Magnetic shielding studies on the alkali molecules Na2 and Cs2 by NMR

NMR in the alkali molecules Na₂ and Cs₂ is performed by the atom-molecule exchange optical pumping method. The shielding differences σ(Na)?σ(Na₂)=(29±16)·10^?6 and σ(Cs)?σ(Cs₂)=(221±12)·10^?6 are obtained. The investigation of the contribution of the valence electron to the magnetic shielding is supported by a NMR experiment in free Cs⁺ ions, which yields the shielding difference σ(Cs)?σ(Cs⁺)=(14±12)·10^?6. These measurements allow an estimation of the spin rotation interaction constant in these molecules.     

Decay of quarks in the Pati-Salam model

We discuss, within the framework of the basic Pati-Salam model, the feasibility of the hypothesis that quarks are unconfined, integer-charged, relatively light (mass ～2?3 GeV) and short-lived (τ_q?10^?12s). Our estimates for the quark life-times vary between 10^?12s and 10⁺¹¹ s for the white and blue quarks and between 10^?12 s and 10⁺¹⁶ s for the red quarks. The life-times depend very sensitively, and it is shown why, on the values of the Salam-Weinberg mixing angle and the quark-gluon coupling constant.     

The anomalous magnetic moment of positive and negative muons

The anomalous g-factor a ≡ (g?2)/2 has been measured for muons of both charges in the Muon Storage Ring at CERN. The two results, a_μ⁺ = 1165910(12) × 10^?9 and a_μ^? = 1165936(12) × 10^?9, are in good agreement with each other, and combine to give a mean a_μ = 1165922(9) × 10^?9, which is very close to the most recent theoretical prediction 1165921(10) × 10^?9. For the experimental results, the total statistical and systematic error is given. The measurements thus confirm the remarkable QED calculation plus hadronic contribution, and serve as a precise verification of the CPT theorem for muons.     

Beta decay of12B and12N to the first excited state of12C (4.44 MeV)

The branching ratios of the beta-decay of¹²B and¹²N to the 4.44 MeV state in¹²C were determined by (βγ-coincidences to be (1.182±0.019)% and (1.898±0.032)% of the total rate, resp. This givesft ^?=(1.407±0.023) · 10⁵ s andft ⁺=(1.406±0.024) · 10⁵ s. For theft-asymmetryδ=(ft ⁺/ft ^?)?1 the valueδ=?(1±14) · 10^?3 was obtained. This is in contrast to other GT mirror transitions which show positiveδ of a few percent.     

Very high energy γ rays from close active galactic nuclei Mkn 421, Mkn 501, and NGC 1275

The results of observations of two types of metagalactic sources, BLLacs Mkn 421 (z = 0.031) and Mkn 501 (z = 0.034) and the Seyfert galaxy NGC 1275 (z = 0.017) are reported. These observations have been carried out with the SHALON mirror telescope (Lebedev Institute of Physics, Russian Academy of Sciences). The γ-ray fluxes (with energies E > 0.8 TeV) from Mkn 421 and Mkn 501, averaged over the entire observation period, were estimated to be (0.63 ± 0.14) × 10^?12 and (0.86 ± 0.13) × 10^?12 cm^?2 s^?1, respectively. The flux from the source NGC 1275 was (0.78 ± 0.13) × 10^?12 cm^?2 s^?1. The energy spectra of γ rays and images of the sources are reported.     

The ground state of molecular hydrogen

The v = 0?0 quadrupole spectrum of H₂ has been recorded using a 0.005-cm^?1 resolution Fourier transform spectrometer. The rotational lines S(1) through S(5) are observable in the spectra, in the region 587 to 1447 cm^?1. The spectral position for S(0) was also obtained from its v = 1-0 ground-state combination difference. The high accuracy of the H₂ measurements has permitted a determination of four rotational constants. These are (in cm^?1) B₀ = 59.33455(6); D₀ = 0.045682(4); H₀ = 4.854(12) × 10^?5; L₀ = ?5.41(12) × 10^?8. The hydrogen line positions will facilitate studies of structure and dynamics in astrophysical objects exhibiting infrared H₂ spectra. The absolute accuracy of frequency calibration over wide spectral ranges was verified using 10-μm CO₂ and 3.39-μm CH₄ laser frequencies. Standard frequencies for 5-μm CO were found to be high by 12 MHz (3.9 × 10^?4 cm^?1).     

