Fabrication and laser performance of highly transparent Nd:YAG ceramics from well-dispersed Nd:Y<Subscript>2</Subscript>O<Subscript>3</Subscript> nanopowders by freeze-drying

Well-dispersed Nd:Y₂O₃ powders with uniform particle size of about 60 nm were synthesized from freeze-dried precursors. Highly transparent 2 at.% Nd:YAG ceramics were fabricated from the as-synthesized Nd:Y₂O₃ powders and commercial Al₂O₃ powders by vacuum sintering at 1,750 °C for 5 h. Phase evolution, microstructures, and spectroscopic properties of the Nd:YAG transparent ceramics were investigated. Freeze-drying played an important role in the synthesis of high-quality Nd:Y₂O₃ nanosized powders, which were essential for the fabrication of highly transparent Nd:YAG ceramics. Optical transmittance of a 3-mm thick sample reached 82% in the wavelength range of 200–900 nm. 5.23 W output power was obtained with 14.3 W diode laser pumping, giving a slope efficiency of 36.5%.     

All solid-state continuous-wave Nd:YAG laser at 1319 and 659.5 nm under direct 885 nm pumping

The continuous-wave high efficiency laser emission of Nd:YAG at the fundamental wavelength of 1319 nm and its 659.5-nm second harmonic obtained by intracavity frequency doubling with an LBO nonlinear crystal is investigated under pumping by diode laser at 885 nm (on the ⁴ F _3/2 → ⁴ I _13/2 transition). An end-pumped Nd:YAG crystal yielded 9.1 W at 1319 nm of continuous-wave output power for 18.2 W of absorbed pump power. The slope efficiency with respect to the absorbed pump power is 0.55. Furthermore, 5.2 W 659.5 nm red light is acquired by frequency doubling, resulting in an optical-to-optical efficiency with respect to the absorbed pump power of 0.286. Comparative results obtained for the pump with diode laser at 808 nm (on the ⁴ F _5/2 → ⁴ I _13/2 transition) are given in order to prove the advantages of the 885 nm wavelength pumping.     

Neodymium concentration dependence of 0.94-, 1.06- and 1.34-μm laser emission and of heating effects under 809- and 885-nm diode laser pumping of Nd:YAG

Laser emission in the 0.94-, 1.06- and 1.34-micron ranges in diluted and concentrated Nd:YAG crystals longitudinally pumped by a 885-nm diode laser on the ⁴ I _9/2→⁴ F _3/2 transition is investigated. Continuous-wave operation at watt level in all these wavelength ranges is demonstrated with a 1.0-at. % Nd:YAG crystal; however, the laser performance is impeded by the low pump absorption efficiency. Improved output power and overall efficiency were obtained with a highly doped 2.5-at. % Nd:YAG crystal: 5.5 W at 1.06 μm and 3.8 W at 1.34 μm with 0.38 and 0.26 efficiencies, respectively. Comparative results with traditional pumping at 809 nm into the highly absorbing ⁴ F _5/2 level are presented, showing the advantage of the direct ⁴ F _3/2 pumping. The influence of the lasing wavelength and of the Nd concentration on the thermal effects induced by the optical pumping in the laser material is discussed. A clear relation between the heat generated in the Nd:YAG crystals in lasing and non-lasing regimes, a function of the Nd doping, is demonstrated. PACS 42.55.Rz; 42.60.By; 42.60.Da     

Optimization of Diode-Pumped Continuous-Wave Tape-Casting YAG/Nd:YAG/YAG-Ceramic Lasers

We demonstrate a diode-laser-pumped solid-state 1.06 μm laser using a novel YAG/Nd:YAG/YAG composite ceramics with a sandwich structure. We optimize the laser performance using different output couplers, pumping beam waists, and cavity lengths. A maximum CW output power of 11 W for the YAG/Nd:YAG/YAG-ceramic laser is obtained at an absorbed pump power of 25 W resulting in a slope efficiency of 49.4%. The excellent output performance shows that the novel YAG/Nd:YAG/YAGceramic material has a great potential in applications with diode-laser pumping.     

Growth and properties of KLu(WO4)2, and novel ytterbium and thulium lasers based on this monoclinic crystalline host

