Measurement of the dipole moment of CF3CN

The Stark effect was observed for K = 0 and K = 1, J = 1 → 2 transitions in CF₃CN. Measurements were made in a Stark modulated microwave spectrometer. The dipole moment obtained was μ = 1.262 ± 0.010 D. An analysis of the effects of electric field inhomogeneities on the observed Stark shifts for K = 0 and K = 1 states is included. Appropriate corrections are given for measuring linear Stark effects in a standard waveguide cell calibrated using a molecule with second-order Stark effect.     

Luminescent characteristics of Vicia faba L. bean leaves treated with SCF extracts of Reynoutria sachalinensis

The effect of supercritical fluid (SCF) extracts of giant knotweed (Reynoutria sachalinensis) on the photosynthetic activity of Vicia faba L. bean leaves was studied by the slow fluorescence induction (SFI) and thermoluminescence (TL) methods. The treatment of plants enhanced their photosynthetic activity. The maximum stimulating effect was observed for an extract prepared using carbon dioxide containing 2% ethanol as a cosolvent. The observed stimulating effect is believed to be associated with an increase in the number of electron carries in the photosynthetic electron transport chain of plant leaves due to the flux of quinonic compounds into plant cells.     

Organic polymer p-n heterostructures for optoelectronics

The photovoltaic effect due to the photogeneration of charge carriers at the interface in organic polymeric p-n-heterostructures based on the developed composites with hole (doped polyimides, conjugated polymers) and electron (doped polyetherimides and carbazolyl-containing polymers) conduction was observed and studied. The best performance was observed for heterostructures with diffuse and developed (bulk) interface. The maximum energy conversion efficiency was found to be 0.5% at λ = 400–650 nm. Components with enhanced photo and thermal stability were used. A weak photovoltaic effect was observed for heterostructures based on conjugated polymers (with a sharp interface). In this case, the rectification (diode) effect was observed for both dark current and photocurrent due to dark and photo injection of carriers from the electrodes at bias voltages across the cell above the injection threshold (V > V _i ). This conclusion is supported by the observation of recombination electroluminescence of the dopant in the n-layer, indicating a full or partial recombination of carriers at the interface. At V < V _i , photocurrent under reverse bias (+A1, ?ITO) is significantly higher than that under forward bias due to an efficient photogeneration of carriers at the interface and separate transport thereof. A sensitivity of about 100 mA/W at λ = 400–500 nm was reached.     

Vortex dynamics in two-dimensional Josephson junction arrays with asymmetrically bimodulated potential

On the basis of resistively-shunted junction dynamics, we study vortex dynamics in two-dimensional Josephson junction arrays with asymmetrically single and bimodulated periodic pinning potential for the full range of vortex density f. The ratchet effect occurring at a certain range of temperature, current, and f, is observed in our simulation. We explain the microscopic behavior behind this effect by analyzing the vortex distribution and interaction. The reversal of the ratchet effect can be observed at several f values for a small driven current. This effect is stronger when the asymmetric potential is simultaneously introduced in two directions.     

Hall mobility of hot electrons in CdS

Photo-Hall effect of hot electrons in a pure single crystal of CdS was observed, for the first time. The measurement was carried out for electric fields up to 4,300 V/cm in magnetic fields up to 40 kOe at 4.2 K. The saturation of the drift velocity V_d of electrons due to optical phonon emission was observed. The saturated value of V_d is found to be about 1.7 × 10⁷ cm/sec.     

Irreversible magnetovolume effect in Nd7Rh3 single crystal

Magnetovolume effect in Nd₇Rh₃ single crystal has been studied by measuring the magnetostriction as a function of external magnetic field at 4.2 K. An irreversible magnetovolume effect having a negative remanent volume magnetostriction was observed when the external magnetic field was applied along the b-axis. The irreversible magnetostrictive effect takes place in the longitudinal magnetostriction along the b-axis. The remanent magnetostriction along the b-axis relaxes after removing external magnetic field for several hours and equilibrium state is stabilized.     

Effect of nitrogen implantation with overlay coatings on microhardness in 4145 steel

The effect of nitrogen implantation on microhardness in 4145 steel was investigated. Practically no increase in microhardness for 10, 20 and 40 gm loads was observed in samples implanted with a dose of 6.5×10¹⁷N⁺ ions cm^?2 at 94 keV. The effect of ion-beam induced intermixing of aluminium and titanium film (400Å), due to nitrogen implantation was also studied. A noticeable increase of 15% in microhardness was observed. Annealing at temperature ∽300°C proved effective, while a decreasing trend in hardness could be observed for annealing temperatures >300°C. Furthermore, preliminary test indicated that these samples were more suitable for wear-protection.     