Occurrence of alternating parity levels in bands of the odd-Z219Ac nucleus

A positive and a negative parity band in²²¹Th have been investigated via the²⁰⁸Pb(¹⁶O, 3n)²²¹Th reaction. Strong E1 transitions compete with stretched E2 transitions deexciting levels of alternating parity. The measured averaged =2.6 · 10^?6 fm^?2 is similar to that observed in neighbouring nuclei. The level scheme may be interpreted assuming an octupole deformed core.     

Ultrasonic preparation of tetraoxalyl ethylenediamine melamine resin-coated multiwalled carbon nanotubes for trace Ni(II) sensing

Under an aid of ultrasonic, tetraoxalyl ethylenediamine melamine resin-coated multiwalled carbon nanotubes were prepared for Ni(II) sensing in aqueous solution. The processes involved the fabrication of tetraoxalyl ethylenediamine melamine resin by one pot way, the coating of tetraoxalyl ethylenediamine melamine resin at multiwalled carbon nanotubes (MWCNTs), and the determination of Ni(II). The present materials were carefully examined by Fourier transform infrared spectroscopy, field emission scanning electron microscope, and electrochemistry techniques. A great deal of amorphous microsphere could be observed for tetraoxalyl ethylenediamine melamine resin with an average diameter of 1.2 μm, and MTE could evenly adhere at the surface of MWCNTs by the ultrasonic. Tetraoxalyl ethylenediamine melamine resin-coated multiwalled carbon nanotube-modified paraffin-impregnated graphite electrode was successfully used for the determination of Ni(II) by differential pulse adsorptive anodic stripping voltammetry. The current responses (?0.3 V) were linearly increased depending on the concentration from 1?×?10^?11 to 3?×?10^?10 M (i (μA)?=?11.1?+?7.9 c (1?×?10^?12 M); R?=?0.9901, 3σ?=?7?×?10^?12 M).     

Radiative decay and autoionization in the4 D-states of the 3d 94s5s configuration in CuI

The CuI 3d ⁹4s5s ⁴ D-states, which lie above the ionization limit, were populated by stepwise collisional and laser excitation. With respect to their total angular momentum, the⁴ D-states have completely different decay modes. Whereas the lifetimesτ(⁴ D _7/2)=8.2(4)·10^?9s andτ(⁴ D _1/2)=7.9(6)·10^?9 s are determinrd by radiative transitions and were measured by time-resolved spectroscopy, the lifetimesτ(⁴ D _5/2)=1.59(6)·10^?12s andτ(⁴ D _3/2)=1.28(5)·10^?12s are due to autoionization and were deduced from the widths of the excitation signals observed by ion detection.     

Spectroscopy of 7Li in stopped pion absorption reactions

The structure of excited levels in the ⁷Li isotope is studied via inclusive and correlation measurements in the stopped π^? meson absorption reactions ¹⁰B(π^?, t)X and ¹²C(π^?, dt)X, respectively. The experiment is conducted using a low-energy pion beam at the LAMPF meson factory. Analysis of the missing mass spectra reveals ⁷Li states with the resonance parameters (E _x , Γ) (4.7, 0.1), (6.6, 0.9), (7.3, 0.1), (9.1, 2.8), and (9.6, 0.4) MeV. A highly excited state with E _x ≈ 11.2 MeV (i.e., an isobar analog of ⁷He) is observed in the ¹⁰B(π^?,t)X reaction. An excited state with E _x = 10.3 ± 0.1 MeV and γ = 1.8 ± 0.4 Mev is observed for the first time in the ¹²C(π^?,dt)X reaction.     

Europium diffusion in SmS

Europium diffusion in samarium sulfide was studied in the temperature range from 780 to 1100°C. Data on the diffusion coefficient and activation energies for the diffusion of europium in single-crystal and polycrystalline SmS samples were obtained. In single-crystal samarium sulfide, europium was shown to migrate predominantly over lattice sites (D ? 10^?12?10^?9 cm²/s). In SmS polycrystals, diffusion was found to exhibit a complex pattern and have both a slow (D ? 10^?10?10^?9 cm²/s) and a fast (D ? 10^?8?10^?7 cm²/s) component. Europium diffusion in a polycrystal is primarily due to europium migration over the boundaries of single-crystal grains in the polycrystal, whose characteristic size is assumed to be that of x-ray coherent-scattering regions.     

