Die β-Zerfallsenergie der Technetiumisotope Tc103, Tc104 und Tc105

Molybdenum fission products from Uranium were rapidly separated using a sublimation technique. Their Technetium daughters could be separated from the Molybdenum sample by a second sublimation. The decay of Tc¹⁰³, Tc¹⁰⁴ and Tc¹⁰⁵ was investigated using scintillation counters and coincidence methods. Tc¹⁰³ decays by the emission of twoβ-groups at energies of 2·0 Mev and 2·2 Mev followed byγ-lines of 135 kev, 215 kev and 350 kev. According to a proposed decay-scheme Tc¹⁰³ decays with aQ-value of 2·35±0·10 Mev into Ru¹⁰³. Tc¹⁰⁵ emits aβ-group of about 3·4 Mev maximum energy followed by a 110 kevγ-transition. TheQ-value of the Tc¹⁰⁵ decay was estimated to be 3·4±0·2 Mev. Fromβ?γ- andγ?γ-coincidence spectra of Tc¹⁰⁴ fourβ?γ-γ-cascades could be identified, which populate excited states of 0·36 Mev, 0·89 Mev, 2·5 Mev, 3·5 Mev and 4·05 Mev in Ru¹⁰⁴. TheQ-value of the Tc¹⁰⁴ decay was found to be 5·85±0·10 Mev. TheQ-values and spin assignements of the groundstates of Tc¹⁰³ and Tc¹⁰⁵ are discussed in a more detailedβ-decay systematic.     

Improved analytical formulae for correcting elastic-scattering effects in X-ray photoelectron spectroscopy

We present new predictive formulae for the correction parameters Q_x and β_eff that are used to account for the effects of elastic scattering in quantitative X-ray photoelectron spectroscopy. These formulae were derived from an analysis of published calculations of Q_x and β_eff from extensive Monte Carlo simulations for a group of elemental solids. Two formulae are given for each parameter. One formula is a function of the single-scattering albedo and the photoelectron emission angle, and is useful for emission angles between 0° and 80°. The other formula is a function only of the single-scattering albedo and is useful for emission angles between 0° and 50°. The single-scattering albedo is in turn a simple function of two material parameters, the inelastic mean free path and the transport mean free path. The latter parameters can be determined readily from available predictive formulae for any material or from databases. The root-mean-square and mean deviations of the Monte Carlo values of Q_x and β_eff from those found with the new formulae are comparable to or smaller than those found with formulae published by Seah and Gilmore.     

Electroproduction of η mesons in the region of the resonanceS 11(1535) at momentum transfers of 2 and 3 GeV2

We report on results of η-electroproduction in the resonance region at momentum transfers ofQ ²=2 GeV² and 3 GeV². The differential cross sections obtained in the region of the second nucleon resonance strongly support the dominance of theS ₁₁(1535) in this channel. The total transverse virtual photoproduction cross section of theS ₁₁(1535) shows a flatQ ²-dependence ～e ^?0.39· Q ². Comparison with the total resonant γ _v p cross section in the second resonance region aroundW=1.5 GeV shows that theD ₁₃(1520) production decreases much faster (～e ^?1.6· Q ²). The data are not compatible with the simple harmonic oscillator quark model with spin and orbit excitation of a quark only.     

States of167Ho from the decay of neutron rich nuclide167Dy

Theβ ^?-decay of ₆₆ ¹⁶⁷ Dy produced through the fast neutron reaction¹⁷⁰Er(n, α)¹⁶⁷Dy has been investigated by using several kinds of detectors and a high-capacity two-parameter recording system. The half-life andβ ^?-decay energy of¹⁶⁷Dy were determined to beT _1/2 = 6.20 ± 0.08min andQ _β-=2.35±0.06, respectively. The observed level scheme of ₆₇ ¹⁶⁷ Ho (completely unknown previously) contains 12 states, among them a 6.0±0.1 μsM2 isomer at 259.3 keV. On the basis of theoretical and systematic considerations combined with multipole determinations, the following Nilsson model assignments are proposed for the lowest states of¹⁶⁷Ho: 0 keV (7?/2 [523]), 259.3 keV (3+/2[411]), 319.8 keV (5/2 3+/2[411]), 392.5 keV (1+/2[411]), 410.0 keV (3/2 1+/2[411]), 569.7 keV (3?/2{7?/2[523], 2⁺}). Theβ-decay proceeds mainly to the proposed gamma-vibrational state at 569.7 keV with an anomalously low logft value 5.4, indicating similarity between the microscopic structures of this state and the famous ¦K ₀?2¦ gamma vibration of¹⁶⁵Ho.     

