共查询到20条相似文献,搜索用时 10 毫秒
1.
Long-range repulsive interaction between molecules on a metal surface induced by charge transfer 总被引:1,自引:0,他引:1
Fernandez-Torrente I Monturet S Franke KJ Fraxedas J Lorente N Pascual JI 《Physical review letters》2007,99(17):176103
The adsorption of a molecular electron donor on Au(111) is characterized by the spontaneous formation of a superlattice of monomers spaced several nanometers apart. The coverage-dependent molecular pair distributions obtained from scanning tunneling microscopy data reveal an intermolecular long-range repulsive potential, which decreases as the inverse of the molecular separation. Density functional theory calculations show a charge accumulation in the molecules due to electron donation into the metal. Our results suggest that electrostatic repulsion between molecules persists on the surface of a metal. 相似文献
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Possible existence of new long range forces and their interaction strength are critically analyzed and reviewed. 相似文献
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Desfrançois C Bouteiller Y Schermann JP Radisic D Stokes ST Bowen KH Hammer NI Compton RN 《Physical review letters》2004,92(8):083003
An excess electron can be bound to a molecule in a very diffuse orbital as a result of the long-range contributions of the molecular electrostatic field. Following a systematic search, we report experimental evidence that quadrupole binding occurs for the trans-succinonitrile molecule (EA=20+/-2 meV), while the gauche-succinonitrile conformer supports a dipole-bound anion state (EA=108+/-10 meV). Theoretical calculations at the DFT/B3LYP level support these interpretations and give electron affinities of 20 and 138 meV, respectively. 相似文献
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The autocatalytic reaction system with a small number of molecules is studied numerically by stochastic particle simulations. A novel state due to fluctuation and discreteness in molecular numbers is found, characterized as an extinction of molecule species alternately in the autocatalytic reaction loop. Phase transition to this state with changes of the system size and flow is studied, while a single-molecule switch of the molecule distributions is reported. The relevance of the results to intracellular processes is briefly discussed. 相似文献
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The spontaneous break-up of thin films is commonly attributed to the destabilizing effect of van der Waals forces. Dispersion forces can be considered in terms of the confinement of the electromagnetic fluctuation spectrum. The principle of confinement is more general than the usual argument of interacting dipole fluctuations. It includes also disjoining pressures that are caused by thermal fluctuations. In this context, we review recent publications on the dewetting of thin polymer films, and argue that the presence of an acoustic disjoining pressure is necessary to adequately describe some of these experimental results.Received: 1 August 2003PACS:
47.20.Ma Interfacial instability - 68.15. + e Liquid thin films - 43.25.Qp Radiation pressure 相似文献
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We discuss the long-range nature of the molecules produced in recent experiments on molecular Bose-Einstein condensation. The properties of these molecules depend on the full two-body Hamiltonian and not just on the states of the system in the absence of interchannel couplings. The very long-range nature of the state is crucial to the efficiency of production in the experiments. Our many-body treatment of the gas accounts for the full binary physics and describes properly how these molecular condensates can be directly probed. 相似文献
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Jordi Sancho-Parramon Salvador Bosch 《Applied Physics A: Materials Science & Processing》2014,115(2):393-397
The strong field localization generated between closely placed metal particles excited by electromagnetic radiation induces intense forces on small polarizable objects. In this study we investigate the optical forces that can be generated in the vicinity of metal nanoparticle clusters using fully electrodynamic numerical simulations. The influence of the cluster configuration as well as of the excitation parameters is analyzed. 相似文献
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Statistical fluid theory for associating fluids containing alternating heteronuclear chain molecules
Statistical associating fluid theory of homonuclear dimerized chain fluids and homonuclear monomer-dimer mixture chain fluids
are extended to fluids containing alternating heteronuclear chain molecules separately. The proposed models account for the
appropriate site-site correlation functions at contact. The modified equations of state show a good agreement with generalized
Flory dimer theory and MD simulation data for small and medium size ratio of hard sphere diameters. 相似文献
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Non-equilibrium molecular dynamics is used to calculate the wavevector and strain rate dependence of shear viscosity in a soft sphere fluid. The calculations are consistent with a non-analytic functional dependence of viscosity with wavevector. A consequence of such non-analyticity would be that the linear and non-linear Burnett coefficients for viscosity would not exist for fluids in three dimensions. The calculations also show the numerical consistency of three different non-equilibrium simulation methods for calculating shear viscosity. 相似文献
