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“液体饱和蒸气压测定”实验新装置 总被引:2,自引:0,他引:2
“液体饱和蒸气压测定”实验新装置李慎新(自贡师范高等专科学校643000)国内许多物理化学实验教材中,“液体饱和蒸气压测定”实验均采用类似图1所示的装置。这种装置主要存在下列缺点:①等压计拐弯多且一端封闭,操作不便、费时,且易损坏。②实验过程中,当调... 相似文献
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In the static method of saturated vapor pressure measurements, the key operation is to adjust the pressure of the system. Because of the invisibility of the gas, it is difficult to control the air flow, which often results in air pouring into the system due to excessive air flow in the constant pressure adjustment process. By designing a mini gas flow control device, the control operation is visualized; thus, problems associated with controlling the air flow can be avoided. Furthermore, frequent adjustment of the air flow becomes unnecessary, greatly reducing the lab hour. 相似文献
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参比注射法测定液体的饱和蒸气压 总被引:1,自引:0,他引:1
参比注射法测定液体的饱和蒸气压赵国华,张舟,赵国菁,李光明(同济大学化学系,上海200092)物理化学实验教学中,传统测定液体饱和蒸气压的方法主要有静态法、动态法和气体饱和法等三种 ̄[1,2]。由于这些方法大多采用了真空系统,整套实验装置体积较大,操... 相似文献
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本文对“纯液体饱和蒸气压测定”实验装置进行了系列改进,较好地处理了以往实验中的难点,提高实验的成功率,使1nP ̄1/T直线的相关系数由0.96上升到0.9999。 相似文献
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通过对液体饱和蒸气压实验装置的改进和实验方案的选择,确定了一种可用于测定水的饱和蒸气压的新方法。改进后的实验不仅减少了环境污染,降低了实验成本,而且操作方便。用经过改进以后的实验方法测定温度范围为50~75℃的水的平均摩尔气化热,数量级与文献值一致,相对误差小于3%。 相似文献
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Saturated vapor pressure was calculated from the nucleation experimental data using the thermodynamically consistent nucleation theory in which the effect of real gas is considered. The cubic polynomial fit equations of saturation pressure for several substances were obtained based on the calculation. The results of the calculations were compared to those of thermodynamic equilibrium equation and the empirical equation and applied to the predictions of the classical nucleation theory. The results show that the saturation pressures estimated from the nucleation data agree fairly well with those of empirical equations for the substances investigated, and this indicates that the predictions from the classical nucleation theory are close to the experimental data. 相似文献
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N. B. Morozova P. P. Semyannikov S. V. Sysoev V. M. Grankin I. K. Igumenov 《Journal of Thermal Analysis and Calorimetry》2000,60(2):489-495
The temperature dependency of the saturated vapor pressure of Ir(acac)3 has been measured by the method of calibrated volume (MCV), the Knudsen method, the flow transpiration method, and the membrane
method. The thermodynamic parameters of phase transition of a crystal to gas were calculated using each of these methods,
and the following values of ΔH
T
0 (kJ mol−1) and ΔS
T
0 (J mol−1K−1), respectively, were obtained: MCV: 101.59, 156.70; Knudsen: 130.54, 224.40; Flow transpiration: 129.34, 212.23; Membrane:
95.45, 149.44
Coprocessing of obtaining data (MCV, flow transportation method and Knudsen method) at temperature ranges 110−200°C as also
conducted:ΔH
T
0 =127.9±2.1 (kJ mol−1 ); ΔS
T
0 =215.2±5.0 (J mol−1 K−1 ).
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
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Principles for applying isothermal heat-conduction calorimetry for direct studies of vapor/liquid equilibria are presented. The ideas have been tested by measurements of the vapor pressure of water over aqueous NaCl(aq) solutions at 25°C. Seven different stock solutions were used with a composition ranging from 0.0879 mol-kg–1 to saturated solution. The imprecision and inaccuracy were not dependent on the composition and were found to be about ±2 Pa over the entire composition range. The sample solution was placed in a container separated from the pure solvent which was kept in the calorimetric cell. Solvent vapor was transported isothermally between the container and the cell by means of an inert carrier gas. The vapor pressure was evaluated by measuring the heat-flow rate associated with the process where the vapor equilibrated with a NaCl(aq) solution is fully saturated by passing through pure solvent. Corrections for treating vapor phase imperfections are presented. The method was found to be fast, accurate, and easy to use. The concept developed here can easily be applied in any commercial heat-conduction calorimeter of modular design. 相似文献
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P. A. Stabnikov I. A. Baidina S. V. Sysoev N. S. Vanina N. B. Morozova I. K. Igumenov 《Journal of Structural Chemistry》2003,44(6):1054-1061
A comprehensive study of copper(II) bis-ketoiminate including tensimetric analysis of sublimation and structure solution has been carried out. The temperature dependence of saturated vapor pressure over Cu(ki)2 crystals derived by the flow method is expressed by the equation lnP(atm)} = 25.31-13750/T, H
subl = -114.2 ± 1.3 kJ· mole-1, Ssubl =210.2 ± 3.0> J· mole-1 · K-1. Crystal data for CuO2N2C10H16: a=15.143(3), b=16.681(8), c=13.795(32) , space group Ccca, Z=12, d
calc = 1.47 g/cm3, R=0.029. The structure is molecular and consists of crystallographically independent Cu(ki)2 complexes of two types, one with a cis structure and the other with a cis–trans disordering. The copper atom has a plane square environment of two oxygen and two nitrogen atoms. In the cis isomer, Cu–O 1.938 and Cu–N 1.895 ; in the disordered complex, all four Cu–O(N) distances are 1.901 . 相似文献