Detection of necking deformation along polypropylene fibres axis at low draw ratios using multiple-beam microinterferometry

A modified drawing device attached with an automated system for producing multiple-beam Fizeau fringes in transmission is used to study the mechanical deformation along polypropylene (PP) fibres at low draw ratios. Two drawing processes are used for drawing PP fibres. In the first process (fast drawing), the necking deformations are formed at draw ratios from 1.2 to 1.9 along the fibre axis. While in the other process (slow/step drawing), these deformations disappeared. The refractive indices calculated at different positions along the fibre axis during the fast- and slow-drawing processes. To overcome the formation of necking deformation along the PP fibres during fast-drawing process, the slow-drawing technique is recommended. Microinterferograms are given for illustration.     

3D refractive index profile for the characterization of necking phenomenon along stretched polypropylene fibres

The phenomenon of neck formation in polymers has attracted considerable attention. During the cold-drawing process an initial undrawn material is transformed into anisotropic one across a narrow transition region called ‘neck’. The Video Opto-Mechanical (VOM) device attached with multiple-beam Fizeau fringes techniques are used to stretch polypropylene (PP) fibres. A iPP sample is stretched to have a neck at room temperature. The optical properties of the deformed material over the necking region are examined. Another PP sample is stretched (without necking deformation) at room temperature and the optical properties are also examined. The task of this study is to characterize and assess the necking phenomenon along cold-drawn polypropylene (iPP) fibre axis. The effect of necking on the optical properties of the fibre is confirmed by the determination of the 3D refractive index profile at different regions along the deformed PP fibre. Also the orientation function is calculated for the necked sample. The contour lines of microinterferograms are given for illustrations.     

Determining the opto-mechanical and geometrical properties of high-density polyethylene fibres

A method is described to determine the opto-mechanical and geometrical properties of high-density polyethylene, HDPE, fibres at the same time for the same region from the fibre. Variations of the transverse sectional shapes, areas, optical and mechanical properties of fibres during the cold drawing process were investigated. A rotator-mechanical drawing device was used for rotating the fibre around its longitudinal axis during the cold drawing process. The Pluta polarizing two-beam interference microscope was attached with the rotator-mechanical drawing device for detecting these variations under the interferometer. The rotator-mechanical drawing device permits determining the tensile stress–strain curve, Poisson's ratio and strain optical coefficient for HDPE fibres. Also, it permits determining the refractive index profile of the drawn fibres taking into considering the transverse sectional area and the enclosed area under the fringe shift. The optical orientation factor and orientation angle was calculated for HDPE fibre to clarify the orientation of molecules during the cold drawing process. Microinterferograms are utilized for illustrations.     

On line interferometric investigation of the neck propagation phenomena of stretched polypropylene fibre

On line interferometric investigation of the neck propagation phenomenon of stretched fibre is carried out using an automatic multiple-beam Fizeau fringes technique. It was observed that under such a deformation condition, a neck deformation is formed and propagated steadily towards the gripped ends of the stretched sample. The neck propagation was recorded carefully during the course of the tests by means of a CCD camera. The fringe shift profile due to the neck formation was analyzed during the propagation stage. A polypropylene (PP) sample was stretched until a neck deformation is formed at room temperature. The 3D time-refractive index profile is investigated to clarify the fixed profile of propagation. The obtained microinterferograms are clarifying the fixed neck profile during the propagation of necking phenomena. The speed of neck propagation was calculated. The dependence of the propagation on the drawing speed and draw ratio was investigated.     

The preparation of multimode glass- and liquid-core optical fibres

A preform technique for drawing cladded-glass and hollow fibres suitable for application to optical communications is described. The parameters which need to be controlled are discussed and the preparation of the preforms is described. The resulting fibres have a high geometric uniformity and a probe beam remains largely at the same angle to the axis after more than 10⁶ reflections at the core/cladding interface. Fibre attenuations of 150, 60 and 5.8 dB km^–1 have been obtained with commercial glasses, preforms made from a special melt at Sheffield University [5], and a commercial liquid, respectively. The fibre drawing process does not appear to introduce any additional impurities and heat treatment has produced a significant reduction of transmission loss in glass fibres.     