High‐quality crystals of monoclinic KLu(WO₄)₂, shortly KLuW, were grown with sizes sufficient for its characterization and substantial progress was achieved in the field of spectroscopy and laser operation with Yb³⁺‐ and Tm³⁺‐doping. We review the growth methodology for bulk KLuW and epitaxial layers, its structural, thermo‐mechanical, and optical properties, the Yb³⁺ and Tm³⁺ spectroscopy, and present laser results obtained in several operational regimes both with Ti:sapphire and direct diode laser pumping using InGaAs and AlGaAs diodes near 980 and 800 nm, respectively. The slope efficiencies with respect to the absorbed pump power achieved with continuous‐wave (CW) bulk and epitaxial Yb:KLuW lasers under Ti:sapphire laser pumping were ≈ 57 and ≈ 66%, respectively. Output powers as high as 3.28 W were obtained with diode pumping in a simple two‐mirror cavity where the slope efficiency with respect to the incident pump power reached ≈ 78%. Passively Q‐switched laser operation of bulk Yb:KLuW was realized with a Cr:YAG saturable absorber resulting in oscillation at ≈ 1031 nm with a repetition rate of 28 kHz and simultaneous Raman conversion to ≈ 1138 nm with maximum energies of 32.4 and 14.4 μJ, respectively. The corresponding pulse durations were 1.41 and 0.71 ns. Passive mode‐locking by a semiconductor saturable absorber mirror (SESAM) produced bandwidth‐limited pulses with duration of 81 fs (1046 nm, 95 MHz) and 114 fs (1030 nm, 101 MHz) for bulk and epitaxial Yb:KLuW lasers, respectively. Slope efficiency as high as 69% with respect to the absorbed power and an output power of 4 W at 1950 nm were achieved with a diode‐pumped Tm:KLuW laser. The slope efficiency reached with an epitaxial Tm:KLuW laser under Ti:sapphire laser pumping was 64 %. The tunability achieved with bulk and epitaxial Tm:KLuW lasers extended from 1800 to 1987 nm and from 1894 to 2039 nm, respectively.     

Efficient continuous-wave 908 nm Nd:YLF laser emission under direct 880 nm pumping

The quasi-three-level 908-nm continuous-wave laser emission under direct diode laser pumping at 880 nm into emitting level ⁴ F _3/2 of Nd:YLF have been demonstrated. An end-pumped Nd:YLF crystal yielded 4.7 W of output power for 11.8 W of absorbed pump power. The slope efficiency with respect to the absorbed pump power was 43.3%. Comparative results obtained for the pump with diode laser at 808 nm, into the highly-absorbing ⁴ F _5/2 level, are given in order to prove the advantages of the 880-nm wavelength pumping.     

Comparison of cw laser performance of Nd:KGW, Nd:YAG, Nd:BEL, and Nd:YVO4 under laser diode pumping

4 crystals under low-power laser diode end-pumping. Output power dependencies on the pump power and the pump wavelength of these diode-pumped solid state lasers were investigated. The high Nd³⁺ concentration of the Nd:KGW samples used in our measurements as well as up-conversion and exited-state absorption processes in Nd:KGW cause the reduced laser output power dependence on the pump wavelength which was experimentally observed. At pump levels up to 270 mW a slope efficiency of η_sl≈46% was reached for the Nd:KGW laser. Nd:KGW microchip laser operation with a slope efficiency of η_sl≈50% was demonstrated. Thermal lensing in Nd:KGW at pump powers up to 3 W was measured. Received: 4 August 1997     

Optical properties and highly efficient laser oscillation of Nd:YAG ceramics

Optical absorption, emission spectra have been measured for polycrystalline Nd-doped Y₃Al₅O₁₂ ceramics. Fluorescence lifetimes of 257.6 μs, 237.6 μs, 184.2 μs and 95.6 μs have been obtained for 0.6%, 1%, 2% and 4% neodymium-doped YAG ceramics, respectively. For the first time, highly efficient laser oscillation at 1064 nm has been obtained with this kind of ceramics. Slope efficiency of 53% has been achieved on a uncoated 4.8-mm thick 1% Nd:YAG ceramics sample. Optical to optical conversion efficiency is 47.6%. Laser oscillation has also been obtained with a 2% Nd:YAG ceramics. The optical properties and laser output results have been compared with that of Nd:YAG single crystal grown by the Czochralski method. Almost identical results have been achieved including laser experiments results. But fabrication of Nd:YAG ceramics is much easier compared to the single-crystal growth method. And also large size (now of about 400 mm diameter×5 mm is available) and high-concentration (>1%) Nd:YAG ceramics can be fabricated. The results show that this kind of Nd:YAG ceramics is a very good alternative to Nd:YAG single crystal. Received: 20 April 2000 / Published online: 16 August 2000     

Diode-pumped Yb:Y<Subscript>2</Subscript>SiO<Subscript>5</Subscript>-LiB<Subscript>3</Subscript>O<Subscript>5</Subscript> cyan laser at 501.7 nm

We describe the output performances of the 928 nm ⁴ F _3/2 → ⁴ I _9/2 transition in Nd:CLNGG under diode-laser pumping. An end-pumped Nd:CLNGG crystal yielded 1.3 W of continuous-wave output power for 17.8 W of absorbed pump power. The slope efficiency with respect to the absorbed pump power was 11.2%. Furthermore, with 17.8 W of diode pump power and the frequency-doubling crystal LiB₃O₅ (LBO), a maximum output power of 260 mW in the blue spectral range at 464 nm has been achieved. The blue output power stability over 4 h is better than 3.2%.     

