Wave Mechanics or Wave Statistical Mechanics

By comparison between equations of motion of geometrical optics and that of classical statistical mechanics, this paper finds that there should be an analogy between geometrical optics and classical statistical mechanics instead of geometrical mechanics and classical mechanics. Furthermore, by comparison between the classical limit of quantum mechanics and classical statistical mechanics, it finds that classical limit of quantum mechanics is classical statistical mechanics not classical mechanics, hence it demonstrates that quantum mechanics is a natural generalization of classical statistical mechanics instead of classical mechanics. Thence quantum mechanics in its true appearance is a wave statistical mechanics instead of a wave mechanics.     

Wave Mechanics or Wave Statistical Mechanics

By comparison between equations of motion of geometrical optics and that of classical statistical mechanics, this paper finds that there should be an analogy between geometrical optics and classical statistical mechanics instead of geometrical mechanics and classical mechanics. Furthermore, by comparison between the classical limit of quantum mechanics and classical statistical mechanics, it finds that classical limit of quantum mechanics is classical statistical mechanics not classical mechanics, hence it demonstrates that quantum mechanics is a natural generalization of classical statistical mechanics instead of classical mechanics. Thence quantum mechanics in its true appearance is a wave statistical mechanics instead of a wave mechanics.     

The renormalization group and the ϵ expansion

The modern formulation of the renormalization group is explained for both critical phenomena in classical statistical mechanics and quantum field theory. The expansion in ? = 4?d is explained [d is the dimension of space (statistical mechanics) or space-time (quantum field theory)]. The emphasis is on principles, not particular applications. Sections 1–8 provide a self-contained introduction at a fairly elementary level to the statistical mechanical theory. No background is required except for some prior experience with diagrams. In particular, a diagrammatic approximation to an exact renormalization group equation is presented in sections 4 and 5; sections 6–8 include the approximate renormalization group recursion formula and the Feyman graph method for calculating exponents. Sections 10–13 go deeper into renormalization group theory (section 9 presents a calculation of anomalous dimensions). The equivalence of quantum field theory and classical statistical mechanics near the critical point is established in section 10; sections 11–13 concern problems common to both subjects. Specific field theoretic references assume some background in quantum field theory. An exact renormalization group equation is presented in section 11; sections 12 and 13 concern fundamental topological questions.     

On the measurability of quantum correlation functions

The concept of correlation function is widely used in classical statistical mechanics to characterize how two or more variables depend on each other. In quantum mechanics, on the other hand, there are observables that cannot be measured at the same time; the so-called incompatible observables. This prospect imposes a limitation on the definition of a quantum analog for the correlation function in terms of a sequence of measurements. Here, based on the notion of sequential weak measurements, we circumvent this limitation by introducing a framework to measure general quantum correlation functions, in principle, independently of the state of the system and the operators involved. To illustrate, we propose an experimental configuration to obtain explicitly the quantum correlation function between two Pauli operators, in which the input state is an arbitrary mixed qubit state encoded on the polarization of photons.     

Quantum Dynamics and Kinematics from a Statistical Model Selected by the Principle of Locality

Quantum mechanics predicts correlation between spacelike separated events which is widely argued to violate the principle of local causality. By contrast, here we shall show that the Schrödinger equation with Born’s statistical interpretation of wave function and uncertainty relation can be derived from a statistical model of microscopic stochastic deviation from classical mechanics which is selected uniquely, up to a free parameter, by the principle of Local Causality. Quantization is thus argued to be physical and Planck constant acquires an interpretation as the average stochastic deviation from classical mechanics in a microscopic time scale. Unlike canonical quantization, the resulting quantum system always has a definite configuration all the time as in classical mechanics, fluctuating randomly along a continuous trajectory. The average of the relevant physical quantities over the distribution of the configuration are shown to be equal numerically to the quantum mechanical average of the corresponding Hermitian operators over a quantum state.     

Dynamical pair correlations of classical and quantum fluids perturbed with weak long-range forces

We study time dependent correlation functions of ideal classical and quantum gases using methods of equilibrium statistical mechanics. The basis for this is the path integral formalism of quantum mechanical systems. By this approach the statistical mechanics of a quantum mechanical system becomes the equivalent of a classical polymer problem in four dimensions where imaginary time is the fourth dimension. Several non-trivial results for quantum systems have been obtained earlier by this analogy. Here we will focus upon particle dynamics. First ideal gases are considered. Then interactions, that are assumed weak and of long range, are added, and methods of classical statistical mechanics are applied to obtain the leading contribution. Comparison is performed with known results of kinetic theory. These results demonstrate how methods developed for systems in thermal equilibrium also is applicable outside equilibrium. Thus, more generally, we have reason to expect that these methods will be accurate and useful for other situations of interacting many-body systems consisting of quantized particles too. To indicate so we sketch the computation of the induced Casimir force between parallel plates filled with ions for the situation where the ions are quantized, but the interaction remains electrostatic. Further in this respect we establish expressions for a leading correction to ab initio calculations for the energies of the quantized electrons of molecules. To our knowledge these two latter applications go beyond earlier results.     

Anomalous isotropic luminescence from anthracene sandwich dimers

A classical statistical probability amplitude is introduced whose square modulus is the distribution function. This enables the analogy between classical statistical mechanics and quantum mechanics to be completed. The analogy is developed until quantum statistical derivations can be used in classical statistical mechanics. Two master equations are found: the classical equivalent of the Pauli Master Equation, and a generally valid master equation. Well-known classical equations are deduced from these in a special representation. Interference terms are found and discussed.     

