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1.
利用二能级体系速率方程,推导了半导体中探测光探测到的法拉第旋转光谱的理论模型,发现电子-空穴对的复合对法拉第旋转信号随时间的衰减有重要影响,并利用该模型对GaAs量子阱中实验测得的法拉第旋转光谱进行拟合,得到GaAs量子阱材料中的电子自旋弛豫时间为73.5 ps,而直接利用单指数进行拟合得到的电子自旋弛豫时间仅为51.3 ps. 因此,直接利用单指数对法拉第旋转光谱进行拟合得到电子自旋弛豫时间的传统做法是不准确的.
关键词:
自旋弛豫时间
时间分辨法拉第旋转光谱
GaAs量子阱 相似文献
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14N核四极共振自旋系统的自旋-晶格弛豫是一种双指数弛豫。本文介绍了14N核四极共振自旋系统的自旋-晶格弛豫时间的3种测量方法,利用可变多面体方法对实验数据进行拟合,获得了14N核四极共振自旋系统的自旋-晶格弛豫时间T1s和T11,对有关文献中关于核四极共振弛豫时间的测量的3个观点提出了质疑。 相似文献
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核磁共振T2谱多指数反演算法是开展复杂体系样品核磁共振(NMR)弛豫研究最重要的数学工具. 常用的T2谱多指数反演算法一般都是事先给出弛豫时间T2分布的布点, 然后转化为线性拟合问题进行求解. 在求解的T2谱较为分散的时候, 反演得到的T2谱精确度不高, 分辨率较低. 非线性拟合是解决这个问题的有效办法. 本文针对分散T2谱反演利用非线性拟合时遇到的初值依赖及运算复杂问题, 利用线性回归最小二乘方法, 改进了其中的带非负约束非线性优化模型, 将搜索的反演参数从T2, f 减少为T2, 加快了收敛速度, 减少了对初值的依赖, 提高了反演精度, 使算法更加稳健. 通过用改进的Levenberg-Marquardt算法和差分进化算法进行计算机模拟反演及实验数据反演, 验证了改进方法在核磁共振T2 谱反演中的有效性. 相似文献
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用极限动力学模型研究了C60分子在有序-无序相变和玻璃态相变温度区间取向 角为98°和38°的取向概率与温度的关系.计算结果在玻璃态相变点附近的85K,90K和有序- 无序相变点的260K分别与实验值相吻合,取向概率对实验值更精确的拟合及其对温度的二阶 导数预言玻璃态相变点在84K.导出了弛豫规律,其结果表明:双能级的C60分子从非平衡态到平衡态的弛豫行为与非指数因子β有关,其总的弛豫时间决定于其中一个较 短的弛豫时间,展宽指数形式保持不变.讨论了KWW方程的非
关键词:
60')" href="#">C60
取向概率
非平衡态弛豫 相似文献
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从极化团簇的随机涨落出发, 利用维纳过程模型, 推导了铁电体中极化长程涨落的弛豫规律以及光强自相关函数所可能的表现形式. 阐述了微观极化团簇的弛豫过程与宏观测量弛豫规律之间的联系. 通过对原有氦氖激光光子关联谱实验装置进行改进, 观测了BaTiO3和0.71Pb(Mg1/3Nb2/3)O3-0.29PbTiO3单晶中极化团簇长程涨落在居里点和立方到四方相变点附近的弛豫过程. 在BaTiO3中发现极化团簇长程涨落在居里点之上4 K存在双弛豫现象, 此现象与其有序无序相变机理相联系. 在Pb(Mg1/3Nb2/3)O3-0.29PbTiO3中发现极化团簇长程涨落在相变点两侧都存在双弛豫现象. 利用推导的理论结果很好地拟合了实验结果并提取了极化团簇长程涨落的弛豫时间. 两种样品中极化团簇长程涨落的弛豫时间都在相变点出现突变, 并呈现临界慢化现象. 相似文献
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 ̄14N核四极共振自旋系统的自旋-晶格弛豫是一种双指数弛豫。本文介绍了 ̄14N核四极共振自旋系统的自旋-晶格弛豫时间的3种测量方法,利用可变多面体方法对实验数据进行拟合,获得了 ̄14N核四极共振自旋系统的自旋-晶格弛豫时间T_1s和T_11,对有关文献中关于核四极共振弛豫时间的测量的3个观点提出了质疑。 相似文献
11.
