低温共烧陶瓷铁氧体环行器的设计与分析

基于叠层片式化结构对工作于S波段的低温共烧陶瓷(LTCC)铁氧体环行器进行设计和分析,模拟研究了器件制备中面临的关键问题对器件频率特性的影响。研究结果表明,采用微波铁氧体层与陶瓷介质层构成混合结构,匹配电路以三维方式进行布线和互联,器件可以获得优良的带内特性。在器件的三维电路布线中,当连接两节阻抗线的导体圆柱端口气隙高度达到20μm时,器件的传输特性和隔离特性急剧恶化。此外,研究还发现微波铁氧体层与陶瓷介质层出现分层时,形成的气隙高度不应大于20μm,否则将导致器件的传输特性和隔离特性显著降低。因此,在进行LTCC铁氧体环行器的制备时,导体圆柱与陶瓷介质层以及微波铁氧体层与陶瓷介质层的异质材料匹配共烧是保障器件优良性能的关键。     

Analysis of Dispersion in Ferrite-superconductor Layered Structures

This paper studies electromagnetic wave propagation in hybrid structures consisting of ferrite and superconducting films. Dispersion relations for transverse electric mode of propagation are derived. Numerical results are presented for two specific structures viz. a ferrite/superconductor structure and a ferrite/superconductor/ferrite structure and dependence of propagation on various structural parameters and frequency are determined. The non-reciprocal nature of propagation is also established.     

Surface modification of M-Ba-ferrite powders by polyaniline: Towards improving microwave electromagnetic response

A composite of polyaniline (PANI)-coated M-type hexagonal barium ferrite (M-Ba-ferrite) powder was prepared by an in situ polymerization of an aniline monomer in the presence of M-Ba-ferrite particles. The obtained composite was characterized by Fourier transform infrared spectra (FT-IR), X-ray diffraction (XRD) and transmission electron microscopy (TEM). The structure and microwave response properties were investigated. The continuous coverage of polyaniline has been produced on the platelet M-Ba-ferrite particle surface, and a core–shell structure has been formed. The results show that the coverage of polyaniline has a great influence on microwave response of M-Ba-ferrite particles. A polyaniline thin layer formed on the surface of a barium ferrite particle changes the character of frequency dispersion of microwave absorption. The results indicate the existence of an interaction at the interface of polyaniline macromolecule and barium ferrite particle, which influences the physical and chemical properties of the composite. The interaction and interfacial polarization are seen as important factors contributing to the influence on microwave response of the PANI-coated ferrite composite powders.     

Abnormal morphology of nanocrystalline Mn–Zn ferrite sintered by pulse electric current sintering

Nanocrystalline manganese–zinc (Mn–Zn) ferrite powders prepared by the sol–gel auto-combustion method are sintered to form bulk ferrite by pulse electric current sintering technique. The sample phase, before sintering and after sintering, is carried out by X-ray diffraction (XRD). The morphology of the sample is observed by scanning electron microscopy (SEM). The results indicate that the bulk ferrite obtained has a pure spinel structure. With special graphite die, a special morphology is observed, which is explained by pressure, temperature and induced electromagnetic field.     

Magnetic-field-induced microstructural features in a high carbon steel during diffusional phase transformation

In this work, a high purity, high carbon steel was heat treated without and with a 12-T magnetic field. The microstructural features induced by magnetic field during its diffusion-controlled austenite decomposition were investigated by means of optical microscopy and SEM/EBSD. It is found that the magnetic field increases the amount of the abnormal structure, which is composed of proeutectoid cementite along the prior austenite boundaries and ferrite around it, because magnetic field increases the austenite grain size and promotes the transformation of carbon-depleted austenite to ferrite. No specific orientation relationship between abnormal ferrite and cementite has been found in the non-field- or the field-treated specimens. Magnetic field evidently promotes the spheroidization of pearlite, due to its effect of enhancing carbon diffusion through raising the transformation temperature and its effect of increasing the relative ferrite/cementite interface energy. As magnetic field favors the nucleation of the high magnetization phase-pearlitic ferrite, the occurrence of the P-P2 OR that corresponds to the situation that ferrite nucleates prior to cementite during pearlitic transformation is enhanced by the magnetic field.     

