Fractional statistical mechanics

The Liouville and first Bogoliubov hierarchy equations with derivatives of noninteger order are derived. The fractional Liouville equation is obtained from the conservation of probability to find a system in a fractional volume element. This equation is used to obtain Bogoliubov hierarchy and fractional kinetic equations with fractional derivatives. Statistical mechanics of fractional generalization of the Hamiltonian systems is discussed. Liouville and Bogoliubov equations with fractional coordinate and momenta derivatives are considered as a basis to derive fractional kinetic equations. The Fokker-Planck-Zaslavsky equation that has fractional phase-space derivatives is obtained from the fractional Bogoliubov equation. The linear fractional kinetic equation for distribution of the charged particles is considered.     

A scaling method for deriving kinetic equations from the BBGKY hierarchy

On the basis of the scale covariance of correlation functions under a coarsegraining in space and time, the Boltzmann equation for neutral gases, the Balescu-Lenard-Boltzmann-Landau equation for dilute plasmas, and linear equations for the variances of fluctuations are derived from the BBGKY hierarchy equations with no short-range correlations at the initial time. This is done by using Mori's scaling method in an extended form. Thus it is shown that the scale invariance of macroscopic features affords a useful principle in nonequilibrium statistical mechanics. It is also shown that there existtwo kinds of correlation functions, one describing the interlevel correlations of the kinetic level with its sublevels and the other representing the fluctuations in the kinetic level.Partially financed by the Scientific Research Fund of the Ministry of Education.     

Kinetic equations for dense fluids

It is demonstrated that the kinetic equation of Davis's effective potential theory follows directly from the application of well-defined approximations to the three-body correlations involved in the second equation of the BBGKY hierarchy. The same, simple mathematical techniques involved in this demonstration are used to derive two other kinetic equations, one of which is a generalization to high densities of the Boltzmann equation. In order to facilitate its application to the calculation of the van Hove and other correlation functions, the kinetic equation of the effective potential theory is Fourier-Laplace transformed: explicit formulae are given for the matrix elements of all operators that occur in this equation.     

The solution of a chain of Bogoliubov quantum kinetic equations for Bose systems interacting by delta potential

The Bogoliubov's hierarchy of quantum kinetic equations that describes the system of Bose particles interacting by delta potential is solved with the help of nonlinear Schrödinger's equations. The solution of the hierarchy is defined in terms of the Bethe ansatz.     

Generalized Boltzmann equation for lattice gas automata

In this paper a theory is formulated that predicts velocity and spatial correlations between occupation numbers that occur in lattice gas automata violating semi-detailed balance. Starting from a coupled BBGKY hierarchy for then-particle distribution functions, cluster expansion techniques are used to derive approximate kinetic equations. In zeroth approximation the standard nonlnear Boltzmann equation is obtained; the next approximation yields the ring kinetic equation, similar to that for hard-sphere systems, describing the time evolution of pair correlations. The ring equation is solved to determine the (nonvanishing) pair correlation functions in equilibrium for two models that violate semidetailed balance. One is a model of interacting random walkers on a line, the other one is a two-dimensional fluid-type model on a triangular lattice. The numerical predictions agree very well with computer simulations.     

Integrable extensions of N = 2 supersymmetric KdV hierarchy associated with the nonuniqueness of the roots of the Lax operator

We present new supersymmetric integrable extensions of the a = 4, N = 2 KdV hierarchy. The root of the supersymmetric Lax operator of the KdV equation is generalized, by including additional fields. This generalized root generates a new hierarchy of integrable equations, for which we investigate the Hamiltonian structure. In a special case our system describes the interaction of the KdV equation with the two MKdV equations.     

Non-interacting dimer kinetics in hypercubic lattices

The exact formulation of the kinetic of dimer in hypercubic lattices is developed in the framework of the kinetic lattice gas model. The so-called local evolution rules are used to obtain the hierarchy of equation of motion for the correlation functions where processes like adsorption and desorption are included. The hierarchy of equations are truncated using a mean field (m, n) closures which allows the analytical treatment of the system. A general expression for non-interacting dimer isotherm and two particle correlation functions are obtained in hypercubic lattices.     

