Approximate solutions for drag coefficient of bubbles moving in shear-thinning elastic fluids

The drag coefficient for bubbles with mobile or immobile interface rising in shear-thinning elastic fluids described by an Ellis or a Carreau model is discussed. Approximate solutions based on linearization of the equations of motion are presented for the highly elastic region of flow. These solutions are in reasonably good agreement with the theoretical predictions based on variational principles and with published experimental data. C _D Drag coefficient - E ^* Differential operator [E ^{* 2} = ²/² + (sin/ ²)/(1/sin /)] - El Ellis number - F _D Drag force - K Consistency index in the power-law model for non-Newtonian fluid - n Flow behaviour index in the Carreau and power-law models - P Dimensionless pressure [=(p – p ₀)/₀ (U /R)] - p Pressure - R Bubble radius - Re ₀ Reynolds number [= 2R U /₀] - Re Reynolds number defined for the power-law fluid [= (2R) ⁿ U ^2–n /K] - r Spherical coordinate - t Time - U Terminal velocity of a bubble - u Velocity - Wi Weissenberg number - Ellis model parameter - Rate of deformation - Apparent viscosity - ₀ Zero shear rate viscosity - Infinite shear rate viscosity - Spherical coordinate - Parameter in the Carreau model - ^* Dimensionless time [=/(U /R)] - Dimensionless length [=r/R] - Second invariant of rate of deformation tensors - ^* Dimensionless second invariant of rate of deformation tensors [=/(U /R)²] - Second invariant of stress tensors - ^* Dimensionless second invariant of second invariant of stress tensor [= / ₀ ² (U /R)²] - Fluid density - Shear stress - ^* Dimensionless shear stress [=/ ₀ (U /R)] - _1/2 Ellis model parameter - ₁ ^2/* Dimensionless Ellis model parameter [= _1/2/ ₀(U /R)] - Stream function - ^* Dimensionless stream function [=/U R ²]     

Transport in ordered and disordered porous media II: Generalized volume averaging

In this paper we develop the averaged form of the Stokes equations in terms of weighting functions. The analysis clearly indicates at what point one must choose a media-specific weighting function in order to achieve spatially smoothed transport equations. The form of the weighting function that produces the cellular average is derived, and some important geometrical theorems are presented.Roman Letters A interfacial area of the- interface associated with the local closure problem, m² - A _e area of entrances and exits for the-phase contained within the averaging system, m² - A _p surface area of a particle, m² - d _p 6V _p/A_p, effective particle diameter, m - g gravity vector, m/s² - I unit tensor - K _m permeability tensor for the weighted average form of Darcy's law, m² - L general characteristic length for volume averaged quantities, m - L _p general characteristic length for volume averaged pressure, m - L characteristic length for the porosity, m - L _v characteristic length for the volume averaged velocity, m - l characteristic length (pore scale) for the-phase - l _i i=1, 2, 3 lattice vectors, m - (y) weighting function - m(–y) (y), convolution product weighting function - _v special weighting function associated with the traditional averaging volume - m _v special convolution product weighting function associated with the traditional averaging volume - m _g general convolution product weighting function - m _V unit cell convolution product weighting function - m _C special convolution product weighting function for ordered media which produces the cellular average - m _D special convolution product weighting function for disordered media - m _M master convolution product weighting function for ordered and disordered media - n unit normal vector pointing from the-phase toward the-phase - p pressure in the-phase, N/m² - p_m superficial weighted average pressure, N/m² - p _m intrinsic weighted average pressure, N/m² - p traditional intrinsic volume averaged pressure, N/m² - p p p _m , spatial deviation pressure, N/m² - r ₀ radius of a spherical averaging volume, m - r _m support of the convolution product weighting function, m - r position vector, m - r position vector locating points in the-phase, m - V averaging volume, m³ - V volume of the-phase contained in the averaging volume, m³ - V _cell volume of a unit cell, m³ - V velocity vector in the-phase, m/s - vm superficial weighted average velocity, m/s - v _m intrinsic weighted average velocity, m/s - V volume of the-phase contained in the averaging volume, m³ - V _p volume of a particle, m³ - v traditional superficial volume averaged velocity, m/s - v v p _m spatial deviation velocity, m/s - x position vector locating the centroid of the averaging volume or the convolution product weighting function, m - y position vector relative to the centroid, m - y position vector locating points in the-phase relative to the centroid, m Greek Letters indicator function for the-phase - Dirac distribution associated with the- interface - V /V, volume average porosity - _m m * . weighted average porosity - mass density of the-phase, kg/m³ - viscosity of the-phase, Ns/m² - V /V, volume fraction of the-phase     