Limits on the impact parameters occuring in specific K−p interactions at 8.25 GeV/c

We have determined a lower limit of the impact parameter for the reactions associated with the channels K^?p → K^?pπ⁺π^?K^?p → λπ⁺π^?π⁰. The limit was found to be highest for the diffractive parts of the first channel (～ 0.52 fm) and smallest for the forward Λ in the second channel (～0.21 fm).We have also examined the elements of the inverse correlation matrix for the transfer: the off-diagonal elements are small (consistent with zero) for n = 4?7 body products. The log 〈Q_i·Q_j〉 of the correlation matrix as a function of $\text{Гi?jГ}$ falls on a straight line and the eigenvalue λ₁ of the transverse momentum transfer eigenfunction was found to increase slightly from ～0.6 for 4-body to ～0.7 for 7-body products. The 〈cosφ_ij〉 of the Q_i, Q_j shows similar behaviour to the 〈Q_i·Q_j〉     

Mössbauer conversion spectroscopy: Measurements on the first excited states of180, 182W and145Pm

The Mössbauer Conversion (MBC) Spectroscopy and criteria for its useful application are discussed and compared with other MB-techniques. By help of the MBC spectroscopy the isomer shift of the first excited state in¹⁸²W was measured and a change in radius ?0.05 · 10^?4>Δ 〈r ²〉/〈r ²〉>?0.28 · 10^?4 derived. The ratio of quadrupole moments of first excited states in¹⁸⁰W and¹⁸²W turns out to be¹⁸⁰ Q/¹⁸² Q=0.976 (30). Due to the excellent statistical quality of the spectra the interference parameter of the 100keVE2 transition in¹⁸²W could be determined to 2β=0.0165(9) for theL-shell. The MB-effect for the 61 keV transition in the instable¹⁴⁵Pm has been detected for the first time. A widthΛ _exp=2.15(58) mm/s was obtained.     

ΔT-window neutron spectrometer

A high resolution neutron spectrometer making use of a ΔT-window filter for the analyser and time-of-flight technique for analysing incident neutron energy has been designed. The spectrometer will provide a continuously variable energy resolution ΔE from 40–50μeV at ∼ 5230μeV. The range of energy transfer allowed is −1450μeV to +2950μeV and the range of wavevector transferQ allowed is 0·82–3·06 ?⁻¹. Depending on the resolution used, the counting rates are expected to vary from 28–60 × 10³ counts/hr if one assumes 10% isotropic elastic scattering from the sample.     

Beta decay energies and nuclear masses of148Ba,148La and151Pr

Theβ-decay energy of the neutron-rich isotopes¹⁴⁸Ba,¹⁴⁸La and¹⁵¹Pr has been measured at the Institute Laue-Langevin (ILL). The¹⁴⁸Ba- and¹⁴⁸La-nuclei were produced using a high-temperature ion source at the OSTIS separator of this institute, whereas samples of¹⁵¹Pr were obtained from the thermal fission of²³⁹Pu, used as a target in the mass separator LOHENGRIN. At both instruments,βγ-coincidences were measured with a plastic scintillator telescope and a Ge(I)-detector, together withβ-singles andγ-singles spectra. Theβ-spectra emitted in coincidence with 44γ-lines in the decay of these nuclei have been evaluated. From their endpoint energies, the followingQ _β -values have been obtained:Q _β (¹⁴⁸Ba)=5115±60keV;Q _β (¹⁴⁸La)=7255±55 keV;Q _β (¹⁵¹Pr)=4170±75 keV. Using these results, the nuclear massesA of these nuclei can be calculated with a relative error ΔA/A?5·10^?7. In addition, the two-neutron separation energies and the mass excesses have been derived; the results are compared with recent predictions of theoretical mass calculations.     

Decay properties of neutron deficient Kr isotopes

The decay properties of the neutron deficient isotopes^73–77Kr and^73–76Br have been studied at the ISOLDE facility at CERN. The total decay energiesQ, as determined fromβ ⁺ singles orβ ⁺ -γ coincidence measurements, are compared with mass formulae.     

