An angle-resolved photoemission study of the chemisorption of chalcogens on Cu(100) III. Cu(100) + p(2 x 2)S

Normal emission ARPES data for Cu(100) with a p(2x2)S overlayer were obtained in the photon energy range hv=11 to 34 eV. These spectra have been compared, within a framework proposed previously, with spectra from clean Cu(100). Changes were found in the Cu emission features, which could be explained by the relaxation of momentum conservation perpendicular to the surface in the optical excitation step and by the relaxation of momentum conservation parallel to the surface in the escape step. These changes include a broadening of the d-band peak and the strong attenuation of the sp-band peak. In addition, a prominent feature appears at about ?4.0 eV at normal emission upon sulfur chemisorption. We tentatively attribute its appearance at normal emission to a new surface umklapp process induced by the overlayer. Changes in the spectrum of scattered electrons were related to modifications of evanescent final states. The sulfur 3p_z^? and 3p_x.y-components could be separated at normal emission and are located at ?4.7 and ?5.4 eV, respectively. No dispersion of the sulfur 3p-bands was detected when the $\text{Γ}\text{X}$ and $\text{Γ}\text{M}$ symmetry lines of the surface Brillouin zone were probed. Sulfur-induced emission above the Cu d-bands was observed and attributed to antibonding states. This emission was directed towards the bulk [011] directions.     

Electronic structure of MgB2 from angle-resolved photoemission spectroscopy

The first angle-resolved photoemission spectroscopy results from MgB2 single crystals are reported. Along the GammaK and GammaM directions, we observed three distinct dispersive features approaching the Fermi energy. These can be assigned to the theoretically predicted sigma (B 2p(x,y)) and pi (B 2p(z)) bands. In addition, a small parabolic-like band is detected around the Gamma point, which can be attributed to a surface-derived state. The overall agreement between our results and the band calculations suggests that the electronic structure of MgB2 is of a conventional nature, thus implying that electron correlations are weak and may be of little importance to superconductivity in this system.     

Common origin of the circular-dichroism pattern in angle-resolved photoemission spectroscopy of SrTiO3 and Cu(x)Bi2Se3

Circular dichroism in the angular distribution of photoelectrons from SrTiO(3):Nb and Cu(x)Bi(2)Se(3) is investigated by 7-eV laser angle-resolved photoemission spectroscopy. In addition to the well-known node that occurs in the circular dichroism pattern when the incidence plane matches the mirror plane of the crystal, we show that another type of node occurs when the mirror plane of the crystal is vertical to the incidence plane and the electronic state is two-dimensional. The flower-shaped circular dichroism patterns in the angular distribution occurring around the Fermi level of SrTiO(3):Nb and around the Dirac point of Cu(x)Bi(2)Se(3) are explained on equal footings. We point out that the penetration depth of the topological states of Cu(x)Bi(2)Se(3) depends on momentum.     

High-resolution angle-resolved photoemission from Cu(610)

Cu(610) has a mean terrace width of six atoms. Although the regular arrangement of steps was verified by SPALEED, no step-induced surface umklapp process could be identified in UPS spectra taken with HeI radiation. This fact allows an easy comparison with results from Cu(100). In particular, we demonstrate that the final state wave vector can be determined by triangulation using exclusively the Cu(610) surface, since equivalent k-space points contribute at different electron emission angles. However, spectra from equivalent points exhibit differences in the UPS linewidth and this gives additional information on the final state lifetime. Finally we discuss the modification of a Tamm state [its analogue is observed at on the (100) surface] due to confinement by the steps.     

Spin- and angle-resolved photoemission from ferromagnetic Fe(001)

For near-normal photoemission from ferromagnetic Fe(001) excited by linearly polarized synchrotron radiation, energy-resolved spin polarization and intensity distribution have been measured at 60 eV photon energy. Calculations using a one-step theory of photoemission consistently reproduce. the present spin-resolved data as well as earlier spin-averaged measurements. The quasi-particle exchange splitting deduced from the data is 2 eV. The agreement with band structure calculations is suggested to be coincidental due to a compensation of real and imaginary self-energy corrections.     

High-resolution angle-resolved photoemission study of oxygen adsorbed Fe/MgO(001)

We have investigated the electronic states of clean Fe(001) and oxygen adsorbed Fe(001)–p(1 × 1)-O films epitaxially grown on MgO(001) substrates by means of polarization-dependent angle-resolved photoemission spectroscopy(ARPES)and extensive density-functional theory(DFT) calculations. The observed Fermi surfaces and band dispersions of pure Fe near the Fermi level were modified upon oxygen adsorption. By the detailed comparison of ARPES and DFT results of the oxygen adsorbed Fe surface, we have clarified the orbital-dependent p–d hybridization in the topmost and second Fe layers.Furthermore, the observed energy levels and Fermi wave numbers for the oxygen adsorbed Fe surface were deviated from the DFT calculations depending on the orbital characters and momentum directions, indicating an anisotropic interplay of the electron correlation and p–d hybridization effects in the surface region.     