Flow in porous media III: Deformable media

Stokes flow in a deformable medium is considered in terms of an isotropic, linearly elastic solid matrix. The analysis is restricted to steady forms of the momentum equations and small deformation of the solid phase. Darcy's law can be used to determine the motion of the fluid phase; however, the determination of the Darcy's law permeability tensor represents part of the closure problem in which the position of the fluid-solid interface must be determined.Roman Letters A interfacial area of the- interface contained within the macroscopic system, m² - A interfacial area of the- interface contained within the averaging volume, m² - A _e area of entrances and exits for the-phase contained within the macroscopic system, m² - A ^* interfacial area of the- interface contained within a unit cell, m² - A _e ^* area of entrances and exits for the-phase contained within a unit cell, m² - E Young's modulus for the-phase, N/m² - e i unit base vectors (i = 1, 2, 3) - g gravity vector, m²/s - H height of elastic, porous bed, m - k unit base vector (=e ₃) - characteristic length scale for the-phase, m - L characteristic length scale for volume-averaged quantities, m - n unit normal vector pointing from the-phase toward the-phase (n = -n ) - p pressure in the-phase, N/m² - P p – g·r, N/m² - r ₀ radius of the averaging volume, m - r position vector, m - t time, s - T total stress tensor in the-phase, N/m² - T ⁰ hydrostatic stress tensor for the-phase, N/m² - u displacement vector for the-phase, m - V averaging volume, m₃ - V volume of the-phase contained within the averaging volume, m³ - v velocity vector for the-phase, m/s Greek Letters V /V, volume fraction of the-phase - mass density of the-phase, kg/m³ - shear coefficient of viscosity for the-phase, Nt/m² - first Lamé coefficient for the-phase, N/m² - second Lamé coefficient for the-phase, N/m² - bulk coefficient of viscosity for the-phase, Nt/m² - T –T ⁰ , a deviatoric stress tensor for the-phase, N/m²     

Mass transport and reaction in catalyst pellets

When heterogeneous chemical reactions take place in porous catalysts, mass transport can occur by bulk diffusion, Knudsen diffusion, and convective transport. Previous studies of these phenomena have been largely based on Maxwell's dusty gas model with the convective transport or Darcy flow added to the diffusive transport. This is done in order to satisfy one of the limiting conditions encountered in the study of flow in porous media. A more fundamental approach consists of the use of the method of volume averaging and the general form of the species momentum equation. For an N-component system, this leads to N independent flux relations to be used in conjunction with the volume-averaged species continuity equations.Roman Letters _A (t) surface area of a species body, m² - a _v interfacial area per unit volume, m^-1 - A _e area of entrances and exits for the -phase contained within the averaging volume, m² - A _K area of the - surface contained within the averaging volume, m² - b _A species A body force, N/kg - b mass average body force, N/kg - B inverse tortuosity tensor for bulk diffusion - c total molar concentration, moles/m³ - c _A species A molar concentration, moles/m³ - _A surface concentration of species A, moles/m² - C_A² intrinsic phase average molar concentration, moles/m³ - c _A – C_A², spatial deviation concentration, moles/m³ - c _A mean molecular speed for species A, m/s - binary diffusion coefficient, m²/s - D _A ^{K, eff} Knudsen diffusion coefficient for species A, m²/s - f vector that maps P _A into P _A , m - g gravitational vector, m/s² - G second order tensor that maps N _A into N _A for free molecule flow conditions - H inverse tortuosity tensor for Knudsen diffusion - I unit tensor - j _A c _A u _A ^* , molar diffusive flux, moles/m²s - K Darcy's Law permeability tensor, m² - L macroscopic length scale, m - L _D diffusive length, m - l characteristic length for the -phase, m - l _A mean free path for species A, m - M _A molecular weight of species A, kg/mole - n outwardly directed unit normal vector - n _K unit normal vector directed from the -phase toward the -phase - n outwardly directed unit normal vector at the entrances and exits of the -phase contained within the averaging volume - N _A c _A v _A molar flux of species A, moles/m²s - N _A intrinsic phase average of the species A molar flux, moles/m²s - \~N _A spatial deviation of the molar flux of species A, moles/m²s - p total pressure, N/m² - P p + , total pressure over and above the hydrostatic pressure, N/m² - P _A partial pressure of species A, N/m² - p _A intrinsic phase average partial pressure, N/m² - P_A – p _A, spatial deviation partial pressure, N/m² - P _A p_A + _AA partial pressure of species A over and above the hydrostatic pressure of species A, N/m² - p _ab diffusive force exerted by species B on species A, N/m³ - universal gas constant, N m/moles K - R _A molar rate of production of species A owing to homogeneous chemical reaction, moles/m³s - molar rate of production of species A owing to heterogeneous chemical reaction, moles/m²s - r _A mass rate of production of species A owing to homogeneous chemical reaction, kg/m³s - r ₀ radius of the averaging volume, m - r position vector, m - t time, s - t _A species stress vector, N/m² - T _A species stress tensor, N/m² - T total stress tensor, N/m² - T temperature, K - T spatial average temperature, K - u _A v _A – v, mass diffusion velocity, m/su _A ^* v_A – v^*, molar diffusion velocity, m/s - u _o velocity of the rigid, solid phase relative to some inertial frame, m/s - v _A species velocity, m/s - v mass average velocity, m/s - v ^* molar average velocity, m/s - v _A ^* species velocity of those molecules of species A generated by chemical reaction, m/s - _A (t) volume of a species A body, m³ - averaging volume, m³ - V volume of the -phase contained within the averaging volume, m³ - V volume of the -phase contained within the averaging volume, m³ - v phase average, mass average velocity, m/s - w arbitrary velocity vector, m/s - x _A c _A /c mole fraction of species A - X _A intrinsic phase average mole fraction - X _A – X _A , spatial deviation mole fraction Greek Letters V/V volume fraction of the -phase - _A sum of all terms in the species A momentum equation that are small compared to the diffusive force, N/m³ - viscosity of the -phase, Ns/m² - _A mass density of species A, kg/m³ - total mass density, kg/m³ - _a species viscous stress tensor, N/m² - total viscous stress tensor, N/m² - tortuosity factor - total body force potential function, Nm/kg - _a species body force potential function, Nm/kg - 3.1416 - _{a a} / mass fraction of species A     

