旋涡的场特征与物质性──离散涡方法基础

旋涡的场特征与物质性──离散涡方法基础吴文权（华东工业大学，上海，２０００９３）关键词旋涡动力学，旋涡场性，旋涡物质性众人关注的不稳定、非定常、分离流动无不与旋涡有关。因而对旋涡的研究吸引了人们的注意。尤其是近来非线性科学的发展，提供了新的思想、方法...     

CCD摄像系统镜头的畸变测量

从畸变定义出发,讨论了畸变数学模型,介绍了精密测角法与比长法综合测量畸变的原理。通过放大率法标定出CCD探测器的像素距离当量,通过质心法求出点目标的质心,质心与原点的像素距离乘以像素距离当量得到精确长度。利用正切函数求出绝对畸变值,用最小二乘法解多组数据超定方程,求出拟和公式的系数。实际计算和数据处理结果表明：畸变数学模型在中视场范围内拟合效果很好。     

Ku波段球体目标系的电磁复合散射研究

研究了球形目标之间的电磁相互作用,得到了目标二次散射场的表达式,给出了目标的复合散射场以及双站复合散射截面,并在Ku波段进行了数值仿真.结果表明：目标的尺寸对前向散射和后向散射均有较大的影响,周围目标的影响呈现出一定的周期性,二次散射随着目标间距的增大而减小,周围目标离前向散射方向越近,对前向散射的影响也越大.目标的二次散射场与一次散射场强度之比在10^-4数量级以上.在研究多粒子的相互影响时,周围的粒子可近似看作尺寸一定的粒子.利用所得结果以及坐标变换可以研究三维体系内粒子间的电磁相 关键词： 散射截面 二次电磁散射 电磁相互作用     

煤颗粒热膨胀量与破碎特性的研究

煤颗粒的热膨胀破碎特性直接影响流化床锅炉的运行效率.本文利用热机械分析仪(TMA)测定了不同种类不同密度的型煤和原煤的热膨胀特性,并对部分破碎微观形貌进行了FSEM观察;通过旋转炉内的燃烧试验研究了热膨胀特性和破碎的关系.研究表明,煤颗粒在燃烧过程中其热膨胀破碎主要发生在挥发分析出阶段;内部挥发分的析出会使颗粒内压增大而产生膨胀,进而产生细小裂纹并破碎;挥发分越高,颗粒密度越大,其热膨胀形变率越大,越容易发生破碎现象;主要挥发分析出后热膨胀引起的破碎可以忽略.     

发射光谱法测定乳浊料中的锆和铪

研究了用碳粉和二氧化钛作缓冲剂同时测定乳浊料中的锆和铪的发射光谱法,选择钛作内标线,不需分离、不需化学处理,直接压样于杯形的石墨电极中,具有简便、快速、准确的特点。对测定条件、干扰因素进行了研究,从而建立测定锆和铪的新方法。锆和铪的分析线分别为327.3和286.6 nm,内标线选择为钛的308.8 nm线,锆和铪的线性范围分别为0～0.50%和0～0.25%。锆和铪的检测限分别为0.001%和0.010%,其回收率为96.67%～105.0%,当n=9时,锆的RSD为3.61%;铪的RSD为4.82%;用于样品的测定取得了满意的结果。     

氧化铁浆液脱硫的实验研究与理论分析

本文实验研究了氧化铁浆液在酸性环境下脱除烟气中的二氧化硫气体。实验在一自制的脱硫塔中进行。通过燃烧液化石油气来产生烟气,将氧化铁的超细粉加入水中作为脱硫介质。实验中研究了二氧化硫初始浓度、水气比对脱硫效率的影响。从实验结果可以看出,脱硫率随着水气比的增加而增大;随二氧化硫的初始浓度的增加,其脱硫率呈降低趋势。在文中同时分析了氧化铁浆液的脱硫机理和此方法脱硫的优点以及目前存在的问题。     

