On the interaction of a beam of polar molecules with a static and a resonant RF field as a source of molecular interferences

A molecular beam interference model is presented based on a two-state interaction between a polar molecule and a resonant RF field as it occurs in the so-called C-field of a typical molecular beam electric resonant spectrometer. The treatment shows the onset of interferences in the beam transmission spectra as well as in its transverse profile. It is demonstrated how the molecular interferences are originated by the wavefunction phase shift introduced by the resonant RF field. Furthermore it is shown that for a given beam velocity and oscillating field frequency the fringes’ visibility depends on the strength of the RF field, i.e. the Rabi frequency, in the transmission spectra. Likewise the presence of a RF field gradient in the perpendicular beam direction gives rise to a peak structure in the transverse beam profile. The theoretical model was applied to simulate a variety of beam transmission spectra under resonant conditions as well as some experimental data already published by our group showing a satisfactory agreement between experimental and simulated data. Finally, the potentiality of this internal state molecular interferometer to carry out studies in matter-wave interferometry is remarked.     

WALL CONDUCTION EFFECT ON THE ONSET OF THERMAL INSTABILITY IN HORIZONTAL RECTANGULAR CHANNELS

The effect of peripheral thermal conduction in the bottom wall on the onset of thermal instability in the thermal entrance region of horizontal, rectangular, bottom-uniform-heated channels was studied by experiment and theoretical simulation. The predicted results of the onset of thermal instability for the cases of uniform peripheral wall heat flux are in agreement with the published experimental data, but the predicted results for the cases of uniform peripheral wall temperature exceed the previous data by about an order of magnitude. The present experimental data reconfirm the present predictions. The effect of increasing the peripheral wall conduction is shown to stabilize the flow.     

Anomalous magnetic field dependence of the thermodynamic transition line in the isotropic superconductor (K,Ba)BiO3

Thermodynamic (specific heat, reversible magnetization, tunneling spectroscopy) and transport measurements have been performed on high quality (K,Ba)BiO3 single crystals. The temperature dependence of the magnetic field H(C(p)) corresponding to the onset of the specific heat anomaly presents a clear positive curvature. H(C(p)) is significantly smaller than the field H(Delta) for which the superconducting gap vanishes but is closely related to the irreversibility line deduced from transport data. Moreover, the temperature dependence of the reversible magnetization presents a strong deviation from the Ginzburg-Landau theory emphasizing the peculiar nature of the superconducting transition in this material.     

High-drive-field domain wall dynamics in low-damping garnet films

Domain wall (DW) dynamics in a low-damping YBiFeGa film with perpendicular magnetic anisotropy was studied under FMR conditions. Measurements were carried out under radial expansion of magnetic bubbles in high pulsed drive fields and in an in-plane de magnetic field. A high-speed image recording technique was employed. The pattern of the dependence of DW velocity on drive field for the parts of the DW oriented parallel and perpendicular to the in-plane field was established. In all cases, this dependence contains a saturation region in which the DW velocity increases noticeably with increasing in-plane field. The experimental data obtained do not agree with theory. A possible explanation for this discrepancy is proposed. The onset of spatially periodic distortions in a moving DW is discussed.     

Confinement of chiral magnetic modulations in the precursor region of FeGe

We report on magnetic susceptibility and specific heat measurements of the cubic helimagnet FeGe in external magnetic fields and temperatures near the onset of long-range magnetic order at TC = 278.2(3) K. Pronounced anomalies in the field-dependent χac(H) data as well as in the corresponding imaginary part χ'ac(H) reveal a precursor region around TC in the magnetic phase diagram. The occurrence of a maximum at T0 = 279.6 K in the zero-field specific heat data indicates a second-order transition into a magnetically ordered state. A shoulder evolves above this maximum as a magnetic field is applied. The field dependence of both features coincides with crossover lines from the field-polarized to the paramagnetic state deduced from χac(T) at constant magnetic fields. The experimental findings are analyzed within the standard Dzyaloshinskii theory for cubic helimagnets. The remarkable multiplicity of modulated precursor states and the complexity of the magnetic phase diagram near the magnetic ordering are explained by the change of the character of solitonic inter-core interactions and the onset of specific confined chiral modulations in this area.     