Investigation of224Ra in the226Ra(α, α′ 2n) reaction

Positive and negative parity bands have been followed up to 10⁺ (possibly 12⁺) and 11^? in²²⁴Ra and are compared to the corresponding bands in the isotone²²⁶Th. If a constant value of the intrinsic quadrupole moment is assumed for allE2 transitions in²²⁴Ra theE1/E2 branching ratios are consistent with an intrinsic dipole moment of ¦Q₁¦=0.032(3)e·fm. This small value, as compared to ¦Q₁¦=0.30(2)e·fm for²²⁶Th, can be explained by an almost complete cancellation of large positive liquid-drop and negative shell-model contributions.     

Microscopic study of neutron-rich dysprosium isotopes

Microscopic studies in heavy nuclei are very scarce due to large valence spaces involved. This computational problem can be avoided by means of the use of symmetry-based models. Ground-state, γ and β bands, and their B(E2) transition strengths in ^160–168Dy isotopes, are studied in the framework of the pseudo-SU(3) model which includes the preserving symmetry Q · Q term and the symmetry-breaking Nilsson and pairing terms, systematically parametrized. Additionally, three rotor-like terms are considered, whose free parameters, fixed for all members of the chain, are used to fine tune the moment of inertia of rotational bands and the band head of γ and β bands. The model succesfully describes in a systematic way rotational features in these nuclei and allows to extrapolate toward the midshell nucleus ¹⁷⁰Dy. The results presented show that it is possible to study a full chain of isotopes or isotones in the region with the present model.     

Static quadrupole moments of the first excited states of 200Hg and 202Hg

The static quadrupole moments Q_2⁺ and B(E2; 0⁺ → 2⁺) values of the 2⁺ first excited states of ²⁰⁰Hg and ²⁰²Hg have been determined using the reorientation effect in Coulomb excitation. An annular silicon surface-barrier detector was used to detect backscattered ⁴He, ¹²C and ¹⁶O projectiles. It is found that for ²⁰⁰Hg, Q_2⁺ = +1.07 ± 0.19 e · b(+0.98 ± 0.19 e · b) for destructive (constructive) interference from the 2^+′ state, and B(E2; 0⁺ → 2⁺) = 0.853 ± 0.007 e² · b². For ²⁰²Hg, we find Q_2⁺ = +1.01 ± 0.13 e · b (+0.87 ± 0.13 e · b) and B(E2; 0⁺ → 2⁺) = 0.605 ± 0.005 e² · b². The Q_2⁺ value obtained for ²⁰⁰Hg is in agreement with previous work, but that for ²⁰²Hg is not. The results obtained are compared with the predictions of various nuclear models, and the mass dependence of Q_2⁺ in the region 182 ≦ A ≦ 206 is examined.     

The moment of inertia in the interacting boson model

We perform a self-consistent cranking calculation of intrinsic states of IBM-1 and IBM-2 for three reasons: (a) to study the effect of Coriolis and centrifugal forces in the IBM; (b) to derive approximate analytic formulae for the energy in some cases where the IBM hamiltonian does not have dynamical symmetry; (c) to study the dependence of the moments of inertia on the variables of the intrinsic IBM states. Choosing a coordinate system where the quadrupole tensor is diagonal reduces the number of variables considerably. Among other applications of our formalism we study the transition between the symmetries SU(3) and SU¹(3) in the IBM-2 hamiltonian H = −(Q_π + Q_ν) · (Q_π + Q_ν). We find that the moments of inertia and the asymmetry variables show a kind of phase transition, as a function of the parameter χ_ν occurring in Q_ν.     

The sign of the quadrupole interaction of the 828 keV state of115In in Zn

Sign and magnitude of the electric quadrupole interaction of the 828 keV state of¹¹⁵In in a Zn single crystal was determined by aβ-γ TDPAC measurement. The result:v _Q =e·'Q _I V _zz /h=?193(13)MH_z confirms the universal correlation between the electronic and ionic contributions to the total electric field gradient proposed by R.S. Raghavan et al.     

Quadrupole interaction of8Li and9Li in LiNbO3 and the quadrupole moment of9Li

The quadrupole interaction of nuclear spin polarized⁸Li (I=2) and⁹Li (I=3/2) in LiNbO₃ has been studied at room temperature. The polarization was achieved by optical pumping of a fast atomic beam with circularly polarized laser light. The atoms were implanted into a hexagonal LiNbO₃ single crystal and the quadrupole splitting ofβ-NMR spectra was measured. A ratio of ¦Q(⁹Li)/Q(⁸Li)¦=0.88(4) for the nuclear quadrupole moments was deduced, yielding a new value of ¦Q(⁹Li)¦=25.3 (9) mb for the quadrupole moment of⁹Li.     