Origin of the variability of the mechanical properties of silk fibres: 3. Order and macromolecule orientation in Bombyx mori bave,hand‐stretched strings and Nephila madagascarensis spider fibres

The comparison of the low wavenumber of polarized Raman spectra (50–300 cm^–1) from Bombyx mori (fresh cocoons fibres, hand‐stretched ‘Crins de Florence’ strings from the gland content, dried gland, regenerated silk films) and Nephila madagascarensis silks reveals the high polarisation of fibre modes and the absence of polarisation for dried gland and regenerated silk films. This is consistent with X‐ray diffraction measurements. The orientation of the fibroin/spidroin chains is due to the stretching during production, as for advanced synthetic fibres. The bandwidth of the ‘ordered chains’ signature is almost the same for the different fibres. However, the degree of polarisation seems to be higher in the case of spider fibre. The huge bandwidth of low wavenumber components of regenerated films indicates high disorder. Measurements along the fibre point out conformation changes with a periodicity (~20 mm) related to the silkworm head motion during the fabrication of the cocoon. Copyright © 2012 John Wiley & Sons, Ltd.     

Enhanced pulse compression induced by the interaction between the third—order dispersion and the cross—phase modulation in birefringent fibres

In this paper,we report on the enhanced pulse compression due to the interaction between the positive third-order dispersion (TOD) and the nonlinear effect (cross-phase modulation effect) in birefringent fibres.Polarization soliton compression along the slow axis can be enhanced in a birefringent fibre with positive third-order dispersion,while the polarization soliton compression along the fast axis can be enhanced in the fibre with negative third-order dispersion.Moreover,there is an optimal third-order dispersion parameter for obtaining the optimal pulse compression.Redshifted initial chirp is helpful to the pulse compression,while blueshifted chirp is detrimental to the pulse compression.There is also an optimal chirp parameter to reach maximum pulse compression.The optimal pulse compression for TOD parameters under different N-order solitons is also found.     

Multi-mode opto-thermo-mechanical stretching system for determination of 3D refractive index along the axis of stretched and/or heated fibres

A multi-mode opto-thermo-mechanical stretching system was modified to study the changes in the 3D of optical and structural properties of stretched fibre along its axis. The structural deformation of isotactic Polypropylene, (iPP), fibres was studied at different draw ratios. The modified system coupled with Pluta polarising interference microscope was used to determine the variation of the birefringence in three dimensions during stretching process. Using this modified system, the multi-necking was detected. Subfringe analysis technique was used to determine the phase distribution of the obtained microinterferograms, which were given for illustration.     

Automatic fringe analysis of two-beam interference patterns for measurement of refractive index and birefringence profiles of fibres

Automatic fringe pattern analysis is a powerful and inexpensive digital image-processing technique. Two-beam polarizing interference Pluta microscope [Pluta M. Opt Acta 1971;18:661, Pluta M. J Microsc 1972;96:309] is automated by the computer-aid via CCD camera and digital frame grabber. Software program is prepared to deal with the duplicated (separated and overlapped) Microinterferograms produced by two-beam polarizing microscope. It also gives an accurate and fast automatic measurement of refractive index and birefringence profiles for fibres. In this paper, the refractive index and birefringence profiles of two different types of fibres, basalt and polypropylene (PP) fibres are presented. A new method to determine the birefringence profile of fibres from non-duplicated microinterferogram is suggested. The cold drawing process for PP fibres is studied.     

Influence of temperature on the optical and structural properties along the diameter of optical fibres

Multiple-beam Fizeau fringes technique with an opto-thermal device is used to study the effect of temperature on the optical properties of Philips graded-index optical fibres. The refractive index profile of the optical fibre is measured at different temperatures. From these profiles the opto-thermal coefficient, the profile shape parameter α, the cladding/core maximum refractive index difference Δn and some guidance parameters of the optical fibre that play an important role in communication are determined. The variation of oscillation and dispersion energies along the diameter of the optical fibre (energy profile) are calculated at different temperatures. An empirical formula of the energy profile is obtained. Microinterferograms are given for illustrations.     