Flow over a body with development of a steady separation zone as re → ∞

This paper discusses formulation of the total problem of flow of an incompressible liquid over a body, with formation of a closed stationary separation zone as Re . The scheme used is based on the method of matched asymptotic expansions [1]. Following [1], it is postulated that the separated zone is developed (i.e., it is not infinitely fragmented and does not vanish as Re ), and the flow inside it has a definite degree of regularity with respect to Re. With these hypotheses we can use the Prandtl-Batchelor theorem [2], which states that, in the limit as Re , a region of circulating flow becomes vortex flow of an inviscid liquid with constant vorticity . Therefore, a basis for constructing matched asymptotic expansions is the vortex-potential problem (the problem of determining a stream function , satisfying the equation = 0 in the region of translational motion and the equation = in a certain region, unknowna priori, of circulating motion). In the general case the solution of the vortex-potential problem depends on two parameters: the total pressure p_o and the vorticity in the separated zone. These parameters appear in the condition for matching the solutions of the first and second boundary-layer approximations (at the boundary of the separated zone for the end Re values) with the corresponding solutions for the inviscid flow. It is shown in the present paper that the conditions for matching the cyclic boundary layer with the external translational flow are the same additional relations which allow us to close the total problem. Thus, in using the method of matched asymptotic expansions to solve the problem of flow over a body with closed stationary separation zones one must simultaneously consider no less than two approximations.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 2, pp. 28–37, March–April, 1978.The authors thank G. Yu. Stepanov for discussion of the paper and valuable comments.     

Diffuse approximation method for solving natural convection in porous media

The diffuse approximation is presented and applied to natural convection problems in porous media. A comparison with the control volume-based finite-element method shows that, overall, the diffuse approximation appears to be fairly attractive.Nomenclature H height of the cavities - I functional - K permeability - p(M _i ,M) line vector of monomials - p ^T p-transpose - M current point - Nu Nusselt number - Ri inner radius - Ro outer radius - Ra Rayleigh number - x, y cartesian coordinates - u, v velocity components - T temperature - M vector of estimated derivatives - _t thermal diffusivity - coefficient of thermal expansion - practical aperture of the weighting function - scalar field - (M, M _i ) weighting function - streamfunction - kinematic viscosity     

Determination of permeability tensors for two-phase flow in homogeneous porous media: Theory

In this paper we continue previous studies of the closure problem for two-phase flow in homogeneous porous media, and we show how the closure problem can be transformed to a pair of Stokes-like boundary-value problems in terms of pressures that have units of length and velocities that have units of length squared. These are essentially geometrical boundary value problems that are used to calculate the four permeability tensors that appear in the volume averaged Stokes' equations. To determine the geometry associated with the closure problem, one needs to solve the physical problem; however, the closure problem can be solved using the same algorithm used to solve the physical problem, thus the entire procedure can be accomplished with a single numerical code.Nomenclature a a vector that maps V onto , m^-1. - A a tensor that maps V onto . - A area of the - interface contained within the macroscopic region, m². - A area of the -phase entrances and exits contained within the macroscopic region, m². - A area of the - interface contained within the averaging volume, m². - A area of the -phase entrances and exits contained within the averaging volume, m². - Bo Bond number (= (=(–)g²/). - Ca capillary number (= v/). - g gravitational acceleration, m/s². - H mean curvature, m^-1. - I unit tensor. - permeability tensor for the -phase, m². - viscous drag tensor that maps V onto V. - ^* dominant permeability tensor that maps onto v , m². - ^* coupling permeability tensor that maps onto v , m². - characteristic length scale for the -phase, m. - l characteristic length scale representing both and , m. - L characteristic length scale for volume averaged quantities, m. - n unit normal vector directed from the -phase toward the -phase. - n unit normal vector representing both n and n . - n unit normal vector representing both n and n . - P pressure in the -phase, N/m². - p superficial average pressure in the -phase, N/m². - p intrinsic average pressure in the -phase, N/m². - p –p , spatial deviation pressure for the -phase, N/m². - r ₀ radius of the averaging volume, m. - r position vector, m. - t time, s. - v fluid velocity in the -phase, m/s. - v superficial average velocity in the -phase, m/s. - v intrinsic average velocity in the -phase, m/s. - v –v , spatial deviation velocity in the -phase, m/s. - V volume of the -phase contained within the averaging volmue, m³. - averaging volume, m³. Greek Symbols V /, volume fraction of the -phase. - viscosity of the -phase, Ns/m². - density of the -phase, kg/m³. - surface tension, N/m. - (v +v ^T ), viscous stress tensor for the -phase, N/m².     