Anregung metastabiler Zustände von Barium und Thallium durch Atomstöße im Stoßwellenrohr

It is shown that relaxation times for the excitation of metastable levels of Ba and Tl by collisons of the ground state atoms with carrier gases Ne and Ar can be measured with good accuracy behind reflected shock waves (2700≦T≦3300 °K) by means of two-channel atomic line absorption spectroscopy. Quenching cross-sections, which thus can be derived, cover in principle the range 10^?14 cm²<Q<10^?21 cm². In collisions with Ar one finds for the deactivation of Ba(¹ D ₂)Q=1.2 · 10^?19cm², of Ba(³ D ₁)Q=0.95 · 10^?19 cm² and of Tl(² P _3/2)Q<5 · 10^?21 cm² without noticeable temperature dependence. From this follows a) (on the basis of the Landau-Zener formula) that the pseudo-crossing of the potential energy curves of Ba-Ar takes place within 0.25 eV of the Ba(D) levels and b) that spin-orbit coupling is not rate controlling in the Ba(³ D ₁ →¹ S ₀) transition. The ratio of cross-sections for quenching of Ba(¹ D ₂) by Ar and Ne is about 3, suggesting that the polarizabilities of the noble gas collision partners play a major rôle in the transition probabilities. The mean self-quenching cross-sectionQ=5 · 10^?16 cm² of Tl(² P _3/2) at 3000 °K is about the same as the one reported for 1000 °K and it exceeds the self-quenching cross-section of metastable Ba by at least one order of magnitude.     

Pauli-correct separable potentials for composite particle interactions

Experimental totalβ-decay energies for short-lived isotopes of gallium and germanium are presented. The sources were produced as mass-separated fission products at the OSIRIS on-line separator at Studsvik. By applyingβ-γ-coincidence methodsQ _α-values were determined for^80,81Ga and^79,81,82Ge. For these nuclei on or close to the shellN =50 and in the vicinity of ther-process “seed”, the atomic mass excess is derived and compared with predictions from mass formulae.     

Kinetic mechanisms of the uptake of atmospheric gases on the surface of sea salts. ClNO3 uptake on MgCl2 · 6H2O/NaCl

The uptake coefficients γ of chlorine nitrate on MgCl₂ · 6H₂O crystallites and a MgCl₂ · 6H₂O-NaCl mixture deposited from an aqueous solution are measured using a flow reactor with a movable salt-substrate-coated insert equipped in combination with a mass spectrometer at 295–428 K, [ClNO₃] = (0.2?12) × 10¹² cm^?3, and [H₂O] = 1.0 × 10¹² ? 4.3 × 10¹⁵ cm^?3. Immediately after the exposure of the salt substrate to a ClNO₃ flow, γ(t) decreases exponentially with time, γ(t) = γ₀ × exp(?t/τ) + γ _s , to a steady-state level, γ _s , which depends on the temperature and the ClNO₃ and H₂O concentrations. The main gas-phase product is Cl₂, HOCl appears only when water vapor is admitted into the reactor. The coefficient of steady-state uptake on wetted MgCl₂ · 6H₂O at 295 K can be described by the approximation γ = a + b [H₂O] with a = 3.5 × 10^?3 cm³ and b = 3.2 × 10^?18 cm³. The mechanism of the uptake of ClNO₃ on MgCl₂ · 6H₂O is discussed. The experimental data are treated within the framework of a steady-state uptake model to estimate the heat of adsorption of ClNO₃ on MgCl₂ · 6H₂O (Q _ad = 62 kJ/mol) and the activation energy of the bimolecular heterogeneous reaction ClNO₃ + Z _s = 2Cl₂ + Mg(NO₃)₂ · 6H₂O (E _a = 21.8 kJ/mol; Z _s denotes a ClNO₃-MgCl₂ · 6H₂O surface complex). When the MgCl₂ · 6H₂O: NaCl is varied from 0 to ～3 wt %, the steady-state uptake coefficient changes from the value corresponding to uptake on pure NaCl to that characteristic of uptake on pure MgCl₂ · 6H₂O.