High-peak power,passively Q-switched,composite, all-poly-crystalline ceramics Nd:YAG/Cr<Superscript>4+</Superscript>:YAG laser and generation of 532-nm green light

Output performances of passively Q-switched, composite Nd:YAG/Cr⁴⁺:YAG lasers that consisted of bonded, all-poly-crystalline ceramics Nd:YAG and Cr⁴⁺:YAG are reported. Laser pulses at 1.06 μm with 2.5-mJ energy and 1.9-MW peak power are obtained from a 1.1-at % Nd:YAG/Cr⁴⁺:YAG ceramics that was quasi-continuous-wave (quasi-CW) pumped with a diode laser. Single-pass frequency doubling with LiB₃O₅ (LBO) nonlinear crystal at room temperature yielded green laser pulses at 532 nm of 0.36-mJ energy and 0.3-MW peak power, with a conversion efficiency of 0.27.     

Passively Q-switched GdVO<Subscript>4</Subscript>/Nd:GdVO<Subscript>4</Subscript> laser with Cr<Superscript>4+</Superscript>:YAG saturable absorber under direct 879 nm diode pumping to the emitting level

A passively Q-switched 1.06 μm laser with Cr⁴⁺:YAG saturable absorber by direct 879 nm diode pumping grown-together composite GdVO₄/Nd:GdVO₄ crystal to the emitting level was demonstrated in this paper. The characteristics of pulsed laser were investigated by using two kinds of Cr⁴⁺:YAG crystal with the initial transmissivity of 80 and 90%, respectively. When the T ₀ = 90% Cr⁴⁺:YAG was used, an average output power of 1.59 W was achieved at an incident pump power of 10 W. The pulse width and repetition rate were 64.5 ns and 170 kHz, respectively. The thermal lens effect of laser crystal was analyzed.     

High-efficiency 17 W, 80 MHz repetition rate,passively mode-locked TEM<Subscript>00</Subscript> Nd:YAG oscillator pumped at 885 nm

We report on a passively mode-locked TEM₀₀ Nd:YAG oscillator with the beam quality at M ² = 1.1 by a semiconductor saturable absorber mirror under 885 nm laser diode direct pumping for the first time. A maximum average output power of 17 W at a repetition rate of 80 MHz with 39 ps pulse width was obtained under the absorbed pump power of 38 W, corresponding to an optical-optical efficiency of 44% and the slope efficiency of 69%, respectively.     

CW mode locked Nd:YVO4 laser pumped by 20-W laser diode bar

The efficient cw mode locking (cw-ML) regime was demonstrated in Nd:YVO₄ laser by means of saturable absorber mirror (SAM). The 0.3-at.% Nd³⁺ doped 10-mm-long YVO₄ crystal end pumped by 20-W diode module with a beam shaper was applied as a gain medium located in the close vicinity to the rear flat mirror of the first arm of Z-type resonator of 316 cm total length with two curved mirrors of 100-cm curvature radii. The SAM of 2%-saturable absorptance and saturation fluence of 50 μJ/cm² was mounted at the opposite end of a resonator. The developed “dynamically stable” cavity design mitigates detrimental role of thermal aberration in gain medium, enforcing clean perfect mode locking even for the highest pump densities. The cw-ML pulses with 47.5 MHz repetition rate and pulse durations in the range of 15–20 ps were observed for a wide range of pump powers and output coupler losses. In the best case, for 32% of output coupler transmission, up to 6.2 W of average power with near 35% slope efficiency was achieved. The thresholds for Q-switched ML, cw-ML regimes were 2.67 W and 6.13 W of pump power, respectively. For the maximum pump power of 20 W we obtained 133 nJ of pulse energy with 16-ps pulse duration, resulting in a peak power higher than 8 kW. The threshold energy density at SAM giving the QML regime was estimated to be about 30 μJ/cm², threshold of cw-ML regime was 220 μJ/cm².     

2.41 W compact efficient CW blue light generation by intra-cavity frequency doubling of a compact Nd:YAG laser

We report on a laser diode end-pumped Nd:YAG blue laser using a three-mirror-folded cavity. Three different crystals cut for type-I critical phase matching are used for the intra-cavity frequency doubling of the laser: 10-mm-long LiB₃O₅ (LBO), 15-mm-long LBO, and 10-mm-long BiB₃O₆ (BIBO). Up to 2.41 W of continuous wave output power in the blue spectral range at 473 nm is achieved with BIBO crystal (1.89 W with LBO) at the incident pump power of 16 W, the light-to-light conversion efficiency is about 15.1%.     