The virtual origin of riblets in an open channel flow

In this paper, a method using the mean velocity profiles for the buffer layer was developed for the estimation of the virtual origin over a riblets surface in an open channel flow. First, the standardized profiles of the mixing length were estimated from the velocity measurement in the inner layer, and the location of the edge of the viscous layer was obtained. Then, the virtual origins were estimated by the best match between the measured velocity profile and the equations of the velocity profile derived from the mixing length profiles. It was made clear that the virtual origin and the thickness of the viscous layer are the function of the roughness Reynolds number. The drag variation coincided well with other results.Nomenclature f _r skin friction coefficient - f _ro skin friction coefficient in smooth channel at the same flow quantity and the same energy slope - g gravity acceleration - H water depth from virtual origin to water surface - H ⁺ u*H/ - H false water depth from top of riblets to water surface - H ⁺ u*H/ - I _e streamwise energy slope - I _b bed slope - k riblet height - k ⁺ u*k/ - l mixing length - l _s standardized mixing length - Q flow quantity - Re Reynolds number volume flow/unit width/v - s riblet spacing - u mean velocity - u* friction velocity = - u* false friction velocity = - y distance from virtual origin - y distance from top of riblet - y ₀ distance from top of riblet to virtual origin - y _v distance from top of riblet to edge of viscous layer - y ⁺ u*y/ - y ⁺ u*y/ - y ₀ ⁺ u*y ₀/ - u ⁺ u*y/ - shifting coefficient for standardization - thickness of viscous layer=y ₀+y - ⁺ u*/ - ⁺ u*/ - eddy viscosity - ridge angle - v kinematic viscosity - density - shear stress     

Concentration dependence of the critical viscoelastic properties of gelatin at the gel point

Gelatin gel properties have been studied through the evolution of the storage [G()] and the loss [G()] moduli during gelation or melting near the gel point at several concentrations. The linear viscoelastic properties at the percolation threshold follow a power-law G()G() and correspond to the behavior described by a rheological constitutive equation known as the Gel Equation. The critical point is characterized by the relation: tan = G/G = cst = tan ( · /2) and it may be precisely located using the variations of tan versus the gelation or melting parameter (time or temperature) at several frequencies. The effect of concentration and of time-temperature gel history on its variations has been studied. On gelation, critical temperatures at each concentration were extrapolated to infinite gel times. On melting, critical temperatures were determined by heating step by step after a controlled period of aging. Phase diagrams [T = f(C)] were obtained for gelation and melting and the corresponding enthalpies were calculated using the Ferry-Eldridge relation. A detailed study of the variations of A with concentration and with gel history was carried out. The values of which were generally in the 0.60–0.72 range but could be as low as 0.20–0.30 in some experimental conditions, were compared with published and theoretical values.     

Effect of measuring volume length on two-component laser velocimeter measurements in a turbulent boundary layer

The effects of finite measuring volume length on laser velocimetry measurements of turbulent boundary layers were studied. Four different effective measuring volume lengths, ranging in spanwise extent from 7 to 44 viscous units, were used in a low Reynolds number (Re=1440) turbulent boundary layer with high data density. Reynolds shear stress profiles in the near-wall region show that u v strongly depends on the measuring volume length; at a given y-position, u v decreases with increasing measuring volume length. This dependence was attributed to simultaneous validations on the U and V channels of Doppler bursts coming from different particles within the measuring volume. Moments of the streamwise velocity showed a slight dependence on measuring volume length, indicating that spatial averaging effects well known for hot-films and hot-wires can occur in laser velocimetry measurements when the data density is high.List of symbols time-averaged quantity - u wall friction velocity, ( _w /)^1/2 - v kinematic viscosity - d _p pinhole diameter - l _eff spanwise extent of LDV measuring volume viewed by photomultiplier - l ⁺ non-dimensional length of measuring volume, l _eff u /v - y ⁺ non-dimensional coordinate in spanwise direction, y u /v - z ⁺ non-dimensional coordinate in spanwise direction, z u /v - U ⁺ non-dimensional mean velocity, /u - u instantaneous streamwise velocity fluctuation, U &#x2329;U - v instantaneous normal velocity fluctuation, V–V - u RMS streamwise velocity fluctuation, u ^21/2 - v RMS normal velocity fluctuation, v ^21/2 - Re Reynolds number based on momentum thickness, U 0/v - R _uv cross-correlation coefficient, u v/u v - R₁₂(0, 0, z) two point correlation between u and v with z-separation, <u(0, 0, 0) v (0, 0, z)>/<u(0, 0, 0) v (0, 0, 0)> - N rate at which bursts are validated by counter processor - T Taylor time microscale, u (dv/dt²)^–1/2     