Weyl Spinor and Solution of Massless Free Field Equations

The massless field equations for arbitrary spin in curved space-time arereconsidered. The general solution of the field equation in Robertson-Walkerspace-time that was previously determined is briefly discussed after explicitlyshowing that the Weyl spinor vanishes. The case of the Lemaître-Tolman-Bondispace-time is studied in detail. The general expression of the corresponding Weylspinor is obtained and some particular situations exploited. The spin-3/2 andspin-2 massless field equations are solved explicitly. The solutions are simplifiedby the existence of nontrivial algebraic constraints. The angular part of theequations is separated by the usual separation method and integrated directly.The other equations that are not separated in the radial and time dependence arereduced to a simple form. The results obtained are extended, as a consequenceof previous results, to the case of arbitrary spin. The solution of the general caseessentially reduces to the treatment of spin 3/2 and spin 2.     

射频磁控溅射法制备SnS_2薄膜结构和光学特性的研究

采用射频磁控溅射法溅射SnS_2靶,在玻璃基片上以不同射频功率和氩气压强制备一系列薄膜样品,研究了不同工艺条件对薄膜特性的影响。利用X射线衍射(XRD)和拉曼光谱(Raman)对薄膜样品的晶体结构和物相进行表征分析。利用X射线能量色散谱(EDS)、紫外-可见-近红外分光光度计(UV-Vis-NIR)对SnS_2薄膜的化学组分、光学特性等进行测试,计算或分析了SnS_2薄膜样品的组分原子比、光学常数和光学带隙。结果表明:制备SnS_2薄膜的最佳工艺条件为射频功率60 W、氩气压强0.5 Pa。在该条件下,所制备的SnS_2薄膜沿(001)晶面择优取向生长,可见光透过率和折射率较高,消光系数较小,直接带隙为2.81 e V。在此基础上,进一步制备了n-SnS_2/p-Si异质结器件。器件具有良好的整流特性及弱光伏特性,反向光电流随光照强度的增加而增大。器件的光电导机制是由SnS_2禁带中陷阱中心的指数分布所控制。     

不同季节的虎杖根茎中8种矿质元素的光谱测定

采用空气-乙炔火焰原子吸收法,测定虎杖根茎的K,Ca,Na,Mg,Fe,zn,Mn,Cu等8种矿质元素的含量。对测定条件进行了实验,选择了最佳电离抑制剂和酸性介质。实验以氯化铯为电离抑制剂,盐酸浓度控制在2％以内,用氯化锶消除磷对Ca的干扰,使吸光值稳定,用标准曲线法进行测定,获得了满意效果。该方法简单、快速、准确,加标回收率为90．5％～108．2％,相对偏差为0．3％～0．7％,适合于植物矿质元素的分析。实验结果表明：虎杖根茎中含有丰富的矿质元素,其中以K,Ca元素含量最高。这与虎杖的药用效果相符。同时,每种元素含量随季节变化而变化,与其生长发育密切相关。     

磁流体动力学磁控进气道流场分布数值模拟

采用磁流体控制的办法能提高超燃冲压发动机的推进性能。结合了Maxwell方程组和描述流体力学规律的Navier-Stokes方程组,并对这些方程进行了简化,建立了适用于计算磁流体动力学(MHD)超燃冲压发动机磁控进气道流场分布的数值模拟模型。研究了在特定工况下,流场特征、电势、电流以及提取功率等参数的变化。磁流体发生器能够降低管道出口马赫数和流向速度,降低出口处的总焓,但是出口处的温度有所提高。在电极上,电势保持常数,而绝缘壁面的电势较高,电场在电极端点出现周期性的极性。y方向电流在电极板附近很高,而在绝缘板上几乎为零。电流主要从正电极流向负电极,而且沿着x方向略有减小。y方向电流最大值出现在绝缘壁面上,而绝缘板上的z方向值几乎为零。z方向电流最大值出现在管道的边角处,而在绝缘壁面上几乎为零,电流在绝缘壁面的法线分量为零。     