The horn, kink and step, dale: from few GeV to few TeV

Rich experimental data have been collected in heavy-ion collisions at high energies to study the properties of strongly interacting matter. As the theory of strong interactions, QCD, predicts asymptotic freedom, the created matter at sufficiently high temperature and density will be dominated by a state of quasi-free quarks and gluons referred to as the Quark-Qluon Plasma (QGP). Experimental signals for the onset of the QGP creation (the onset of the deconfinement) have been predicted within the statistical model for the early stage of nucleus-nucleus collisions. In this model the existence of two different phases is assumed: confined mater and the QGP, as well as a first order phase transition between them. Until recently, these predictions were confirmed only by the NA49 experiment at the CERN SPS. In this report recent results from STAR at RHIC/BNL and from ALICE at LHC/CERN, related to the onset of deconfinement, will be compared to published results from NA49.     

Neutron diffraction study of magnetic properties of TmCo2

The present neutron diffraction studies have confirmed that TmCo₂ represents an exception within the RCo₂ series. It was found that, in contrast with other heavy RCo₂ compounds, the Co sublattice in TmCo₂ does not order magnetically below the Curie temperature (T_c = 3.9 K). This is assumed to be due the fact that in TmCo₂ the intersublattice (f-d) molecular field is smaller than the critical field necessary to induce magnetic order within the Co sublattice, as is the case in other RCo₂ compounds. Furthermore, we show that the magnetic structure and the onset of long-range order in TmCo₂ depend sensitively on the sample preparation, which partly explains the differing results published earlier.     

Recent advances in linear and non‐linear Raman spectroscopy. Part IX

This annual review is published to provide an overview of advances in the field of Raman spectroscopy as reflected in papers published each year in the Journal of Raman Spectroscopy (JRS) as well as in trends across related journals that have published papers in the broad field of Raman spectroscopy. The content is obtained from statistical data on article counts obtained from Thomson Reuters ISI Web of Science Core Collection by year and by subfield of Raman spectroscopy. Additional information is gleaned from presentations at the VIII International Conference on Advanced Vibrational Spectroscopy (ICAVS‐8) in Vienna, Austria in July 2015 and those featuring Raman scattering at SCIX 2015 organized by the Federation of Analytical Chemistry and Spectroscopy Societies (FACSS) in Providence, Rhode Island, USA, in September/October 2015. Coverage is also provided for topics from the conference ECONOS 2015 held in April in Leuven, Belgium. Finally, papers published in JRS in 2014 are highlighted and arranged by topics at the frontier of Raman spectroscopy. Taken from these various viewpoints, it is clear that Raman spectroscopy continues to be a rapidly expanding field that provides sensitive photonic information of matter at the molecular level in an ever‐widening arena of novel applications. Copyright © 2015 John Wiley & Sons, Ltd.     

Computer simulation of stoichiometric hydroxyapatite: Structure and substitutions

A force field for the modeling of hydroxyapatite; Ca₁₀(PO₄)₆OH₂ (HAP) is established based upon transferable potentials. Ca-O, P-O and O-O potentials were transported from those previously published for fluorapatite and based on single crystal experimental data. The interactions of hydroxyl oxygen with calcium and phosphate were re-scaled by fitting to experimental data for CaO and AlPO₄, respectively, to account for the reduction in the oxygen charge from −2.0 to −1.426. Force field accuracy is tested by comparing the calculated and experimental values for the cell constant and atom positions in the unit cell. The elastic constants and bulk modulus calculated for HAP are in close agreement with the experimental results. The potentials were also used to calculate the compressibility data of HAP and fluorapatite, and these results also agree with the published experimental data. Using formal charges for metal cations allows modeling the complete solid solution of Cd-Ca hydroxyapatite with a good accuracy.     