Heteroclinic orbits in singular systems: A unifying approach

We consider singularly perturbed systems , such that=f(, _o, 0). _o ^m , has a heteroclinic orbitu(t). We construct a bifurcation functionG(, ) such that the singular system has a heteroclinic orbit if and only ifG(, )=0 has a solution=(). We also apply this result to recover some theorems that have been proved using different approaches.     

Flow in porous media II: The governing equations for immiscible,two-phase flow

The Stokes flow of two immiscible fluids through a rigid porous medium is analyzed using the method of volume averaging. The volume-averaged momentum equations, in terms of averaged quantities and spatial deviations, are identical in form to that obtained for single phase flow; however, the solution of the closure problem gives rise to additional terms not found in the traditional treatment of two-phase flow. Qualitative arguments suggest that the nontraditional terms may be important when / is of order one, and order of magnitude analysis indicates that they may be significant in terms of the motion of a fluid at very low volume fractions. The theory contains features that could give rise to hysteresis effects, but in the present form it is restricted to static contact line phenomena.Roman Letters (, = , , and ) A interfacial area of the- interface contained within the macroscopic system, m² - A _e area of entrances and exits for the -phase contained within the macroscopic system, m² - A interfacial area of the- interface contained within the averaging volume, m² - A ^* interfacial area of the- interface contained within a unit cell, m² - A _e ^* area of entrances and exits for the-phase contained within a unit cell, m² - g gravity vector, m²/s - H mean curvature of the- interface, m^–1 - H area average of the mean curvature, m^–1 - H – H , deviation of the mean curvature, m^–1 - I unit tensor - K Darcy's law permeability tensor, m² - K permeability tensor for the-phase, m² - K viscous drag tensor for the-phase equation of motion - K viscous drag tensor for the-phase equation of motion - L characteristic length scale for volume averaged quantities, m - characteristic length scale for the-phase, m - n unit normal vector pointing from the-phase toward the-phase (n = –n ) - p _c p – P , capillary pressure, N/m² - p pressure in the-phase, N/m² - p intrinsic phase average pressure for the-phase, N/m² - p – p , spatial deviation of the pressure in the-phase, N/m² - r ₀ radius of the averaging volume, m - t time, s - v velocity vector for the-phase, m/s - v phase average velocity vector for the-phase, m/s - v intrinsic phase average velocity vector for the-phase, m/s - v – v , spatial deviation of the velocity vector for the-phase, m/s - V averaging volume, m³ - V volume of the-phase contained within the averaging volume, m³ Greek Letters V /V, volume fraction of the-phase - mass density of the-phase, kg/m³ - viscosity of the-phase, Nt/m² - surface tension of the- interface, N/m - viscous stress tensor for the-phase, N/m² - / kinematic viscosity, m²/s     

Dynamic-mechanical properties of a bitumen-silica composite

Summary The dynamic-mechanical behaviour of bitumensilica composites is described by a linear biparabolic model. Its mathematical expression allows the calculation of the mean relaxation times () either at different temperatures and given filler contents or for diverse filler contents () at imposed temperatures. At fixed filler concentration and within restricted temperature domains, obeys Arrhenius' law. The activation energies are respectively close to 10 kcal/mole (creep) and 30 kcal/mole (glass-transition). varies exponentially with. The mathematical treatment of the expressions ofE , as a function of temperature and of, leads to a general equation relating the complex modulus to temperature, frequency and filler content. A unique master curve, accounting for the viscoelastic behaviour of the composites, in limited ranges, can thus be constructed.

---

Zusammenfassung Das dynamisch-mechanische Verhalten von Bitumen-Siliziumdioxyd-Zusammensetzungen kann durch ein lineares biparabolisches Modell beschrieben werden. Sein mathematischer Ausdruck erlaubt die Ausrechnung der mittleren Relaxationszeiten () entweder für verschiedene Temperaturen bei gegebenem Füllstoffgehalt oder für unterschiedliche Siliziumdioxydmengen () bei bekannter Temperatur. Für einen bestimmten Füllstoffgehalt folgt in einem beschränkten Temperaturbereich dem Arrheniusschen Gesetz. Die Aktivierungsenergien betragen näherungsweise 10 kcal/Mol (Fließprozeß) bzw. 30 kcal/Mol (Glasübergang). ändert sich exponentiell mit. Die mathematische Umformung der Ausdrücke fürE und als Funktion der Temperatur und des Parameters ergibt eine allgemeine Gleichung, die den komplexen Modul mit der Temperatur, der Frequenz und dem Füllstoffgehalt verknüpft. Man kann eine einzige Masterkurve bilden, die das viskoelastische Verhalten der Zusammensetzungen zumindest in begrenzten Bereichen beschreibt.