Control of crystalline phases in magnetic Fe nanoparticles inserted inside a matrix of porous carbon

Two magnetic composites made up of Fe nanoparticles (Fe-NPs) embedded in a porous amorphous carbon matrix are presented. One of the samples, Fe-S-AC, was obtained with the aid of sucrose and the other, Fe-AC, in the absence of this substance. The XRD patterns show Bragg diffraction peaks associated with α-Fe and γ-Fe crystalline phases in the Fe-AC sample, while only peaks corresponding to the α-Fe phase are observed for Fe-S-AC powders. The Fe-NPs exhibit broad particle-size distributions for both samples, 5–50 nm for Fe-AC, whereas two populations (2–8 and 10–70 nm) for the Fe-S-AC composite are found. This fact gives rise to poorly defined blocking temperatures, as it can be deduced from the broad maxima observed in M_ZFC(T) variations. In addition, M(H) curves for both Fe-AC and Fe-S-AC samples reveal the existence of exchange-bias effect for T<60 K, probably due to a magnetic coupling within a core/shell structure of the Fe-NPs, although this effect was observed to be less significant for Fe-S-AC.     

Equilibrated thermodesorption studies of adsorption of n-hexane and n-heptane on zeolites Y, ZSM-5 and ZSM-11

Gravimetric measurements of thermodesorption of n-hexane and n-heptane were performed under quasi-equilibrium conditions. Differential thermodesorption profiles for ZSM-5 and ZSM-11 showed two peaks, but for Y zeolites, only one thermodesorption peak was observed. A model function, derived from the Langmiur adsorption model, was fitted to the experimental data, and the model parameters (the adsorption entropy and enthalpy) were estimated. The two-step desorption profiles observed for ZSM-5 and ZSM-11 were attributed to the commensurate freezing effect, i.e. a transition in the adsorbed phase resulting in ordering of the adsorbed molecules in the zeolite channels. The results observed for ZSM-11 indicate that the zigzag channels typical for ZSM-5 micropore system are not necessary for this transition to occur.     

Channelingeffekte bei der Lichtausbeute von Anthrazen-, Naphthalin- undp-Terphenylkristallen bei Anregung mit α-Teilchen

The scintillation light yield of anthracene atT=300 °K andT=80 °K and of naphthalene andp-terphenyl atT=80 °K was investigated for impact directions in the (a, c)-plane. The light yield was measured for welldefined integration times. The relative depth of the channeling-minimum observed for impact directions parallel to thec-axis of anthracene is found to increase with increasing integration times. For the first time channeling-minima of the light yield were observed at impact directions parallel to thec- and the [102]-axis of naphthalene and thec- and [¯102]-axis ofp-terphenyl. The [¯102]-axis ofp-terphenyl shows a more pronounced effect than thec-axis.     

Angular dependent negative magnetoresistance in Si-MOS (111) inversion layers

The negative transverse magnetoresistance effect was observed in n-inversion layers in Si-MOS (111) surfaces at temperatures between 1.5 and 8.3 K. The negative magnetoresistance depends only on the normal component of the magnetic field to the surface and has a saturation value at high fields. The difference between the resistivity at zero field and that at saturation field increases logarithmically with decreasing temperature such as the effect due to the s-d scattering (Kondo effect).     

Electrochemical promotion of propane oxidation over Pd, Ir, and Ru catalyst-electrodes deposited on YSZ

The effect of electrochemical promotion of catalysis was investigated for the oxidation of propane using Pd, Ir, and Ru catalyst-electrodes sputter-deposited on YSZ disks in the temperature range of 250–450 °C. Electrophobic type behavior was observed, i.e., the catalytic reaction rate was found to increase with catalyst potential. The observed rate changes under polarization were strongly non-Faradaic and exceeded under anodic potential application the electrocatalytic rate of O^2? supply to the catalyst surface, I/2F, by up to a factor of 250 for Pd, 125 for Ir, and 15 for Ru catalyst-electrodes.     

Study of phase transitions and properties of tetragonal (Pb,La)(Zr,Ti)O3 ceramics—II: Diffuse phase transitions and thermodynamics

The diffuse phase transition in tetragonal PLZT materials has been investigated. Strongly broadened permitivity curves were observed for materials with a relative high La content. Curie-Weiss behaviour in the permittivity curves is observed only at temperatures far above the apparent Curie temperature.A latent heat effect is observed at the sharp FE_t → PE_c transition in PLZT x/30/70 materials with a low La content (x<16 at° La). This heat effect decreases linearly with increasing La content. The diffuse tetragonal → cubic transition is attended with a very small heat-effect and a low value (≈0.04 cal/mol°C) for the entropy difference between high and low temperature phase could be determined.Consequently, polarisation fluctuations are possible in a certain temperature interval around the transition.     

