Ferromagnetism in hydrogenated graphene nanopore arrays

Theoretically, the so-called zigzag edge of graphenes provides localized electrons due to the presence of flat energy bands near the Fermi level. Spin interaction makes the localized spins strongly polarized, yielding ferromagnetism. However, in most experimental studies, ferromagnetism has been observed in uncontrollable and complicated carbon-based systems. Here, we fabricate graphenes with honeycomblike arrays of hexagonal nanopores, which have a large ensemble of hydrogen-terminated and low-defect pore edges that are prepared by a nonlithographic method (nanoporous alumina templates). We observe large-magnitude ferromagnetism derived from electron spins localizing at the zigzag nanopore edges. This promises to be a realization of graphene magnets and novel spintronic devices.     

Delay of Spatial Quantum Correlations in Magnetic Nanostructures

Simultaneous quantum correlations between two spins in magnetic nanostructures are considered in the model of a linear chain of a finite number of atoms with exchange interaction between electron spins of neighboring atoms in the framework of the Heisenberg ferromagnetism theory. We assume that in the initial state, the spins of all chain atoms except the first two are oriented along the same direction. The spins of the first two atoms are flipped. Due to the exchange interaction, this initial state generates a spin flip wave along the chain. The expressions obtained for nonstationary quantum amplitudes of the flip probability waves for an even number of spins can be used for calculating quantum correlations between two spins separated by a large distance in a chain. Numerical calculations of the spin correlator reveal that the correlation between two spins in the chain occurs with a delay on the order of the time of propagation of the exchange interaction along the spin chain. After the delay, the spin correlation amplitude abruptly increases followed by subsequent oscillatory temporal behavior.     

Phase Transition of a Distance-Dependent Ising Model on the Barabasi-Albert Network

We report our investigation on the behaviour of distance-dependent Ising models, which are located on the BA model network. The interaction strength between two nodes （the spins） is considered to obey an exponential decay dependence on the geometrical distance. The Monte Carlo simulation shows a phase transition from ferromagnetism to paramagnetism, and the critical temperature approaches a constant temperature as the interaction decaying exponent increases.     

Aligned CuO nanorod arrays: fabrication and anisotropic ferromagnetism

Copper oxide (CuO) is a p-type semiconductor with a band gap of 1.2 eV, which is well known in high-temperature superconductor and antiferromagnetic (AFM) materials through Cu–O–Cu super-exchange interaction. In this paper, we report the strong anisotropic ferromagnetism (FM) in aligned CuO nanorod arrays synthesized by a microwave-assisted hydrothermal method. The transmission electron microscopy (TEM) image shows that the CuO nanorod consists of a large number of smaller nanorods with almost the same growth direction. The X-ray diffraction (XRD) pattern indicates that the CuO nanorods are well crystallized with highly preferred orientation of the [020] direction. These CuO nanorod arrays show room-temperature ferromagnetism, with strong magnetic anisotropy when the magnetic field is applied perpendicular or parallel to the rod axis. This phenomenon of room-temperature ferromagnetism in those aligned CuO nanorods might originate from uncompensated surface spins and shape anisotropy of the nanorods.     

Anomalous ferromagnetism in manganites by finite block spin phenomenology

We investigate the relation between ferromagnetism and spin glasses which have been observed in manganese oxides.We want to explain the spin-glass phase on the basis of finite-sized block spin concepts.Then the phase of colossal ferromagnetism in manganites may be considered as the ferromagnetic ordering between block spins comprised of many random spins with respective majority spin directions. Using the Curie law for block spins, the magnetization and susceptibility are obtained in the lower-temperature and higher-temperature approximations of Brillouin function. The resistivity is also obtained from the electric susceptibility.     

Magnetic Impurity Band and Photoinduced Magnetic Phase Transition in Diluted Magnetic Semiconductors

Applying the dynamical coherent potential approximation (dynamical CPA) to a model of diluted magnetic semiconductors (DMSs), in which both random impurity distribution and thermal fluctuation of localized spins are taken into account, the spin-polarized band and the carrier spin polarization are calculated for various magnetizations. In order to clarify the role of impurity depth on the occurrence of ferromagnetism, three typical cases are investigated: (a) II-VI DMS, (b) deep impurity level, and (c) strong exchange interaction. The present study reveals that the impurity depth of magnetic ions strongly enhances the carrier spin polarization (CSP) and accordingly, leads to a high Curie temperature. This means that photoinduced ferromagnetism with high Curie temperature can be expected in a DMS with a deep impurity depth and strong exchange interaction.     

