Synthesis and Crystal Structure of a 2-D Framework Supramolecular Complex [Cd2（phen）2（adip）（NO3）2]

1 INTRODUCTION In the design of crystal molecule, inorganic crystal engineering is one of the focused fields that are ever developing[1]. The introduction of different metal ions and bridging ligands often gives rise to novel physical and chemical properties[2~4]. Conse- quently, the supramolecular compounds constructed from weak interactions, such as hydrogen bond, π-π stacking, C–H???O interaction, ion-π interaction and hy- drophobing interaction, have become the new focus of cryst…     

Hydrothermal Synthesis and Crystal Structure of a Novel Composite Keggin-type Arsenotungstate： [Ni（phen）2] [Hphen] （AsW12O40）

A novel polyoxometalate-based composite compound [Ni(phen)2][Hphen](AsW12O40) (phen = 1,10-phenanthroline) 1 has been hydrothermally synthesized and characterized by elemental analysis, IR, TGA, ESR spectroscopy and single-crystal X-ray diffraction. Each structure unit of 1 consists of one polyoxoanion AsW12O403-, one free phenanthroline molecule and one coordination cation [Ni(phen)2]2+. The title compound crystallizes in the orthorhombic system, space group P212121, with a = 12.2383(7), b = 21.0884(11), c = 22.3237(12) , V = 5761.4(5) 3, Mr = 3520.44, Z = 4, Dc = 4.059 g/cm3, F(000) = 6204, μ(MoKα) = 24.844 mm-1, GOF = 1.022, the final R = 0.0376 and wR = 0.0742 (I > 2σ(I)) for 865 parameters and 9637 observed reflections with I > 2σ(I).     

Synthesis and Crystal Structure of [La（BTC）（H2O）6]n

1 INTRODUCTION desired topologies owing to their rich coordination modes[8~12] and we have been exploring the chemi- The assembly of metal-organic infinite frame- stry of coordination polymers constructed by tran- works via coordination of metal ions with multifunc- sition metals and benzoic multicarboxylic acids[13~16]. tional organic ligands is a field of increasing inte- In addition, lanthanide ions have high affinity for rest[1~4]. A rational designed and predictable coor- hard donor a…     

Synthesis and Crystal Structure of a 1-D Coordination Polymer [Pb（ANS）2（phen）]n

A new one-dimensional coordination polymer, [Pb(phen)(ANS)2]n (ANS = 2-ami- nonaphthalene-1-sulfonate, phen = 1,10-phenanthroline), has been prepared by hydrothermal synthesis and structurally characterized by elemental analysis, IR and single-crystal X-ray diffrac- tion. The results determined by XRD reveal that the complex crystallizes in monoclinic, space group P21/c with a = 16.8374(14), b = 16.9825(14), c = 9.9392 (8) , β = 95.9830(10)o, V = 2826.5(4) 3, Mr = 831.86, Dc = 1.955 g/cm3, μ(MoKα) = 6.173 mm-1, F(000) = 1624, Z = 4, the final R = 0.0272 and wR = 0.0694 for 4305 observed reflections (I > 2σ(I)). In the complex, the adjacent lead(II) ions are bridged through the oxygen atoms of sulfonate groups in a syn-syn conformation, yielding an infinite zigzag chain. And the intermolecular N–H···O hydrogen bonds link the chains into two-dimensional layered networks, which are further assembled into a separate two-layer-film-like packing structure.     

