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1.
Conclusions Simple routes for the synthesis of (2RS, 8R)-(–)-2-propionoxy-8-methyldecane (I) the pheromone of the leaf beetleDiabrotica virgifera virgifera — from chiral monofunctional synthons, obtained from the available (S)-(+)-3,7-dimethyl-1,6-octadiene, were developed.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2080–2083, September, 1987.It corresponds to Communication 4 in the series Terpenes in Organic Synthesis. For the preceding Communication, cf. [1].  相似文献   

2.
    
The synthesis has been achieved of optically active (S)-(+)-14-methyloctadec-1-ene — the sex pheromone of the leaf miner peach mothLyonetia clerkella Linne from the readily accessible enantiomerically enriched (ee 50%) (S)-(+)-3,7-dimethyloct-1,6-diene.Institute of Organic Chemistry, Urals Branch, Russian Academy of Sciences, Ufa. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 714–717, November–December, 1992.  相似文献   

3.
    
2-6-Dimethyloctan-1-ol, the formate of which is a mimic of the aggregation pheromone of the flour beetlesTribolium confusum andT. castaneum, has been synthesized by the hydroboration of 2,6-diemthyloct-1-ene, obtained from -methylvaleric acid.Institute of Organic Chemistry, Urals Branch, Russian Academy of Sciences, Ufa. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 571–573, September–October, 1992.  相似文献   

4.
    
Schemes are proposed for the synthesis of (±)-3-methylheneicosan-2-one and (±)-2-acetoxy-3,7-dimethylpentadecane — racemic analogues of the sex pheromones of the common cockroach (Blatella germanica) and of plane sawflies of the generaDiprion andNeodiprion, respectively, using the reductive -vinylation of -olefins.Institute of Chemistry of the Bashkir Scientific Center, Urals Division of the Russian Academy of Sciences, Ufa. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 567–571, September–October, 1992.  相似文献   

5.
The new alkaloid folidine with mp 148–149°C (acetone-petroleum ether) has been isolated from the epigeal part of the plantHaplophyllum foliosum Vved., and on the basis of spectral characteristics and passage to the known alkaloid folifidine (8-hydroxy-4-methoxy-1-methyl-2-quinoline) its structure has been established as 4-methoxy-1-methyl-8-(2-oxo-3-methylbutoxy)-2-quinolone.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 823–824, November–December, 1985.  相似文献   

6.
Two trail attractants for the termiteR. lucifugus have been isolated from the plantZizyphus jujuba: - and -bisabolenes. The threshold concentrations of the actions of these substances amounts to 10–9 g/liter. -Bisabolene in the range of concentrations of 1–10–6 g/liter is a powerful repellant for termites.Institute of Physiologically Active Substances, Academy of Sciences of the USSR, Chernogolovka. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 416–419, May–June, 1989.  相似文献   

7.
    
Summary The roots ofArtemisia dracunculus L. have yielded a new isocoumarin — artemidiol — with the composition C13H14O4, mp 131.5–133°C, which has the structure of 3-(1-2-dihydroxybutyl)isocoumarin.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 720–723, November–December, 1974.  相似文献   

8.
    
Summary From the roots ofPrangos ferulacea (L.) Lindl. has been isolated a new furocoumarin (I), C10H14O5, with mp 136.5–138.5°C (from ethanol), [] D 20 ± 0° (chloroform), which we have calledgosferol.On the basis of a study of the UV, IR, NMR, and mass spectra and the chemical properties of gosferol, the structure 5-(2-hydroxy-3-methylbutenyloxy)furo-2,3:7,6-coumarin has been proposed for it.Leningrad Sanitary and Hygienic Medical Institute. S. Ordzhonikidze All-Union Chemical and Pharmaceutical Scientific-Research Institute. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 49–54, January–February, 1972.  相似文献   

9.
The structure of an extracellular mannan formed by the yeastBullera tsugae has been studied. It has been shown that the repeating unit of this polysaccharide contains -(13)- and -(14)-bound D-mannopyranose residues in equimolar ratio. A comparison has been made of the polymer under investigation with the extracellular mannan from a yeast of the genusRhodotorula. Leningrad Institute of Pharmaceutical Chemistry. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 746–750, November–December, 1985.  相似文献   

10.
Summary It has been established that substance 4, isolated previously fromBidens tripartita, is (R-2)isookanin 7-O--D-glucopyranoside [(R-2)flavanomarein]. The compound isolated is a new one for the genusBidens L.Khar'kov State Pharmaceutical Institute. Khar'kov Scientific-Research Institute of Pharmaceutical Chemistry. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 144–147, March–April, 1975.  相似文献   

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