The crystal structure of copper dipyridine dibromide Cu(C5H5N)2Br2

The X-ray structural analysis of copper dipyridine dibromide was carried out. The substance is monoclinic, its space group isP2₁/n, having the lattice constantsa=8.30 kXU,b=17.72 kXU,c=4.04 kXU,=96°,Z=2. The localization of the heavy atoms was carried out by means of the projections of the Patterson functionsP(u, v) andP(v, w), which provided the bases for determining the signs of the majority of structure factors. The projections of the electron density(x, y) and(y, z) were calculated on the basis of these data. The positions of the atoms were refined three times by methods of differential syntheses and by geometrical analysis. The structure of CuPy₂Br₂ is very close to that of CuPy₂Cl₂ [1], [2], differing from it primarily in the orientation of the symmetry elements with respect to the crystallographic axes. In both structures the copper atom is octahedrally coordinated with four halogen and two nitrogen atoms. The nitrogen atoms and two bromine atoms are bound to the copper covalently in the structure of the bromine derivative, as follows from the length of the bonds (Cu-N 1.99 kXU, Cu-Br, 2.46 kXU), while the remaining two bromine atoms are bound to the copper by weaker bonds and mediate the chain formation of molecules in the direction of thec axis.

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Cu(C₅H₅N)₂Br₂

. , 2₁/ ==8,30 kX,b=17,72 kX,=4,04 kX,=96°,z=2. (, v) P(v, w), . (, ) (, z). . CuPy₂Br₂ u₂1₂, . . , (-N 1,99 kX, u-r 2,46 kX), .

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The authors thank M. Serátor for supplying the crystal samples and for initiating the work, the management of the Institute of Technical Physics, Czechoslovak Academy of Sciences, in Prague and especially Dr. A. Línek for making it possible to calculate some of the Fourier maps on the special computer Elika and finally A. lechtová for carefully calculating the Fourier maps and structure factors.

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The first stage of this work was reported on at the 3rd State Conference on Inorganic Chemistry, held in Bratislava from June 29th to July 4th, 1959.     

К ТЕОРИИ ГРАВИТАЦИОННОГО ИЗЛУЧЕНИЯ

. , , , . , . . . . , , . ; , .

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On the theory of gravitational radiation

The equations of motion of weakly radiating particles are investigated in a linear approximation in which the pseudo-Euclidian metric remains valid but energy changes caused by gravitational radiation are considered. The classical relativistic equations of motion with variable rest mass are applied. An elementary theory of the gravitational radiation of a rotator is formulated. The results are applied for particles in circular accelerators. It is found that a rotator with non-zero rest mass cannot exist for an unlimited period and that it cannot exceed the velocity of light. This explains why particles with non-zero rest mass cannot attain the velocity of light in circular accelerators; it is also shown that the gravitational radiation of particles in circular accelerators does not exist in practice.

     

КОРРЕКЦИОННЫЕ ФАКТО РЫ ПРИ АБСОЛЮТНОЙ ДОЗ ИМЕТРИИ ПЛОСКИХ ИСТОЧНИКОВβ-ИЗЛУЧЕНИЯ С ПОМОЩЬЮ СЧЕТЧИКА ГЕЙГЕРА-МЮЛ ЛЕРА

n n, n , .     

The effect of microsegregation on the generation of dislocations in zinc single crystals

The applicability of Tiller's considerations on the production of dislocations is proved. The density of dislocations appearing during impurity microsegregation increases with increasing rate of growth as a consequence of the corresponding change in the effective distribution coefficient. The real value of C at the microsegregation boundaries is at least twice as great as the average value of the concentration of impurities in the crystal in question.

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. , , . C , .

     

К ОПРЕДЕЛЕНИЮ ПОСТОЯ ННЫХ РЕШЕТКИ МЕТОДОМ ДЕБАЯ-ШЕРРЕР А

, , , .     

К ВОПРОСУ O КРИТИЧЕСКО Й ЧАСТОТЕ ПРИ ПРЕРЫВИСТОМ ОСВЕ ЩЕНИИ

c , c n , n AgBr. .     

КОГЕРЕНТНОЕ ИЗЛУЧЕН ИЕ СИНХРОТРОННЫХ СГУ СТКОВ ЭЛЕКТРОНОВ В ЗАМКНУТ ОМ РЕЗОНАТОРЕ

. , .

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The coherent radiation of synchrotron electron clusters in a closed resonator

A study is made of the electromagnetic interaction of electrons in thin relativistic clusters during coherent radiation in a synchrotron. The magnitude and form of the tangential component of the force, acting on an isolated electron of a cluster of electrons, is expressed.