Status and plans of the NA61/SHINE physics program

One of the NA61/SHINE experiment??s goals is to discover the critical point of strongly interacting matter and study the properties of the onset of deconfinement. This is to be achieved by performing a two-dimensional phase diagram (T-?? _B ) scan??measuring hadron production in collisions of various beam particles and targets at various beam energies. NA61/SHINE also collects data for the T2K experiment, which are just about to be published.     

Muon level crossing resonance in niobium

A useful guide to detecting quadrupole level crossing resonance (QLCR) spectra is to search in the vicinity of B_E\cdot(\gamma_n/\gamma_μ), where B_E is the onset magnetic field for the decoupling of the quadrupole interaction, as seen in muon spin rotation linewidths. More detailed predictions of the positions and intensities of the resonances require numerical simulations taking account of the local geometry of the muon site. We present such simulations for muons adjacent to nuclei of spin 9/2 and demonstrate a pronounced dependence on the anisotropy of the quadrupole coupling tensor. Simulations for the specific cases of muons located at the octahedral and tetrahedral interstices in niobium metal are compared with the experimentally detected spectrum in a polycrystalline sample. This revised version was published online in August 2006 with corrections to the Cover Date.     

Unified picture of the distribution of electric field gradients at Cu, O, and Tm sites in ReBa2Cu3O7−δ

An abundant set of published experimental NMR/NQR data on electric field gradients in ReBa₂Cu₃O_7−δ high temperature conductors, where Re=Y and Tm, is used as a test for the singlet-correlated band theory. Because of the unusual spectral weight (“capacity”) of this band, it has been possible to match the number of holes per lattice site to photoemission data on the energy spectrum and the location of the Fermi level. In the framework of a unified picture of the distribution of holes (charges) it has been possible for the first time to explain satisfactorily the observed electric field gradients at the Cu(1), Cu(2), O(1), O(2), O(3), and O(4) sites, as well as NMR and inelastic neutron scattering data on the crystal electric field at the Tm ions. Zh. éksp. Teor. Fiz. 111, 144–157 (January 1997)     

μSR studies of magnetic properties of CeRhSb and La0.1Ce0.9RhSb

Zero, longitudinal, and transverse field μSR data are reported for CeRhSband La_0.1Ce_0.9RhSbdown to 45 mK. The muon spin relaxation at temperatures above a few Kelvin is caused by nuclear dipoles. Only at lower temperatures the additional depolarizing effect of electronic moments is observable, signalizing the onset of magnetic correlations in the 4f moment system. These findings are compared to the corresponding data on CeNiSn, showing that the ground state properties are basically alike in the two materials, that is, magnetic correlations develop, but remain weakly dynamic and long range antiferromagnetic order does not set in. The results for La_0.1Ce_0.9RhSbdiffer little from those of pure CeRhSb, indicating that the magnetic ground state properties as seen by μSR have not been altered significantly. The muonic Knight shift in CeRhSb exhibits similar features as the bulk susceptibility in the temperature range between 20 and 2 K. This revised version was published online in July 2006 with corrections to the Cover Date.     

基于变量变换伽辽金法光波导半矢量分析

基于变量变换伽辽金法(VTGM),建立了半矢量分析光波导本征值问题的数理模型;获得了矩形光波导、脊形光波导的本征模的模场分布及归一化传播常数,计算结果和已发表的结果非常接近.半矢量VTGM采用平面映射边界条件,避免了边界截断,又能反映模场的偏振特性,是一种较为理想的光子器件分析方法.     