Interaction of the ground state of quarter-filled one-dimensional strongly correlated electronic system with localized spins

We study numerically the ground-state properties of the one-dimensional quarter-filled strongly correlated electronic system interacting antiferromagnetically with localized S = 1/2 spins. It is shown that the charge-ordered state is significantly stabilized by the introduction of relatively small coupling with the localized spins. When the coupling becomes large the spin and charge degrees of freedom behave quite independently and the ferromagnetism is realized. Moreover, the coexistence of ferromagnetism with charge order is seen in the strongly interacting region. The present theoretical results are to be compared with the experiments on phthalocyanine compounds.     

Ising ferromagnetism and domain morphology in the fractional quantum Hall regime

The density driven quantum phase transition between the unpolarized and fully spin polarized nu = 2/3 fractional quantum Hall state is accompanied by hysteresis in accord with 2D Ising ferromagnetism and domain formation. The temporal behavior is reminiscent of the Barkhausen and time-logarithmic magnetic after-effects ubiquitous in familiar ferromagnets. It too suggests domain morphology and, in conjunction with NMR, intricate domain dynamics, which is partly mediated by the contact hyperfine interaction with nuclear spins of the host semiconductor.     

Ferromagnetism in GaN:Gd: a density functional theory study

First-principle calculations of the electronic structure and magnetic interaction of GaN:Gd have been performed within the generalized gradient approximation (GGA) of the density functional theory with the on-site Coulomb energy U taken into account (also referred to as GGA+U). The ferromagnetic p-d coupling is found to be over 2 orders of magnitude larger than the s-d exchange coupling. The experimental colossal magnetic moments and room-temperature ferromagnetism in GaN:Gd reported recently are explained by the interaction of Gd 4f spins via p-d coupling involving holes introduced by intrinsic defects such as Ga vacancies.     

A finite block spin model for permanent magnets

We propose a finite block spin phenomenology for permanent magnets in which we consider an average domain as a block spin. The permanent ferromagnetism arises in two ways: (1) the ferromagnetism that occurs inside a big block spin, i.e. the intrablock ferromagnetism, and the ferromagnetism between small block spins (SBSs) in a big block spin (BBS) which can be induced by collective ferromagnetic pairing between two SBSs mediated by temperature-irreversible bosonic strains; and (2) the ferromagnetism between BBSs, i.e. the interblock ferromagnetism. The coercivity originates from temperature-irreversible strains treated as external phonons.     

Ferromagnetism in the Hubbard Model: A Constructive Approach

It is believed that strong ferromagnetic orders in some solids are generated by subtle interplay between quantum many-body effects and spin-independent Coulomb interactions between electrons. Here we describe our rigorous and constructive approach to ferromagnetism in the Hubbard model, which is a standard idealized model for strongly interacting electrons in a solid. We introduce a class of Hubbard models in any dimensions which are nonsingular in the sense that both the Coulomb interaction and the density of states (at the Fermi level) are finite. We then prove that the ground states of the models exhibit saturated ferromagnetism, i.e., have maximum total spins. Combined with our earlier results, the present work provides nonsingular models of itinerant electrons with only spin-independent interactions where low energy behaviors are proved to be that of a healthy ferromagnetic insulator.     

On the coexistence of superconductivity and ferromagnetism

The magnetic scattering of electrons is studied, paying special attention to the problem of coexistence of superconductivity and ferromagnetism. The utilized model consists of two electronic bands, one of which can become superconducting, and a system of localized spins. The calculated transition temperatures of the superconduction and the magnetic subsystems show regions of coexistence for not too large exchange interactions. Generally speaking, coexistence is favoured due to spin-orbit scattering as well as due to the interaction of the superconducting band with the normal band in certain cases.     

1H and 129Xe NMR absorption line shapes in the presence of highly polarized and concentrated xenon solutions in high magnetic field

The presence of highly concentrated dissolved laser-polarized xenon (approximately 1mol/L, polarization up to 0.2) induces numerous effects on proton and xenon NMR spectra. We show that the proton signal enhancements due to (129)Xe-(1)H cross-relaxation (SPINOE) and overall shifts of the proton resonances due to the average dipolar shift created by the intense xenon magnetization are correlated. Protons behave as very useful sensors of the xenon magnetization. Indeed the xenon resonances exhibit many features such as superimposition of narrow lines on the main resonance due to clustering effects, or such as a polarization-dependent line broadening that is tentatively assigned to the effects of temperature fluctuations that decorrelate some distant dipolar field effects from local interactions, transforming xenon spins from "like" to "unlike" spins. These spectral features make difficult the determination of the average dipolar field by means of the xenon resonance but have interesting consequences on the heteronuclear polarization transfer experiment in Hartmann-Hahn conditions (SPIDER).     