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. . .     

On the problem of the phase shifts of reflected light

. , . , . .

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On the problem of the phase shifts of reflected light

The paper solves the topical question of phase shifts when light is reflected. By introducing the reflection tensor and its transformation it was found that all phase shifts hitherto given in the literature can be used. It was proved that when different phase shifts are used the corresponding unit vectors must be oriented. If an arbitrary coordinate system and the relations pertaining to it are used consistently it is not possible by calculation or experiment to arrive at contradictory results.

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. , , . .: , 1961. . 45–49 . . , .. . , .     

Studium der photodielektrischen Erscheinung an lumineszierenden Zinkkadmiumsulfiden

Zusammenfassung Die spektrale Abhägigkeit der photodielektrischen Eigenschaften der lumineszierenden Zinkkadmiumsulfide verschiedener Zusammensetzung zeigt, da eine Beimengung von Kupfer das Eintreten von Zuständen mit groer Polarisierbarkeit hervorruft, die eine Änderung der realen Komponente der Dielektrizitätskonstanten zur Folge haben. Die Kupferkonzentration kann dabei so gering sein, da sie in der Lumineszenzemission gar nicht zur Geltung kommt. Die Infrarotmaxima der Verluste entsprechen Niveaus, die von anderen Autoren und mit anderen Methoden festgestellt wurden. Das Maximum des Exzitationsspektrums im Bereiche des Ausläufers der Absorptionskante hängt mit dem Maximum der Änderung der realen Komponente der Dielektrizitätskonstante zusammen.

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-

- , , . , . , . .

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Nunmehr im Physikalischen Institut der Karlsuniversität, Prag.     

ЗАВИСИМОСТЬ ПОЧЕРНЕ НИЯ ФОТОГРАФИЧЕСКОЙ ЭМУЛЬСИИ ОТ ЭНЕРГИИβ-ИЗЛУЧЕНИЯ

, - - . , - , , :³²P,³⁵S ⁹⁰Sr+⁹⁰Y.     

The internal friction of longitudinal oscillations in ferromagnetic materials

The paper deals with the theory of the new magnetomechanical phenomenon in an alternating field [6, 7]. The first part concerns the internal friction of longitudinal oscillations of a ferromagnetic material in the shape of a wire in a constant magnetic field. It is assumed that the medium in which the sample oscillates is conducting and has a certain permeability. Equations defining the magnetic field in the oscillating material are derived from the basic thermodynamic relations. The term describing the non-conservative force component in a complex formulation is used to determine the internal friction. A general relation between the internal friction and the magnetic field is derived, as well as other expressions, which are a simplification of it. The second part of the paper deals with internal friction in an alternating field. It is shown that the solution can be transformed to the sum of the internal frictions of the different harmonic oscillations, which are obtained as a partial solution of the problem on the assumption that the elastic oscillations in interaction with the field oscillations are separated into their harmonic components. The calculation then becomes that of the internal friction considered in the first part of the paper. In this case the internal friction significantly depends on the field amplitude. The functional dependence of the internal friction peak on the frequency of the mechanical oscillations is also calculated. The agreement of the theory with experiment is satisfactory.

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e . , , , . , . , . , , , . , , , . , . . . .

     

Металлографические методы определепия нлотности дислокаци й В монокристаллах германия

, , . , .1) . .     

О СУЩЕСТВОВАНИИ ОТРИ ЦАТЕЛЬНОГО ЯВЛЕНИЯ БАРКГАУЗЕНА

. . , . , . , . coo , 13. 5. 1954 . - .     

On the energy balance in the optics of metals

On the basis of the boundary conditions of the electromagnetic theory an explicit calculation of the absorption in a thin metallic film was carried out with the result that transport and interference components were found to exist. By applying the method to a simple metal-dielectric boundary the physical interpretation was given of the energy balance, which had hitherto been regarded as unclear. It was also explained why the reversibility principle fails when applied to a metal-dielectric boundary.

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, . - , . , - .