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We present the first direct depletion potential measurements for a single colloidal sphere close to a wall in a suspension of rigid colloidal rods. Since all particle interactions are as good as hard-core-like, the depletion potentials are of entirely entropic origin. We developed a density functional theory approach that accurately accounts for this experimental situation. The depletion potentials calculated for different rod number densities are in very good quantitative agreement with the experimental results. 相似文献
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《Physics letters. [Part B]》1999,446(2):111-116
We revisit and extend previous work on neutrino mediated long range forces in a background at finite temperature. For Dirac neutrinos, we correct existing results. We also give new results concerning spin-independent as well as spin-dependent long range forces associated to Majorana neutrinos. An interesting outcome of the investigation is that, for both types of neutrinos whether massless or not, the effect of the relic neutrino heat bath is to convert those forces into attractive ones in the supra-millimeter scale while they stay repulsive within the sub-millimeter scale. 相似文献
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Hua-Xing Chen 《理论物理通讯》2022,74(12):125201
After examining Feynman diagrams corresponding to the ${\bar{D}}^{(* )}{{\rm{\Sigma }}}_{c}^{(* )}$, ${\bar{D}}^{(* )}{{\rm{\Lambda }}}_{c}$, ${D}^{(* )}{\bar{K}}^{* }$, and ${D}^{(* )}{\bar{D}}^{(* )}$ hadronic molecular states, we propose a possible binding mechanism induced by shared light quarks. This mechanism is similar to the covalent bond in chemical molecules induced by shared electrons. We use the method of QCD sum rules to calculate its corresponding light-quark-exchange diagrams, and the obtained results indicate a model-independent hypothesis: the light-quark-exchange interaction is attractive when the shared light quarks are totally antisymmetric so they obey the Pauli principle. We build a toy model with four parameters to formulize this picture and estimate binding energies of some possibly-existing covalent hadronic molecules. A unique feature of this picture is that the binding energies of the (I)JP = (0)1+ $D{\bar{B}}^{* }/{D}^{* }\bar{B}$ hadronic molecules are much larger than those of the (I)JP = (0)1+ ${{DD}}^{* }/\bar{B}{\bar{B}}^{* }$ ones, while the (I)JP = (1/2)1/2+ $\bar{D}{{\rm{\Sigma }}}_{c}/\bar{D}{{\rm{\Sigma }}}_{b}/B{{\rm{\Sigma }}}_{c}/B{{\rm{\Sigma }}}_{b}$ hadronic molecules have similar binding energies. 相似文献
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Hisakazu OGITA Yoshiyuki RIKITAKE Jun MIYOSHI Yoshimi TAKAI 《Proceedings of the Japan Academy. Series B, Physical and biological sciences》2010,86(6):621-629
Nectins have recently been identified as new cell adhesion molecules (CAMs) consisting of four members. They show immunoglobulin-like structures and exclusively localize at adherens junctions (AJs) between two neighboring cells. During the formation of cell–cell junctions, nectins function in cooperation with or independently of cadherins, major CAMs at AJs. Similar to cadherins, which are linked to the actin cytoskeleton by binding to catenins, nectins also bind to afadin through their C-terminal region and are linked to the actin cytoskeleton. In addition to nectins, there are nectin-like molecules (Necls), which resemble nectins in their structures and consist of five members. Nectins and Necls are involved in the formation of various kinds of cell–cell adhesion, and also play key roles in diverse cellular functions including cell movement, proliferation, survival, and differentiation. Thus, nectins and Necls are crucial for physiology and pathology of multicellular organisms. 相似文献
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Jun Rui 《中国科学:物理学 力学 天文学(英文版)》2023,(11):239-240
<正>Ultracold polar molecules have emerged as a new research frontier in quantum physics and chemistry [1]. These molecules exhibit rich internal rotational, vibrational, and electronic levels, providing new resources for quantum control and quantum metrology. The intrinsic permanent electric dipole moment of polar molecules enables the strong longrange and anisotropic dipole-dipole interaction between spatially displaced molecules and constitutes a valuable tool for simulating novel long-r... 相似文献
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We show that two overlapping linearly polarized laser pulses of frequencies omega and its second harmonic 2omega can strongly orient linear polar molecules, by adiabatic passage along dressed states. The resulting robust orientation can be interpreted as a laser-induced localization in the effective double well potential created by the fields, which induces a preliminary molecular alignment. The direction of the orientation can be selected by the relative phase of the fields. 相似文献
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基于扩散动力学与细胞信号传导动力学,研究药物小分子对细胞周期的阻滞特性.理论模型考虑药物小分子穿越细胞膜输运的动力学特性,以及进入细胞内的药物分子对细胞周期的阻滞效应.研究发现,穿越细胞膜内层进入细胞内的药物分子,将会在很大程度上决定药物分子对相关的靶向基因、蛋白的阻滞功效.细胞膜对药物分子的输运特性,是影响药物分子阻滞细胞周期的关键因素.另外,药物分子的降解程度,将会改变药物分子与靶向基因、蛋白作用时间,进而改变对相关细胞生长增殖的抑制效应.通过对模型中各参数的敏感度分析,我们确认了药物分子穿越细胞膜、进入细胞内过程的多种因素对细胞周期的抑制效应.本文理论结果符合模拟、实验观测,进一步深刻揭示了药物小分子阻滞细胞周期的物理机制,可为设计确切的疗法药物提供必要的参考和新方案. 相似文献