Analysis of the ν6(A″2) band of cyclopropane-d6 recorded under high resolution

The parallel band ν₆(A″₂) of C₃D₆ near 2336 cm^?1 has been studied with high resolution (Δν = 0.020 – 0.024 cm^?1) in the infrared. The band has been analyzed using standard techniques and the following parameters have been determined: B″ = 0.461388(20) cm^?1, D″_J = 3.83(17) × 10^?7 cm^?1, ν₀ = 2336.764(2) cm^?1, α^B = (B″ ? B′) = 8.823(12) × 10^?4 cm^?1, β^J = (D″_J ? D′_J) = 0, and α^C = (C″ ? C′) = 4.5(5) × 10^?4 cm^?1.     

The vibration-rotation HDO absorption spectrum between 8558 and 8774 cm−1

The absorption spectrum of HDO has been recorded in the region 8558–8774 cm^?1 using a high-sensitivity intracavity F₂^?:LiF center laser spectrometer. The absorption sensitivity is 10^?7 cm^?1 and the line-center determination accuracy is about 4 × 10^?2 cm^?1. The spectrum was interpreted and the absorption lines were attributed to the ν₂ + 2ν₃ band of HDO. Energy levels up to J = 12 and rotational and centrifugal parameters of the vibrational (012) state were obtained.     

Mass and magnetic moment of Σ− by the exotic atom method

The energies and lineshapes of five circular transitions (n = 15 → n = 14 through n = 11 → = 10) of the Σ^?Pb atom were measured wit of the transitions 15 → 14 through 12 → 11 were determined; these energies were compared with energies calculated from quantum electrodynamics, and the mass of Σ^? was adjusted to achieve a best fit. The result was m_Σ^? = 1197.24 ±0.15 MeV. The lineshape of the 12→11 transition, which is broadened by the fine structure, has been analyzed to extract the magnetic moment of Σ^?. The result was μ_Σ^? = ?1.40_?0.28^+0.41or 0.651_?0.40^+0.28 nuclear magnetons. Comparisons with SU (3) predictions are made.     

Lepton charge and model of weak interactions with μ-e transitions

The gauge model of weak interactions is proposed and μ^±?e^? transitions predicted by the model are discussed. Estimates are given for μ^±→e^? transitions on hadrons like K⁺→π^?μ⁺e⁺ with Γ (K⁺→π^?μ⁺e⁺) ? 10^?11Γ(K⁺ and μ^? capture on nuclei with W(μ^?→e⁺) ? 10^?12W(μ^? → ν). Single μ^± production in e^? beams with a cross section δ ～ 10^?42?10^?41 cm² is predicted.     

Analysis of the 2ν3 band of 12CD3F at 5.06 μm recorded under high resolution

The 2ν₃(A₁) band of ¹²CD₃F near 5.06 μm has been recorded with a resolution of 20–24 × 10^?3 cm^?1. The value of the parameter (α^B ? α^A) for this band was found to be very small and, therefore, the K structure of the R(J) and P(J) manifolds was unresolved for J < 15 and only partially resolved for larger J values. The band was analyzed using standard techniques and values for the following constants determined: ν₀ = 1977.178(3) cm^?1, B″ = 0.68216(9) cm^?1, D″_J = 1.10(30) × 10^?6 cm^?1, α^B = (B″ ? B′) = 3.086(7) × 10^?3 cm^?1, and β^J = (D″_J ? D′_J) = ?3.24(11) × 10^?7 cm^?1. A value of α^A = (A″ ? A′) = 2.90(5) × 10^?3 cm^?1 has been obtained through band contour simulations of the R(J) and P(J) multiplets.     