Green function theory of dynamic conductivity

The transport processes can be discussed either by kinetic equation method or by correlation function method. Using the former, linear transport equations are developed for the study of dynamic conductivity of a quantum imperfect gas employing a resolution of BBGKY hierarchy using Green functions. From this transport equation a modified form of Kubo (correlation function) formula is obtained to show the equivalence between the two methods. This equivalence may be used for the justification of the concept of adiabatic switching of the field. The simple formula derived, gives the conductivity in terms of one-particle Green function, unlike the usual discussions which express it in higher order Green functions.     

Comments on the Grad procedure for the Fokker-Planck equation

If the kinetic equation of a macroscopic system is expanded with respect to the velocity in terms of orthogonal functions, e.g., in terms of Hermite functions, one obtains an infinite hierarchy of equations for the expansion coefficients. Grad's method consists in truncating this hierarchy and investigating the remaining finite system. In this paper we set up conditions under which this procedure is rigorously justified in case of the Fokker-Planck equation.     

Connected kernel methods in nuclear reactions: (III). Effective interactions

The recently derived connected kernel equation (CKE) for N-body scattering operators is applied to direct nuclear reactions. A spectral representation is derived for the kernel of the CKE in order to obtain manageable approximations. This allows the kernel to be split into orders corresponding to the propagation of different numbers of bound clusters. By formally solving one part of the kernel at a time, the CKE is written as a hierarchy of nested equations in increasingly many variables. The first equation of this hierarchy is a set of coupled channel Lippmann-Schwinger equations coupling together all two-cluster channels. These equations reduce to the usual coupled channel equations for inelastic scattering and to the coupled channel Born approximation for rearrangement reactions when weak coupling assumptions are made. The second equation of the hierarchy is a two-variable integral equation for the effective interactions appearing in the coupled channel equations. The driving terms and kernel of this integral equation are obtained from the third equation of the hierarchy which is a three-variable integral equation and so forth. The use of the spectral expansion results in a renormalized theory in the sense that the bound state and reaction problems are separated. This permits the inclusion of nuclear models in the theory in a straightforward manner. The hierarchy is applied to a particular example, that of nucleon-nucleus scattering. For this case the hierarchy is truncated at the level allowing no more than three clusters in the continuum. By suppressing exchange and keeping only one-particle transfer and single-nucléon knockout channels, a set of equations for the optical potentials and transfer operators is obtained. These equations provide a three-body treatment of the single scattering approximation to the optical potential. Iteration of the equations yields the usual single scattering approximation in first order including three-body off-shell effects. After suppression of Fermi motion and off-shell effects, the standard impulse approximation is recovered. Modifications of the method for other cases are discussed and other possible applications suggested.     

An alternative construction of the Percus-Yevick equation based on the equilibrium BBGKY hierarchy

The existing derivations of the Percus-Yevick equation are not readily extendable into the nonequilibrium domain. In particular, the elegant Percus functional construction relies on a test particle theorem which lacks an exact nonequilibrium generalization. We propose here a new construction which utilizes some elementary ideas of functional expansions together with the equilibrium BBGKY hierarchy of equations. Also, we feel this new construction provides fresh insight into the physical basis of the equilibrium Percus-Yevick equation.This research was supported in part by a grant from the Faculty Research Award Program of the City University of New York.     

Statistical mechanics of a relativistic magnetized plasma and its radiation field

A relativistic BBGKY hierarchy for the system of a magnetized plasma plus radiation is developed in a manifestly covariant way. It is based on the Abraham-Lorentz-Dirac equation. Simple kinetic equations are obtained and briefly analysed.     

On the kinetics of spinodal decomposition

We discuss the kinetics of phase separation based on the mechanism of spinodal decomposition. The starting point is Boltzmann's transport equation. A perturbation theory will be developed leading to a hierarchy of differential equations for the local density. The first member of this hierarchy is a nonlinear wave-type equation, which linearized version will be solved in order to discuss the behaviour of the amplification factor. Additionally, we compare our results with those of standard diffusion-type approximations and molecular dynamics calculations.Research supported in part by National Science Foundation, Grant ENG-7 515 882-A01     

The Hamiltonian structure associated to evolution-type Lagrangians

It is demonstrated that, for a certain class of Lagrangians, which includes those for the Korteweg-de Vries (KdV) hierarchy, the Hamiltonian structure provided by the Hamilton-Cartan formalism is precisely the one discovered by Gardner for the KdV equation. A simple geometric relation between the Cartan 2-forms for this class of Lagrangians and the Cartan 1-forms for the associated stationary problems is given. This relation provides a new proof of the theorem of Bogoyavlenski-Novikov and Gel'fand-Dikii on the integrability of the stationary Korteweg-de Vries equations.Research supported by the Natural Sciences and Engineering Research Council of Canada.     