V.G. Kunde W.C. Maguire 《Journal of Quantitative Spectroscopy & Radiative Transfer》1974,14(8):803-817
A transmittance model has been developed for interpretation of high spectral resolution measurements of laboratory absorption and of planetary thermal emission. The high spectral resolution requires transmittances to be computed monochromatically by summing the contribution of individual molecular absorption lines. A magnetic tape atlas of H2O, O3, and CO2 molecular line parameters serves as input to the transmittance model with simple empirical representations used for continuum regions wherever suitable laboratory data exist. The theoretical formulation of the transmittance model and the computational procedures used for the evaluation of the transmittances are discussed, and application of the model to several homogenous path laboratory absorption examples is demonstrated. 相似文献
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The second Szigeti relation was used to obtain the temperature dependence of the Szigeti effective charge, es. The results are discussed in the framework of the deformation dipole model. Recent experimental data are used to show that the volume derivatives of es of most ionic solids are positive, thus providing evidence that the deformation dipole model is qualitatively valid. 相似文献
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混凝土是一种应用广泛的复合材料,其动态性能及抗侵彻毁伤效应的研究越来越依赖于数值模拟,其中混凝土HJC模型是应用最广泛的本构模型之一。在介绍HJC模型的基础上,应用LS-DYNA数值模拟方法进行HJC本构模型抗侵彻性能的参数敏感性研究,通过大量数值模拟得出HJC模型的抗侵彻敏感参数有:无侧限单轴抗压强度fc、压实点压力plock、特征化粘性强度A、特征化压力硬化因子B和压力硬化指数N。在混凝土的抗侵彻数值模拟过程中,重点是确定敏感参数的取值,以提高数值模拟的精度和质量,做到合理地选择试验方法和安排试验量。 相似文献
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Self-consistent Hartee-Fock-LCAO calculations on a linear NiN2 cluster are used to explain the two-peak structure observed in core level photoemission from N2 adsorbed on the Ni (100) surface. The two observed peaks are due to different N2 core hole final states, a screened and an unscreened final state that can be clearly identified in the cluster model. The energy separation and intensity ratio (computed using the sudden approximation) of the two final states in NiN2 are comparable with the experimental peak separation and intensity ratio for reasonable cluster geometries. A comparison with previous model studies on NiCO is used to explain the different shape of the core level spectra of N2 and CO adsorbed on nickel surfaces. 相似文献
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建立了一种简便的、适用于磁畴模型应用的Tb0.3Dy0.7Fe2 合金本构参数辨识方法. 针对Tb0.3Dy0.7Fe2合金磁畴模型中本构参数不明确且直接实验测试困难的问题, 提出了一种数值计算与实验测试相结合的参数辨识方法. 采用坐标变换与绘制自由能等势曲线相结合的方法, 简化了载荷作用下Tb0.3Dy0.7Fe2 合金内磁畴角度偏转的数值计算, 研究了合金磁畴角度偏转模型的参数依赖性. 在此基础上, 结合简单的实验测试, 建立了Tb0.3Dy0.7Fe2合金各向异性常数K1 和K2、能量分布因子ω、晶轴取向分布的辨识及修正方法. 该方法能够简单、快速地完成Tb0.3Dy0.7Fe2 合金磁畴模型中本构参数的辨识, 对完善磁致伸缩材料磁畴偏转的数值计算模型非常有意义. 理论分析可为类磁致伸缩材料磁机耦合模型的建立、完善, 以及材料本构参数的辨识、获取提供参考. 相似文献
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Dorota Nowak-Wo?ny Tomasz Janiczek Witold Mielcarek Juliusz B. Gajewski 《Journal of Electrostatics》2009,67(1):18-21
Modified bismuth oxide (Bi2O3) is of great importance to fuel cells and oxide varistors. The electrical parameters of Bi2O3 vary with its modifying components as well as with its aging temperature. This paper presents an analysis of impedance test results carried out to find an equivalent electric model and the relationship between the model's elements to various additives used to modify Bi2O3 and to changes in aging temperature. The proposed model was tested via computer simulation and the model parameters correlated to individual modifiers. 相似文献
17.