Results on the production cross sections π−p → neutrals and π− p→ χ↳2γ0n at 3.8, 6, 8 and 12 GeV/c

The ratio between the cross sections for the reactions $\text{π}{}^{\mathrm{?}}\text{p→}\text{χ}\text{?}{}_{\mathrm{2\gamma }}{}^0\text{n}$ and π^?p → η_→2γ n has been measured to be (2.4 ± 0.9) × 10^?2, (2.1 ± 0.6) × 10^?2 and (2.8 ± 1.3) × 10^?2 at 3.8,6,8 and 12 GeV/c incident momentum respectively.At the same momenta the cross section for π^t- p → neutrals is (1.48 ± 0.09) mb, (0.86 ± 0.05) mb, (0.64 ± 0.04) mb and (0.42±0.03) mb.     

EPR study of Fe3+ and Mn2+ in CeO2 and ThO2

Attempts were made to grow CeO₂ and ThO₂ single crystals doped with transition metal ions. Only Fe³⁺ and Mn²⁺ could be detected by the EPR technique. The EPR spectrum of Fe³⁺ in CeO₂ exhibits the well-known fine structure in cubic fields. The parameters areg=2.0044(1) anda=15.6(1)·10^?4 cm^?1. The hyperfine constantA for⁵⁷Fe in hexahedral coordination was found to be 8.9(1)·10^?4 cm^?1. The EPR spectrum of Mn²⁺ in CeO₂ reveals two cubic Mn²⁺ centers. The parameters for center 1 areg=1.9999(1) andA=86.9(1)·10^?4 cm^?1 and for center 2g=1.9984(1) andA=87.0(1)·10^?4 cm^?1. Heating the Mn doped CeO₂ samples in hydrogen, the Mn²⁺ centers transform from cubic into trigonal centers with approximate values ofg=1.9988(2),A=84.5(6)·10^?4 cm^?1 andD=203(1)·10^?4 cm^?1. The two observed Mn²⁺ centers in ThO₂ exhibita priori axial symmetry with approximate values ofg=2.0006(2),A=88.9(4)·10^?4 cm^?1 andD=33(3)·10^?4 cm^?1.     

Tunable laser Stark-difference spectra of CD3OH

We present Doppler resolution limited spectra of the P(J) and R(J) multiplets for J ≦ 10 of the 10-μm CO stretch band of ¹²CD₃¹⁶OH using a tunable diode laser. Relative frequencies within the multiplets accurate to ±0.0002–0.0005 cm^?1 are obtained, but no absolute frequencies are given. We are able to assign most of the hindered rotation and K substructure in these multiplets. The assignments are based on analyses of Stark-difference spectra combined with the ground-state microwave data and the intensity variations which are expected theoretically. The ground and excited state A, K = 1 asymmetry splitting parameters are measured to be δ₁″ = (8.5450 ± 0.0080) × 10^?3cm^?1 and δ₁′ = (9.7706 ± 0.0080) × 10^?3cm^?1, respectively. The ground-state value agrees well with the microwave results. A rapid-scan system for recording data and a computer-aided technique for calibrating and plotting the spectra are described.     

Thermodynamic properties of the CeSn3 mixed valence compound

We have measured on the CeSn₃ compound, the expansion coefficient between 80 and 800 K at normal pressure, the isothermal compressibility in the 0–8 GPa pressure range at room temperature and the heat capacity at constant pressure in the 60–300 K temperature range. The experimental data were compared with those previously found for the isomorphous LaSn₃ phase, assumed as a proper reference material for the study of the intermediate valency states in CeSn₃. Both the thermal expansion (3α) and the isothermal compressibility (k) of CeSn₃ show behaviours quite different from those of LaSn₃: for instance, in the standard conditions, 3α is 55 × 10^?6K^?1for CeSn₃ and 38 × 10^?6K^?1for LaSn₃; k is 15 × 10^?12 Pa^?1 and 12 × 10^?12 Pa^?1 respectively for CeSn₃ and LaSn₃. The thermal behaviour of the molar specific heat at constant pressure of CeSn₃ is similar to that of LaSn₃ for temperatures lower than 50 K. In the 70–300 K temperature range, the heat capacity of CeSn₃ is clearly higher than that of LaSn₃, ΔC_p being maximum near 150 K. The analysis of the calorimetric data show that the electronic coefficient γ of CeSn₃ is temperature dependent: its value varies from 53 mJ K^?2 mole^?1 at low temperature 24 mJ K^?2 mole^?1 at 300 K.