Transport Equations of Plasma in a Curvilinear Magnetic Field

The problem of transport equations of a collisional plasma in a curvilinear magnetic field is studied. Two main approaches to this problem are presented: that based on using the Boltzmann kinetic equation and the drift kinetic equation approach. In the frame of the first approach a multimoment transport equation set is found which is more general than the transport equation sets of Braginskii and Grad. The tensor equations of this set are described in an arbitrary curvilinear coordinate system. This allow to use these equations in problems of a plasma confined in toroidal magnetic configurations. Simplification of the multimoment transport equation set in the case of high magnetic field is performed. In the frame of the drift kinetic equation approach, a generalization of the drift transport equations derived earlier by the authors (Zh. Eksp. Teor. Fiz. 83 (1982) 139) is given.     

A new hierarchy system on the basis of a “Master” Boltzmann equation for microscopic density

It is shown that Boltzmann's equation written in terms of microscopic density (namely the unaveraged Boltzmann function) has a wider range of validity as well as finer resolvability for fluctuations than the conventional Boltzmann equation governing Boltzmann's function. In fact the new Boltzmann equation for ideal gases has implications as a microscopically exact continuity equation like Klimontovich's equation for plasmas, and can be derived without invoking any statistical concepts, e.g., distribution functions, or molecular chaos. The Boltzmann equation in the older formalism is obtained by averaging this equation only under a restricted condition of the molecular chaos. The new Boltzmann equation is seen to contain information comparable with Liouville's equation, and serves as a master kinetic equation. A new hierarchy system is formulated in a certain parallelism to the BBGKY hierarchy. They are shown to yield an identical one-particle equation. The difference between the two hierarchy systems first appears in the two-particle equation. The difference is twofold. First, the present formalism includes thermal fluctuations that are missing in the BBGKY formalism. Second, the former allows us to formulate multi-time correlations as well, whereas the latter is restricted to simultaneous correlation. These two features are favorably utilized in deriving the Landau-Lifshitz fluctuation law in a most straightforward manner. Also, equations describing the nonequilibrium interaction between thermal and fluid-dynamical fluctuations are derived.     

Analytical and Numerical Studies of the One-Dimensional Spin Facilitated Kinetic Ising Model

The one-dimensional spin facilitated kinetic Ising model is studied analytically using the master equation and by simulations. The local state of the spins (corresponding to mobile and immobile cells) can change depending on the state of the neighbored spins, which reflects the high cooperativity inherent in glassy materials. The short-time behavior is analyzed using a Fock space representation for the master equation. The hierarchy of evolution equations for the averaged spin state and the time dependence of the spin autocorrelation function are calculated with different methods (mean-field theory, expansion in powers of the time, partial summation) and compared with numerical simulations. The long-time behavior can be obtained by mapping the one-dimensional spin facilitated kinetic Ising model onto a one-dimensional diffusion model containing birth and death processes. The resulting master equation is solved by van Kampen's size expansion, which leads to a Langevin equation with Gaussian noise. The predicted autocorrelation function and the global memory offer in the long-time limit a screened algebraic decay and a stretched exponential decay, respectively, consistent with numerical simulations.     

A stochastic approach to the kinetic theory of gases

A theory of fluctuations in non-equilibrium diluted gases is presented. The velocity distribution function is treated as a stochastic variable and a master equation for its probability is derived. This evolution equation is based on two processes: binary hard sphere collisions and free flow. A mean-field approximation leads to a non-linear master equation containing explicitly a parameter which represents the spatial correlation length of the fluctuations. An infinite hierarchy of equations for the successive moments is found. If the correlation length is sufficiently short a truncation after the first equation is possible and this leads to the Boltzmann kinetic equation. The associated probability distribution is Poissonian. As to the fluctuation of the macroscopic quantities, an approximation scheme permits to recover the Langevin approach of fluctuating hydrodynamics near equilibrium and its fluctuation-dissipation relations.