---

Résumé Le comportement mécanique dynamique des composites à base de bitume et de silice peut être décrit par un modèle biparabolique linéaire. L'expression mathématique permet le calcul des temps moyens () de relaxation d'une part aux différentes températures, à taux de charge donné, et d'autre part pour diverses valeurs des taux de charge (paramètre) à température imposée. A taux de charge donné, et pour des domaines de température restreints, suit la loi d'Arrhénius. Les énergies apparentes d'activation sont respectivement voisines de 10 kcal/mole (processus de fluage) et de 30 kcal/mole (passage à l'état vitreux). Avec, varie exponentiellement. L'évaluation mathématique deE , de en fonction deT et de conduit à une expression générale du module complexe en fonction de la température, de la fréquence et du taux de charge. On peut donc construire une courbe maitresse unique qui décrit entièrement, mais dans des domaines restreints, le comportement viscoélastique des composites.

---

---

With 6 figures     

Transport in ordered and disordered porous media IV: Computer generated porous media for three-dimensional systems

In the method of volume averaging, the difference between ordered and disordered porous media appears at two distinct points in the analysis, i.e. in the process of spatial smoothing and in the closure problem. In theclosure problem, the use of spatially periodic boundary conditions isconsistent with ordered porous media and the fields under consideration when the length-scale constraint,r ₀L is satisfied. For disordered porous media, spatially periodic boundary conditions are an approximation in need of further study.In theprocess of spatial smoothing, average quantities must be removed from area and volume integrals in order to extractlocal transport equations fromnonlocal equations. This leads to a series of geometrical integrals that need to be evaluated. In Part II we indicated that these integrals were constants for ordered porous media provided that the weighting function used in the averaging process contained thecellular average. We also indicated that these integrals were constrained by certain order of magnitude estimates for disordered porous media. In this paper we verify these characteristics of the geometrical integrals, and we examine their values for pseudo-periodic and uniformly random systems through the use of computer generated porous media.

Nomenclature

Roman Letters A interfacial area of the- interface associated with the local closure problem, m² - A _e area of entrances and exits for the-phase contained within the averaging system, m² - a _i i=1, 2, 3 gaussian probability distribution used to locate the position of particles - I unit tensor - L general characteristic length for volume averaged quantities, m - L characteristic length for , m - L characteristic length for , m - characteristic length for the -phase particles, m - ⁰ reference characteristic length for the-phase particles, m - characteristic length for the-phase, m - _i i=1, 2, 3 lattice vectors, m - m convolution product weighting function - m _v special convolution product weighting function associated with the traditional volume average - n _i i=1, 2, 3 integers used to locate the position of particles - n unit normal vector pointing from the-phase toward the-phase - n _e outwardly directed unit normal vector at the entrances and exits of the-phase - r _p position vector locating the centroid of a particle, m - r gaussian probability distribution used to determine the size of a particle, m - r ₀ characteristic length of an averaging region, m - r position vector, m - r _m support of the weighting functionm, m - averaging volume, m³ - V volume of the-phase contained in the averaging volume,, m³ - x positional vector locating the centroid of an averaging volume, m - x ₀ reference position vector associated with the centroid of an averaging volume, m - y position vector locating points relative to the centroid, m - y position vector locating points in the-phase relative to the centroid, m Greek Letters indicator function for the-phase - Dirac distribution associated with the- interface - V /V, volume average porosity - /L, small parameter in the method of spatial homogenization - standard deviation ofa _i - _r standard deviation ofr - _r intrinsic phase average of      

Transcendentally small transversality in the rapidly forced pendulum

The rapidly forced pendulum equation with forcing sin((t/), where =<₀^p,p = 5, for ₀, sufficiently small, is considered. We prove that stable and unstable manifolds split and that the splitting distanced(t) in the ( ,t) plane satisfiesd(t) = sin(t/) sech(/2) +O( ₀ exp(–/2)) (2.3a) and the angle of transversal intersection,, in thet = 0 section satisfies 2 tan/2 = 2S _s = (/2) sech(/2) +O(( ₀ /) exp(–/2)) (2.3b) It follows that the Melnikov term correctly predicts the exponentially small splitting and angle of transversality. Our method improves a previous result of Holmes, Marsden, and Scheuerle. Our proof is elementary and self-contained, includes a stable manifold theorem, and emphasizes the phase space geometry.     