A novel video opto-mechanical (VOM) device for studying the effect of stretching speed on the optical and structural properties of fibers

Using a novel video opto-mechanical (VOM) device, the effect of stretching speed on the optical and structural properties of polypropylene (PP) fibers during the dynamic stretching process is studied. The objective of the present study is to correlate the optical and mechanical properties of PP fibers with the speed of stretching using the multiple-beam Fizeau fringes system. The skeletonization of the multiple-beam Fizeau fringes are determined automatically by using one-dimension Fourier transform method. The stepper motor is adjusted in order to stretch the fibers continuously with constant and uniform speed until breaking of the fiber. The refractive indices, birefringence, transverse sectional area and the orientation function of PP fibers are studied as a function of the draw ratio at different speeds of stretching. An empirical formula is given to correlate the birefringence of PP fiber and both the draw ratio and the speed of stretching. Stretching process of PP with low speed (slow stretching) is recommended to overcome the necking deformation along the fiber. The VOM device could be used to measure the yield strain. The draw ratio-stretching speed superposition is discussed with some details. Microinterferograms are given for illustration.     

Methods to determine surface energies of natural fibres: a review

To tailor the interaction across composite interfaces especially for the development of green composites, i.e. composites made completely from renewable materials, information about the fibre surfaces is required. We review the current state of the art of methods to determine the surface tension of natural fibres and discuss the advantages and disadvantages of techniques used. Although numerous techniques have been employed to characterise surface tension of natural fibres, it seems that commonly used wetting techniques are very much more affected by the non-ideal character of natural fibres. Inverse Gas Chromatography (IGC) is a much better suited technique to determine the surface energetic properties of natural fibres than wetting techniques. The surface tension of natural reinforcements, determined using IGC, was reported for nanosized bacterial cellulose as well as bamboo, cornhusk, flax, hemp and sisal, covering a wide range of cellulose content. The effect of methods to separate/extract fibres from the plants as well as of a few surface modification procedures on the fibre surface properties is also reviewed. The dispersive part of the natural fibre surface tension γ ^d _S varies from 32 to 61 mJ/m². The fibre surface tension increases with increasing cellulose content of natural fibres. We also found that a higher basicity (Donor Number, K _B to Acceptor Number, K _Aratio) was observed for fibres containing more cellulose. This may be reflective of higher crystalline cellulose content in the surfaces of the fibres, as only the ether linkage of the cellulose is labile for hydrogen bonding.     

Analysis of the heterogeneous dynamics of imidazolium-based [Tf2N−] ionic liquids using molecular simulation

The complex dynamic behaviour of the imidazolium-based ionic liquids [C_nmim⁺][Tf₂N^?], n = 4, 8, 12 is examined at various temperatures and at atmospheric pressure using molecular dynamics simulation. An existing all-atom force field is further optimised in order to attain reasonable agreement with experimental data for transport properties, such as self-diffusivities and viscosities. Dynamical heterogeneity phenomena are quantified through the calculation of the non-Gaussian parameter and the deviation of the self-part of the van Hove correlation function from the expected normal distribution. From this analysis, ions that move faster or slower than expected are detected in the system. These subsets of ‘fast’ and ‘slow’ ions form individual clusters consisting of either mobile or immobile ions. Detailed analysis of the ions’ diffusion reveals preferential motion along the direction of the alkyl tail for the cation and along the vector that connects the two sulphur atoms for the anion. For the longest alkyl tails, the heterogeneity in the dynamics becomes more pronounced and is preserved for several nanoseconds, especially at low temperatures.     

Generation of hollow crystalline tungsten oxide fibres

Hollow fibres of crystalline W₁₈O₄₉, arranged in a pine-tree-like structure, were generated by heating WS₂ powder in oxygen. SEM, TEM, X-ray and electron diffraction studies show that the individual fibres are composed of single-crystal tungsten oxide whiskers. One-dimensional growth, involving heat dissipation along the fibre axis, is proposed.     

