti-hydrogen {(\bar{\rm H}_{\mu}}) Formation in Low-energy Three-body Reactions

A few-body type computation is performed for a three-charge-particle collision with participation of a slow antiproton ${\bar{\rm{p}}}$ and a muonic muonium atom (true muonium), i.e. a bound state of two muons ${(\mu^{+}\mu^{-})}$ in its ground state. The total cross section of the following reaction ${\bar{\rm p}+(\mu^{+}\mu^{-}) \rightarrow \bar{\rm{H}}_{\mu} + \mu^{-}}$ , where muonic anti-hydrogen ${\bar{\rm{H}}_{\mu}=(\bar{\rm p}\mu^{+})}$ is a bound state of an antiproton and positive muon, is computed in the framework of a set of coupled two-component Faddeev-Hahn-type equation. A better known negative muon transfer low energy three-body reaction: ${{\rm t}^{+} + ({\rm d}^{+}\mu^{-})\rightarrow ({\rm t}^{+}\mu^{-}) + {\rm d}^{+}}$ is also computed as a test system. Here, t⁺ is triton and d⁺ is deuterium.     

On the Quasi-linear Elliptic PDE {-\nabla \cdot ( \nabla{u}/ \sqrt{1-| \nabla{u} |^2}) = 4 \pi \sum_k a_k \delta_{s_k}} in Physics and Geometry

It is shown that for each finite number N of Dirac measures ${\delta_{s_n}}$ supported at points ${s_n \in {\mathbb R}^3}$ with given amplitudes ${a_n \in {\mathbb R} \backslash\{0\}}$ there exists a unique real-valued function ${u \in C^{0, 1}({\mathbb R}^3)}$ , vanishing at infinity, which distributionally solves the quasi-linear elliptic partial differential equation of divergence form ${-\nabla \cdot ( \nabla{u}/ \sqrt{1-| \nabla{u} |^2}) = 4 \pi \sum_{n=1}^N a_n \delta_{s_n}}$ . Moreover, ${u \in C^{\omega}({\mathbb R}^3\backslash \{s_n\}_{n=1}^N)}$ . The result can be interpreted in at least two ways: (a) for any number N of point charges of arbitrary magnitude and sign at prescribed locations s _n in three-dimensional Euclidean space there exists a unique electrostatic field which satisfies the Maxwell-Born-Infeld field equations smoothly away from the point charges and vanishes as |s| ?? ??; (b) for any number N of integral mean curvatures assigned to locations ${s_n \in {\mathbb R}^3 \subset{\mathbb R}^{1, 3}}$ there exists a unique asymptotically flat, almost everywhere space-like maximal slice with point defects of Minkowski spacetime ${{\mathbb R}^{1, 3}}$ , having lightcone singularities over the s _n but being smooth otherwise, and whose height function vanishes as |s| ?? ??. No struts between the point singularities ever occur.     

Preliminary studies of the Raman spectra of \hbox {Ag}_{2}\hbox {Te}\hbox { and }\hbox {Ag}_{5}\hbox {Te}_{3}

The theoretical calculations indicated that the monoclinic low-temperature phase of silver telluride $(\upbeta \hbox {-Ag}_{2}\hbox {Te})$ is a new binary topological insulator with highly anisotropic single Dirac cone surface. We obtained $\upbeta \hbox {-Ag}_{2}\hbox {Te}$ crystal ingots containing few grains by the Bridgman method. We also deposited thin films of tellurium, $\hbox {Ag}_{5}\hbox {Te}_{3}\hbox { and }(\hbox {Te+Ag}_{5}\hbox {Te}_{3})$ by thermal evaporation method. The Raman spectra of $\upbeta \hbox {-Ag}_{2}\hbox {Te}$ , tellurium and $\hbox {Ag}_{5}\hbox {Te}_{3}$ were measured at three excitation wave lengths: 633, 515 and 488 nm. The Raman active modes of $\upbeta \hbox {-Ag}_{2}\hbox {Te}$ , tellurium and $\hbox {Ag}_{5}\hbox {Te}_{3}$ are situated at frequencies below 300  $\hbox {cm}^{-1}$ while vibrations of other phases appear at higher frequencies.     

A new analysis improving the evidence of a narrow peak in the invariant-mass distribution of the \Lambdap system observed in the \bar{{p}} annihilation at rest on 4He

The presence of a narrow peak in the $ \Lambda$ p invariant-mass distribution observed in the $ \bar{{p}}$ annihilation reaction at rest $\ensuremath \bar{p} {}^4\mathrm{He}\rightarrow p\pi^-p\pi^+\pi^-n X$ is discussed again through an analysis procedure which improves the ratio signal/background in comparison with the previous analysis. The peak is centred at 2223.2±3.2_stat±1.2_syst MeV and has a statistical significance of 4.7 $ \sigma$ , values compatible with those published previously. If interpreted as the result of the decay into $ \Lambda$ p of a $\ensuremath { }_{\bar{K}}{}^2\mathrm{H}$ bound system, the corresponding binding energy should be B = - 151.0±3.2_stat±1.2_syst MeV and the width $ \Gamma_{{FWHM}}^{}$ < 33.9±6.2 MeV. The production rate has a lower limit of 1.2 10^-4. Data on the $ \bar{{p}}$ annihilation reaction at rest $ \bar{{p}}$ ⁴He $ \rightarrow$ p $ \pi^{-}_{}$ p $ \pi^{-}_{}$ p _s X , analyzed for the first time, lead to a result in qualitative agreement with the previous one.     