Motion of chains in polypeptide brushes

A simple model of a polypeptide multi-chain layer was designed and studied. Each chain was constructed on a flexible [310] lattice and terminally attached to an impenetrable surface. The chains consisted of hydrophilic and hydrophobic amino acid residues. The force field consisted of the long-range contact potential between polymer segments and the short range repulsion. The Monte Carlo simulations of this model were carried out using the Metropolis algorithm. The influence of the grafting density, the temperature and the sequence of the chain on the static properties of the system were studied. The size and structure of the polymer film formed near the surface were investigated. The low temperature structures of brushes were described and compared. We found that the influence of temperature on the size and structure of the dense brushes was rather small. The temperature dependences of the diffusion coefficient were studied and compared for different sequences of amino acid residues.     

基于线偏振光反射率测量介质折射率的研究

研究线偏振光的振幅反射率与介质折射率的关系,提出一种测量介质材料折射率的方法。文中从菲涅耳公式出发,推导出各向同性介质的线偏振光反射率与折射率的关系式,给出基于线偏振光反射率测定介质折射率的原理。设计实验方案,在不同入射角情况,定出线偏振光p方向和s方向两种线偏振光在玻璃表面的反射率,得到线偏振光振幅反射率随入射角变化的实验曲线。依此实验数据得出材料的折射率。结果表明,测出的介质材料的折射率与理论值相符,所采取的测定方案可行。     

高功率宽谱开关振荡器

采用1/4波长开关同轴谐振器技术路线,开展了高功率宽谱微波产生及耦合输出技术研究。设计振荡器工作在200 MHz,低阻抗1/4波长同轴传输线与传输线一端的环形多通道气体火花开关构成谐振器,耦合器由集中电容和分布电感构成,实现宽谱微波的能量提取。通过数值模拟研究了振荡器的振荡及耦合输出过程,分析了高压脉冲馈入方式、谐振器阻抗特性及开关齿槽结构对环形开关导通特性的影响。数值模拟和实验结果证明,采用直馈方式、高阻结构和齿槽结构有利于形成开关多通道导通,并提高开关导通的稳定性。在输出电压为500 kV的Marx脉冲功率源平台上构建了高功率宽谱微波产生实验装置,实验得到的宽谱微波振荡频率为195 MHz,辐射因子约150 kV,频谱带宽约30%。     

Ultrasonic attenuation due to hopping of silver ions in superionic conductors

The conductivity and ultrasonic absorption in superionic conductors are condsidered. The hopping motion of silver ions exhibit collective properties because of the Fermi type site occupation numbers. The calculated a.c. conductivity is different from the ordinary Drude expression. The ultrasonic wave modulate the hopping motion of the silver ions and produce space charge. The dissipation of the wave energy is due to this production and is calculated as Joule heating. The absorption coefficient is proportional to the conductivity and the square power of the frequency in agreement with the experimental results.     

Studies on growth and characterization of l-alanine strontium chloride trihydrate single crystals for optical applications

The optically transparent nonlinear optical single crystals of l-alanine strontium chloride trihydrate (LASCT) were grown by slow evaporation solution growth method using water as solvent. The purity of the crystals was increased by the method of recrystallization. The grown crystals were analyzed by the single crystal X-ray diffraction pattern which proved that LASCT belongs to monoclinic crystal system. The presence of various functional groups and modes of vibrations were identified by FTIR spectroscopy. The optical absorption study confirms the suitability of the crystal for device applications. The thermal strength and the decomposition of the grown crystals were studied using TG/DTA analyses. The dielectric constant and dielectric loss measurements of the grown crystals at different frequencies of the applied field were measured and reported. The mechanical strength of the crystal is estimated by Vicker's hardness test. The nonlinear optical properties of the grown crystals were confirmed by second harmonic generation test which shows the suitability of NLO applications.     