Johannes Tran-Gia Tobias Wech Dietbert Hahn Thorsten A. Bley Herbert Köstler 《Magnetic resonance imaging》2014
Purpose
To include the flip angle distribution caused by the slice profile into the model used for describing the relaxation curves observed in inversion recovery Look–Locker FLASH T1 mapping for a more accurate determination of the relaxation parameters.Materials and methods
For each inversion time, the flip angle dependent signal of the mono-exponential relaxation model is integrated across the slice profile. The resulting Consideration of Slice Profiles (CSP) relaxation curves are compared to the mono-exponential signal model in numerical simulations as well as in phantom and in-vivo experiments.Results
All measured relaxation curves showed systematic deviations from a mono-exponential curve increasing with flip angle and T1 but decreasing with repetition time. Additionally, the accuracy of T1 was found to be largely dependent on the temporal coverage of the relaxation curve. All these systematic errors were largely reduced by the CSP model.Conclusion
The proposed CSP model represents a useful extension of the conventionally used mono-exponential relaxation model. Despite inherent model inaccuracies, the mono-exponential model was found to be sufficient for many T1 mapping situations. However, if only a poor temporal coverage of the relaxation process is achievable or a very precise modeling of the relaxation course is needed as in model-based techniques, the mono-exponential model leads to systematic errors and the CSP model should be used instead. 相似文献18.
Dieter Müller 《Zeitschrift für Physik A Hadrons and Nuclei》1971,241(5):466-472
The effective InteractionU for a shell model with hamiltonianH m is investigated by means of a “mixed” model with hamiltonianH m . For this model the Bornv. Neumann expansion of the effective interaction? reduces to its first two terms. Within the finite dimensional function space ? n used in the shell model calculation the operatorsU and? are exactly equivalent. This is used to show that an energy independent approximation forU- if it is possible at all-is necessarily equal to the residual interaction, i.e. to the difference between nucleon-nucleon interaction and shell model interaction. 相似文献
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Criteria are discussed for the practical application of ‘valence-electron only’ calculations aimed at simulating ab initio all-electron calculations on molecules containing heavy atoms with many core electrons. A theoretical model is outlined based on the use of pseudopotentials derived from atomic SCF calculations. The model has been used in calculations for NaH, Na2, H2S, S2, H2S2, HCl, Cl2 and NaCl, and has been tested by comparison with reference all-electron calculations. Most of these tests employ double-zeta basis sets and SCF wavefunctions, although polarization functions and complete valence-electron CI wavefunctions have been used in some cases. The model is generally successful for ground-state equilibrium structures, charge distributions and orbital energies. 相似文献
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A theoretical study is carried out to explain the magnetic properties of uranium compounds of NaCl, anti-Cu2Sb and Th3P4 type. The electronic model used is a modified free electron model along the lines of the band structure for NaCl type uranium compounds previously reported. An exchange interaction via the conduction electrons is assumed for the mechanism of magnetic ordering. The molecular field approximation is used to calculate θ, TN and the exchange interaction constants. The stability range of various magnetic ordering states and the variation of θ, TN and exchange interaction constants are obtained as functions of lattice parameter. These results well explain the experimental data. 相似文献