Simulation of coexisting ferromagnetic order and disorder of geometrically frustrated Co2Cl(OH)3

The ground state and phase transition of Co₂Cl(OH)₃ were investigated by Monte Carlo simulation. This compound is a magnet, with a pyrochlore structure distorted along one axis. The magnetic structure at low temperatures consists of coexisting ferromagnetism and random spin, according to experiments. However, the formation mechanism of the coexistence and the interaction between the spins were unclear. We assumed an anisotropic Ising model and examined the ground state by multicanonical Monte Carlo simulation. In a nearest neighbor model, the ground states were highly degenerated. Almost all of the states were spin glass states, but a few of the states were ferromagnetic. The latter magnetic states were ferromagnetic at triangular layers and two in-one out random state at Kagome layers. The latter states should be stabilized if weak ferromagnetic interactions exist between second nearest neighbor spins and correspond to the states reported by the experiments. This expectation was confirmed by simulation.     

Ultrafast enhancement of ferromagnetism via photoexcited holes in GaMnAs

We report on the observation of ultrafast photoenhanced ferromagnetism in GaMnAs. It is manifested as a transient magnetization increase on a 100 ps time scale, after an initial subpicosecond demagnetization. The dynamic magnetization enhancement exhibits a maximum below the Curie temperature T(c) and dominates the demagnetization component when approaching T(c). We attribute the observed ultrafast collective ordering to the p-d exchange interaction between photoexcited holes and Mn spins, leading to a correlation-induced peak around 20 K and a transient increase in T(c).     

First-Principles Study on Magnetic Properties of V-Doped ZnO Nanotubes

Electronic and magnetic properties of V-doped ZnO nanotubes in which one of Zn^2＋ ions is substituted by V^2＋ ions are studied by the first-principles calculations of plane wave ultra-soft pseudo-potential technology based on the spin-density function theory. The computational results reveal that spontaneous magnetization in Vdoped （9,0） ZnO nanotubes can be induced without p-type or n-type doping treatment, and the ferromagnetism is isotropic and independent of the chirality and diameter of the nanotubes. It is found that V-doped ZnO nanotubes have large magnetic moments and are ferromagnetic half-metal materials. Moreover, the ferromagnetic coupling among V atoms is generated by O 2p electron spins and V 3d electron spins localized at the exchanging interactions between magnetic transitional metal （TM） impurities. The appearance of ferromagnetism in V-doped ZnO nanotubes gives some reference to fabrication of a transparent ferromagnet which may have a great impact on industrial applications in magneto-optical devices.     

Calculation of the Parameters of the Dimeric Association of Water Molecules and Determination of Their Temperature Dependence

The conditions are determined, and the parameters for the onset of the mode of dimeric molecular association in the water system are estimated. The characteristics of dimeric associates of molecules are determined. The region of anomalous thermal compression water is increased from T ≤ 4°C to T ≤ 66.4°C by introducing the temperature equivalent T₀ of the energy of proton transition from molecule to molecule into the parameter of resonant interaction of atoms of different molecules. The time of transfer of excitation energy correlates with the periods of the valence and deformation vibrations of the molecules. Therefore, a molecule that performs valence vibrations “has time” to store an excitation energy sufficient to provide a parallel orientation of the spins of the nuclei of the hydrogen atoms in the molecules. Molecules that perform deformation vibrations have zero spins because of the smallness of the frequencies of such vibrations.     

A new two-dimensional pulse sequence for T(2)* measurements of protons in (13)C isotopomers

A new two-dimensional pulse sequence for T(2)* measurement of protons directly coupled to (13)C spins is proposed. The sequence measures the tranverse relaxation time of heteronuclear proton single-quantum coherence under conditions of free precession and is therefore well suited to evaluate relaxation losses of proton magnetization during preparation delays of heteronuclear pulse experiments in analytical NMR. The relevant part of the pulse sequence can be inserted as a "building block" into any direct or inverse detecting H,C correlation pulse sequence if proton spin-spin relaxation is to be investigated. In this contribution, the building block is inserted into a HETCOR as well as into a HMQC pulse sequence. Experimental results for the HETCOR-based sequence are given.     

Two magnetic regimes in doped ZnO corresponding to a dilute magnetic semiconductor and a dilute magnetic insulator

Films of ZnO doped with magnetic ions Mn and Co and, in some cases, with Al have been fabricated with a very wide range of carrier densities. Ferromagnetic behavior is observed in both insulating and metallic films, but not when the carrier density is intermediate. Insulating films exhibit variable range hopping at low temperatures and are ferromagnetic at room temperature due to the interaction of the localized spins with static localized states. The magnetism is quenched when carriers in the localized states become mobile. In the metallic (degenerate semiconductor) range, robust ferromagnetism reappears together with very strong magneto-optic signals and room temperature anomalous Hall data. This demonstrates the polarization of the conduction bands and indicates that, when ZnO is doped into the metallic regime, it behaves as a genuine magnetic semiconductor.