Hydrothermal Synthesis, Crystal Structure and Photoluminescent Property of a Metal-organic Coordination Polymer with Supramolecular Structure： [Cd2（dpphen）2（BDC）0.5Cl3]n

A novel metal-organic coordination polymer [Cd2(dpphen)2(BDC)0.5Cl3]n (dpphen = 4,7-diphenyl-1,10-phenanthroline, BDC = terephthalate) 1 has been obtained by using hydrothermal synthesis and characterized by elemental analysis, IR, fluorescence spectrum and single-crystal X-ray diffraction. The complex crystallizes in triclinic, space group P1 with a = 9.981(5), b = 10.436(5), c = 21.104(10) , α = 94.640(7), β = 103.160(7), γ = 92.958(8)o, V = 2127.8(17) 3, C52H34Cd2Cl3N4O2, Mr = 1077.98, Dc = 1.682 g/cm3, μ(MoKα) = 1.237 mm-1, F(000) = 1074, Z = 2, the final R = 0.0314 and wR = 0.0757 for 7358 observed reflections (I > 2σ(I)). Furthermore, compound 1 shows blue photoluminescent property at room temperature.     

Synthesis and Crystal Structure of Zinc Complex [Zn（bipy）3][Zn（SCN）4]

1 INTRODUCTION The design and synthesis of metal-organic frame-work structure have been studied widely during thepast decade not only because of their intriguing ar-chitectures but also their unexpected properties forpotential practical applications in a wide number offields, such as asymmetric catalysis, magnetism, pho-toluminescence and so on[1～3]. These novel struc-tures can be rapidly and efficiently synthesized fromsimple subunits, where the metal ions, bi- or multi-dentate organic l…     

Synthesis and Crystal Structure of a Novel Three-dimensional Supramolecular Compound [（AgI3）（4-HBPFA）2（H2O）]

1 INTRODUCTION In recent years, the rational design and synthesisof metal-directed supramolecular frameworks throughintermolecular hydrogen bonds, π-π stacking interac-tion or other weak interactions have received muchattention because of their interesting molecular topo-logies and various potential applications in catalysis,superconductor, magnetism, nonlinear optics, sen-sors and molecular recognition[1～4]. On the otherhand, the attachment of mono- or polypyridyl frag-ments to a ferr…     

Synthesis and Crystal Structure of a Ruthenium（Ⅱ） Compound of Dinitrogen

The title compound [Ru（bph）（PPh3）2（N2）]·（PF6）·1.5CH2Cl2 （bph = N-（benzoyl）- N＇-（picolinylidene）-hydrazine） has been prepared and characterized by X-ray diffraction analysis. It crystallizes in the monoclinic system, space group P21/n with a = 13.5201（6）, b = 15.5078（6）, c = 25.0656（13） A, β= 100.257（3）°, C50.50H43Cl3F6N5OP3Ru, Mr= 1150.23, V= 5171.4（4） A3, Z = 4, F（000） = 2332, Dc = 1.477 g/cm^3 and ,μ（MoKa） = 0.615 mm^-1. The structure was refined to R = 0.0524 and wR = 0.1398 for 8060 observed reflections （I 〉 2σ（I））. The Ru-N2 and N-N bond distances are 1.919（4） and 1.133（5）A, respectively.     

Synthesis and Crystal Structure of a New Imidazole Coordinated Octamolybdate Compound

1 INTRODUCTION Polyoxometallates are of great interest not only for their structural variety but also for their un- expected properties[1, 2]. These inorganic anions had been widely investigated in catalysis, biology, me- dicine, magnetochemistry and materials science[3～6]. Especially, the studies on the organic ligands coor- dinated by polyoxometallates might help to under- stand the catalytic mechanism of polyoxometallates. In recent years, several octamolybdates containing organic l…     

Synthesis and Crystal Structure of a Genistein-derived Compound

A genistein derivative, 5-hydroxy-3-（4-hydroxyphenyl）-7-（2-（piperidin- 1-yl）ethoxy）- 4H-chromen-4-one 3, was designed, prepared and structurally characterized by single-crystal X-ray diffraction. X-ray structure analysis reveals that 3 crystallizes in the orthorhombic system, space group Pbca, with a = 16.238（3）, b = 10.308（2）, c = 22.987（5）A, V = 3847.6（13）A3, Z = 8,μ= 0.093 mm^-1, Dc = 1.317 g/cm^3, F（000） = 1616, R = 0.0789 and wR = 0.1554 for 1463 observed reflections with I 〉 2σ（I）.     