Synthesis, characterization and microwave absorption properties of titania-coated barium ferrite composites

Anatase titania-coated barium ferrite composites were prepared by a heterogeneous precipitation method in the presence of barium ferrite particles. The obtained samples were characterized by ξ-pH, TEM, EDX and XRD. The complex permittivity and permeability were studied in the frequency range of 2-12 GHz. The structure and microwave response properties are investigated. The results show that the coverage of titania has a great influence on microwave response of barium ferrite. The formation of an anatase titania nano-layer on the surface of a barium ferrite particle changes the character of the frequency dispersion of the complex permittivity. Comparing the anatase titania-coated barium ferrite composites with the uncoated barium ferrite, the complex permittivity of the anatase titania-coated barium ferrite composites is higher than that of uncoated barium ferrite. The complex permeability of composites was found to decrease with an increase in frequency as well as with the molar ratio of Ti:Ba. The enhancement of the complex permittivity may be due to dipolar polarization and interfacial polarization. The maximum reflection loss was obtained at the Ti:Ba ratio of 1:10, and the peak of the maximum reflection loss shifts to a lower frequency value with increasing titania fraction. By changing the thickness of titania coverage, the frequency dependence of the complex permittivity could be adjusted, which provides us an opportunity for the synthesis of tailored particles.     

Experimental investigation of the wave profile excited by a narrow transducer in a dielectric–ferrite–dielectric structure

The results from an experimental study of the diffraction profiles of magnetostatic backward volume waves (MSBVW) excited by a finite linear transducer placed on the surface of tangentially magnetized ferrite film in a dielectric–ferrite–dielectric structure are presented. Theoretical calculations and experimental data are compared.     

Quasi-optical ferrite devices for millimeter and submillimeter wave bands

Main features of the development of quasi-optical ferrite devices, using Faraday effect, are considered. Properties of a polarizing divider and a ferrite rotator of a polarization plane are analysed with standpoint of minimum losses. A matching method, based on an utilization of the rotator element in a form of the multilayers ferrite structure, which can be adjusted independently for right-handed and left-handed cyrcularly polarized waves, is suggested. It is shown, that this method allows to obtain a total matching in a quasi-optical transmission line. Results of an investigation of quasi-optical ferrite devices for the oversized round waveguide withH ₁₁ mode are presented.     

掺钛的锰锌铁氧体的中子衍射

锰锌铁氧体广泛用于各种有线通讯设备中,其使用的频率为几百kHz到几十MHz。但纯的锰锌铁氧体的磁导率(μ)的温度系数(在—40℃至80℃范围内)较大,在应用中使频率发生漂移,给使用造成了困难。为了改善μ(T)曲线,而添加了少量的各种元素进行试验,其中发现Ti对改善μ(T)曲线的效果较好。为了弄清Ti的作用,对含Ti的(Mn-Zn)Fe₂O₄的结构进行了中子衍射分析,得到的结果是:Ti择优占据B位,Mn及Zn择优占据A位,并测定了分子磁矩。最后对结果进行了初步的讨 关键词：     

Effects of molybdenum on precipitation behaviours in aged cast stainless steels

The effects of Mo on precipitation behaviours in aged cast stainless steels have been investigated. Mo-free CF3 steel and Mo-bearing CF3M steel, both of which consisted of a duplex structure of ferrite and austenite phases, were prepared. Microstructural evolution in the ferrite phase during ageing at 723 K has been observed by transmission electron microscopy (TEM). Precipitates in CF3 steel were identified to belong to the G-phase and possess lattice coherency with the ferrite phase at interphase boundaries. On the other hand, precipitates in CF3M steel were found to be nanodomains of not only to the G-phase but also to another phase enriched in Mo. Some of the nanodomains containing Mo exhibited diffraction patterns having pseudo five-fold symmetry, but others exhibited regular periodicity in high-resolution TEM images. The atomic structure of the Mo-related nanodomains is proposed to be a distorted χ-phase that retains coherency with the matrix.     