Modelling of heat transfer by conduction in a transition region between a porous medium and an external fluid

We study the modelling of purely conductive heat transfer between a porous medium and an external fluid within the framework of the volume averaging method. When the temperature field for such a system is classically determined by coupling the macroscopic heat conduction equation in the porous medium domain to the heat conduction equation in the external fluid domain, it is shown that the phase average temperature cannot be predicted without a generally negligible error due to the fact that the boundary conditions at the interface between the two media are specified at the macroscopic level.Afterwards, it is presented an alternative modelling by means of a single equation involving an effective thermal conductivity which is a function of point inside the interfacial region.The theoretical results are illustrated by means of some numerical simulations for a model porous medium. In particular, temperature fields at the microscopic level are presented.Roman Letters _sf interfacial area of thes-f interface contained within the macroscopic system m² - A _sf interfacial area of thes-f interface contained within the averaging volume m² - C _p mass fraction weighted heat capacity, kcal/kg/K - g vector that maps to _s , m - h vector that maps to _f , m - K _eff effective thermal conductivity tensor, kcal/m s K - l _s,l _f microscopic characteristic length m - L macroscopic characteristic length, m - n _fs outwardly directed unit normal vector for thef-phase at thef-s interface - n outwardly directed unit normal vector at the dividing surface. - R ₀ REV characteristic length, m - T _i macroscopic temperature at the interface, K - error on the external fluid temperature due to the macroscopic boundary condition, K - T ^* macroscopic temperature field obtained by solving the macroscopic Equation (3), K - V averaging volume, m³ - V _s,V _f volume of the considered phase within the averaging volume, m³. - _mp volume of the porous medium domain, m³ - _ex volume of the external fluid domain, m³ - _s , _f volume of the considered phase within the volume of the macroscopic system, m³ - dividing surface, m² - x, z spatial coordinates Greek Letters _s, _f volume fraction - ratio of the effective thermal conductivity to the external fluid thermal conductivity - ^* macroscopic thermal conductivity (single equation model) kcal/m s K - _s, _f microscopic thermal conductivities, kcal/m s K - spatial average density, kg/m³ - microscopic temperature, K - ^* microscopic temperature corresponding toT ^*, K - spatial deviation temperature K - error in the temperature due to the macroscopic boundary conditions, K - ^* _i macroscopic temperature at the interface given by the single equation model, K - spatial average - ^s , ^f intrinsic phase average.     

Heat conduction in a cylinder crossed by an electric current with skin effect

The steady periodic temperature distribution in an infinitely long solid cylinder crossed by an alternating current is evaluated. First, the time dependent and non-uniform power generated per unit volume by Joule effect within the cylinder is determined. Then, the dimensionless temperature distribution is obtained by analytical methods in steady periodic regime. Dimensionless tables which yield the amplitude and the phase of temperature oscillations both on the axis and on the surface of copper or nichrome cylindrical electric resistors are presented.

---

Wärmeleitung in einem stromdurchflossenen Zylinder unter Berücksichtigung des Skin-Effektes

Zusammenfassung Es wird die periodische Temperaturverteilung für den eingeschwungenen Zustand in einem unendlich langen, von Wechselstrom durchflossenen Vollzylinder ermittelt. Zuerst erfolgt die Bestimmung der zeitabhängigen, nichgleichförmigen Energiefreisetzung pro Volumeneinheit des Zylinders infolge Joulescher Wärmeentwicklung und anschließend die Ermittlung der quasistationären Temperaturverteilung auf analytischem Wege. Amplitude und Phasenverzögerung der Temperaturschwingungen werden für die Achse und die Oberfläche eines Kupfer- oder Nickelchromzylinders tabellarisch in dimensionsloser Form mitgeteilt.

---

Nomenclature A integration constant introduced in Eq. (2) - ber, bei Thomson functions of order zero - Bi Biot numberhr ₀/ - c speed of light in empty space - c ₁,c ₂ integration constants introduced in Eq. (46) - c _p specific heat at constant pressure - E electric field - E _z component ofE alongz - E time independent part ofE, defined in Eq. (1) - f function ofs and defined in Eq. (11) - g function ofs and defined in Eq. (37) - h convection heat transfer coefficient - H magnetic field - i imaginary uniti=(–1)^1/2 - I electric current - I _eff effective electric currentI _eff=I/2^1/2 - Im imaginary part of a complex number - J _n Bessel function of first kind and ordern - J electric current density - q _g power generated per unit volume - time average of the power generated per unit volume - time averaged power per unit length - r radial coordinate - R electric resistance per unit length - r ₀ radius of the cylinder - Re real part of a complex number - s dimensionless radial coordinates=r/r ₀ - s, s integration variables - t time - T temperature - time averaged temperature - T _f fluid temperature outside the boundary layer - time average of the surface temperature of the cylinder - u, functions ofs, and defined in Eqs. (47) and (48) - W Wronskian - x position vector - x real variable - Y _n Bessel function of second kind and ordern - z unit vector parallel to the axis of the cylinder - z axial coordinate - · modulus of a complex number - equal by definition Greek symbols amplitude of the dimensionless temperature oscillations - electric permittivity - dimensionless temperature defined in Eq. (16) - ₀, ₁, ₂ functions ofs defined in Eq. (22) - thermal conductivity - dimensionless parameter=(2)^1/2 - magnetic permeability - ₀ magnetic permeability of free space - function of defined in Eq. (59) - dimensionless parameter=c _p/() - mass density - electric conductivity - dimensionless time=t - phase of the dimensionless temperature oscillations - function ofs:= ₁+i ₂ - angular frequency - dimensionless parameter=()^1/2 r ₀     