     

Time production and spatial distribution of macroscopic space charges in D-C discharge plasma

It is shown for a one-dimensional approximation that, around a disturbance in the ion concentrationn ₊(x, t) in the axial direction of a cylindrical plasma, a corresponding electron distributionn _–(x, t) is established with such a large velocity that under the usual conditions of a discharge plasma this electron distribution follows the relatively slow changes in ion concentration practically without delay. Relation (24) then holds for the electron concentration, the parametersl ₁,l _D being given by Eqs. (15) and (16). As long as the disturbance of the ions isn ₊(x) 0, a space chargeq ₀(n ₊-n_–) is produced and maintained in the plasma even if the disturbance of the equilibrium state of the plasma in the initial stage was electrically neutral (i.e.n ₊(x, t=0)==n _–(x,t=0)). The dimensions of these space charges can be many orders larger than the Debye characteristic lengthl _D ; this is shown on an example of a spatially periodic curven ₊(x). The unique (quasi-stationary) expression of the electron concentrationn _– by means of the deflection of the ion concentrationn ₊(x, t) permits a considerable simplification of the solution of the problems connected with axially disturbing the homogeneous state of a plasma, sincen _–(x, t) can be eliminated from the equations of continuity of the plasma by substituting from (24), and the problem becomes that of determining the curve of the ion concentrationn ₊ from the equations modified in this way.

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, ₊(, t) - _–(, t) , . (24), l ₁ l _D (15) (16). ₊() 0, q ₀(n₊ — n_–), , (..n ₊(x,0)=_–(, 0)). () _{– +}(, t) , , . . _–(, t) n ₊ .

     

The motion of 90° wedge domains in BaTiO3 in an alternating electric field

The paper deals with the motion of 90° wedge domains in BaTiO₃ in an alternating field of 50 c/s. The critical field, the positional hysteresis loops with double asymmetry, the production of wedges with polarization perpendicular to the field and 180° substructure in the wedges were studied. The differences between the behaviour of the wedges and the individual 90° walls are pointed out which are caused by differences in the energy balance of these formations and by different interactions with 180° processes. The upper limit of contribution of the wedge motion to the initial permittivity is estimated. The results are discussed from the phenomenological point of view.

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90° BaTiO₃

90° BaTiO₃ , 50 Hz. , , , , , , 180° . 90° , 180° . , . .

     

On the mechanism of rendering visible dislocations on the surface of iron crystals by anodic dissolving

The paper contains further results of studying dislocations rendered visible by anodic dissolving on the surface of single crystals of alpha-iron. The influence of the crystallographic orientation of the surface is investigated, the effect of carbon is confirmed and the anodic process is studied. The mechanism of dissolving of the crystal is given and a new more suitable method of rendering dislocations visible is derived.

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, . , . , .

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The author thanks F. Kroupa and J. Hejduk for critical remarks and discussion.     

ФОТОЭЛЕКТРИЧЕСКИЕ С ВОЙСТВА АНТИМОНИДА ГАЛЛИЯ

(GaSb), - 120–340 °K. : E₂=(0,773–0,75.10^–6 T ²) ., - .     

Der Zusammenhang zwischen der magnetischen Suszeptibilität und der chemischen Bindung halbleitender Verbindungen mit Sphaleritstruktur

Zusammenfassung Auf Grund einer einfachen Vorstellung wird gezeigt, wie sich mit Hilfe der magnetischen Suszeptibilität bei halbleitenden Verbindungen von Sphaleritstruktur die Abweichung von der idealen Kovalenzbindung vergleichen läßt und wie man die Messung der magnetischen Suszeptibilität zur Abschätzung der Energie des verbotenen Bandes und umgekehrt verwenden kann. Gleichzeitig werden die bei Zimmertemperatur bestimmten Werte der molaren Suszeptibilität der Verbindungen ZnSe, CdTe, CuBr, AgI, CdS und ZnS angegeben.

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, . ZnSe, CdTe, CuBr, AgI, CdS ZnS .

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Der Autor ist Frau Dr. N. A. Gorjunova (Physikalisch-technisches Institut, Leningrad) und Herrn Dr. E. Klier (Mathematisch-physikalische Fakultät, Prag) für die Verleihung der Proben und Herrn P. Jansa (Institut für Festkörperphysik, Prag) für die Hilfe bei der Messung zu Dank verpflichtet.     

The influence of oscillations on ionization in a discharge path

The paper solves the problem of gas ionization in a discharge path in a very dilute gas, where the free path of the electrons is much larger than the dimensions of the path and the transit time of the electrons between the electrodes is of the order of the period of the applied h-f voltage. It was found that for a certain ratio of the transit time of the electrons between the electrodes in the discharge path to the period of the h-f oscillation, resonance occurs when the wattless current component is zero. The electron density rises in the path and thus also the gas ionization.

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, , , . , , . , .

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In conclusion, the author would like to thank F. Benda for preparing the equipment, M. Kivánek for preparing the equipment and some of the measurements, and A. Hrdá for the measurements and for working out the case with equally large a-c and d-c voltages within the framework of her thesis.