Diode-pumped CW Nd:YAG laser at 1356 nm based on the <Superscript>4</Superscript><Emphasis Type="Italic">F</Emphasis><Subscript>3/2</Subscript>-<Superscript>4</Superscript><Emphasis Type="Italic">I</Emphasis><Subscript>13/2</Subscript> transition

We describe the output performances of the 1356 nm ⁴ F _3/2-⁴ I _13/2 transition (generally used for a 1319 nm transition) in Nd:YAG under in-band pumping with diode laser at the 809 nm wavelength. An end-pumped Nd:YAG crystal yielded 1.02 W of continuous-wave (CW) output power for 18.2 W of incident pump power. Moreover, intracavity second-harmonic generation (SHG) has also been achieved with a power of 290 mW at 678 nm by using a LiB₃O₅ (LBO) nonlinear crystal. The red beam quality factor M ₂ was less than 1.37. The red power stability was less 3.2% in 4 h.     

Highly efficient Nd:GdVO4/BiBO laser at 456 nm under direct 880 nm diode laser pumping

The continuous-wave high-efficiency laser emission of Nd:GdVO₄ at the second-harmonic of 456 nm obtained by intracavity frequency doubling with an BiB₃O₆(BiBO) nonlinear crystal is investigated under pumping by diode laser at 880 nm into emitting level ⁴F_3/2. About 3.8 W at 456 nm with M² = 1.4 was obtained from a 5 mm-thick 0.4 at.% Nd:GdVO₄ laser medium and a 12 mm-long BiBO nonlinear crystal in a Z-type cavity for 13.9 W absorbed pump power. An optical-to-optical efficiency with respect to the absorbed pump power was 0.274. Comparative results obtained for the pump with diode laser at 808 nm, into the highly-absorbing ⁴F_5/2 level, are given in order to prove the advantages of the 880 nm wavelength pumping.     

CW and passive Q-switching of 1331-nm Nd:GGG laser with Co<Superscript>2+</Superscript>:LMA saturable absorber

In this paper, the output performances at 1331 nm in continuous-wave (CW) operation and the passive Q-switching regime of a Nd:Gd₃Ga₅O₁₂(Nd:GGG) laser crystal have been investigated under pumping with diode lasers. A maximum CW output power of 1.5 W was reached at an incident pump power of 7.5 W; the overall optical-to-optical efficiency and the slope efficiency with respect to the pump power were 21.5% and 19.4%, respectively. The passive Q-switching regime was achieved with Co²⁺:LaMgAl₁₁O₁₉ (Co²⁺:LMA) saturable absorber (SA) crystals. A maximum average output power of 183 mW was recorded with a Co²⁺:LMA SA with initial transmission T _i of 90%. The pulse energy was 18.7 μJ and the pulse duration was 26.1 ns, which correspond to a pulse peak power of 0.7 kW. With a Co²⁺:LMA SA with T _i=81%, the average power decreased to 131 mW. However, the pulse energy increased to 21.4 μJ, the pulse duration was 16.4 ns and the pulse peak power increased to 1.3 kW.     

Lasing of a single crystal Nd fluoride fiber

We present laser action in a single crystal fluoride fiber obtained by the micro-pulling-down technique. The 700 μm diameter and 1 cm long Nd:LiYF₄ fiber was pumped by a beam shaped diode bar emitting at 806 nm. A peak power of 300 mW was achieved with a slope efficiency of 12%. When considering the pump power fraction absorbed by the laser mode, a slope efficiency of 37% was achieved. To the best of our knowledge, this is the first report of a Nd: LiYF₄ fiber laser.     

Powerful solid-state transversely diode-pumped YAG: Nd lasers with improved radiation quality

YAG: Nd lasers with transverse diode pumping of a cylindrical active (lasing) element are developed and studied. Pumping is carried out with continuous-wave (cw) laser diode array modules. At pump powers of 500, 820, and 1400 W, the output powers of the lasers operating in the multimodal regime are, respectively, 150, 350, and 500 W. The optical efficiency exceeds 30%. In the case of an unstable resonator operating in the negative branch of the stability diagram, the laser power equals 320 W with a beam divergence only twice as large as the diffraction limit. The design of a YAG: Nd laser pumped with pulsed-periodic laser diode array modules is presented. The total pump energy is 5 J, and the width and repetition rate of pulses are, respectively, 250 μs and 100 Hz.     

Diode-pumped passively Q-switched Nd:GdVO4 lasers operating at 1.06 μm wavelength

With a 10-W diode laser to pump Nd:GdVO₄ crystal in a folded cavity, we demonstrated Cr⁴⁺:YAG passively Q-switched Nd:GdVO₄ lasers at 1.06 μm. The maximum average output power of 2.1 W and the highest peak power of 625 W were, respectively, obtained when the initial transmissions of the Cr⁴⁺:YAG crystals were 90% and 80%. Received: 8 September 1999 / Revised version: 30 December 1999 / Published online: 8 March 2000