Synthesis and Crystal Structure of a Novel Zinc Phosphonate Compound： [Zn（phen）（m-OOCC6H4PO3H）]

A novel zinc（H） metal phosphonate compound [Zn（phen）（m-OOCC6H4PO3H）] 1 （phen = phenanthroline） has been synthesized under hydrothermal conditions. Single-crystal X-ray structure analysis reveals that compound 1 belongs to the triclinic system, space group P1 with a = 9.3356（19）, b = 10.203（2）,c = 10.743（2）A,α = 76.3030（70）, β= 69.2317（51）, y = 84.3833（74）°,V = 929.4（3） ,A3, Z = 2, C2OH15N2O5PZn, Mr = 459.68, Dc = 1.643 g/cm^3,μ= 1.444, mm^-1, F（000） = 468, the final R = 0.0330 and wR = 0.0848. In the structure, the central ion Zn（H） is five-coordinated, linking three O atoms with one from carboxyl and the other two from phosphonyl group. The remained two coordinate sites were occupied by two N atoms from one phen molecule to form the asymmetric unit. Then every two adjacent asymmetric units are bridged by the O atoms from phosphonate group and carboxyl to give rise to a 1D chain along the b axis. These chains are constructed by weak π-π stacking interactions and C-H…π interactions to generate a 3D supramolecular framework.     

Hydrothermal Synthesis and Crystal Structure of a New Supramolecular Channel Framework Based on Cu Complexes and Polyoxovanadate:[Cu(I)(phen)_2]_5[HV_(15)O_(36)(Cl)]_(0.65)[H_3V_(16)O_(38)(Cl)]_(0.35)·2H_2O

1 INTRODUCTION In the past years, polyoxovanadates have attracted extensive interest in solid-state material chemistry owing to the formation of mixed-valence com- pounds that exhibit rich electronic and magnetic properties relevant to catalysis, medicine and ma- terials science[1～4]. The following polyoxovanadates have been found and structurally characterized: [V5O14]3-, [V6O19]8-, [V10O28]6-, [V12O32]4-, [V13- O34]3-, [V15O36]5-, [V15O42]9-, [V17O42]4-, [V18- O42]12-, [V16O38]7…     

三维超分子化合物[H_2(C_4H_(10)N_2)](SO_4)(H_2O)的制备、晶体结构及差热-热重性质研究

用MnSO4H2O和哌嗪在水-甲醇混合溶剂中反应得到了1个超分子化合物[H2(C4H10N2)](SO4)(H2O) (C4H14N2O5S)。 该晶体属单斜晶系, 空间群为P21/n, 晶胞参数为: a = 6.386(1), b = 11.695(2), c = 11.680(2) ? = 101.06(3), V = 856.1(3) 3, Z = 4, Mr =202.23 , Dc = 1.569 g/cm3, F(000) = 432, ?= 0.368 mm-1。 该化合物是由[H2(C4H10N2)]2+、SO42-、H2O通过氢键自组装而形成的。 其中[H2(C4H10N2)]2+存在2种椅式构象:一种[H2(C4H10N2)]2+与4个SO42-、2个H2O通过氢键相连, 另一种[H2(C4H10N2)]2+则与6个SO42-相连。 它们分别沿着b、c方向交替排列展开, 通过SO42-桥联成二维的层状结构;层与层之间在NH…O、CH…O、OH…O氢键的作用下互相连接, 形成了具有网状结构的三维超分子化合物。 差热及热重测试表明:该化合物从92℃开始分解,首先失去1个H2O, 然后再失去[H2(C4H10N2)]2+和SO4 2-。     

[Cd(HO-BDC)(phen)·H2O]n的合成和晶体结构研究

A novel coordination ploymer [Cd(HO-BDC)(phen)·H₂O]_n (where HO-BDC is 5-Hydroxyisophthalic acid and phen is 1,10-phenanthroline) has been synthesized and characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. The crystal belongs to monoclinic, space group P2/c, with a=0.876 4(2) nm, b=1.233 0(3) nm, c=1.761 2(4) nm, β=109.152(9)°, V=1.797 8(7) nm³, Z=4, M_r=490.73, D_c=1.813 g·cm^-3, F(000)=976, μ=1.258 mm^-1, the final R=0.043 8 and wR=0.098 9 for 2 880 observed reflections with I>2σ(I). The structural analysis shows that the complex has a one-dimensional chain structure. CCDC: 609770.     