Measurement and modeling of the sooting propensity of binary fuel mixtures

The sooting behaviour of binary fuel mixtures was evaluated both experimentally and through computer simulations. The soot volume fraction in laminar diffusion flames of mixtures of ethylene/propane, methane/ethylene, methane/propane, methane/ethane, methane/butane, ethane/propane and ethane/ethylene fuels was measured using 2-dimensional line of sight attenuation. A synergistic effect was observed for the ethylene/propane, methane/ethylene, methane/ethane and ethane/ethylene mixtures. The synergistic effect translated into a higher soot concentration for a mixture fraction than could be yielded by the added contribution of both pure fuels. Such an effect was not observed for the methane/propane, methane/butane and ethane/propane mixtures. Through experiments in which the flame temperature was kept constant, it was determined that the synergistic effect in the methane/ethylene mixture is very temperature dependent whereas, that in the ethylene/propane mixture is not. This phenomenon was further studied through the modeling of the ethylene/propane mixture. Numerical simulations were carried out using two different soot models. The simulations confirmed the presence of a synergistic effect. It was found that the effect could be directly correlated to a synergistic effect in the concentration of n-C₄H₅ and n-C₄H₃, which could be traced back to an interaction between ethylene and methyl radical species. These results yield further insight into the pathways to soot formation and highlight the importance of further analyzing binary fuel mixtures as a means of understanding soot formation in practical devices using industrial fuels.     

The line broadening and shift effects on the CO J=5-4 transition at 576 GHz induced by collisions with rare gases

The line profile of the CO J=5-4 transition at 576 GHz was measured precisely by a BWO-based submillimeter wave spectrometer. The foreign-gas effect on the broadening and shift of rare gases were determined together with the self-collision effects. The observed profiles exhibit clearly the Dicke narrowing effect for the cases of rare gas mixtures, and the Galatry function was used as the lineshape function in the analysis.     

Shubnikov-de Haas effect in Bismuth in high magnetic fields

Shubnikov-de Haas effect in Bi was observed in pulsed high magnetic fields up to 420 kG. Hole resonances were observed up to the second (N = 1) and the third (N = 2) peaks for the magnetic fields along the bisectrix and the binary axes, respectively. From the analysis of the resonant magnetic fields, changes of the Fermi level and the carrier concentration were calculated. The field at which the semimetal to semiconductor transition will occur was estimated as 850 kG ∽ 1 MG for the field direction parallel to the binary axis. Anomalously large decrease of the magnetoresistance was observed above 300 kG.     

Microwave spectroscopy of propynal in the v2 = 1 vibrational state by IR-MW triple resonance

Infrared-microwave triple resonance was applied to microwave spectroscopy of propynal, HCCCHO, in the v₂ = 1 vibrational state. Eleven microwave transitions were newly observed by using a Zeeman-tuned 3.51 μm HeXe laser as the infrared radiation source. The spectrum was analyzed including the 11 transitions previously observed by double resonance. A least-squares fit of the 13 low-J transitions revealed that the rotational constants in the K_?1 = 1 states were slightly different from those of the K_?1 = 0 states. A higher-order rotational resonance was proposed for explanation of the effect.     

Observation of the ABC effect and final-state isospin

Despite the number of inclusive measurements of the pionic fusion reactions, the nature of the ABC effect discovered in 1960 was not completely established. Exclusive measurements of the doublepion-production reactions leading to either fused d, ³He and ⁴He nuclear final states or pp pairs are analyzed. A significant ABC effect—enhancement in the region of low ππ mass—is found only in the isoscalar ππ channel while in the isovector channels it is small or absent. For the reaction with isovector pp final state an ABC effect was not observed even at the special kinematic conditions to reproduce a quasi-bound two-proton state. The total cross sections for the d and 4He fusion reactions show similar resonance-like energy dependence.     

Microwave spectrum,structure, dipole moment,and internal rotation of the trans isomer of ethyl methyl sulfide

The microwave spectra of the trans isomer of ethyl methyl sulfide and its 10 isotopic species were measured. The r_s structure of this isomer was determined from the observed moments of inertia. The dipole moment and its direction in the molecule were determined by Stark effect measurements of low J transitions for the normal and CH₃CH₂SCD₃ species. The barrier to internal rotation of the SCH₃ group was calculated from the observed A-E splittings of the transitions. The present results were compared with those for the analogous molecules.     

Suppression of charmonium production in PbPb collisions at 158 GeV/c per nucleon and quark-gluon deconfinement

An anomalous suppression of the charmonium yield in central collisions was observed in studying charmonium production in collisions of Pb nuclei accelerated to a momentum of 158 GeV/c per nucleon with Pb target nuclei. It is shown that, in peripheral collisions, the ratio of the cross section for J/ψ production to the cross section for the Drell-Yan process decreases exponentially (as in the case of collisions of lighter nuclei) owing to the ordinary absorption of J/gy in nuclear matter. The observed threshold effect of the anomalous suppression of charmonium production agrees well with the predictions based on the assumption of Debye color screening in the formation of quark-gluon plasma.