Magnetically Controlled Tunneling of a TE Wave through the Ferrite—ε-Negative Layer Structure

We have considered the tunneling of a normally incident electromagnetic wave through a bilayer structure that consists of a ferrite layer and an adjoining layer with a negative permittivity. The ferrite layer is transversely magnetized by an external magnetic field that corresponds to the range of negative values of the effective permeability. It has been shown that the transmission of the structure can be controlled in wide limits by varying the external magnetic field. In particular, nearly perfect tunneling (viz., nonreflective transmission of incident radiation) can be realized.     

基于磁光子晶体的低损耗窄带THz滤波器

本文提出一种采用石榴石型铁氧体磁性材料的太赫兹滤波器,利用波导线缺陷和腔内点缺陷的耦合特性,通过改变腔内介质柱半径及分布,实现对某个波长的耦合,达到了高效率滤波的功能;改变外磁场的大小,影响铁氧体材料的磁导率变化,使谐振频率发生改变,从而对THz波进行滤波.应用平面波展开法(PWM)和时域差分有限法(FDTD)进行仿真分析,研究结果表明,该滤波器其插入损耗为0.0997 d B,3 d B带宽为8.22 GHz,实现了低损耗窄带滤波.     

Effect of surfactants on wet grinding of barium hexaferrite powders and on the microstructure of sintered magnets on their basis

The effect of citric acid and isopropyl alcohol on the wet grinding of the mixture of initial ferriteforming components and synthesized ferrite charge has been analyzed. It has been established that the introduction of admixtures during wet grinding makes it possible to substantially reduce the ferrite synthesis temperature and the sintering temperature of green billets and to improve the magnetic properties of permanent magnets made of barium ferrites by the formation of a dense, fine-grained structure. The increase in the activity of powders is explained by the formation of active jelly-like interlayers on the surfaces of particles during wet grinding.     

ZnFe2O4 nanoparticles for ferrofluids: A combined XANES and XRD study

A soft-chemistry method is used to synthesize zinc ferrite nanoparticles to prepare a magnetic fluid. We investigate here their internal structure by X-ray Absorption Near Edge Spectroscopy (XANES) and X-Ray Diffraction (XRD). A cross analysis of XANES and Rietveld refinement of XRD spectra shows non-equilibrium site occupancy with respect to bulk zinc ferrite, suggesting a cation redistribution that enhances the magnetic and magneto-optical responses of the nanoparticles.     

离子型钴铁氧体磁流体的稀土改性与机理研究

采用化学共沉淀法以柠檬酸三钠为表面改性剂制备了离子型稀土复合钴铁氧体磁流体.利用X衍射仪和透射电镜对磁粒子的组成、结构及粒径进行了分析.利用古埃磁天平和分光光度计研究了稀土离子改性对磁流体饱和磁化强度和磁感应的影响,实验结果表明:合成过程中添加稀土离子能明显降低磁性纳米粒子的粒径,制得的磁粒子均呈球形,钴铁氧体磁粒子的粒径为12～15nm,稀土钴铁氧体磁粒子的粒径为6～8nm.利用稀土改性的微观模型解释了粒径的降低.添加Dy3+能提高饱和磁化强度和磁感应,添加Y3+则能提高磁感应,却降低了饱和磁化强度.并从理论上对其改性机理进行了详细的分析.     

TE10矩形波导中填充金属线阵和铁氧体合成的新型左手媒质

在TE₁₀矩形波导中填充金属线阵和铁氧体合成了一种新型的左手媒质结构.分别使用了转移函数矩阵方法以及全波仿真工具Ansoft HFSS对所提出的结构进行了分析.结果表明,在横向磁化铁氧体等效磁导率实部为负的频段范围内,该合成结构呈现左手通带特性并伴随着后向波的传播现象.由于横向磁化铁氧体的等效磁导率为负的频段范围可调,故所提出的结构具有左手通带范围可调的特性. 关键词： 左手媒质 10矩形波导')" href="#">TE₁₀矩形波导 金属线阵 铁氧体     

Magnetic losses of the soft magnetic composites consisting of iron and Ni–Zn ferrite