Homoclinic Saddle-Node Bifurcations in Singularly Perturbed Systems

In this paper we study the creation of homoclinic orbits by saddle-node bifurcations. Inspired on similar phenomena appearing in the analysis of so-called localized structures in modulation or amplitude equations, we consider a family of nearly integrable, singularly perturbed three dimensional vector fields with two bifurcation parameters a and b. The O() perturbation destroys a manifold consisting of a family of integrable homoclinic orbits: it breaks open into two manifolds, W ^s() and W ^u(), the stable and unstable manifolds of a slow manifold . Homoclinic orbits to correspond to intersections W ^s()W ^u(); W ^s()W ^u()= for a<a*, a pair of 1-pulse homoclinic orbits emerges as first intersection of W ^s() and W ^u() as a>a*. The bifurcation at a=a* is followed by a sequence of nearby, O( ²(log)²) close, homoclinic saddle-node bifurcations at which pairs of N-pulse homoclinic orbits are created (these orbits make N circuits through the fast field). The second parameter b distinguishes between two significantly different cases: in the cooperating (respectively counteracting) case the averaged effect of the fast field is in the same (respectively opposite) direction as the slow flow on . The structure of W ^s()W ^u() becomes highly complicated in the counteracting case: we show the existence of many new types of sometimes exponentially close homoclinic saddle-node bifurcations. The analysis in this paper is mainly of a geometrical nature.     

On nonlinear problems of mixed type: A qualitative theory using infinite-dimensional center manifolds

We consider the equation a(y)u_xx+div_y(b(y)_yu)+c(y)u=g(y, u) in the cylinder (–l,l)×, being elliptic where b(y)>0 and hyperbolic where b(y)<0. We construct self-adjoint realizations in L₂() of the operatorAu= (1/a) div_y(b_yu)+(c/a) in the case ofb changing sign. This leads to the abstract problem u_xx+Au=g(u), whereA has a spectrum extending to + as well as to –. For l= it is shown that all sufficiently small solutions lie on an infinite-dimensional center manifold and behave like those of a hyperbolic problem. Anx-independent cross-sectional integral E=E(u, u_x) is derived showing that all solutions on the center manifold remain bounded forx ±. For finitel, all small solutionsu are close to a solution on the center manifold such that u(x)-(x) Ce ^-(1-|x|) for allx, whereC and are independent ofu. Hence, the solutions are dominated by hyperbolic properties, except close to the terminal ends {±1}×, where boundary layers of elliptic type appear.     

Optical co-ordinates in general relativity 2 — the problem of distance

Summary Let denote the congruence of null geodesics associated with a given optical observer inV ₄. We prove that determines a unique collection of vector fieldsM₍₎ ( =1, 2, 3) and ₍₀₎ overV ₄, satisfying a weak version of Killing's conditions.This allows a natural interpretation of these fields as the infinitesimal generators of spatial rotations and temporal translation relative to the given observer. We prove also that the definition of the fieldsM₍₎ and ₍₀₎ is mathematically equivalent to the choice of a distinguished affine parameter f along the curves of, playing the role of a retarded distance from the observer.The relation between f and other possible definitions of distance is discussed.

---

Sommario Sia la congruenza di geodetiche nulle associata ad un osservatore ottico assegnato nello spazio-tempoV ₄. Dimostriamo che determina un'unica collezione di campi vettorialiM₍₎ ( =1, 2, 3) e ₍₀₎ inV ₄ che soddisfano una versione in forma debole delle equazioni di Killing. Ciò suggerisce una naturale interpretazione di questi campi come generatori infinitesimi di rotazioni spaziali e traslazioni temporali relative all'osservatore assegnato. Dimostriamo anche che la definizione dei campiM₍₎, ₍₀₎ è matematicamente equivalente alla scelta di un parametro affine privilegiato f lungo le curve di, che gioca il ruolo di distanza ritardata dall'osservatore. Successivamente si esaminano i legami tra f ed altre possibili definizioni di distanza in grande.

---

---

Work performed in the sphere of activity of: Gruppo Nazionale per la Fisica Matematica del CNR.