Inverse photoemission from Cu(001)

Bremsstrahlung ultraviolet spectra for Cu(001) are calculated for a photon energy ηω=9.7 eV within the framework of an inverse one-step model of photoemission for several angles of incidence of the electron beam. The comparison with recently reported experimental data shows that both the calculated energy dispersion of the peak in the spectra and the variation of the peak intensity are in reasonable agreement with the experiment.     

Electronic structure of the YH3 phase from angle-resolved photoemission spectroscopy

Yttrium can be loaded with hydrogen up to high concentrations causing dramatic structural and electronic changes of the host lattice. We report on angle-resolved photoemission experiments of the Y trihydride phase. Most importantly, we find the absence of metal d bands at the Fermi level and a set of flat, H-induced bands located at much higher binding energy than predicted, indicating an increased electron affinity at H sites.     

Inverse photoemission spectroscopy of the unoccupied electronic structure of Na/Cu(110)

The unoccupied electronic states of Na thin films on a Cu(110) substrate have been measured by inverse photoemission spectroscopy (IPES). The IPES spectrum provides the intensity of the unoccupied states, which decreases with increasing Na coverage at off-normal incidence of the electron beam. The IPES spectra at 17 and 19 eV incident electron energies show a shift towards the Fermi level with increasing Na coverage for the peak at ∼7.8 eV.     

Unusual electronic structure of Dirac material BaMnSb_2 revealed by angle-resolved photoemission spectroscopy

High resolution angle resolved photoemission measurements and band structure calculations are carried out to study the electronic structure of BaMnSb_2. All the observed bands are nearly linear that extend to a wide energy range. The measured Fermi surface mainly consists of one hole pocket around Γ and a strong spot at Y which are formed from the crossing points of the linear bands. The measured electronic structure of BaMnSb_2 is unusual and deviates strongly from the band structure calculations. These results will stimulate further efforts to theoretically understand the electronic structure of BaMnSb_2 and search for novel properties in this Dirac material.     

Pseudogap of metallic layered nickelate R(2-x)Sr(x)NiO4 (R = Nd, Eu) crystals measured using angle-resolved photoemission spectroscopy

We have investigated charge dynamics and electronic structures for single crystals of metallic layered nickelates, R(2-x)Sr(x)NiO4 (R = Nd, Eu), isostructural to La(2-x)Sr(x)CuO4. Angle-resolved photoemission spectroscopy on the barely metallic Eu(0.9)Sr(1.1)NiO4 (R = Eu, x = 1.1) has revealed a large hole surface of x2-y2 character with a high-energy pseudogap of the same symmetry and comparable magnitude with those of underdoped (x<0.1) cuprates, although the antiferromagnetic interactions are 1 order of magnitude smaller. This finding strongly indicates that the momentum-dependent pseudogap feature in the layered nickelate arises from the real-space charge correlation.     

Electronic structure of heavy fermion system CePt_2In_7 from angle-resolved photoemission spectroscopy

We have carried out high-resolution angle-resolved photoemission measurements on the Ce-based heavy fermion compound CePt_2In_7 that exhibits stronger two-dimensional character than the prototypical heavy fermion system CeCoIn_5.Multiple Fermi surface sheets and a complex band structure are clearly resolved. We have also performed detailed band structure calculations on CePt_2In_7. The good agreement found between our measurements and the calculations suggests that the band renormalization effect is rather weak in CePt_2In_7. A comparison of the common features of the electronic structure of CePt_2In_7 and CeCoIn_5 indicates that CeCoIn_5 shows a much stronger band renormalization effect than CePt_2In_7. These results provide new information for understanding the heavy fermion behaviors and unconventional superconductivity in Ce-based heavy fermion systems.     

Mechanisms of high-order perturbative photoemission from Cu(001)

We observed high-order 2- to 4-photon photoemission and above threshold photoemission (ATP) processes with 3.07 eV light from the Cu(001) surface. The intensity of 3-photon photoemission via excitation through the n = 1 image potential state significantly exceeded that of the 2-photon process. The ATP occurs either via single photon transitions from the image potential resonances above the vacuum level or by multiphoton transitions from image potential states below the vacuum level. The experimental ratio of the m- to (m + 1)-photon process yields is sensitive to the electronic band structure of the solid.