Unification theory of classical statistical uncertainty relation and quantum uncertainty relation and its applications

General classical statistical uncertainty relation is deduced and generalized to quantum uncertainty relation. We give a general unification theory of the classical statistical and quantum uncertainty relations, and prove that the classical limit of quantum mechanics is just classical statistical mechanics. It is shown that the classical limit of the general quantum uncertainty relation is the general classical uncertainty relation. Also, some specific applications show that the obtained theory is self-consistent and coincides with those from physical experiments.     

Interpretation of the hydrodynamical formalism of quantum mechanics

The hydrodynamical formalism for the quantum theory of a nonrelativistic particle is considered, together with a reformulation of it which makes use of the methods of kinetic theory and is based on the existence of the Wigner phase-space distribution. It is argued that this reformulation provides strong evidence in favor of the statistical interpretation of quantum mechanics, and it is suggested that this latter could be better understood as an almost classical statistical theory. Moreover, it is shown how, within this context, the Wigner and the Margenau-Hill functions are not equivalent, and that the latter is essentially unsatisfactory, as well as the associated symmetrization rule. Arguments in favor of a stochastic picture of the phenomena at the microscopic level are also presented.     

Probability and logical structure of statistical theories

A characterization of statistical theories is given which incorporates both classical and quantum mechanics. It is shown that each statistical theory induces an associated logic and joint probability structure, and simple conditions are given for the structure to be of a classical or quantum type. This provides an alternative for the quantum logic approach to axiomatic quantum mechanics. The Bell inequalities may be derived for those statistical theories that have a classical structure and satisfy a locality condition weaker than factorizability. The relation of these inequalities to the issue of hidden variable theories for quantum mechanics is discussed and clarified.     

Stochastic phase spaces and master Liouville spaces in statistical mechanics

The concept of probability space is generalized to that of stochastic probability space. This enables the introduction of representations of quantum mechanics on stochastic phase spaces. The resulting formulation of quantum statistical mechanics in terms of -distribution functions bears a remarkable resemblance to its classical counterpart. Furthermore, both classical and quantum statistical mechanics can be formulated in one and the same master Liouville space overL ²(). A joint derivation of a classical and quantum Boltzman equation provides an illustration of the practical uses of these formalisms.Supported in part by an NRC grant.     

Molecular dynamics studies of thermal conductivity time correlation functions

The Green–Kubo time correlation function for the thermal conductivity in liquid argon is studied for a thermodynamic state close to the triple point by standard molecular dynamics simulations. The collective heat flux vector has been separated into contributions originated at the kinetic energy, the intermolecular potential and the pair virial function. Furthermore, the Green–Kubo time correlation functions have been broken down into partial n-body terms (n=1,2,3,4). The most important contribution to the thermal conductivity is represented by the auto correlation of the virial term. In contrast to other collective phenomena described by time correlation functions involving n-body terms, the partial Green–Kubo time correlation functions for the thermal conductivity are not affected by exponential long-time tails.     

Equations for generating functionals in classical and quantum statistical mechanics

This paper develops a formalism for the generating functionals for partial distribution functions in classical statistical mechanics and partial density matrices in quantum statistical mechanics. For the case of a large canonical ensemble, functional equations are written with respect to the functionals introduced. Each functional system creates a system of integral equations for distribution functions or density matrices.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii Fizika, No. 9, pp. 98–102, September, 1971.     

Diagram Expansions in Nonequilibrium Statistical Mechanics Classical Limit Considerations

A diagram expansion is proposed for calculating traces of the kind Tr{Ae^?itLB} which are of interest for calculating time correlation functions and expectation values in nonequilibrium statistical mechanics. Arbitrary initial conditions are considered. In the classical limit the diagram expansion of FUJITA is obtained. A systematic method for obtaining quantum corrections including exchange and symmetry effects is proposed.     

Contextuality in Classical Physics and Its Impact on the Foundations of Quantum Mechanics

It is shown that the hallmark quantum phenomenon of contextuality is present in classical statistical mechanics (CSM). It is first shown that the occurrence of contextuality is equivalent to there being observables that can differentiate between pure and mixed states. CSM is formulated in the formalism of quantum mechanics (FQM), a formulation commonly known as the Koopman–von Neumann formulation (KvN). In KvN, one can then show that such a differentiation between mixed and pure states is possible. As contextuality is a probabilistic phenomenon and as it is exhibited in both classical physics and ordinary quantum mechanics (OQM), it is concluded that the foundational issues regarding quantum mechanics are really issues regarding the foundations of probability.     

Much Polyphony but Little Harmony: Otto Sackur’s Groping for a Quantum Theory of Gases

The endeavor of Otto Sackur (1880–1914) was driven, on the one hand, by his interest in Nernst’s heat theorem, statistical mechanics, and the problem of chemical equilibrium and, on the other hand, by his goal to shed light on classical mechanics from the quantum vantage point. Inspired by the interplay between classical physics and quantum theory, Sackur chanced to expound his personal take on the role of the quantum in the changing landscape of physics in the turbulent 1910s. We tell the story of this enthusiastic practitioner of the old quantum theory and early contributor to quantum statistical mechanics, whose scientific ontogenesis provides a telling clue about the phylogeny of his contemporaries.     

Classical Mechanics Without Determinism

Classical statistical particle mechanics in the configuration space can be represented by a nonlinear Schrödinger equation. Even without assuming the existence of deterministic particle trajectories, the resulting quantum-like statistical interpretation is sufficient to predict all measurable results of classical mechanics. In the classical case, the wave function that satisfies a linear equation is positive, which is the main source of the fundamental difference between classical and quantum mechanics.