Hydrothermal Synthesis and Crystal Structure of [Mn（phen）-（m-phth）]n （phen=1 ,10-phenanthroline, m-phth=isophthalate）

Introduction Recently, many novel polymers with a variety of metal ions have been prepared and structurally characterized owing to the versatility of carboxylate ligands.1-5 Much attention has been devoted to this field partly because polymers of carboxylate ligands are good candidates for the investigation of exchange-coupling interactions between adjacent metal ions. A successful strategy to synthesize these complexes is the reaction of metal salts with properly selected multi-dentate carbox…     

Hydrothermal Synthesis and Crystal Structure of a Cadmium(II) Polymer with One-dimensional Chain Structure: [Cd(bpy)(BDC)]_n·nbpy

A metal-organic coordination polymer [Cd(bpy)(BDC)]n·nbpy (bpy = 2,2-bipyri- dine, H2BDC = terephthalic acid) has been hydrothermally synthesized and structurally characteri- zed by elemental analysis, IR spectrum, TG and single-crystal X-ray diffraction. The complex crystallizes in monoclinic, space group C2/c with a = 15.723(5), b = 21.695(5), c = 7.576(5) , β = 116.171(7)o, V = 2319.3(18) 3, C28H20CdN4O4, Mr = 588.88, Dc = 1.686 g/cm3, μ(MoKα) = 0.987 mm-1, F(000) = 1184, Z = 4, the final R = 0.0464 and wR = 0.0831 for 1882 observed reflections (I > 2σ(I)). It exhibits a three-dimensional network with channels constructed from one-dimensional coordination chains via C–H···O hydrogen bonds and significant aromatic π-π stacking interactions.     

Synthesis, Crystal Structure and Magnetic Property of the Polymeric Ribbon： [Co（ip）（phen）]n

1 INTRODUCTION The design and synthesis of metal-organic coor- dination polymers are of current interest owing to their intriguing architectures and potential applica- tions, such as catalysis, fluorescence and magne- tism[1～4]. Many transition metal-organic polymers have been synthesized and exhibit interesting magneticproperties[5～9]. Among them, coordination polymers constructed by dicarboxylate ligands have attracted considerable attention due to their rich coordination modes and di…     

双核锌配合物[Zn(dna)(phen)(H_2O)]的合成、结构及性质

以5,5'-二硫代双(2-硝基苯甲酸)(H2dna)和1,10-邻菲啰啉(phen)为配体在水热条件下合成了标题配合物,并利用元素分析、傅里叶变换红外光谱、X射线单晶衍射、X射线粉末衍射以及热重分析等技术手段对该配合物进行了结构和性质表征。晶体结构分析表明:配合物为单斜晶系,P2_1/n空间群,a=1.5312(3)nm,b=1.16054(18)nm,c=1.5609(3)nm,β=110.451(2)°,V=2.5990(7)nm~3,Z=4。该配合物为环状双核结构。基于氢键作用邻近的双核分子相连形成一维超分子链。而邻近超分子链又基于S幆O和CH幆π的弱相互作用扩展形成三维超分子网结构。该配合物失水后的产物保持相对稳定,直到245~450℃配体才开始分解,表现出良好的热稳定性。配合物在波长为280 nm的光源激发下,在440 nm有较强的荧光发射峰,且发射峰的形状与H2dna配体相似,但配合物的荧光强度相比H2dna配体有了明显的增强。