Recent advances in linear and nonlinear Raman spectroscopy. Part IV

The purpose of the review is to provide a concise overview of recent advances in the broadly defined field of Raman spectroscopy as reflected in part by the many articles published each year in the Journal of Raman Spectroscopy (JRS) as well as in trends across all related journals publishing in this research area. Context for the review is provided by considering statistical data on citations for the Thompson Reuters ISI Web of Science by year and by subfield of Raman spectroscopy. Additional statistics of number of papers and posters presented by category at the XXII International Conference on Raman Spectroscopy (ICORS 2010) is also provided. Papers published in JRS in 2009, as reviewed here, reflect trends at the cutting edge of Raman spectroscopy which is expanding rapidly as a sensitive photonic probe of matter at the molecular level with an ever widening sphere of novel applications. Copyright © 2010 John Wiley & Sons, Ltd.     

Dielectric constant and threshold electric field of charge-density-waves with strong impurity pinning

The dielectric constant ε and the threshold electric field E_T for the onset of charge-density-wave conduction are investigated within the phenomenological model proposed by Tua and Zawadowski for the strong pinning regime. The static dielectric constant ε (E) in a bias electric field E is found to be almost independent of E provided that E is not too close to E_T. For relatively small values of the pinning strength, the product ε E_T becomes independent of the parameters of the theory. Good agreement is found with the available experimental data on NbSe₃ for the case of strong pinning obtained by radiation damage.     

Angular-distribution He(I)/Ne(l) photoelectron Spectra of H2, N2 and other small molecules

Measurements on hydrogen yield essentially equal He(I) and Ne(I) anisotropy parameters, in contrast to previous experimental results but in agreement with all theoretical calculations. For nitrogen ionized with Ne(I) the onset of autoionization is accompanied (as in oxygen) by a markedly more isotropic electron angular distribution. For the other molecules studied examination of the present and published sets of β-values reveals that the small differences again noted are indeed systematic, and can thus be allowed for. Responsibility for these effects is attributed to isotropic surface scattering.     

Onset of Lasing in Small Devices: The Identification of the First Threshold through Autocorrelation Resonance

A simple technique for identifying the onset of coherent emission in mesoscale lasers, which makes use of a small‐amplitude modulation added to the pump, is introduced. The optimal modulation frequency is obtained from the radio‐frequency power spectrum of the unperturbed laser emission. The identification of the lasing onset rests on the appearance of a resonance in the experimentally measured zero‐order autocorrelation function (g⁽²⁾(0)) plotted as a function of the pump rate. Numerical proof is provided in support of the autocorrelation resonance. The intrinsic simplicity of this technique and its inherent compatibility with photon counting makes it an excellent tool for certifying the onset of laser emission independent of the laser cavity volume. Recently published measurements of g⁽²⁾(0), obtained in nanolasers, support the extension of this technique to nanoscale devices.     

溴代聚苯乙烯机械特性的模拟计算

介绍使用计算机模拟软件,建立的聚苯乙烯和溴代聚苯乙烯非晶态高分子模型.选择适于有机高分子的DREIDING分子力场,根据模型的原子类型,参照文献数据修改其力场参数.在此力场下对模型进行能量优化,使模型尽量符合实际材料.然后,使用分子模拟法中的机械特性模拟,选择一定的计算方法和力学参量,模拟玻璃态物质在外张力下的形变,并计算出其力学特性参数,如体积模量、杨氏模量、泊松比等,给出了PS的应力-应变曲线以及各力学特性随溴代量变化情况.     

Field dependence of the superconducting transition and of the onset of magnetism in Y4Co3

Measurements of a.c.-susceptibility in the temperature range from 0.1–12 K superimposed over d.c.-magnetic fields up to 1 T are reported. The results in zero d.c.-field have revealed the onset of magnetic order at 5.6 K and indicated a superconducting transition at 2 K. This transition was determined from the center of susceptibility decrease, in agreement with the result published recently by Kolodziejczyk et al. The superconducting transition is suppressed by an applied field of about 1 T. Down to the lowest obtainable temperature no reappearance of magnetic order has been found even in the highest applied field.