Finite W-Superalgebras and Truncated Super Yangians

Let ${Y_{m|n}^{\ell}}$ be the super Yangian of general linear Lie superalgebra for ${\mathfrak{gl}_{m|n}}$ . Let ${e \in \mathfrak{gl}_{m\ell|n\ell}}$ be a “rectangular” nilpotent element and ${\mathcal{W}_e}$ be the finite W-superalgebra associated to e. We show that ${Y_{m|n}^{\ell}}$ is isomorphic to ${\mathcal{W}_e}$ .     

Quantum Sphere {\mathbb{S}^4} as a Non-Levi Conjugacy Class

We construct a ${U_\hbar(\mathfrak{sp}(4))}$ -equivariant quantization of the four-dimensional complex sphere ${\mathbb{S}^4}$ regarded as a conjugacy class, Sp(4)/Sp(2) ×?Sp(2), of a simple complex group with non-Levi isotropy subgroup, through an operator realization of the quantum polynomial algebra ${\mathbb{C}_\hbar[\mathbb{S}^4]}$ on a highest weight module of ${U_\hbar(\mathfrak{sp}(4))}$ .     

Complex Vector Formalism of Harmonic Oscillator in Geometric Algebra: Particle Mass,Spin and Dynamics in Complex Vector Space

Elementary particles are considered as local oscillators under the influence of zeropoint fields. Such oscillatory behavior of the particles leads to the deviations in their path of motion. The oscillations of the particle in general may be considered as complex rotations in complex vector space. The local particle harmonic oscillator is analyzed in the complex vector formalism considering the algebra of complex vectors. The particle spin is viewed as zeropoint angular momentum represented by a bivector. It has been shown that the particle spin plays an important role in the kinematical intrinsic or local motion of the particle. From the complex vector formalism of harmonic oscillator, for the first time, a relation between mass $m$ and bivector spin $S$ has been derived in the form $\varvec{\sigma }_3 mc^2{\mathcal {J}}_{\pm } =\lambda \Omega _{\mathbf{s}} \cdot \mathrm{{S}} {\mathcal {J}}_{\pm }$ . Where, $\Omega _{s}$ is the angular velocity bivector of complex rotations, $c$ is the velocity of light. The unit vector $\varvec{\sigma }_3$ acts as an operator on the idempotents ${\mathcal {J}}_{+}$ and ${\mathcal {J}}_{-}$ to give the eigen values $\lambda =\pm 1.$ The constant $\lambda $ represents two fold nature of the equation corresponding to particle and antiparticle states. Further the above relation shows that the mass of the particle may be interpreted as a local spatial complex rotation in the rest frame. This gives an insight into the nature of fundamental particles. When a particle is observed from an arbitrary frame of reference, it has been shown that the spatial complex rotation dictates the relativistic particle motion. The mathematical structure of complex vectors in space and spacetime is developed.     

Joint System Quantum Descriptions Arising from Local Quantumness

We study the entropy flux in the stationary state of a finite one-dimensional sample ${\mathcal{S}}$ connected at its left and right ends to two infinitely extended reservoirs ${\mathcal{R}_{l/r}}$ at distinct (inverse) temperatures ${\beta_{l/r}}$ and chemical potentials ${\mu_{l/r}}$ . The sample is a free lattice Fermi gas confined to a box [0, L] with energy operator ${h_{\mathcal{S}, L}= - \Delta + v}$ . The Landauer-Büttiker formula expresses the steady state entropy flux in the coupled system ${\mathcal{R}_l + \mathcal{S} + \mathcal{R}_r}$ in terms of scattering data. We study the behaviour of this steady state entropy flux in the limit ${L \to \infty}$ and relate persistence of transport to norm bounds on the transfer matrices of the limiting half-line Schrödinger operator ${h_\mathcal{S}}$ .     

Decay rate ratios of \varUpsilon (5S)\to B{\bar{B}} reactions

We calculate the decay rate ratios for OZI allowed decays of ?(5S) to two B mesons by using the decay amplitudes which incorporate the wave function of the ?(5S) state. We obtain the result that the branching ratio of the ?(5S) decay to $B_{s}^{*}{\bar{B}}_{s}^{*}$ is much larger than the branching ratio to $B_{s}{\bar{B}}_{s}^{*}$ or ${\bar{B}}_{s}B_{s}^{*}$ , in good agreement with the recent experimental results of CLEO and BELLE. This agreement with the experimental results is made possible since the nodes of the ?(5S) radial wave function induce the nodes of the decay amplitude. We find that the results for the ?(5S) decays to $B_{u}^{(*)}{\bar{B}}_{u}^{(*)}$ or $B_{d}^{(*)}{\bar{B}}_{d}^{(*)}$ pairs are sensitive to the parameter values used for the potential between heavy quarks.