Effect on flow properties of tin-stabilized rigid PVC by PE paraffins having different degrees of branching

The processing properties of a rigid PVC compound with various amounts of different lubricants were studied with a torque rheometer. The plasticizing behavior was measured in a mixer and recorded as torque versus time. The fusion time and the torque at fusion and of the molten material were evaluated. The compounds were extruded with a laboratory extruder and a capillary die. The torque of the screw, the melt pressure, and temperature in the barrel and the die and the output were measured. The shear stress and shear rate were calculated from these results. The lubricants, one paraffin and five polyethylenes, had molecular weights of 700 to 3500. The dependence of the processing behavior on the molecular weight of the lubricants is discussed. There is no single value which can be given but numerous interdependent parameters can be used to obtain a prediction of the processing properties of the material.     

环境气体种类对激光烧蚀粒子速度劈裂的影响

采用蒙特-卡罗(Monte Carlo)方法, 模拟了激光烧蚀粒子输运动力学过程, 在环境气体压强为100 Pa的情况下, 研究了环境气体种类(He, Ne, Ar和假想气体等)对烧蚀粒子速度劈裂的影响. 研究结果表明, 在四种环境气体中传输的烧蚀粒子均出现了速度劈裂现象, 形成速度劈裂所需时间按He, Ne, 假想气体和Ar的次序减小. 还研究了环境气体分子的质量和半径对烧蚀粒子速度劈裂的影响, 形成速度劈裂所需时间随环境气体分子半径(或质量)增大而减小. 在假想气体中, 两速度峰强度相等时的强度最小. 结合欠阻尼振荡模型和惯性流体模型, 对劈裂的形成时间进行了解释. 所得结论可为进一步定量研究纳米晶粒生长机理提供基础.     

超支化聚合物吸附金、铂和钯及化学光谱行为的研究

超支化聚合物在盐酸介质中分离富集金、铂和钯,具有吸附速度快、吸附容量大的特点。将吸附后的树脂灰化,用碳粉、硫酸锶和氧化锆作缓冲剂, 采用发射光谱法同时测定金、铂和钯,选择锆作内标线,直接压样于杯形的石墨电极中,测定简便、快速和准确。对测定条件、干扰因素进行了研究,以此建立测定金、铂和钯的新方法。金、铂和钯的分析线分别为312.3, 306.5和311.4 nm,内标线选择为310.7 nm的锆,金、铂和钯的线性范围分别为0～0.20%,0～0.40%和0～0.20%。金、铂和钯的检测限分别为0.010%,0.003%和0.003%。用于样品的测定获得了满意结果。     

4 MV静电加速器调试中出现的问题及解决方案

 4 MV静电加速器由高压系统、离子源及束流系统、控制系统和气体系统四部分组成。调试中出现了离子源不起弧、加速管破裂、控制系统失灵和输电带输电能力降低等技术问题,分析了出现这些问题的原因,然后分别采取了相应的措施加以解决：变换工作流程,在每次关机前先把引出电压降为零,开机时等离子源起弧后再把引出电压升到预定值;对过渡法兰进行车加工,重新封装;对高压端的控制设备采取屏蔽措施,在输入、输出端使用TVS二极管,对控制软件进行抗干扰设计;对绝缘气体进行循环干燥等。调试出了流强为100 μA、能量在3 MeV以上的稳定质子流。     

延时法测量条纹相机μs档扫描非线性

为实现μs档条纹相机扫描非线性标定,建立了基于延时可调信号源和外触发激光器的条纹相机μs档扫描非线性标定系统,弥补了标准具法的不足。系统通过延时值的递增,得到条纹相机扫描速度在全扫程的变化。系统中时间关系抖动来源主要是测试设备延时抖动和条纹相机触发延时抖动。时间抖动测试与分析显示,条纹相机延时抖动±0.6ns,测试设备延时抖动±0.3ns,系统总时间抖动±0.7ns。系统时间抖动会造成最终时间轴信息的起伏。大量数值模拟分析表明,时间轴起伏对系统时间抖动的影响±2ns,在可以接受的范围内。因此,该系统能够胜任条纹相机μs扫程时间信息的测量标定。