Ferromagnetic powders which are surrounded by an electrically insulating film (soft magnetic composites (SMCs)) exhibit unique magnetic properties, such as relatively low magnetic losses and 3D isotropic magnetic behavior. In some electromagnetic applications, including microwave frequency range applications, it is necessary to increase electrical resistivity without any noticeable reduction in magnetic properties. To achieve this purpose, electrically resistant materials, for example, ferrites with acceptable magnetic properties, are suitable candidates. This paper focuses on the effects of the synthesized Ni–Zn ferrite addition on the magnetic properties of the SMCs containing Ni–Zn ferrite within iron particles. The structure was studied by means of X-ray diffraction (XRD). The microstructure and the powder morphology were examined by the use of scanning electron microscopy (SEM). The magnetic measurements on powders and samples were carried out using a vibrating sample magnetometer (VSM) and an LCR meter, respectively. The results indicate that the lowest magnetic loss and the highest magnetic permeability are related to the composites with 20 wt% ferrite and 2 wt% ferrite, respectively. Also, the composites with 10 wt% ferrite show a good combination of magnetic loss and magnetic permeability in the range 0–500 kHz.     

Improved electrical,magnetic and dielectric properties of polypyrol (PPy) substituted spinel ferrite composites

CoTb_0.03Fe_1.97O₄ ferrite and poypyrrole (PPy) polymer nano composites were prepared by mixing the nano crystalline ferrite with poypyrrole (PPy) by following the solid state reaction synthesis route. The XRD patterns of CoTb_0.03Fe_1.97O₄ spinel ferrite powders and polymer (PPy) exhibited single phase spinel structure. The amorphous nature of PPy was evidenced by the broad peaks of XRD patterns. The surface morphology unfolded heterogeneous distribution in composites and ferrite. The grains in ferrite were spherical in shape with clear boundaries. The morphology was appreciably altered by the inclusion of ferrite contents. The higher activation energy and resistivity aroused due to blocking of conduction mechanism owing to nanoparticles embedded in the PPy matrix. A downfall in the dielectric loss of the composites is observed as the frequency of the applied field is increased. The incorporation of ferrite contents optimized the magnetic parameters of the composites. The enhanced coercivity (Hc) of these nanocomposites might be beneficial for memory devices.     

应变对钴铁氧体电子结构和磁性能影响的第一性原理研究

尖晶石型钴铁氧体(CoFe₂O₄)因具有良好的电磁性质, 广泛应用于计算机技术、航空航天及医学生物等领域. 特别是钴铁氧体薄膜在磁电复合材料中具有良好的应用前景. 本文基于密度泛函理论的第一性原理平面波赝势法, 结合广义梯度近似, 通过采用更接近于实验上外延生长的二维应变模型, 研究了钴铁氧体薄膜的结构稳定性、电子结构和磁性能. 结果表明: 在二维应变作用下, 反尖晶石结构的钴铁氧体比正尖晶石结构的稳定, 但是与平衡基态相比, 两者能量差减小, 这表明在应变作用下, 八面体晶格中的Co²⁺离子与四面体晶格中的Fe³⁺离子更容易进行位置交换, 形成混合型结构的钴铁氧体; 同时随着应变的增大, 钴铁氧体的能带带隙减小, 晶格中的原子磁矩发生变化, 但总磁矩变化不明显. 关键词： 尖晶石型钴铁氧体 第一性原理 电子结构 磁性能     

Deformation analysis of ferrite/pearlite banded structure under uniaxial tension using digital image correlation

The ferrite/pearlite banded structure causes the anisotropic behavior of steel. In this paper, digital image correlation (DIC) was used to analyze the micro deformation of this microstructure under uniaxial tension. The reliability of DIC for this application was verified by a zero-deformation experiment. The results show that the performance of DIC can satisfy the requirements of the tensile deformation measurement. Then, two uniaxial tensile tests in different directions (longitudinal direction and transverse direction) were carried out and DIC was used to measure the micro deformation of the ferrite/pearlite banded structure. The measured results show that the ferrite bands undergo the main deformation in the transverse tension, which results in the relatively weaker tensile properties in the transverse direction than in the longitudinal direction. This work is useful to guide the modification of the bands morphology and extend the application scope of DIC.