Influence of Fibre Taper on the Interfacial Shear Stress in Fibre-Reinforced Composite Materials during Elastic Stress Transfer

The paper is concerned with finite element (FE) analysis of stress transfer from an elastic matrix to an elastic fibre, which need not be a uniform cylinder, in a fibre-reinforced composite material. Axisymmetric models of fibres embedded in co-axial cylindrical matrices were investigated by the FE method. Fibre shapes investigated were cylindrical, ellipsoidal, paraboloidal taper and conical taper. The effects of varying the fibre aspect ratio, q (ranging 200 to 3500) and Young's modulus (relative to that of the matrix), E _f /E _m (ranging 10³ to 10⁶) were investigated. The results show that ellipsoidal and parabolic tapers lead to a similar distribution of interfacial shear stress (τ) to that observed for a uniform cylindrical fibre, except that the magnitude of the stress is higher. For a conical taper (except for q = 200, E _f /E _m = 10⁶), the interfacial stress increases to a maximum between the centre and the end of the fibre and then decreases towards the fibre ends. The effect of fibre taper on the distribution of τvalues is reflected in the axial tensile stress, σ_z , distribution induced in a fibre. For example, for a fibre with a conical taper, the distribution of τ values can lead to an even distribution of σ_z along the length of a fibre.     

Polarisation-sensitive four-wave mixing and soliton self-frequency shift effect in the highly birefringent photonic crystal fibre

By adjusting the polarisation state of the pump at 805 nm parallel to slow (x) and fast (y) axes of the highly birefringent photonic crystal fibre with zero dispersion wavelengths 790 nm and 750 nm, this paper demonstrates the efficient polarisation-sensitive four wave mixing involved in pump, anti-Stokes and Stokes signals and soliton self-frequency shift effects induced by the phase-matching between red-shifted solitons and blue-shifted dispersive waves. If the reduction of coupling efficiency to the circular pump laser mode or other circular fibres due to asymmetry of the core is neglected, more than 98% of the total input power is kept in a single linear polarisation. Controlled dispersion characteristic of the doublet of fundamental guided-modes results in achieving light field strongly confined in principal axes of photonic crystal fibre, and enhancing the corresponding nonlinear-optical process through the remarkable nonlinear birefringence.     

Determination of the optical and geometrical properties of fibres having skin–core structure

A method is suggested to determine both the refractive index and the transverse sectional shape and area of fibres, having skin–core structure, at the same time for the same region of the fibre. The method depends on using a fibre rotator device attached with Pluta polarizing interference microscope, to record the variation of the fibre thickness at each angle of rotation. Nylon 6 fibres having skin–core structure were used in this study. Beck-line method was used to determine the refractive index of the skin for light vibrating parallel and perpendicular to the fibre axis. To confirm the results of the suggested method, the optical microscope was used to determine the transverse sectional shapes of bundles of nylon 6 fibres. The mean refractive indices of the skin and core of nylon 6 fibres were determined. Microinterferograms are given for illustration.     

Study of optical fibre structures by atomic force microscopy

A novel method using atomic force microscopy (AFM) to study optical fibre structures at the fibre end-face has been successfully developed. The doping concentration profiles of fibres revealed by differential etching speeds in a saturated solution of ammonium bifluoride at room temperature (25°C) were obtained from AFM topographic images. The superior spatial resolution of AFM made it possible to resolve concentric structures a hundred times smaller than the feature, due to the difference in the known refractive index (n) of 1×10^-3. Fibres with small core diameters and anisotropic structures, such as polarization-maintaining fibres, were studied with ease.     

Optical fibre strength/fatigue experiments

New techniques for measuring and analysing the strength characteristics of optical waveguide fibres have evolved as the strength of the optical fibres improved. A recent life-fatigue experiment is described and the results analysed in terms of the most commonly used theoretical model which results in the power law V = AKⁿ. Ten m long fibre samples were tensilely stressed in a high humidity environment by both fixed (static fatigue) and constant rate (dynamic fatigue) loads. The respective test values for the power law exponent, the fatigue constant ‘n’, were 38 and 17. The results of the tests indicate the more conservative value, 17, for practical engineering design, and the need for incorporating an ageing term in the model.     

Modes in weakly guiding elliptical optical fibres

Approximate and much simplified dispersion relations are obtained for the problem of optical wave propagation within weakly guiding elliptical fibres. The refractive index difference between the core and its cladding of weakly guiding optical fibres that are contenders for use as practical optical communication lines is very small; i.e., (n ₁/n₀–1) 1 wheren ₁ is the core index andn ₀ is the cladding index. These greatly simplified dispersion relations are then used to calculate the propagation constants for several higher order modes on an elliptical optical fibre.Supported partly by NELC, San Diego; this paper was presented at 1974 URSI Electromagnetic Waves Conference, London.